CN104193086B - The apparatus and method of a kind of villages and small towns collective and distributive type sewage fast processing - Google Patents

The apparatus and method of a kind of villages and small towns collective and distributive type sewage fast processing Download PDF

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CN104193086B
CN104193086B CN201410361263.5A CN201410361263A CN104193086B CN 104193086 B CN104193086 B CN 104193086B CN 201410361263 A CN201410361263 A CN 201410361263A CN 104193086 B CN104193086 B CN 104193086B
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sewage
water
packing
flow
aeration
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CN104193086A (en
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张列宇
王雷
席北斗
苏靖
李曹乐
李国文
余芃飞
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CNHOMELAND ENVIRONMENTAL PROTECTION Co Ltd
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CNHOMELAND ENVIRONMENTAL PROTECTION Co Ltd
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Abstract

A device for villages and small towns collective and distributive type sewage fast processing, comprising: two sections of grid makers, and the water outlet of this grid maker imports one-level surface turbulence screen apparatus, and the water outlet of one-level surface turbulence screen apparatus imports A 2/ O combined-flow flap soil oozes system, A 2the water outlet that/O combined-flow flap soil oozes system imports secondary surface turbulence screen apparatus, and the water outlet of secondary surface turbulence screen apparatus imports cyclone desanding device.The invention also discloses the method utilizing said apparatus to carry out villages and small towns collective and distributive type sewage fast processing.

Description

一种村镇集散型污水快速处理的装置和方法A device and method for rapid treatment of village and town collection and distribution sewage

技术领域technical field

本发明涉及一种村镇集散型污水快速处理的装置。The invention relates to a device for rapid treatment of collected and distributed sewage in villages and towns.

本发明还涉及利用上述装置进行污水处理的方法。The present invention also relates to a method for sewage treatment using the above-mentioned device.

背景技术Background technique

我国村镇水环境现状我国是农业大国,农村面积占全国土地总面积的57.59%,但由于种种原因对农村水污染的治理一直不够重视。污染防治投资几乎全部投到工业和城市,而农村环保设施几乎为零。近年来农村水环境状况越来越恶化,污染事故时有发生。其主要原因:乡镇企业排放的污染物造成水环境污染;农药、化肥的大量不合理使用造成面源污染;养殖场的废水排放对水环境造成污染;污水回灌导致水质恶化;居民生活污水和废弃物的随意排放对水环境造成污染。农村水环境的恶化不仅对粮食造成减产,而且直接威胁着居住在广大农村地区农民的身体健康。这已严重影响到广大农村的生态、生产和生活安全及经济的发展。Current situation of water environment in villages and towns in my country my country is a large agricultural country, and the rural area accounts for 57.59% of the total land area of the country. However, due to various reasons, the control of rural water pollution has not been paid enough attention. Pollution prevention and control investment is almost all invested in industry and cities, while rural environmental protection facilities are almost zero. In recent years, the situation of rural water environment has been deteriorating, and pollution accidents have occurred from time to time. The main reasons are: water environment pollution caused by pollutants discharged by township enterprises; non-point source pollution caused by a large number of unreasonable use of pesticides and chemical fertilizers; wastewater discharge from farms pollutes water environment; sewage recharge leads to water quality deterioration; domestic sewage and The random discharge of waste pollutes the water environment. The deterioration of rural water environment not only reduces grain production, but also directly threatens the health of farmers living in vast rural areas. This has seriously affected the ecology, production and life safety and economic development of vast rural areas.

村镇污水特征及处理要求:Village and town sewage characteristics and treatment requirements:

(1)村镇人口较少,分布广而且分散,污水水质、水量波动性大,排水管网很不健全,因此,所选污水处理工艺应抗冲击负荷能力强,且宜就近单独处理;(1) The population of villages and towns is small, the distribution is wide and scattered, the water quality and volume of sewage fluctuate greatly, and the drainage pipe network is very unsound. Therefore, the selected sewage treatment process should have strong impact load resistance and should be treated separately nearby;

(2)村镇经济力量薄弱,因此,污水处理应充分考虑造价低、运行费用少、低能耗或无能耗的工艺;(2) The economic power of villages and towns is weak, therefore, sewage treatment should fully consider the process of low construction cost, low operating cost, low energy consumption or no energy consumption;

(3)村镇缺乏污水处理专业人员,所选工艺应管理简单,维护方便。(3) Villages and towns lack sewage treatment professionals, and the selected process should be easy to manage and easy to maintain.

村镇污水处理模式在我国各地域发展不平衡,不同村镇差别较大,加之农村地区长期以来形成的居住方式、生活习惯等差异,应根据农村特定情况选择适合的处理方法,其特点应满足处理方法简单、建设费用低、操作简便等特征。The development of village and town sewage treatment models is unbalanced in various regions of my country, and the differences between different villages and towns are large. In addition, the differences in living styles and living habits have been formed in rural areas for a long time. Appropriate treatment methods should be selected according to the specific conditions in rural areas. Simple, low construction cost, easy operation and so on.

发明内容Contents of the invention

本发明的目的在于提供一种村镇集散型污水快速处理的装置。The purpose of the present invention is to provide a device for rapid treatment of village and town collection and distribution sewage.

本发明的又一目的在于提供一种利用上述装置对村镇集散型污水进行快速处理的方法。Another object of the present invention is to provide a method for rapidly treating village and town collecting and distributing sewage by using the above-mentioned device.

为实现上述目的,本发明提供的村镇集散型污水快速处理的装置,其包括:In order to achieve the above object, the device for rapid treatment of village and town collection and distribution sewage provided by the present invention includes:

两段格栅机,格栅机的框体内布设有粗筛网和细筛网两段筛网,经过格栅机处理的污水通过增压泵导入一级表层湍流筛滤装置内;Two-stage grill machine, the frame of the grill machine is equipped with a coarse screen and a fine screen, and the sewage treated by the grill machine is introduced into the first-level surface turbulence screening device through the booster pump;

一级表层湍流筛滤装置由多孔板分为上、下两个部分,多孔板孔洞呈倾斜状,多孔板上方铺设石英砂作为筛滤填料;筛滤填料的底部设有纳米曝气头,筛滤填料内表层通过缩口进水管与两段格栅机连接;The first-level surface turbulence screening device is divided into upper and lower parts by a porous plate. The inner surface of the filter packing is connected to the two-stage grill machine through the shrinkage inlet pipe;

一级表层湍流筛滤装置对应于缩口进水管的另一侧下方设有缩口反洗管,通过反冲洗阀门连接增压泵,缩口反洗管的上方设有回流槽;The first-level surface turbulence screening device is provided with a shrinkage backwash pipe under the other side corresponding to the shrinkage inlet pipe, and the booster pump is connected through the backwash valve, and a reflux tank is arranged above the shrinkage backwash pipe;

多孔板下方为储水箱,储水箱内壁均匀负载一层非金属掺杂光催化剂,储水箱底部安装有紫外灭菌灯,在紫外灭菌灯的空隙间设置纳米曝气头,储水箱内部剩余空间填充有半导体负载填料;Below the perforated plate is the water storage tank. The inner wall of the water storage tank is evenly loaded with a layer of non-metallic doped photocatalyst. The bottom of the water storage tank is equipped with an ultraviolet sterilization lamp. Filled with semiconductor loaded filler;

一级表层湍流筛滤装置的储水箱的出水口通过一液压泵与A2/O复合流折板土渗系统下半部分的上处理区相连,A2/O复合流折板土渗系统下半部分下处理区的出水导入A2/O复合流折板土渗系统上半部分的下处理区;The water outlet of the water storage tank of the first-level surface turbulence screening device is connected to the upper treatment area of the lower part of the A 2 /O composite flow baffle soil infiltration system through a hydraulic pump, and the lower part of the A 2 /O composite flow baffle soil infiltration system The effluent from the lower half of the treatment area is introduced into the lower treatment area of the upper half of the A 2 /O compound flow baffle soil infiltration system;

A2/O复合流折板土渗系统分为上半部分和下半部分,上半部分由折板形成上下两个处理区,上处理区使用鹅卵石对污水进行缺氧好氧处理以及出水导水,下处理区采用碎石以及粗砂混合而成的混合填料在好氧环境下对污水进行处理,污水流动方向为水平潜流;下半部分由折板形成上下两个处理区,上处理区采用碎石以及粗砂混合而成的混合填料在厌氧环境下对污水进行处理,污水流动方向为水平潜流,下处理区采用鹅卵石对污水进行厌氧处理以及出水导水,污水流动方向为垂直潜流;The A 2 /O composite flow baffle soil infiltration system is divided into an upper part and a lower part. The upper part is composed of folded slabs to form upper and lower treatment areas. Water, the lower treatment area uses a mixed filler made of gravel and coarse sand to treat sewage in an aerobic environment, and the direction of sewage flow is horizontal subsurface flow; The mixed packing made of crushed stone and coarse sand is used to treat the sewage in an anaerobic environment. The sewage flow direction is horizontal subsurface flow. The lower treatment area uses pebbles to treat the sewage anaerobically and guide the water outlet. The sewage flow direction is vertical. undercurrent;

