CN104230109A - System and method for treating high-organic-matter-content high-ammonia-nitrogen wastewater by UASB/A/MBBR (upflow anaerobic sludge blanket/anoxic/moving bed biofilm reactor) combined chemical process - Google Patents

System and method for treating high-organic-matter-content high-ammonia-nitrogen wastewater by UASB/A/MBBR (upflow anaerobic sludge blanket/anoxic/moving bed biofilm reactor) combined chemical process Download PDF

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CN104230109A
CN104230109A CN201410489914.9A CN201410489914A CN104230109A CN 104230109 A CN104230109 A CN 104230109A CN 201410489914 A CN201410489914 A CN 201410489914A CN 104230109 A CN104230109 A CN 104230109A
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mbbr
reactor
water
uasb
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CN104230109B (en
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李相昆
孙豆豆
朱昆
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Harbin Institute of Technology Shenzhen
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Abstract

UASB/A/MBBR结合化学法处理高有机物高氨氮废水的系统和方法,本发明属于工业废水处理与再生领域,它为了解决现有处理高有机物、高氨氮废水的净化效果不理想的问题。本发明废水处理系统包括UASB反应器、缺氧池、MBBR反应器、沉淀池、中沉池和化学沉淀池,MBBR反应器后接缺氧池,缺氧池的出水一部分进入MBBR反应器,另一部分出水进入中沉池,中沉池沉淀的污泥再回流至MBBR反应器。本发明采用厌氧好氧相结合的处理方法,将MBBR厌氧生物处理设备置于工艺的前端,废水经厌氧处理后生化性提高,后续的好氧生物处理进一步去除水中的有机物,经本发明处理的废水中COD和氨氮去除率均能够达到95%以上。

A system and method for UASB/A/MBBR combined with chemical methods to treat wastewater with high organic matter and high ammonia nitrogen. The invention belongs to the field of industrial wastewater treatment and regeneration. It aims to solve the problem that the purification effect of wastewater with high organic matter and high ammonia nitrogen is not ideal. The waste water treatment system of the present invention comprises UASB reactor, anoxic tank, MBBR reactor, settling tank, medium settling tank and chemical settling tank, and MBBR reactor is connected with anoxic tank, and part of the effluent of anoxic tank enters MBBR reactor, and another Part of the effluent enters the intermediate sedimentation tank, and the sludge deposited in the intermediate sedimentation tank is returned to the MBBR reactor. The present invention adopts the combined anaerobic and aerobic treatment method, places the MBBR anaerobic biological treatment equipment at the front end of the process, the biochemical properties of the wastewater are improved after anaerobic treatment, and the subsequent aerobic biological treatment further removes organic matter in the water. The removal rate of COD and ammonia nitrogen in the wastewater treated by the invention can reach more than 95%.

Description

UASB/A/MBBR is in conjunction with the system and method for chemical Treatment height organism high ammonia-nitrogen wastewater
Technical field
The invention belongs to Industrial Wastewater Treatment and regeneration field, specifically for the low cost of high organism, high ammonia-nitrogen wastewater, high-level efficiency treatment system and processing method.
Background technology
Along with China's rapid development of economy, chemical industry and related industries are day by day prosperous, and high organism, high ammonia-nitrogen wastewater increase gradually, constitute serious threat to the health of the mankind.High organism, high ammonia-nitrogen wastewater are extensively present in food-processing industry, are characterized in complicated component, not only containing raw materials for production, also containing many side reaction products.Organic content is high, and wherein COD content is generally at more than 2000mg/L, and ammonia nitrogen concentration is at hundreds of milligrams per liter.A large amount of discharges of high organism, high ammonia-nitrogen wastewater, can cause receive water quality degenerate, water body blackout smelly, not only make water body lose use value, more have a strong impact on the eubiosis and human health.And some synthetic macromolecule organism are wherein difficult to be biodegradable, and easily accumulate in the environment, produce serious toxic action to biology.
