CN104164219A - Shape-stabilized phase-change energy storage material and preparation method thereof - Google Patents
Shape-stabilized phase-change energy storage material and preparation method thereof Download PDFInfo
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- CN104164219A CN104164219A CN201410330814.1A CN201410330814A CN104164219A CN 104164219 A CN104164219 A CN 104164219A CN 201410330814 A CN201410330814 A CN 201410330814A CN 104164219 A CN104164219 A CN 104164219A
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- Prior art keywords
- storage material
- gac
- paraffin
- copper powder
- change heat
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- 239000011232 storage material Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000004146 energy storage Methods 0.000 title abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 13
- 239000010439 graphite Substances 0.000 claims abstract description 13
- 239000012188 paraffin wax Substances 0.000 claims abstract description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000002844 melting Methods 0.000 claims abstract description 3
- 230000008018 melting Effects 0.000 claims abstract description 3
- 238000005338 heat storage Methods 0.000 claims description 22
- 238000004513 sizing Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 10
- 238000001291 vacuum drying Methods 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 238000009713 electroplating Methods 0.000 claims description 3
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 235000019809 paraffin wax Nutrition 0.000 claims description 2
- 235000019271 petrolatum Nutrition 0.000 claims description 2
- 230000008859 change Effects 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000012071 phase Substances 0.000 description 5
- 238000004134 energy conservation Methods 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000012782 phase change material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a shape-stabilized phase change energy storage material and a preparation method, the shape-stabilized phase change energy storage material is composed of paraffin, expandable graphite, active carbon and copper powder by mixing, wherein paraffin mass fraction accounts for 75%, paraffin melting point is selected between 40-60 DEG C, expandable graphite mass fraction accounts for 10%, and active carbon and copper powder mass fraction accounts for 15%. The material has the advantages of faster heat absorption and heat release speed, no corrosivity to metal containers and no changed profile after phase change.
Description
One, technical field
The present invention relates to phase-change heat-storage material field, refer in particular to a kind of phase-change heat-storage material that utilizes organism and expanded graphite, gac and copper powder compounded preparation.
Two, background technology
Energy-conservation and environmental protection is an important topic of field of energy utilization, and the latent heat of phase change storage power of utilizing phase-change heat-storage material is a kind of novel power-saving technology.Phase change material, in phase transition process, absorbs the heat of surrounding environment, and when envrionment temperature reduces around, environment release of heat towards periphery, controls ambient temperature and energy-conservation object thereby reach.It all has wide practical use in fields such as sun power utilization, energy recovery, air conditioner refrigerating, building energy conservation, aerospace.
Sun power, as a kind of energy of inexpensive clean, is widely used in the middle of productive life at present, but because the supply and demand of sun power quantitatively with on the time can not well be mated and coordinate, causes mass energy waste.As sun power surplus on daytime, cause sun power to waste, and night and overcast and rainy sun power are not enough.The current poor shortcoming of heat accumulating ubiquity heat conductivility, the phase-change thermal storage parts of therefore making, due to poor thermal conductivity, cannot be given full play to the heat storage function of heat accumulating.Secondly,, when heat accumulating generation solid-liquid phase change, can cause leakage problem.
In order to address the above problem, can be by compound to phase-change heat-storage material and the strong base material of certain capacity of heat transmission, and add shaping material, and make a kind of composite phase-change heat-storage material, improve thermal conductivity and the sizing characteristic of heat accumulating.
Three, summary of the invention
The object of this invention is to provide a kind of sizing phase-change heat-storage material, in the operating temperature range of the transformation temperature of this phase-change heat-storage material in solar water heater, latent heat of phase change is higher, and heat conductivility is better, while there is solid-liquid phase change, can keep shape invariance.
Another object of the present invention is to provide the preparation method of above-mentioned sizing phase-change heat-storage material.
The object of the invention is to be achieved through the following technical solutions:
A kind of sizing phase-change heat-storage material, it is characterized in that: this sizing phase-change heat-storage material is mixed and formed by paraffin, gac, copper powder and expanded graphite, wherein Quality of Paraffin Waxes mark accounts for 75%, and select paraffin melting point between 40～60 DEG C, expanded graphite massfraction accounts for 10%, and gac and copper powder massfraction total account for 15%.