A2/O复合流折板土渗系统的出水连接二级表层湍流筛滤装置;The outlet water of A 2 /O compound flow baffle soil infiltration system is connected to the secondary surface turbulence screening device;

二级表层湍流筛滤装置由多孔板分为上、下两个部分,多孔板孔洞呈倾斜状,多孔板上方铺设改性锰砂与天然沸石分子筛混合物作为筛滤填料;筛滤填料的底部设有纳米曝气头,筛滤填料内表层通过缩口进水管与A2/O复合流折板土渗系统的出水口连接;The secondary surface turbulence screening device is divided into upper and lower parts by a porous plate. The holes of the porous plate are inclined. The mixture of modified manganese sand and natural zeolite molecular sieve is laid on the porous plate as the sieve packing; the bottom of the sieve packing is set There is a nano-aeration head, and the inner surface of the filter packing is connected to the water outlet of the A 2 /O compound flow baffle soil infiltration system through the shrinkage water inlet pipe;

二级表层湍流筛滤装置对应于缩口进水管的另一侧下方设有缩口反洗管,通过反冲洗阀门连接增压泵,缩口反洗管的上方设有回流槽;The secondary surface turbulence screening device is provided with a shrinkage backwash pipe under the other side corresponding to the shrinkage inlet pipe, and the booster pump is connected through the backwash valve, and a return tank is arranged above the shrinkage backwash pipe;

多孔板下方为储水箱,储水箱内壁均匀负载一层非金属掺杂光催化剂,储水箱底部安装有紫外灭菌灯,在紫外灭菌灯的空隙间设置纳米曝气头,储水箱内部剩余空间填充有半导体负载填料;Below the perforated plate is the water storage tank. The inner wall of the water storage tank is evenly loaded with a layer of non-metallic doped photocatalyst. The bottom of the water storage tank is equipped with an ultraviolet sterilization lamp. Filled with semiconductor loaded filler;

二级表层湍流筛滤装置位于回流槽一侧设置有曝气管,曝气管设有多个细孔曝气孔,细孔曝气孔垂直向上;在筛滤填料上方安装有超声波发生仪;The secondary surface turbulence screening device is located on one side of the reflux tank and is equipped with an aeration tube. The aeration tube is equipped with multiple fine-pore aeration holes, and the fine-pore aeration holes are vertically upward; an ultrasonic generator is installed above the sieve packing;

二级表层湍流筛滤装置的储水箱的出水口通过液压泵连接旋流除砂装置,旋流除砂装置的上部分别连接至一级表层湍流筛滤装置的缩口反洗管和二级表层湍流筛滤装置的缩口反洗管;The water outlet of the water storage tank of the secondary surface turbulence screening device is connected to the cyclone desanding device through a hydraulic pump, and the upper part of the cyclone desanding device is connected to the shrinking backwash pipe of the primary surface turbulent screening device and the secondary surface desanding device respectively. Shrink backwash pipe of turbulent flow screening device;

旋流除砂装置的底部开设有排泥口,顶部设置有搅拌机的电机,搅拌机的叶轮向上倾斜,旋转时将使池中污水作螺旋运动,污水中的密度较大的砂粒被甩向旋流除砂装置的池壁,在重力作用下沉入砂斗。The bottom of the cyclone desanding device is provided with a mud outlet, and the top is equipped with a mixer motor. The impeller of the mixer is inclined upward. When rotating, the sewage in the pool will make a spiral movement, and the dense sand in the sewage will be thrown to the cyclone. The pool wall of the sand removal device sinks into the sand bucket under the action of gravity.

所述的装置中,两段格栅机中的粗筛网精度为21mm,细筛网精度为8mm;粗筛网和细筛网与水平呈60度夹角布设。In the device, the precision of the coarse screen in the two-stage grid machine is 21 mm, and the precision of the fine screen is 8 mm; the coarse screen and the fine screen are arranged at an angle of 60 degrees to the horizontal.

所述的装置中,一级表层湍流筛滤装置中的筛滤填料是粒径为7-30mm的大颗粒石英砂。In the device, the sieve filler in the primary surface turbulent sieve device is large-grained quartz sand with a particle size of 7-30mm.

所述的装置中,二级表层湍流筛滤装置中的筛滤填料是粒径为0.5-1.0mm的改性锰砂与粒径为1.2-2.0mm的天然沸石分子筛混合物。In the device, the sieving filler in the secondary surface turbulent sieving device is a mixture of modified manganese sand with a particle size of 0.5-1.0 mm and natural zeolite molecular sieves with a particle size of 1.2-2.0 mm.

所述的装置中,储水箱内壁均匀负载的非金属掺杂光催化剂为纳米TiO2粉体。In the device, the non-metal doped photocatalyst uniformly loaded on the inner wall of the water storage tank is nano TiO 2 powder.

所述的装置中,储水箱内部剩余空间填充的半导体负载填料为纳米TiO2粉体负载在立体网状聚丙烯形成的填料。In the device, the semiconductor-loaded filler filled in the remaining space inside the water storage tank is the filler formed by nano- TiO2 powder loaded on three-dimensional network polypropylene.

所述的装置中,一级表层湍流筛滤装置和二级表层湍流筛滤装置中的纳米曝气头均分别各自连接纳米曝气机。In the device, the nano-aeration heads in the first-level surface turbulent filtering device and the second-level surface turbulent filtering device are respectively connected to nano-aerators.

所述的装置中,旋流除砂装置中的搅拌机转速为10-30r/min。In the described device, the rotational speed of the agitator in the cyclone desanding device is 10-30r/min.

本发明提供的利用上述装置进行村镇集散型污水快速处理的方法:The method provided by the present invention utilizes the above-mentioned device to carry out the method for rapid treatment of village and town collecting and distributing sewage:

污水在重力作用下通过两段筛网拦截液体中的固态颗粒,并连续清除流体中的杂物,由埋在筛滤填料表层的进水管导入一级表层湍流筛滤装置内进行筛滤,进水过程中利用进水错流的冲击力扰动筛滤填料表层,形成湍流,防止污染物质在筛滤填料表层堆积对水流的顺利通过形成阻力;Under the action of gravity, the sewage passes through the two-stage screen to intercept the solid particles in the liquid, and continuously removes the impurities in the fluid. The water inlet pipe buried in the surface layer of the filter packing is introduced into the first-level surface turbulent filter device for sieving. During the water process, the impact force of the cross-flow of the incoming water is used to disturb the surface of the sieve packing to form turbulence and prevent the accumulation of pollutants on the surface of the sieve packing to form resistance to the smooth passage of water flow;

一级表层湍流筛滤装置进行间歇曝气,曝气时的气泡冲击筛滤填料,打散筛滤填料表面的污染物质层并使其浮起,使得污水能顺利经过筛滤填料过滤;The first-level surface turbulent sieving device performs intermittent aeration, and the air bubbles impact the sieve packing during aeration, breaking up the pollutant layer on the surface of the sieve packing and making it float, so that the sewage can pass through the sieve packing smoothly;

经过一级表层湍流筛滤装置处理的污水从下半部分的上处理区进入A2/O复合流折板土渗系统后,由A2/O复合流折板土渗系统的下半部分中的上处理区使用混合填料在厌氧环境下对污水进行处理,污水流动方向为水平潜流,下处理区采用鹅卵石对污水进行厌氧处理以及出水导水,污水流动方向为垂直潜流;出水导入上半部分中的下处理区采用混合填料在好氧环境下对污水进行处理,污水流动方向为水平潜流,上处理区使用鹅卵石对污水进行缺氧好氧处理以及出水导水;After the sewage treated by the first-level surface turbulence screening device enters the A 2 /O composite flow baffle soil infiltration system from the upper treatment area of the lower half, it is passed through the lower half of the A 2 /O composite flow baffle soil infiltration system. The upper treatment area uses mixed fillers to treat sewage in an anaerobic environment. The direction of sewage flow is horizontal subsurface flow. The lower treatment area uses pebbles to treat sewage anaerobically and conduct water discharge. The direction of sewage flow is vertical subsurface flow; The lower treatment area in the half part uses mixed fillers to treat sewage in an aerobic environment, and the sewage flow direction is horizontal subsurface flow, and the upper treatment area uses pebbles to treat sewage with anoxic aerobic conditions and guide water out;

自A2/O复合流折板土渗系统下部进入的污水经过水平潜流-垂直导水进行初步处理,通过使用折板延长缺氧-厌氧部分,将污水内难降解物质大量分解,并将出水导入A2/O复合流折板土渗系统上部潜流折板上行池,进行缺氧-好氧处理,在微生物-填料-植物的协同作用下对污水进行处理,分解其中的易降解有机物,并去除其他污染物质;The sewage entering from the lower part of the A 2 /O composite flow baffle soil infiltration system is initially treated through horizontal underflow-vertical water diversion. By using the baffle to extend the anoxic-anaerobic part, a large amount of refractory substances in the sewage are decomposed, and the The effluent is introduced into the upper tank of the A 2 /O composite flow baffle soil infiltration system, and the anoxic-aerobic treatment is carried out. The sewage is treated under the synergy of microorganisms, fillers and plants, and the easily degradable organic matter in it is decomposed. and remove other pollutants;