Traditional biological treatment process or employing Anaerobic Microbiological Treatment Technology, or adopt easy-to-keep biological treatment technology.Although Anaerobic Microbiological Treatment Technology has the advantages such as energy consumption is low, sludge age is little, after anaerobic biological treatment, effluent quality is poor, and single anaerobic biological treatment effluent quality is difficult to reach emission standard.And anaerobic biodegradation speed is lower under cold condition, capacity of resisting impact load is low.The problems such as high organism, high ammonia-nitrogen wastewater, single aerobic treatment technology wants normal operation, must ensure normal organic loading and hydraulic load, and this will inevitably cause again structures volume large, and aeration rate is large, and sludge yield is many, and working cost is high.
Summary of the invention
The object of the invention is to solve the undesirable problem of the decontamination effect improving of system and method for the high organism of existing process, high ammonia-nitrogen wastewater, and provide UASB/A/MBBR in conjunction with the system and method for chemical Treatment height organism high ammonia-nitrogen wastewater.
UASB/A/MBBR of the present invention comprises UASB (upflow anaerobic sludge blanket process) reactor in conjunction with the system of chemical Treatment height organism high ammonia-nitrogen wastewater, anoxic pond (A), MBBR reactor (MBBR), settling tank, medium sediment pool and chemical precipitation pond, equalizing tank is communicated with the water-in being positioned at UASB reactor bottom by a water pipe, top in UASB reactor is provided with triphase separator, the water outlet being positioned at UASB reactor top is communicated with the first water-in of anoxic pond by No. two water pipes, the water outlet on anoxic pond top is connected to the water-in at medium sediment pool top by No. three water pipes, the water outlet of medium sediment pool is connected with the water-in in chemical precipitation pond, the water outlet in chemical precipitation pond is connected with the second water-in of MBBR reactor by No. six water pipes, one end of No. four water pipes communicates with No. three water pipes, the other end of No. four water pipes is communicated on the first water-in of MBBR reactor bottom, the water outlet on MBBR reactor top is communicated with the water-in at settling tank top by No. five water pipes, the water outlet being positioned at settling tank top is connected with rising pipe, one end of return line communicates with No. five water pipes, the other end of return line is connected on the second water-in of anoxic pond, the mud discharging mouth be positioned at bottom medium sediment pool is communicated with the mud inlet of MBBR reactor bottom by a shore pipe, the mud discharging mouth be positioned at bottom settling tank is connected with the mud inlet of anoxic pond by No. two shore pipes, excess sludge relief outlet is had in No. two shore pipes, spoil disposal passage is provided with bottom chemical precipitation pond, aerating apparatus is provided with in MBBR reactor.
UASB/A/MBBR of the present invention realizes according to the following steps in conjunction with the method for chemical Treatment height organism high ammonia-nitrogen wastewater:
One, the suspended substance in pre-treatment removal water and the waste water of floating matter enter equalizing tank;
Two, first the waste water flowed out from equalizing tank enter UASB reactor, and in UASB reactor, anerobe is degraded to organism, and the biogas simultaneously generated is discharged from UASB reactor;
Three, the waste water after UASB reactor for treatment enters anoxic pond with the nitrification liquid refluxed from MBBR reactor and after the returnedactivatedsludge that settling tank is discharged mixes, in anoxic pond, the organism after denitrifying bacterium utilizes UASB reactor for treatment in waste water carries out denitrification denitrogenation;
Four, a part of waste water flowed out from anoxic pond enters MBBR reactor, completes organic removal and nitrification by the microorganism of the suspension growth that exists in MBBR reactor and apposition growth;
Enter medium sediment pool from another part waste water of anoxic pond outflow and carry out mud-water separation, the precipitating sludge separated is back to MBBR reactor, and the supernatant liquor separated then enters chemical precipitation pond, in chemical precipitation pond, add MgCl 26H 2o and NaHPO 412H 2o also stirs, by the NH in waste water 4 +reaction generates magnesium ammonium phosphate sediment thing, and the supernatant liquor after staticly settling is back to MBBR reactor, precipitates the chemical sludge obtained and discharges;
Five, the waste water after MBBR reactor for treatment enters settling tank and carries out mud-water separation, the hydraulic detention time controlled in settling tank is 2h ~ 3h, isolated supernatant liquor is discharged as water purification, isolated a part of precipitating sludge is back to anoxic pond as returnedactivatedsludge, isolated another part precipitating sludge, as excess sludge discharge, completes the process of UASB/A/MBBR in conjunction with chemical Treatment height organism high ammonia-nitrogen wastewater.