The preparation method of above-mentioned composite phase-change heat-storage material, adopts following steps:
(1) expansible black lead is placed in to 60 DEG C of vacuum drying ovens dry 10 hours, then dried expansible black lead powder is placed in to stainless steel vessel, be heated to 800 DEG C and expand 60 seconds, obtain expanded graphite;
(2) be placed in copper electroplating liquid energising using bar shaped activated carbon as negative electrode and electroplate, after gac is pulverized, be placed in 60 DEG C of vacuum drying ovens and dry 5 hours, obtain gac-copper powder mixture;
(3) paraffin, gac-copper powder mixture and expanded graphite are mixed and heated to 80 DEG C of blend by the mass ratio of 7.5: 1.5: 1, under agitation adsorb about 1 hour, make sizing phase-change heat-storage material.
The present invention has three advantages:
(1) the sizing phase-change heat-storage material heat conductivility that prepared by the present invention is higher, and heat absorption heat release speed is faster;
(2) the sizing phase-change heat-storage material that prepared by the present invention does not change its chemical property, there is no corrodibility for metal vessel;
(3) the sizing phase-change heat-storage material that prepared by the present invention can not change its profile in the time of phase transformation, can effectively prevent from revealing.
Four, embodiment
With example, embodiments of the present invention are described further below:
10g expansible black lead is placed in to 60 DEG C of vacuum drying ovens dry 10 hours, then dried expansible black lead powder is placed in to stainless steel vessel, be heated to 800 DEG C and expand 60 seconds, obtain expanded graphite; Be placed in copper electroplating liquid energising using the gac of elongate in shape as negative electrode and electroplate, after gac is pulverized, be placed in 60 DEG C of vacuum drying ovens and dry 5 hours, obtain gac-copper powder mixture; Get 75g fusing point and mix with 10g expanded graphite at paraffin, 15g gac-copper powder mixture of 60 DEG C, be heated to 80 DEG C of blend, under agitation adsorb about 1 hour, make sizing phase-change heat-storage material.The transformation temperature of this material is 60 DEG C, and latent heat of phase change is 145kJ/kg.
Claims (2)
1. a sizing phase-change heat-storage material, it is characterized in that: this sizing phase-change heat-storage material is mixed and formed by paraffin, gac, copper powder and expanded graphite, wherein Quality of Paraffin Waxes mark accounts for 75%, and select paraffin melting point between 40～60 DEG C, expanded graphite massfraction accounts for 10%, and gac and copper powder massfraction total account for 15%.
2. a preparation method for sizing phase-change heat-storage material claimed in claim 1, is characterized in that it comprises the steps:
(1) expansible black lead is placed in to 60 DEG C of vacuum drying ovens dry 10 hours, then dried expansible black lead powder is placed in to stainless steel vessel, be heated to 800 DEG C and expand 60 seconds, obtain expanded graphite;
(2) be placed in copper electroplating liquid energising using bar shaped activated carbon as negative electrode and electroplate, after gac is pulverized, be placed in 60 DEG C of vacuum drying ovens and dry 5 hours, obtain gac-copper powder mixture;