经A2/O复合流折板土渗系统处理的污水由埋在筛滤填料表层的进水管导入二级表层湍流筛滤装置内进行筛滤,进水过程中利用进水错流的冲击力扰动筛滤填料表层,形成湍流,防止污染物质在筛滤填料表层堆积对水流的顺利通过形成阻力;The sewage treated by the A 2 /O compound flow baffle soil infiltration system is introduced into the second-level surface turbulent flow screening device through the water inlet pipe buried in the surface layer of the filter packing for sieving, and the impact force of the cross-flow of the incoming water is used in the process of water inflow Disturb the surface of the filter packing to form turbulent flow and prevent the accumulation of pollutants on the surface of the filter packing to form resistance to the smooth passage of water flow;

二级表层湍流筛滤装置进行间歇曝气,曝气时的气泡冲击筛滤填料,打散筛滤填料表面的污染物质层并使其浮起,使得污水能顺利经过筛滤填料过滤;填料上方右端设置有曝气管,曝气管设有多个细孔曝气孔,曝气孔垂直向上,气泡将浮起的污染物推至水面,溢流至回流槽,与进水混合调节进水水质,同时延长筛滤装置使用寿命及反洗周期;The secondary surface turbulent sieving device performs intermittent aeration, and the air bubbles impact the sieve packing during aeration, breaking up the pollutant layer on the surface of the sieve packing and making it float, so that the sewage can pass through the sieve packing smoothly; above the packing The right end is provided with an aeration tube, and the aeration tube is equipped with a plurality of fine aeration holes, and the aeration holes are vertically upward, and the air bubbles push the floating pollutants to the water surface, overflow to the return tank, and mix with the incoming water to adjust the incoming water Water quality, while prolonging the service life of the filter device and the backwash cycle;

一级表层湍流筛滤装置和二级表层湍流筛滤装置底部的纳米曝气头进气为O2,用于清洁填料;储水箱内纳米曝气头的进气为O3,通过纳米曝气大量获得羟基自由基,与紫外灭菌灯、半导体负载填料共同提高氧化效果,同时其中富含羟自由基的出水在装置进行反洗时,冲刷筛滤填料,使筛滤填料得到清洁与再生;The air intake of the nano-aeration head at the bottom of the first-level surface turbulence screening device and the second-level surface turbulence screening device is O 2 , which is used to clean the packing; the intake air of the nano-aeration head in the water storage tank is O 3 , through nano-aeration A large number of hydroxyl radicals are obtained, and the oxidation effect is improved together with the ultraviolet sterilizing lamp and the semiconductor-loaded filler. At the same time, the effluent rich in hydroxyl radicals flushes the sieve packing when the device is backwashed, so that the sieve packing is cleaned and regenerated;

二级表层湍流筛滤装置的出水导入旋流除砂装置,去除污水中的砂粒,污水经上述处理后达标排放;The effluent from the secondary surface turbulence screening device is introduced into the cyclone desanding device to remove the sand particles in the sewage, and the sewage is discharged up to the standard after the above treatment;

二级表层湍流筛滤装置的出水同时回流至A2/O复合流折板土渗系统进水,调节水质并刺激植物生长过程分泌次生物质。The effluent from the secondary surface turbulence screening device is simultaneously returned to the A 2 /O composite flow baffle soil infiltration system to regulate water quality and stimulate the secretion of secondary substances during plant growth.

所述的方法中,一级表层湍流筛滤装置和二级表层湍流筛滤装置中的紫外灭菌灯平均照射剂量在300J/m2以上。In the method, the average irradiation dose of ultraviolet germicidal lamps in the first-level surface turbulent sieving device and the second-level surface turbulent sieving device is above 300 J/m 2 .

本发明使用格栅机过滤污水中的大型漂浮物,随后使用表层湍流筛滤装置降低污水内悬浮物及胶体,以降低后续土渗系统的水力负荷,降低系统堵塞的风险系数,再使用表层湍流筛滤装置对污水进行深度处理,降低污水浊度,提高其透明度,使污水达到国家排放标准。本发明的工艺操作简单、效果明显,基建费用低、运行简单、易操作、可避免处理过程中二次污染的产生,提升污水出水水质并对可回收资源再利用。其中表层湍流筛滤装置中纳米二氧化钛晶体作为光触媒在紫外灯照射下激发极具氧化力的自由负离子,同时在纳米曝气过程中以及超声波发生过程激发的能量亦可发生并加强自由负离子的产生,达成光催化效果;而自由负离子以及其摆脱共价键的束缚后留下空位,与纳米气泡表面带有的电荷同时产生微电解效果,可灭杀大肠杆菌、金黄色葡萄球菌、病毒等,分解残留难降解有机化合物及有毒物质,持久安全的对污水进行消毒降解。针对环境类激素(如激素类农药、抗生素、二恶英、雌激素以及人工合成激素等微量有害化学物质)的处理方面具有很大的优势,能够使绝大部分有机物完全矿化或分解,对污水进行筛滤处理的同时对其出水净化、消毒,出水较好的达到国家要求标准。The present invention uses a grid machine to filter large floating objects in sewage, and then uses a surface turbulent flow screening device to reduce suspended matter and colloids in the sewage, so as to reduce the hydraulic load of the subsequent soil infiltration system and reduce the risk factor of system blockage, and then use the surface turbulent flow The screening device performs advanced treatment on the sewage, reduces the turbidity of the sewage, improves its transparency, and makes the sewage meet the national discharge standard. The process of the invention is simple in operation, obvious in effect, low in capital construction cost, simple in operation, easy to operate, can avoid secondary pollution in the process of treatment, improves the quality of sewage effluent and reuses recyclable resources. Among them, the nano-titanium dioxide crystals in the surface turbulent sieving device are used as photocatalysts to excite highly oxidative free negative ions under the irradiation of ultraviolet lamps. At the same time, the energy excited during the nano-aeration process and the ultrasonic generation process can also occur and strengthen the production of free negative ions. Achieve photocatalytic effect; free negative ions and their vacancies after getting rid of the bondage of covalent bonds, and the charge on the surface of nanobubbles produce micro-electrolysis effect at the same time, which can kill Escherichia coli, Staphylococcus aureus, viruses, etc., and decompose Residual refractory organic compounds and toxic substances are used to disinfect and degrade sewage in a durable and safe manner. It has great advantages in the treatment of environmental hormones (such as hormone pesticides, antibiotics, dioxins, estrogens, and artificial synthetic hormones and other trace harmful chemicals), which can completely mineralize or decompose most of the organic matter. While the sewage is screened and treated, the effluent is purified and disinfected, and the effluent better meets the national requirements.

附图说明Description of drawings

图1是本发明的村镇集散型污水快速处理的装置结构示意图。Fig. 1 is a schematic structural diagram of a device for rapid treatment of village and town collection and distribution sewage according to the present invention.

附图中主要组件符号说明:Explanation of main component symbols in the attached drawings:

1粗筛网;2两段格栅机;3细筛网;4增压泵;5缩口进水管;6筛滤填料;7一级表层湍流筛滤装置;8二级表层湍流筛滤装置;9缩口反洗管;10反洗阀门;11植物系统;12鹅卵石;13折板;14混合填料;15A2/O复合流折板土渗系统;16电机;17旋流除砂装置;18叶轮;19液压泵;20出水阀门;21紫外灭菌灯;22多孔板;23纳米曝气头;24半导体负载填料;25储水箱;26纳米曝气机;27超声波发生仪;28曝气管;29回流槽。1 Coarse screen; 2 Two-stage grille machine; 3 Fine screen; 4 Booster pump; ;9 Shrink backwash pipe; 10 Backwash valve; 11 Plant system; 12 Cobblestone; 13 Folded plate; 18 impeller; 19 hydraulic pump; 20 water outlet valve; 21 ultraviolet sterilizing lamp; 22 porous plate; 23 nano aeration head; 24 semiconductor loaded packing; 25 water storage tank; Tube; 29 reflux tanks.

具体实施方式detailed description

以下结合附图对本发明作详细描述。需要说明的是,在以下叙述中提到的左、右、上、下等均是以附图所示的方向为准。The present invention will be described in detail below in conjunction with the accompanying drawings. It should be noted that the left, right, up, down, etc. mentioned in the following descriptions are all based on the directions shown in the drawings.

请参阅图1。See Figure 1.