The bioremediation that the present invention adopts anaerobic-aerobic to combine, anaerobic biological treatment is placed in the front end of technique, high organism, high ammonia-nitrogen wastewater are after anaerobic treatment, biodegradability improves, follow-up Aerobic biological process then can remove the organism in water further, play the object of deep purifying water quality, achieve the low-cost high-efficiency purifying treatment of high organism (COD2000 ~ 3000mg/L), high ammonia nitrogen (ammonia nitrogen 250 ~ 500mg/L) waste water.
Chemical precipitation method is coupling in biological treatment system, part high ammonia-nitrogen wastewater is processed, the influent ammonium concentration of MBBR reactor is reduced, solve high-concentration ammonia-nitrogen to the active suppression problem of nitrobacteria.
UASB/A/MBBR of the present invention comprises following advantage in conjunction with chemical Treatment height organism high ammonia-nitrogen wastewater:
1, anaerobism and aerobic combination technique is adopted.First, not easily biodegradable larger molecular organics can be degraded to biodegradable small organic molecule by anerobe, improves the biodegradability of waste water, and the biogas simultaneously producing calorific value higher is utilized as the energy.Aerobic system then then purifies water further, ensures effluent quality.
2, secondly, the biogas that anaerobic reactor produces can be used for the electric energy that the stirring in anoxic pond and chemical precipitation pond and Aerobic Pond aeration consume, and saves the energy consumption for the treatment of processes.
3, the employing of easy-to-keep biological treatment system MBBR reactor makes poky nitrobacteria can be retained in reactive system, improves the nitrification efficiency of system.
4, the organic waste water after anaerobic treatment contains easy degradation of small molecular organism, is easily utilized by denitrifying bacterium and carry out denitrogenation after entering anoxic pond.
5, a high-concentration ammonia nitrogenous wastewater part carries out chemical treatment removal ammonia nitrogen, enters MBBR reactor, reduces the ammonia nitrogen loading of system, ensure effluent quality through chemically treated waste water after mixing without chemically treated waste water.Also weaken the nitrobacteria activity inhibition of high-concentration ammonia-nitrogen to biological treatment system simultaneously.
6, the chemical sludge that chemical treating process produces processes further and can obtain available compound manure, achieves the recycling of being turned waste into wealth by ammonia nitrogen in sewage.
The part of contaminated water of 7, drawing from anoxic pond is introduced into medium sediment pool precipitation, and precipitating sludge is back to follow-up MBBR reactor, ensure that the microbial biomass of system, avoids the sludge loss in system.
8, oxygen-starved area is due to the existence of denitrification, makes its water outlet pH value near weakly alkaline, after chemical precipitation pond is placed in anoxic pond, meets the weak basic condition that chemical precipitation method removes ammonia nitrogen.
Accompanying drawing explanation
Fig. 1 is the operation logic figure of UASB/A/MBBR of the present invention in conjunction with the system of chemical Treatment height organism high ammonia-nitrogen wastewater, and the solid line wherein with arrow is the traffic direction of waste water, and the dotted line with arrow is the traffic direction of mud;
Fig. 2 is the COD removal effect figure of embodiment one UASB/A/MBBR in conjunction with chemical Treatment height organism high ammonia-nitrogen wastewater;
Fig. 3 is the ammonia nitrogen removal design sketch of embodiment one UASB/A/MBBR in conjunction with chemical Treatment height organism high ammonia-nitrogen wastewater.