(3) paraffin, gac-copper powder mixture and expanded graphite are mixed and heated to 80 DEG C of blend by the mass ratio of 7.5: 1.5: 1, under agitation adsorb about 1 hour, make sizing phase-change heat-storage material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410330814.1A CN104164219A (en) | 2014-07-09 | 2014-07-09 | Shape-stabilized phase-change energy storage material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410330814.1A CN104164219A (en) | 2014-07-09 | 2014-07-09 | Shape-stabilized phase-change energy storage material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104164219A true CN104164219A (en) | 2014-11-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410330814.1A Pending CN104164219A (en) | 2014-07-09 | 2014-07-09 | Shape-stabilized phase-change energy storage material and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN104164219A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106543970A (en) * | 2015-09-22 | 2017-03-29 | 镇江新梦溪能源科技有限公司 | A kind of NEW TYPE OF COMPOSITE organic shaping heat accumulating and preparation method thereof |
| CN106543971A (en) * | 2015-09-22 | 2017-03-29 | 镇江新梦溪能源科技有限公司 | A kind of NEW TYPE OF COMPOSITE Organic substance phase-change heat-storage material and preparation method thereof |
| CN106543972A (en) * | 2015-09-22 | 2017-03-29 | 镇江新梦溪能源科技有限公司 | A kind of NEW TYPE OF COMPOSITE Organic phase change thermal storage material and preparation method thereof |
| CN106543969A (en) * | 2015-09-22 | 2017-03-29 | 镇江新梦溪能源科技有限公司 | A kind of NEW TYPE OF COMPOSITE Organic substance sizing heat accumulating and preparation method thereof |
| CN107338026A (en) * | 2017-06-07 | 2017-11-10 | 常州苏达欧包装材料有限公司 | A kind of composite phase-change heat-storage material and preparation method thereof |
| CN115819021A (en) * | 2022-11-30 | 2023-03-21 | 重庆海润节能技术股份有限公司 | Backfill material and backfill method for vertical spiral buried pipe ground source heat pump |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286268A (en) * | 2011-06-27 | 2011-12-21 | 南京大学 | Reinforced conductive composite phase-change heat storage material and preparation method thereof |
| CN102977859A (en) * | 2012-12-06 | 2013-03-20 | 盘锦科隆精细化工有限公司 | Preparation method of organic hybrid phase change material |
| CN103334039A (en) * | 2013-07-15 | 2013-10-02 | 深圳市东维丰电子科技股份有限公司 | Copper-based nano diamond composite material and preparation method thereof |
| CN103773318A (en) * | 2012-10-24 | 2014-05-07 | 中国石油化工股份有限公司 | Preparation method of phase-change energy-storage material |
-
2014
- 2014-07-09 CN CN201410330814.1A patent/CN104164219A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286268A (en) * | 2011-06-27 | 2011-12-21 | 南京大学 | Reinforced conductive composite phase-change heat storage material and preparation method thereof |
| CN103773318A (en) * | 2012-10-24 | 2014-05-07 | 中国石油化工股份有限公司 | Preparation method of phase-change energy-storage material |
| CN102977859A (en) * | 2012-12-06 | 2013-03-20 | 盘锦科隆精细化工有限公司 | Preparation method of organic hybrid phase change material |
| CN103334039A (en) * | 2013-07-15 | 2013-10-02 | 深圳市东维丰电子科技股份有限公司 | Copper-based nano diamond composite material and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106543970A (en) * | 2015-09-22 | 2017-03-29 | 镇江新梦溪能源科技有限公司 | A kind of NEW TYPE OF COMPOSITE organic shaping heat accumulating and preparation method thereof |
| CN106543971A (en) * | 2015-09-22 | 2017-03-29 | 镇江新梦溪能源科技有限公司 | A kind of NEW TYPE OF COMPOSITE Organic substance phase-change heat-storage material and preparation method thereof |
| CN106543972A (en) * | 2015-09-22 | 2017-03-29 | 镇江新梦溪能源科技有限公司 | A kind of NEW TYPE OF COMPOSITE Organic phase change thermal storage material and preparation method thereof |
| CN106543969A (en) * | 2015-09-22 | 2017-03-29 | 镇江新梦溪能源科技有限公司 | A kind of NEW TYPE OF COMPOSITE Organic substance sizing heat accumulating and preparation method thereof |
| CN107338026A (en) * | 2017-06-07 | 2017-11-10 | 常州苏达欧包装材料有限公司 | A kind of composite phase-change heat-storage material and preparation method thereof |
| CN115819021A (en) * | 2022-11-30 | 2023-03-21 | 重庆海润节能技术股份有限公司 | Backfill material and backfill method for vertical spiral buried pipe ground source heat pump |
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Application publication date: 20141126 |