本发明提供的村镇集散型污水快速处理的装置,其主要结构包括:The device for rapid treatment of village and town collection and distribution sewage provided by the present invention, its main structure includes:

两段格栅机2,格栅机2的框体内布设有粗筛网1(如精度为21mm)和细筛网3(如精度为8mm)两段筛网,粗筛网1和细筛网3在框体与水平呈60度夹角布设,污水在重力作用下通过粗、细两段筛网,拦截液体中的固态颗粒,并连续清除流体中杂物的固液分离设备;经过格栅机2处理的污水通过增压泵4导入一级表层湍流筛滤装置内7。Two-stage grid machine 2, the frame of the grid machine 2 is equipped with a coarse screen 1 (for example, the precision is 21mm) and a fine screen 3 (for example, the precision is 8mm) two-stage screen, the coarse screen 1 and the fine screen 3. It is arranged at an angle of 60 degrees between the frame and the horizontal. Under the action of gravity, the sewage passes through the coarse and fine two-stage screens to intercept the solid particles in the liquid and continuously remove the impurities in the fluid. Solid-liquid separation equipment; The sewage treated by the machine 2 is introduced into the first-level surface turbulence screening device 7 through the booster pump 4 .

一级表层湍流筛滤装置7由多孔板22分为上、下两个部分。多孔板22孔洞呈倾斜状,多孔板22上方铺设一层筛滤填料6,筛滤填料6是粒径为7-30mm的大颗粒石英砂。筛滤填料6的底部设有纳米曝气头23,筛滤填料6内表层通过缩口进水管5与两段格栅机2连接。一级表层湍流筛滤装置7对应于缩口进水管5的另一侧下方设有缩口反洗管9,通过反冲洗阀门10连接增压泵4。多孔板22下方为储水箱25,储水箱25内壁均匀负载一层非金属掺杂光催化剂(如纳米TiO2粉体),储水箱25底部安装有紫外灭菌灯21,在紫外灭菌灯21的空隙间设置纳米曝气头23,储水箱25内部剩余空间填充有半导体负载填料24(如纳米TiO2粉体负载在立体网状聚丙烯填料),本发明将半导体负载填料24固定在载体上,解决了常规光催化剂需要分散剂协同使用的弊端,减少了催化剂的流失现象,避免了反应结束后催化剂的分离步骤。The primary surface turbulence screening device 7 is divided into upper and lower parts by a perforated plate 22 . The holes of the perforated plate 22 are inclined, and a layer of sieve packing 6 is laid on the top of the perforated plate 22. The sieve packing 6 is large-grained quartz sand with a particle size of 7-30 mm. The bottom of the sieve packing 6 is provided with a nano aeration head 23 , and the inner surface of the sieve packing 6 is connected to the two-stage grill machine 2 through the shrinkage inlet pipe 5 . The first-level surface turbulence screening device 7 is provided with a shrinkage backwash pipe 9 under the other side corresponding to the shrinkage inlet pipe 5 , and is connected to the booster pump 4 through a backwash valve 10 . The bottom of the perforated plate 22 is a water storage tank 25, and the inner wall of the water storage tank 25 is evenly loaded with a layer of non-metal doped photocatalyst (such as nano-TiO 2 powder). Nano-aeration heads 23 are set between the gaps, and the remaining space inside the water storage tank 25 is filled with semiconductor-loaded fillers 24 (such as nano- TiO2 powder loaded on three-dimensional network polypropylene fillers), and the present invention fixes the semiconductor-loaded fillers 24 on the carrier , which solves the disadvantages of conventional photocatalysts that require the coordinated use of dispersants, reduces the loss of catalysts, and avoids the separation of catalysts after the reaction.

一级表层湍流筛滤装置7的储水箱25的出水口通过一液压泵19与A2/O复合流折板土渗系统15相连。The water outlet of the water storage tank 25 of the primary surface turbulence screening device 7 is connected to the A 2 /O compound flow baffle soil infiltration system 15 through a hydraulic pump 19 .

A2/O复合流折板土渗系统15分为上下两个部分,上半部分由折板13分成上下两个处理区A和B,上处理区A使用鹅卵石对污水进行缺氧好氧处理以及出水导水,下处理区B采用碎石以及粗砂混合而成的混合填料14在好氧环境下对污水进行处理,污水流动方向为水平潜流;下半部分同样由折板13分成上下两个处理区,上处理区C采用碎石以及粗砂混合而成的混合填料在厌氧环境下对污水进行处理,污水流动方向为水平潜流,下处理区D采用鹅卵石对污水进行厌氧处理以及出水导水,污水流动方向为垂直潜流。The A 2 /O compound flow baffle soil infiltration system 15 is divided into upper and lower parts, the upper part is divided into upper and lower treatment areas A and B by the baffle plate 13, and the upper treatment area A uses pebbles to treat sewage with anoxic and aerobic conditions As well as the outlet water guide, the lower treatment area B adopts the mixed filler 14 mixed with crushed stone and coarse sand to treat the sewage in an aerobic environment, and the sewage flow direction is horizontal subsurface flow; In the upper treatment area C, the mixed filler made of gravel and coarse sand is used to treat the sewage in an anaerobic environment, and the sewage flow direction is horizontal subsurface flow; the lower treatment area D uses pebbles to treat the sewage anaerobically and The outlet water guides water, and the direction of sewage flow is vertical subsurface flow.

污水自下部顶端进水,经过水平潜流-垂直导水进行初步处理,处理过程中合理使用折板,延长系统内缺氧-厌氧部分,将污水内难降解物质大量分解,通过增压泵将其出水导入上部潜流折板上行池,进行缺氧-好氧处理,在微生物-填料-植物的协同作用下对污水进行处理,分解其中的易降解有机物,并去除其他污染物质。Sewage enters the water from the top of the lower part, and undergoes preliminary treatment through horizontal submerged flow and vertical water diversion. During the treatment process, folding plates are used reasonably to extend the anoxic-anaerobic part of the system, and a large amount of refractory substances in the sewage are decomposed. The effluent is introduced into the upper submerged flow plate ascending tank for anoxic-aerobic treatment, and the sewage is treated under the synergistic effect of microorganisms-fillers-plants, decomposing easily degradable organic matter and removing other pollutants.

A2/O复合流折板土渗系统15连接二级表层湍流筛滤装置8,二级表层湍流筛滤装置8与一级表层湍流筛滤装置7的结构、工作原理基本相同。不同之处是在二级表层湍流筛滤装置8的筛滤填料6是粒径为0.5-1.0mm的改性锰砂与粒径为1.2-2.0mm的天然沸石分子筛混合物,是集吸附、离子交换、混凝及去除重金属为一体的多功能混合填料。同时在筛滤填料6的上方位于回流槽29一侧设置有曝气管28,曝气管28设有多个细孔曝气孔,细孔曝气孔垂直向上;在筛滤填料6上方安装有超声波发生仪27。二级表层湍流筛滤装置8的储水箱25的出水口通过液压泵19连接旋流除砂装置17,旋流除砂装置17的底部开设有排泥口(公知技术,图中未示),顶部设置有搅拌机的电机16,搅拌机的叶轮18向上倾斜,旋转时将使池中污水作螺旋运动(搅拌机转速可以控制在10-30r/min)。污水中的砂粒由于所受离心力不同,相对密度较大的砂粒被甩向旋流除砂装置17的池壁,在重力作用下沉入砂斗。旋流除砂装置17的上部分别连接至一级表层湍流筛滤装置7的缩口反洗管9和二级表层湍流筛滤装置8的缩口反洗管9。The A 2 /O composite flow baffle soil infiltration system 15 is connected to the secondary surface turbulent screening device 8 , the structure and working principle of the secondary surface turbulent screening device 8 is basically the same as that of the primary surface turbulent screening device 7 . The difference is that the sieve filler 6 in the secondary surface turbulence sieving device 8 is a mixture of modified manganese sand with a particle size of 0.5-1.0mm and a natural zeolite molecular sieve with a particle size of 1.2-2.0mm, which is a collection of adsorption, ion A multi-functional mixed filler that exchanges, coagulates and removes heavy metals. At the same time, an aeration pipe 28 is arranged on one side of the reflux tank 29 above the sieve packing 6, and the aeration pipe 28 is provided with a plurality of fine-pore aeration holes, and the fine-pore aeration holes are vertically upward; Ultrasonic generator 27 is arranged. The water outlet of the water storage tank 25 of the secondary surface turbulence screening device 8 is connected to the cyclone desandering device 17 through the hydraulic pump 19, and the bottom of the cyclone desandering device 17 is provided with a mud discharge port (known technology, not shown in the figure), The top is provided with the motor 16 of the agitator, and the impeller 18 of the agitator is inclined upwards, which will make the sewage in the pool do a spiral motion (the rotational speed of the agitator can be controlled at 10-30r/min) during rotation. The sand particles in the sewage are due to different centrifugal forces, and the sand particles with relatively high density are thrown to the pool wall of the cyclone sand removal device 17, and sink into the sand bucket under the action of gravity. The upper part of the cyclone desanding device 17 is respectively connected to the necking backwash pipe 9 of the first-level surface turbulence screening device 7 and the necking backwash pipe 9 of the second-level surface turbulence screening device 8 .