Embodiment
Embodiment one: present embodiment UASB/A/MBBR comprises UASB reactor 2 in conjunction with the system of chemical Treatment height organism high ammonia-nitrogen wastewater, anoxic pond 3, MBBR reactor 4, settling tank 7, medium sediment pool 5 and chemical precipitation pond 6, equalizing tank 1 is communicated with the water-in be positioned at bottom UASB reactor 2 by a water pipe 11, top in UASB reactor 2 is provided with triphase separator 2-1, the water outlet being positioned at UASB reactor 2 top is communicated with the first water-in of anoxic pond 3 by No. two water pipes 12, the water outlet on anoxic pond 3 top is connected to the water-in at medium sediment pool 5 top by No. three water pipes 13, the water outlet of medium sediment pool 5 is connected with the water-in in chemical precipitation pond 6, the water outlet in chemical precipitation pond 6 is connected with the second water-in of MBBR reactor 4 by No. six water pipes 16, one end of No. four water pipes 14 communicates with No. three water pipes 13, the other end of No. four water pipes 14 is communicated on the first water-in bottom MBBR reactor 4, the water outlet on MBBR reactor 4 top is communicated by the water-in of No. five water pipes 15 with settling tank 7 top, the water outlet being positioned at settling tank 7 top is connected with rising pipe, one end of return line 17 communicates with No. five water pipes 15, the other end of return line 17 is connected on the second water-in of anoxic pond 3, the mud discharging mouth be positioned at bottom medium sediment pool 5 is communicated with the mud inlet bottom MBBR reactor 4 by a shore pipe 21, the mud discharging mouth be positioned at bottom settling tank 7 is connected with the mud inlet of anoxic pond 3 by No. two shore pipes 22, excess sludge relief outlet is had in No. two shore pipes 22, spoil disposal passage is provided with bottom chemical precipitation pond 6, aerating apparatus is provided with in MBBR reactor 4.
Biological wastewater treatment technology is a kind of method of wastewater treatment of economy, but the organic loading that biological processing unit can bear is limited.The ammonia nitrogen of high density can produce restraining effect to the activity of nitrobacteria.Adopt chemical precipitation method to combine with biological nitration in present embodiment and purifying treatment is carried out to ammonia nitrogen in high density, not only economy but also efficient.
Remove organism in water and ammonia nitrogen further by Aerobic biological process, serve the effect purified water further.Anaerobic biological treatment is organically combined with Aerobic biological process high organism, high ammonia-nitrogen wastewater are processed, give full play to respective advantage, achieve the low-cost high-efficiency purifying treatment of high organism, high ammonia-nitrogen wastewater.
Embodiment two: present embodiment and embodiment one are provided with whipping appts unlike in anoxic pond 3 and chemical precipitation pond 6.
Embodiment three: present embodiment and embodiment one or two are provided with nitrification liquid reflux pump unlike in return line 17, is provided with sludge reflux pump in a shore pipe 21 and No. two shore pipes 22.
Embodiment four: present embodiment UASB/A/MBBR implements according to the following steps in conjunction with the method for chemical Treatment height organism high ammonia-nitrogen wastewater:
One, the suspended substance in pre-treatment removal water and the waste water of floating matter enter equalizing tank 1;
Two, first the waste water flowed out from equalizing tank 1 enter UASB reactor 2, and in UASB reactor 2, anerobe is degraded to organism, and the biogas simultaneously generated is discharged from UASB reactor 2;
Three, the waste water after UASB reactor 2 processes enters anoxic pond 3 with the nitrification liquid refluxed from MBBR reactor 4 and after the returnedactivatedsludge that settling tank 7 is discharged mixes, in anoxic pond 3, denitrifying bacterium utilizes the organism in UASB reactor 2 processed waste water to carry out denitrification denitrogenation;
Four, a part of waste water flowed out from anoxic pond 3 enters MBBR reactor 4, completes organic removal and nitrification by the suspension growth of existence in MBBR reactor 4 and the microorganism of apposition growth;
Enter medium sediment pool 5 from another part waste water of anoxic pond 3 outflow and carry out mud-water separation, the precipitating sludge separated is back to MBBR reactor 4, and the supernatant liquor separated then enters chemical precipitation pond 6, in chemical precipitation pond 6, add MgCl 26H 2o and NaHPO 412H 2o also stirs, by the NH in waste water 4 +reaction generates magnesium ammonium phosphate sediment thing, and the supernatant liquor after staticly settling is back to MBBR reactor 4, precipitates the chemical sludge obtained and discharges;
Five, the waste water after MBBR reactor 4 processes enters settling tank 7 and carries out mud-water separation, the hydraulic detention time controlled in settling tank 7 is 2h ~ 3h, isolated supernatant liquor is discharged as water purification, isolated a part of precipitating sludge is back to anoxic pond 3 as returnedactivatedsludge, isolated another part precipitating sludge, as excess sludge discharge, completes the process of UASB/A/MBBR in conjunction with chemical Treatment height organism high ammonia-nitrogen wastewater.