一级表层湍流筛滤装置7和二级表层湍流筛滤装置8在进行筛滤时,储水池内纳米曝气间歇曝气,曝气时储水池内气压增大,空气被多孔板切割成为气泡鼓起,冲击筛滤填料,打散填料表面的污染物质层并使其浮起,使得污水能顺利经过筛滤填料过滤;填料上方右端设置有曝气管,曝气管设有多个细孔曝气孔,曝气孔垂直向上,气泡将浮起的污染物推至水面,于右侧溢流至回流槽,与进水混合调节进水水质,同时延长筛滤装置使用寿命及反洗周期,对于进水浊度较低的情况,甚至可以无需反冲洗,不断运行净化污水。When the primary surface turbulent screening device 7 and the secondary surface turbulent screening device 8 perform screening, the nano-aeration in the storage tank is intermittently aerated, and the air pressure in the storage tank increases during aeration, and the air is cut into air bubbles by the porous plate Bulge, impact the sieve packing, break up the pollutant layer on the surface of the packing and make it float, so that the sewage can pass through the sieving packing smoothly; there is an aeration tube at the right end above the packing, and the aeration tube is equipped with multiple fine holes The aeration hole, the aeration hole is vertically upward, the air bubbles push the floating pollutants to the water surface, overflow to the return tank on the right side, mix with the influent water to adjust the influent water quality, and prolong the service life of the screening device and the backwashing cycle , For the case of low influent turbidity, even without backwashing, it can continue to purify sewage.

一级表层湍流筛滤装置7和二级表层湍流筛滤装置8中的筛滤填料底部纳米曝气头进气为O2,用于清洁填料;储水箱内纳米曝气头的进气为O3,通过纳米曝气大量获得羟基自由基,与紫外灭菌灯和半导体负载填料共同提高高级氧化效果,同时其中富含羟自由基的出水在装置进行反洗时,冲刷筛滤填料,较好的做到填料清洁与再生。紫外灭菌灯平均照射剂量在300J/m2以上。The air intake of the nano-aeration head at the bottom of the filter packing in the first-level surface turbulence screening device 7 and the second-level surface turbulence screening device 8 is O 2 for cleaning the packing; the air intake of the nano-aeration head in the water storage tank is O 3. A large number of hydroxyl radicals can be obtained through nano-aeration, which can improve the advanced oxidation effect together with the ultraviolet sterilizing lamp and semiconductor-loaded fillers. At the same time, the effluent rich in hydroxyl radicals can wash the sieve fillers when the device is backwashed, which is better It is best to clean and regenerate the packing. The average irradiation dose of ultraviolet germicidal lamp is above 300J/m 2 .

使用纳米曝气的方式提高-OH产生率,由于微气泡具有庞大的数量、比表面积、缓慢的上升速度,大大增加了气液接触面积、接触时间,有利于臭氧溶于水中,克服了臭氧难溶于水的缺点。微气泡内部具有较大的压力且纳米气泡破裂时界面消失,周围环境剧烈改变产生的化学能促使产生更多的羟基自由基,增强臭氧氧化分解有机物的能力。Use nano-aeration to increase the production rate of - OH. Due to the large number of microbubbles, specific surface area, and slow rising speed, the gas-liquid contact area and contact time are greatly increased, which is conducive to the dissolution of ozone in water and overcomes the difficulty of ozone The disadvantage of being soluble in water. The inside of the microbubbles has a large pressure and the interface disappears when the nanobubbles are broken. The chemical energy generated by the drastic changes in the surrounding environment promotes the generation of more hydroxyl radicals, which enhances the ability of ozone to oxidize and decompose organic matter.

臭氧在紫外光的照射作用下产生·OH,臭氧能带走二氧化钛光致电子空穴对中的电子,从而产生了更多的羟基自由基,加速了有机物的降解,通过·OH的强氧化作用对有机污染物进行处理。Ozone produces OH under the irradiation of ultraviolet light. Ozone can take away the electrons in the photoinduced electron-hole pairs of titanium dioxide, thereby generating more hydroxyl radicals and accelerating the degradation of organic matter. Through the strong oxidation of OH Treat organic pollutants.

两段格栅机的右端通过增压泵4,在一级表层湍流筛滤装置工作时导入格栅机出水,缩口进水管5埋在筛滤填料6表层,进水过程中利用进水错流的冲击力扰动筛滤填料表层,形成湍流,防止由于污染物质在筛滤填料表层堆积而对水流的顺利通过形成阻力。二级表层湍流筛滤装置工作时,导入A2/O复合流折板土渗系统15的进水,形成与在一级表层湍流筛滤装置工作时的状态。The right end of the two-stage grill machine passes through the booster pump 4, and when the first-level surface turbulence screening device is working, it is introduced into the grill machine to discharge water, and the shrinkage inlet pipe 5 is buried in the surface layer of the screen packing 6. The impact force of the flow disturbs the surface of the sieve packing to form a turbulent flow, preventing the accumulation of pollutants on the surface of the sieve packing and forming resistance to the smooth passage of the water flow. When the secondary surface turbulent sieve device is working, the water inflow into the A 2 /O composite flow baffle soil infiltration system 15 is formed to be in the same state as that of the primary surface turbulent sieve device.

由于一、二级表层湍流筛滤装置内的曝气头均连接一纳米曝气机,在一、二级表层湍流筛滤装置进行反冲洗时,纳米曝气头开始曝气,在高温纳米曝气的情况下对砂粒进行纳米曝气处理,在高温、纳米微小泡的剪切力以及曝气过程中产生的冲击力的作用下,清洗填料截流的杂质、胶体以及表面生长的生物膜。同时通过增压泵导入旋流除砂装置的出水进行反冲洗,缩口反洗管对筛滤填料施加一个向左的方向力,而储水箱在充水过程中,液面上的空气被强力挤压,通过多孔板上升至筛滤填料层,使筛滤填料呈现沸腾流动状态,储水箱内空气排空后,水流继续通过多孔板孔洞右倾斜向上高速流动,同时整个反冲洗过程中缩口反洗管内水流向左冲洗,整个筛滤填料在水流的冲击力下形成快速运转的湍流,筛滤填料在不同方向力作用下形成的逆时针小旋涡中相互摩擦,附着的有机污染物得以去除,有利于取得较为纯净的填料。Since the aeration heads in the primary and secondary surface turbulent screening devices are connected to a nano aerator, when the primary and secondary surface turbulent screening devices are backwashed, the nano aerator starts to aerate. Under the condition of air, the sand particles are subjected to nano-aeration treatment. Under the action of high temperature, the shear force of nano-microbubbles and the impact force generated during the aeration process, the impurities, colloids and biofilms that are intercepted by the filler are cleaned. At the same time, the outlet water from the cyclone desanding device is introduced into the cyclone desanding device through the booster pump for backwashing. The shrinking backwashing pipe exerts a force in the left direction on the screen packing, and the air on the liquid surface is forced by the water storage tank during the water filling process. Squeeze and rise to the filter packing layer through the porous plate, so that the filter packing presents a state of boiling flow. After the air in the water storage tank is emptied, the water flow continues to flow upward at a high speed through the holes of the porous plate, and at the same time shrinks during the entire backwashing process. The water in the backwash pipe flushes to the left, and the entire sieve packing forms a fast-moving turbulent flow under the impact of the water flow, and the sieve packing rubs against each other in the counterclockwise small vortex formed under the force of different directions, and the attached organic pollutants are removed. , which is conducive to obtaining a relatively pure filler.

本发明先后采用三级反冲洗技术进行反冲洗:The present invention successively adopts three-stage backwashing technology to carry out backwashing:

一级反冲洗为曝气循环反冲洗,由于污染物质在填料表面的堆积,污水难以透过填料之间的空隙渗透下去,在筛滤过程中进行反冲洗,开启曝气管28并间歇开启多孔板上方纳米曝气机26,集水池内纳米曝气头不连续工作,空气自多孔板向上鼓起,分割成小气泡,间歇冲散筛滤填料上的致密污物层,污染物质层破碎成片状浮起,在曝气管的浮力以及缩口管进水时向右推力的协同作用下产生波轮效果,大力清洗填料表层片状致密污染物,溢流至回流槽,使填料截留的污染物集中排除装置外,与进水混合重新处理,污水也可继续自分子筛空隙渗透下去;一级反冲洗可延长筛滤装置使用寿命及反洗周期,对于进水浊度较低的情况,甚至可以无需反冲洗,使装置不断运行净化污水。The first-level backwash is an aeration cycle backwash. Due to the accumulation of pollutants on the surface of the filler, it is difficult for the sewage to penetrate through the gaps between the fillers. Backwashing is performed during the screening process, and the aeration pipe 28 is opened and the porous is intermittently opened. The nano-aerator 26 above the plate, the nano-aerator head in the sump works discontinuously, the air bulges upward from the porous plate, divides into small bubbles, and intermittently washes away the dense dirt layer on the sieve packing, and the pollutant layer is broken into Flake floating, under the synergy of the buoyancy of the aeration tube and the rightward thrust of the constriction tube when the water enters, a pulsator effect is produced, vigorously cleaning the sheet-shaped dense pollutants on the surface of the packing, overflowing to the backflow tank, and making the trapped pollutants in the packing In addition to the concentrated pollutant removal device, it is mixed with the influent for retreatment, and the sewage can continue to permeate through the gap of the molecular sieve; the first-stage backwash can prolong the service life of the sieving device and the backwash cycle. For the case of low influent turbidity, Even without backwashing, the device can be continuously operated to purify sewage.