Embodiment five: present embodiment and embodiment four are 4kgCOD/ (m unlike the volumetric loading of UASB reactor 2 in step 2 3d) ~ 5kgCOD/ (m 3d).Other step and parameter identical with embodiment four.
Embodiment six: present embodiment and embodiment four or five are 2h ~ 3h unlike hydraulic detention time in anoxic pond 3 in rate-determining steps three, and dissolved oxygen remains on below 0.5mg/L.Other step and parameter identical with embodiment four or five.
Embodiment seven: one of present embodiment and embodiment four to six are 6h ~ 7h unlike the hydraulic detention time of MBBR reactor 4 in rate-determining steps four, and dissolved oxygen is 2mg/L-4mg/L.Other step and parameter identical with one of embodiment four to six.
Embodiment eight: one of present embodiment and embodiment four to seven are 100% unlike return sludge ratio in step 5.Other step and parameter identical with one of embodiment four to seven.
Embodiment one: the method that the UASB/A/MBBR in the present embodiment application embodiment one carries out wastewater treatment in conjunction with chemical Treatment height organism high ammonia-nitrogen wastewater system is implemented according to the following steps:
One, the suspended substance in pre-treatment removal water and the waste water of floating matter enter equalizing tank 1;
Two, first the waste water flowed out from equalizing tank 1 enter UASB reactor 2, and in UASB reactor 2, anerobe is degraded to organism, and the biogas simultaneously generated is discharged from UASB reactor 2, and the volumetric loading of control UASB reactor 2 is 5kgCOD/ (m 3d);
Three, the waste water after UASB reactor 2 processes enters anoxic pond 3 with the nitrification liquid refluxed from MBBR reactor 4 and after the returnedactivatedsludge that settling tank 7 is discharged mixes, in anoxic pond 3, denitrifying bacterium utilizes the organism in UASB reactor 2 processed waste water to carry out denitrification denitrogenation, controlling hydraulic detention time in anoxic pond 3 is 3h, and dissolved oxygen is 0.5mg/L;
Four, a part of waste water flowed out from anoxic pond 3 enters MBBR reactor 4, organic removal and nitrification is completed by the suspension growth of existence in MBBR reactor 4 and the microorganism of apposition growth, the hydraulic detention time of control MBBR reactor is 7h, and dissolved oxygen is 3mg/L;
Enter medium sediment pool 5 from another part waste water of anoxic pond 3 outflow and carry out mud-water separation, the precipitating sludge separated is back to MBBR reactor 4, and the supernatant liquor separated then enters chemical precipitation pond 6, in chemical precipitation pond 6, add MgCl 26H 2o and NaHPO 412H 2o also carries out stirring 20min, by the NH in waste water 4 +reaction generates magnesium ammonium phosphate sediment thing, staticly settles the supernatant liquor after 25min and is back to MBBR reactor 4, precipitates the chemical sludge obtained and discharges;
Five, the waste water after MBBR reactor 4 processes enters settling tank 7 and carries out mud-water separation, the hydraulic detention time controlled in settling tank 7 is 3h, isolated supernatant liquor is discharged as water purification, isolated a part of precipitating sludge is back to anoxic pond 3 as returnedactivatedsludge, isolated another part precipitating sludge is as excess sludge discharge, return sludge ratio is 100%, completes the process of UASB/A/MBBR in conjunction with chemical Treatment height organism high ammonia-nitrogen wastewater.
The splitting ratio of anoxic pond water outlet in the present embodiment step 4 is 0.5, and namely anoxic pond water outlet enters medium sediment pool and carries out the flow of chemical denitrogenation and the ratio of water outlet total flux.
The present embodiment water inlet adopts and in sanitary sewage, adds glucose and ammonium chloride to simulate high organism high ammonia-nitrogen wastewater, regulate the COD of water inlet at 2250 ~ 2750mg/L, ammonia nitrogen is at 250 ~ 425mg/L, pH value is 6.7 ~ 7.4, monitor reactive system water outlet COD and ammonia nitrogen, after stable, UASB/A/MBBR reaches more than 95% and 97% in conjunction with chemical method respectively to the COD of high organism high ammonia-nitrogen wastewater and ammonia nitrogen removal frank.Can think and successfully realize UASB/A/MBBR in conjunction with chemical method to high organism high ammonia-nitrogen wastewater purifying treatment.

Claims (8)

1.UASB/A/MBBR结合化学法处理高有机物高氨氮废水的系统,其特征在于该UASB/A/MBBR结合化学法处理高有机物高氨氮废水的系统包括UASB反应器(2)、缺氧池(3)、MBBR反应器(4)、沉淀池(7)、中沉池(5)和化学沉淀池(6),调节池(1)通过一号水管(11)与位于UASB反应器(2)底部的进水口相通,在UASB反应器(2)内的上部安装有三相分离器(2-1),位于UASB反应器(2)上部的出水口通过二号水管(12)与缺氧池(3)的第一进水口相通,缺氧池(3)上部的出水口通过三号水管(13)连接到中沉池(5)顶部的进水口,中沉池(5)的出水口与化学沉淀池(6)的进水口相连,化学沉淀池(6)的出水口通过六号水管(16)与MBBR反应器(4)的第二进水口相连,四号水管(14)的一端与三号水管(13)相通,四号水管(14)的另一端连通到MBBR反应器(4)底部的第一进水口上,MBBR反应器(4)上部的出水口通过五号水管(15)与沉淀池(7)顶部的进水口相通,位于沉淀池(7)上部的出水口与出水管相连,回流管(17)的一端与五号水管(15)相通,回流管(17)的另一端连接到缺氧池(3)的第二进水口上,位于中沉池(5)底部的排泥口通过一号排泥管(21)与MBBR反应器(4)底部的进泥口相通,位于沉淀池(7)底部的排泥口通过二号排泥管(22)与缺氧池(3)的入泥口相连,在二号排泥管(22)中开有剩余污泥排出口,在化学沉淀池(6)底部设有排泥通道,在MBBR反应器(4)内设置有曝气装置。1. The system of UASB/A/MBBR combined with chemical method for treating wastewater with high organic matter and high ammonia nitrogen, characterized in that the system for treating wastewater with high organic matter and high ammonia nitrogen combined with UASB/A/MBBR with chemical method includes UASB reactor (2), anoxic pool (3), MBBR reactor (4), settling tank (7), medium settling tank (5) and chemical settling tank (6), regulating tank (1) is located in UASB reactor (2) through No. 1 water pipe (11) The water inlet at the bottom of the ) is connected, and a three-phase separator (2-1) is installed on the upper part of the UASB reactor (2), and the water outlet positioned at the top of the UASB reactor (2) passes through No. 2 water pipe (12) and the anoxic pool The first water inlet of (3) communicates, and the water outlet on the anoxic tank (3) top is connected to the water inlet on the top of the middle sedimentation tank (5) by No. 3 water pipes (13), and the water outlet of the middle sedimentation tank (5) is connected to The water inlet of chemical sedimentation tank (6) links to each other, and the water outlet of chemical sedimentation tank (6) links to each other with the second water inlet of MBBR reactor (4) by No. 6 water pipe (16), and one end of No. 4 water pipe (14) is connected with No. three water pipes (13) are connected, and the other end of No. four water pipes (14) is connected to the first water inlet at the bottom of the MBBR reactor (4), and the water outlet on