二级反冲洗为空气脉冲反冲洗,由于污水浊度过高,导致污染物质在填料表面的大量堆积,仅仅靠一级反冲洗步骤仍不能达到继续筛滤的效果。此时停止进水并关闭一、二级表层湍流筛滤装置的出水阀门20,开启增压泵4和反洗阀门10,启动多孔板上方纳米曝气机26,将旋流除砂装置中的出水导入一、二级表层湍流筛滤装置的缩口进水管。在回水压力的作用下,储水箱中的全部空气受到快速挤压,沿多孔板上的细孔上升,全部筛滤填料层在上升空气、旋转扰动的波轮作用及填料下纳米曝气头的冲击力作用下,填料间隙的污染物质破碎浮起,又在曝气管的浮力以及进水冲击挡流板向右推力的协同作用下,溢流至回流槽与初始进水混合,待水面快速下降。过滤速率重新稳定后,关闭增压泵4、多孔板下方纳米曝气机26和反洗阀门10,开启出水阀门20,恢复进水继续进行筛滤处理。The second-stage backwash is an air pulse backwash. Due to the high turbidity of the sewage, a large amount of pollutants accumulate on the surface of the filler. The effect of continuous screening cannot be achieved only by the first-stage backwash step. Stop water inlet and close the water outlet valve 20 of the first and second surface layer turbulent flow screening device at this moment, open the booster pump 4 and backwash valve 10, start the nano aerator 26 above the perforated plate, the cyclone desanding device The outlet water is introduced into the shrinkage inlet pipes of the primary and secondary surface turbulence screening devices. Under the action of the backwater pressure, all the air in the water storage tank is squeezed rapidly and rises along the pores on the porous plate. Under the action of the impact force, the pollutants in the packing gap are broken and floated, and under the synergistic effect of the buoyancy of the aeration tube and the rightward thrust of the water impact baffle, they overflow to the return tank and mix with the initial water, and wait for the water surface drop rapidly. After the filtration rate is stabilized again, close the booster pump 4, the nano aerator 26 under the perforated plate and the backwash valve 10, open the water outlet valve 20, resume the water intake and continue the screening process.

三级反冲洗为曝气湍流反冲洗,此时一、二级反冲洗已经不足以解决污染物质对填料的覆盖、阻塞问题,污水大量积聚不得过滤。此时停止进水,开启增压泵4、反洗阀门10和出水阀门20,启动超声波发生仪27及纳米曝气机26,反向启动液压泵19,将出水大量导入集水池中:The third-stage backwashing is aeration turbulent backwashing. At this time, the first and second-stage backwashing are not enough to solve the problem of covering and blocking the filler by pollutants, and a large amount of sewage cannot be filtered. Now stop water intake, open booster pump 4, backwash valve 10 and water outlet valve 20, start ultrasonic generator 27 and nano aerator 26, reverse start hydraulic pump 19, a large amount of water will be imported in the sump:

⑴集水池内部空气沿多孔板细孔上升搅拌,填料底部纳米曝气头开始曝气,填料上方涡轮不断转动;⑴The air inside the sump rises and stirs along the pores of the perforated plate, the nano-aeration head at the bottom of the filler starts to aerate, and the turbine above the filler keeps rotating;

⑵利用纳米曝气技术冲击、氧化、气浮及高温作用协同清洗,上方填料呈现湍流状态,进行无规则高速运动状态,填料在水流旋涡的冲击力和气泡的剪切力作用下相互摩擦,填料上附着的有机污染物能够去除,得到较为纯净的填料;⑵Using nano-aeration technology impact, oxidation, air flotation and high temperature to clean together, the upper filler is in a state of turbulence, and is in a state of irregular high-speed movement. The filler rubs against each other under the impact of the water vortex and the shear force of the air bubbles. The organic pollutants attached to the surface can be removed to obtain a relatively pure filler;

⑶利用超声波发生仪在液体介质中产生超声波,在筛滤填料表面产生空化效应,空化汽泡在闭合过程中破裂时形成的冲击波,会在其周围产生上千个气压的冲击压力,作用在填料表面上破坏污物之间粘性,并使它们迅速分散在反洗液中,从而达到填料表面洁净的效果。⑶Using an ultrasonic generator to generate ultrasonic waves in the liquid medium, a cavitation effect is generated on the surface of the sieve packing, and the shock wave formed when the cavitation bubble breaks during the closing process will generate thousands of air pressure shock pressures around it. Break the stickiness between the dirt on the surface of the filler, and make them quickly disperse in the backwash solution, so as to achieve the effect of cleaning the surface of the filler.

⑷空气排净后,出水池的出水继续导入,富含羟自由基的出水冲洗湍流状态的的填料颗粒表面及微孔,剥离污染物质,填料得到再生。⑷After the air is exhausted, the effluent from the effluent tank continues to be introduced, and the effluent rich in hydroxyl radicals washes the surface and micropores of the filler particles in the turbulent state, strips off the pollutants, and the filler is regenerated.

⑸而污染物质在水流冲击力及右侧曝气管气浮作用下不断向上浮至水面,自左端进水堰及右端回流槽流出与初始进水混合。经过三级反冲洗,内部污染物被清洗排空殆尽。(5) The pollutants float upwards to the water surface continuously under the impact force of the water flow and the air flotation of the right aeration tube, and flow out from the left inlet weir and the right return trough to mix with the initial inlet water. After three-stage backwashing, the internal pollutants are cleaned and emptied.

常规砂滤是在过滤过程中不扰动砂层,使水流从砂子细小缝隙之间流过。通常采用不扰动砂层,压实填料、增加水压、砂上附加网格等手段改进砂滤过程,让水流从砂子细小缝隙之间流过,而污染物质停留在砂层的表层上。本发明则是利用缩口管高压进水扰动填料表层,防止污染物质堆积对水流的顺利通过形成阻力,同时利用高级氧化、超声波、纳米曝气、气泡的冲击力和剪切力等手段改进装置,利用分子筛、锰砂等填料进行优化设计,最后使用三级反冲洗等改进处理过程。本装置对胶体、纤维、藻类等悬浮物的截留效果好,对于浊度较低水质甚至无需反冲洗,即可完成处理过程,同时具有去除臭味,灭杀细菌、病原菌等微生物,分解难降解的少量残留表面活化剂、多氯联苯等难降解有机化合物的功效。Conventional sand filtration does not disturb the sand layer during the filtration process, allowing water to flow through the small gaps in the sand. Usually, the sand filtration process is improved by means of not disturbing the sand layer, compacting the filler, increasing the water pressure, and adding grids on the sand, so that the water flows through the small gaps in the sand, while the pollutants stay on the surface of the sand layer. The present invention utilizes the high-pressure water inlet of the constricted tube to disturb the surface layer of the filler, prevents the accumulation of pollutants from forming resistance to the smooth passage of the water flow, and uses advanced oxidation, ultrasonic waves, nano-aeration, impact force and shear force of air bubbles to improve the device. , use molecular sieve, manganese sand and other fillers to optimize the design, and finally use three-stage backwashing to improve the treatment process. The device has a good interception effect on suspended solids such as colloids, fibers, algae, etc. For water with low turbidity, the treatment process can be completed even without backwashing. At the same time, it can remove odors, kill bacteria, pathogenic bacteria, etc. The efficacy of a small amount of residual surfactants, polychlorinated biphenyls and other refractory organic compounds.

本发明的碳掺杂的纳米TiO2粉体的制备:Carbon-doped nano TiO of the present invention Preparation of powder:

采用均匀沉淀法和水热法两步过程制备碳掺杂的纳米TiO2。以硫酸钛和尿素为前驱,葡萄糖为碳源,具体制备过程如下:取6.48g27硫酸钛和3.24g54尿素(硫酸钛与尿素的摩尔比为1:2)溶于去离子水中,再加入适量的葡萄糖0.6搅拌均匀,1:2:0.023在90℃的条件下反应2h。待反应结束后取出反应物干燥、反复水洗至中性,再次干燥,用球磨机研磨得到碳掺杂的纳米TiO2粉体。Carbon-doped nano-TiO 2 was prepared by a two-step process of uniform precipitation and hydrothermal method. With titanium sulfate and urea as the precursor, glucose as the carbon source, the specific preparation process is as follows: take 6.48g27 titanium sulfate and 3.24g54 urea (the molar ratio of titanium sulfate and urea is 1:2) dissolved in deionized water, and then add an appropriate amount of Glucose 0.6 was stirred evenly, and 1:2:0.023 was reacted at 90°C for 2 hours. After the reaction is finished, the reactant is taken out and dried, repeatedly washed with water until neutral, dried again, and ground with a ball mill to obtain carbon-doped nano TiO 2 powder.