the top of the MBBR reactor (4) passes through No. five water pipes (15) It communicates with the water inlet at the top of the sedimentation tank (7), the water outlet at the upper part of the sedimentation tank (7) is connected with the outlet pipe, one end of the return pipe (17) communicates with No. 5 water pipe (15), and the other end of the return pipe (17) One end is connected to the second water inlet of the anoxic tank (3), and the mud discharge port at the bottom of the intermediate sedimentation tank (5) communicates with the mud inlet at the bottom of the MBBR reactor (4) through No. 1 mud discharge pipe (21) , the sludge outlet located at the bottom of the sedimentation tank (7) is connected to the mud inlet of the anoxic tank (3) through the No. At the outlet, a sludge discharge channel is provided at the bottom of the chemical sedimentation tank (6), and an aeration device is provided in the MBBR reactor (4). 2.根据权利要求1所述的UASB/A/MBBR结合化学法处理高有机物高氨氮废水的系统,其特征在于在缺氧池(3)和化学沉淀池(6)中设置有搅拌装置。2. The system of UASB/A/MBBR combined with chemical method for treating wastewater with high organic matter and high ammonia nitrogen according to claim 1, characterized in that a stirring device is arranged in the anoxic tank (3) and the chemical sedimentation tank (6). 3.根据权利要求1所述的UASB/A/MBBR结合化学法处理高有机物高氨氮废水的系统,其特征在于在回流管(17)中设置有硝化液回流泵,在一号排泥管(21)和二号排泥管(22)中设置有污泥回流泵。3. UASB/A/MBBR according to claim 1 combines chemical method to process the system of high organic matter high ammonia nitrogen waste water, it is characterized in that in return pipe (17) be provided with nitrifying liquid backflow pump, in No. 1 sludge discharge pipe ( 21) and the No. 2 sludge discharge pipe (22) are provided with a sludge return pump. 4.UASB/A/MBBR结合化学法处理高有机物高氨氮废水的方法,其特征在于是按以下步骤实现:4. The method of UASB/A/MBBR combined with chemical method to treat high organic matter and high ammonia nitrogen wastewater is characterized in that it is realized according to the following steps: 一、经预处理去除水中的悬浮物和漂浮物的废水进入调节池(1);1. The wastewater that has been pretreated to remove suspended solids and floating solids in the water enters the regulating tank (1); 二、从调节池(1)流出的废水首先进入UASB反应器(2),在UASB反应器(2)内厌氧菌对有机物进行降解,同时生成的沼气从UASB反应器(2)排出;2. The wastewater flowing out from the regulating tank (1) first enters the UASB reactor (2), and the anaerobic bacteria in the UASB reactor (2) degrade the organic matter, and the generated biogas is discharged from the UASB reactor (2); 三、经UASB反应器(2)处理后的废水与从MBBR反应器(4)回流的硝化液以及从沉淀池(7)排出的回流活性污泥混合后进入缺氧池(3),在缺氧池(3)中,反硝化细菌利用UASB反应器(2)处理后废水中的有机物进行反硝化脱氮;3. After the waste water treated by the UASB reactor (2) is mixed with the nitrification liquid returned from the MBBR reactor (4) and the returned activated sludge discharged from the sedimentation tank (7), it enters the anoxic pool (3). In the oxygen pool (3), the denitrifying bacteria use the organic matter in the wastewater treated by the UASB reactor (2) to denitrify and denitrify; 四、从缺氧池(3)流出的一部分废水进入MBBR反应器(4),通过MBBR反应器(4)内存在的悬浮生长和附着生长的微生物完成有机物的去除和硝化作用;4. A part of the waste water flowing out from the anoxic pond (3) enters the MBBR