纳米TiO2粉体负载在填料上的方法:The method of loading nano TiO 2 powder on the filler:

采用聚丙烯材质的立体网状结构填料,将纳米TiO2粉体与去离子水(粉体与水的质量比为1:20)混合,用超声波超声成乳浊液,将洁净的立体网状结构填料浸入与乙醇1:1混合的钛酸酯偶联剂,缓慢搅拌一段时间,然后将填料取出放入TiO2乳浊液中继续搅拌一段时间,取出后放入烘箱中干燥(85℃以下)2h,即制得负载纳米TiO2的聚丙烯悬浮填料,其外观呈淡黄色,膜层较均匀。The three-dimensional network structure filler made of polypropylene is used to mix nano-TiO 2 powder with deionized water (the mass ratio of powder to water is 1:20), and the emulsion is formed by ultrasonic wave, and the clean three-dimensional network The structural filler is immersed in the titanate coupling agent mixed with ethanol 1:1, stirred slowly for a period of time, then the filler is taken out and placed in the TiO 2 emulsion to continue stirring for a period of time, after taking it out, put it in an oven to dry (below 85°C ) 2h, that is, the polypropylene suspension filler loaded with nano-TiO 2 is obtained, its appearance is light yellow, and the film layer is relatively uniform.

Claims (10)