reactor (4), and the removal and nitrification of organic matter are completed by the microorganisms of suspended growth and attached growth in the MBBR reactor (4); 从缺氧池(3)流出的另一部分废水进入中沉池(5)进行泥水分离,分离出来的沉淀污泥回流至MBBR反应器(4),而分离出来的上清液则进入化学沉淀池(6),向化学沉淀池(6)中投加MgCl2·6H2O和NaHPO4·12H2O并进行搅拌,将废水中的NH4 +反应生成磷酸铵镁沉淀物,静置沉淀后的上清液回流至MBBR反应器(4),沉淀得到的化学污泥排出;Another part of the wastewater flowing out from the anoxic tank (3) enters the intermediate sedimentation tank (5) for mud-water separation, and the separated sedimentation sludge is returned to the MBBR reactor (4), while the separated supernatant enters the chemical sedimentation tank (6), add MgCl 2 6H 2 O and NaHPO 4 12H 2 O to the chemical sedimentation tank (6) and stir, and react the NH 4 + in the waste water to generate ammonium magnesium phosphate precipitate, after static precipitation The supernatant is returned to the MBBR reactor (4), and the chemical sludge obtained by the precipitation is discharged; 五、经MBBR反应器(4)处理后的废水进入沉淀池(7)进行泥水分离,控制沉淀池(7)中的水力停留时间为2h~3h,分离出的上清液作为净水排出,分离出的一部分沉淀污泥作为回流活性污泥回流至缺氧池(3),分离出的另一部分沉淀污泥作为剩余污泥排放,完成UASB/A/MBBR结合化学法处理高有机物高氨氮废水的处理。5. The wastewater treated by the MBBR reactor (4) enters the sedimentation tank (7) for mud-water separation, and the hydraulic retention time in the sedimentation tank (7) is controlled to be 2h to 3h, and the separated supernatant is discharged as clean water. A part of the separated sedimentation sludge is returned to the anoxic tank (3) as return activated sludge, and another part of the separated sedimentation sludge is discharged as the remaining sludge to complete the UASB/A/MBBR combined chemical method to treat high-organic and high-ammonia-nitrogen wastewater processing. 5.根据权利要求4所述的UASB/A/MBBR结合化学法处理高有机物高氨氮废水的方法,其特征在于步骤二中UASB反应器(2)的容积负荷为4kgCOD/(m3·d)~5kgCOD/(m3·d)。5. UASB/A/MBBR according to claim 4 combines the method for processing high organic matter high ammonia nitrogen waste water with chemical method, it is characterized in that the volume load of UASB reactor (2) is 4kgCOD/(m 3 ·d) in step 2 ~5 kgCOD/(m 3 ·d). 6.根据权利要求4所述的UASB/A/MBBR结合化学法处理高有机物高氨氮废水的方法,其特征在于控制步骤三中缺氧池(3)中水力停留时间为2h~3h,溶解氧保持在0.5mg/L以下。6. UASB/A/MBBR according to claim 4 combines the method for chemically treating high-organic high-ammonia-nitrogen wastewater, characterized in that the hydraulic retention time in the anoxic pool (3) in the control step 3 is 2h~3h, dissolved oxygen Keep it below 0.5mg/L. 7.根据权利要求4所述的UASB/A/MBBR结合化学法处理高有机物高氨氮废水的方法,其特征在于控制步骤四中MBBR反应器(4)的水力停留时间为6h~7h,溶解氧为2mg/L~4mg/L。7. UASB/A/MBBR according to claim 4 combines the method for processing high-organic high-ammonia-nitrogen waste water with chemical method, it is characterized in that the hydraulic retention time of MBBR reactor (4) in the control step 4 is 6h~7h, dissolved oxygen It is 2mg/L~4mg/L. 8.根据权利要求4所述的UASB/A/MBBR结合化学法处理高有机物高氨氮废水的方法,其特征在于步骤五中污泥回流比为100%。8. The UASB/A/MBBR combined chemical method for treating waste water with high organic matter and high ammonia nitrogen according to claim 4, characterized in that the sludge reflux ratio in step 5 is 100%.
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