1.一种村镇集散型污水快速处理的装置,其包括:1. A device for rapid treatment of village and town collection and distribution sewage, which includes: 两段格栅机,格栅机的框体内布设有粗筛网和细筛网两段筛网,经过格栅机处理的污水通过增压泵导入一级表层湍流筛滤装置内;Two-stage grill machine, the frame of the grill machine is equipped with a coarse screen and a fine screen, and the sewage treated by the grill machine is introduced into the first-level surface turbulence screening device through the booster pump; 一级表层湍流筛滤装置由多孔板分为上、下两个部分,多孔板孔洞呈倾斜状,多孔板上方铺设石英砂作为筛滤填料;筛滤填料的底部设有纳米曝气头,筛滤填料内表层通过缩口进水管与两段格栅机连接;The first-level surface turbulence screening device is divided into upper and lower parts by a porous plate. The inner surface of the filter packing is connected to the two-stage grill machine through the shrinkage inlet pipe; 一级表层湍流筛滤装置对应于缩口进水管的另一侧下方设有缩口反洗管,通过反冲洗阀门连接增压泵,缩口反洗管的上方设有回流槽;The first-level surface turbulence screening device is provided with a shrinkage backwash pipe under the other side corresponding to the shrinkage inlet pipe, and the booster pump is connected through the backwash valve, and a reflux tank is arranged above the shrinkage backwash pipe; 多孔板下方为储水箱,储水箱内壁均匀负载一层非金属掺杂光催化剂,储水箱底部安装有紫外灭菌灯,在紫外灭菌灯的空隙间设置纳米曝气头,储水箱内部剩余空间填充有半导体负载填料;Below the perforated plate is the water storage tank. The inner wall of the water storage tank is evenly loaded with a layer of non-metallic doped photocatalyst. The bottom of the water storage tank is equipped with an ultraviolet sterilization lamp. Filled with semiconductor loaded filler; 一级表层湍流筛滤装置的储水箱的出水口通过一液压泵与A2/O复合流折板土渗系统下半部分的上处理区相连,A2/O复合流折板土渗系统下半部分下处理区的出水导入A2/O复合流折板土渗系统上半部分的下处理区;The water outlet of the water storage tank of the first-level surface turbulence screening device is connected to the upper treatment area of the lower part of the A 2 /O composite flow baffle soil infiltration system through a hydraulic pump, and the lower part of the A 2 /O composite flow baffle soil infiltration system The effluent from the lower half of the treatment area is introduced into the lower treatment area of the upper half of the A 2 /O compound flow baffle soil infiltration system; A2/O复合流折板土渗系统分为上半部分和下半部分,上半部分由折板形成上下两个处理区,上处理区使用鹅卵石对污水进行缺氧好氧处理以及出水导水,下处理区采用碎石以及粗砂混合而成的混合填料在好氧环境下对污水进行处理,污水流动方向为水平潜流;下半部分由折板形成上下两个处理区,上处理区采用碎石以及粗砂混合而成的混合填料在厌氧环境下对污水进行处理,污水流动方向为水平潜流,下处理区采用鹅卵石对污水进行厌氧处理以及出水导水,污水流动方向为垂直潜流;The A 2 /O composite flow baffle soil infiltration system is divided into an upper part and a lower part. The upper part is composed of folded slabs to form upper and lower treatment areas. Water, the lower treatment area uses a mixed filler made of gravel and coarse sand to treat sewage in an aerobic environment, and the direction of sewage flow is horizontal subsurface flow; The mixed packing made of crushed stone and coarse sand is used to treat the sewage in an anaerobic environment. The sewage flow direction is horizontal subsurface flow. The lower treatment area uses pebbles to treat the sewage anaerobically and guide the water outlet. The sewage flow direction is vertical. undercurrent; A2/O复合流折板土渗系统的出水连接二级表层湍流筛滤装置;The outlet water of A 2 /O compound flow baffle soil infiltration system is connected to the secondary surface turbulence screening device; 二级表层湍流筛滤装置由多孔板分为上、下两个部分,多孔板孔洞呈倾斜状,多孔板上方铺设改性锰砂与天然沸石分子筛混合物作为筛滤填料;筛滤填料的底部设有纳米曝气头,筛滤填料内表层通过缩口进水管与A2/O复合流折板土渗系统的出水口连接;The secondary surface turbulence screening device is divided into upper and lower parts by a porous plate. The holes of the porous plate are inclined. The mixture of modified manganese sand and natural zeolite molecular sieve is laid on the porous plate as the sieve packing; the bottom of the sieve packing is set There is a nano-aeration head, and the inner surface of the filter packing is connected to the water outlet of the A 2 /O compound flow baffle soil infiltration system through the shrinkage water inlet pipe; 二级表层湍流筛滤装置对应于缩口进水管的另一侧下方设有缩口反洗管,通过反冲洗阀门连接增压泵,缩口反洗管的上方设有回流槽;The secondary surface turbulence screening device is provided with a shrinkage backwash pipe under the other side corresponding to the shrinkage inlet pipe, and the booster pump is connected through the backwash valve, and a return tank is arranged above the shrinkage backwash pipe; 多孔板下方为储水箱,储水箱内壁均匀负载一层非金属掺杂光催化剂,储水箱底部安装有紫外灭菌灯,在紫外灭菌灯的空隙间设置纳米曝气头,储水箱内部剩余空间填充有半导体负载填料;Below the perforated plate is the water storage tank. The inner wall of the water storage tank is evenly loaded with a layer of non-metallic doped photocatalyst. The bottom of the water storage tank is equipped with an ultraviolet sterilization lamp. Filled with semiconductor loaded filler; 二级表层湍流筛滤装置位于回流槽一侧设置有曝气管,曝气管设有多个细孔曝气孔,细孔曝气孔垂直向上;在筛滤填料上方安装有超声波发生仪;The secondary surface turbulence screening device is located on one side of the reflux tank and is equipped with an aeration tube. The aeration tube is equipped with multiple fine-pore aeration holes, and the fine-pore aeration holes are vertically upward; an ultrasonic generator is installed above the sieve packing; 二级表层湍流筛滤装置的储水箱的出水口通过液压泵连接旋流除砂装置,旋流除砂装置的上部分别连接至一级表层湍流筛滤装置的缩口反洗管和二级表层湍流筛滤装置的缩口反洗管;The water outlet of the water storage tank of the secondary surface turbulence screening device is connected to the cyclone desanding device through a hydraulic pump, and the upper part of the cyclone desanding device is connected to the shrinking backwash pipe of the primary surface turbulent screening device and the secondary surface desanding device respectively. Shrink backwash pipe of turbulent flow screening device; 旋流除砂装置的底部开设有排泥口,顶部设置有搅拌机的电机,搅拌机的叶轮向上倾斜,旋转时将使池中污水作螺旋运动,污水中的密度较大的砂粒被甩向旋流除砂装置的池壁,在重力作用下沉入砂斗。The bottom of the cyclone desanding device is provided with a mud outlet, and the top is equipped with a mixer motor. The impeller of the mixer is inclined upward. When rotating, the sewage in the pool will make a spiral movement, and the dense sand in the sewage will be thrown to the cyclone. The pool wall of the sand removal device sinks into the sand bucket under the action of gravity. 2.根据权利要求1所述的装置,其中,两段格栅机中的粗筛网精度为21mm,细筛网精度为8mm;粗筛网和细筛网与水平呈60度夹角布设。2. The device according to claim 1, wherein the precision of the coarse screen in the two-stage grid machine is 21 mm, and the precision of the fine screen is 8 mm; the coarse screen and the fine screen are arranged at an angle of 60 degrees to the horizontal. 3.根据权利要求1所述的装置,其中,一级表层湍流筛滤装置中的筛滤填料是粒径为7-30mm的大颗粒石英砂。3. The device according to claim 1, wherein the sieve filler in the primary surface turbulence sieving device is large-grained quartz sand with a particle diameter of 7-30 mm. 4.根据权利要求1所述的装置,其中,二级表层湍流筛滤装置中的筛滤填料是粒径为0.5-1.0mm的改性锰砂与粒径为1.2-2.0mm的天然沸石分子筛混合物。4. The device according to claim 1, wherein the sieve filler in the secondary surface turbulence screening device is a natural zeolite molecular sieve with a particle diameter of 0.5-1.0mm modified manganese sand and a particle diameter of 1.2-2.0mm mixture. 5.根据权利要求1所述的装置,其中,储水箱内壁均匀负载的非金属掺杂光催化剂为纳米TiO2粉体。5. The device according to claim 1, wherein the non-metal doped photocatalyst uniformly loaded on the inner wall of the water storage tank is nano TiO 2 powder. 6.根据权利要求1所述的装置,其中,储水箱内部剩余空间填充的半导体负载填料为纳米TiO2粉体负载在立体网状聚丙烯形成的填料。6. The device according to claim 1, wherein the semiconductor-loaded filler filled in the remaining space inside the water storage tank is nano TiO 2 powder loaded on a three-dimensional network polypropylene to form a filler. 7.根据权利要求1所述的装置,其中,一级表层湍流筛滤装置和二级表层湍流筛滤装置中的纳米曝气头均分别各自连接纳米曝气机。7. The device according to claim 1, wherein the nano-aeration heads in the primary surface turbulent sieving device and the secondary surface turbulent sieving device are respectively connected to nano-aerators. 8.根据权利要求1所述的装置,其中,旋流除砂装置中的搅拌机转速为10-30r/min。8. The device according to claim 1, wherein the rotational speed of the agitator in the cyclone sand removal device is 10-30r/min. 9.利用权利要求1所述装置进行村镇集散型污水快速处理的方法:9. Utilize the described device of claim 1 to carry out the method for the rapid treatment of village and town collection and distribution type sewage: 污水在重力作用下通过两段筛网拦截液体中的固态颗粒,并连续清除流体中的杂物,由埋在筛滤填料表层的进水管导入一级表层湍流筛滤装置内进行筛滤,进水过程中利用进水错流的冲击力扰动筛滤填料表层,形成湍流,防止污染物质在筛滤填料表层堆积对水流的顺利通过形成阻力;Under the action of gravity, the sewage passes through the two-stage screen to intercept the solid particles in the liquid, and continuously removes the impurities in the fluid. The water inlet pipe buried in the surface layer of the filter packing is introduced into the first-level surface turbulent filter device for sieving. During the water process, the impact force of the cross-flow of the incoming water is used to disturb the surface of the sieve packing to form turbulence and prevent the accumulation of pollutants on the surface of the sieve packing to form resistance to the smooth passage of water flow; 一级表层湍流筛滤装置进行间歇曝气,曝气时的气泡冲击筛滤填料,打散筛滤填料表面的污染物质层并使其浮起,使得污水能顺利经过筛滤填料过滤;The first-level surface turbulent sieving device performs intermittent aeration, and the air bubbles impact the sieve packing during aeration, breaking up the pollutant layer on the surface of the sieve packing and making it float, so that the sewage can pass through the sieve packing smoothly; 经过一级表层湍流筛滤装置处理的污水从下半部分的上处理区进入A2/O复合流折板土渗系统后,由A2/O复合流折板土渗系统的下半部分中的上处理区使用混合填料在厌氧环境下对污水进行处理,污水流动方向为水平潜流,下处理区采用鹅卵石对污水进行厌氧处理以及出水导水,污水流动方向为垂直潜流;出水导入上半部分中的下处理区采用混合填料在好氧环境下对污水进行处理,污水流动方向为水平潜流,上处理区使用鹅卵石对污水进行缺氧好氧处理以及出水导水;After the sewage treated by the first-level surface turbulence screening device enters the A 2 /O composite flow baffle soil infiltration system from the upper treatment area of the lower half, it is passed through the lower half of the A 2 /O composite flow baffle soil infiltration system. The upper treatment area uses mixed fillers to treat sewage in an anaerobic environment. The direction of sewage flow is horizontal subsurface flow. The lower treatment area uses pebbles to treat sewage anaerobically and conduct water discharge. The direction of sewage flow is vertical subsurface flow; The lower treatment area in the half part uses mixed fillers to treat sewage in an aerobic environment, and the sewage flow direction is horizontal subsurface flow, and the upper treatment area uses pebbles to treat sewage with anoxic aerobic conditions and guide water out; 自A2/O复合流折板土渗系统下部进入的污水经过水平潜流-垂直导水进行初步处理,通过使用折板延长缺氧-厌氧部分,将污水内难降解物质大量分解,并将出水导入A2/O复合流折板土渗系统上部潜流折板上行池,进行缺氧-好氧处理,在微生物-填料-植物的协同作用下对污水进行处理,分解其中的易降解有机物,并去除其他污染物质;The sewage entering from the lower part of the A 2 /O composite flow baffle soil infiltration system is initially treated through horizontal underflow-vertical water diversion. By using the baffle to extend the anoxic-anaerobic part, a large amount of refractory substances in the sewage are decomposed, and the The effluent is introduced into the upper tank of the A 2 /O composite flow baffle soil infiltration system, and the anoxic-aerobic treatment is carried out. The sewage is treated under the synergy of microorganisms, fillers and plants, and the easily degradable organic matter in it is decomposed. and remove other pollutants; 经A2/O复合流折板土渗系统处理的污水由埋在筛滤填料表层的进水管导入二级表层湍流筛滤装置内进行筛滤,进水过程中利用进水错流的冲击力扰动筛滤填料表层,形成湍流,防止污染物质在筛滤填料表层堆积对水流的顺利通过形成阻力;The sewage treated by the A 2 /O compound flow baffle soil infiltration system is introduced into the second-level surface turbulent flow screening device through the water inlet pipe buried in the surface layer of the filter packing for sieving, and the impact force of the cross-flow of the incoming water is used in the process of water inflow Disturb the surface of the filter packing to form turbulent flow and prevent the accumulation of pollutants on the surface of the filter packing to form resistance to the smooth passage of water flow; 二级表层湍流筛滤装置进行间歇曝气,曝气时的气泡冲击筛滤填料,打散筛滤填料表面的污染物质层并使其浮起,使得污水能顺利经过筛滤填料过滤;填料上方右端设置有曝气管,曝气管设有多个细孔曝气孔,曝气孔垂直向上,气泡将浮起的污染物推至水面,溢流至回流槽,与进水混合调节进水水质,同时延长筛滤装置使用寿命及反洗周期;The secondary surface turbulent sieving device performs intermittent aeration, and the air bubbles impact the sieve packing during aeration, breaking up the pollutant layer on the surface of the sieve packing and making it float, so that the sewage can pass through the sieve packing smoothly; above the packing The right end is provided with an aeration tube, and the aeration tube is equipped with a plurality of fine aeration holes, and the aeration holes are vertically upward, and the air bubbles push the floating pollutants to the water surface, overflow to the return tank, and mix with the incoming water to adjust the incoming water Water quality, while prolonging the service life of the filter device and the backwash cycle; 一级表层湍流筛滤装置和二级表层湍流筛滤装置底部的纳米曝气头进气为O2,用于清洁填料;储水箱内纳米曝气头的进气为O3,通过纳米曝气大量获得羟基自由基,与紫外灭菌灯、半导体负载填料共同提高氧化效果,同时其中富含羟自由基的出水在装置进行反洗时,冲刷筛滤填料,使筛滤填料得到清洁与再生;The air intake of the nano-aeration head at the bottom of the first-level surface turbulence screening device and the second-level surface turbulence screening device is O 2 , which is used to clean the packing; the intake air of the nano-aeration head in the water storage tank is O 3 , through nano-aeration A large number of hydroxyl radicals are obtained, and the oxidation effect is improved together with the ultraviolet sterilizing lamp and the semiconductor-loaded filler. At the same time, the effluent rich in hydroxyl radicals flushes the sieve packing when the device is backwashed, so that the sieve packing is cleaned and regenerated; 二级表层湍流筛滤装置的出水导入旋流除砂装置,去除污水中的砂粒,污水经上述处理后达标排放;The effluent from the secondary surface turbulence screening device is introduced into the cyclone desanding device to remove the sand particles in the sewage, and the sewage is discharged up to the standard after the above treatment; 二级表层湍流筛滤装置的出水同时回流至A2/O复合流折板土渗系统进水,调节水质并刺激植物生长过程分泌次生物质。The effluent from the secondary surface turbulence screening device is simultaneously returned to the A 2 /O composite flow baffle soil infiltration system to regulate water quality and stimulate the secretion of secondary substances during plant growth. 10.根据权利要求9所述的方法,其中,一级表层湍流筛滤装置和二级表层湍流筛滤装置中的紫外灭菌灯平均照射剂量在300J/m2以上。10. The method according to claim 9, wherein the average irradiation dose of the ultraviolet germicidal lamp in the primary surface turbulent sieving device and the secondary surface turbulent sieving device is above 300J/m 2 .
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