CN104148036A - Metal foam carrier CO2 adsorbent - Google Patents
Metal foam carrier CO2 adsorbent Download PDFInfo
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- CN104148036A CN104148036A CN201410359743.8A CN201410359743A CN104148036A CN 104148036 A CN104148036 A CN 104148036A CN 201410359743 A CN201410359743 A CN 201410359743A CN 104148036 A CN104148036 A CN 104148036A
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- adsorbent
- metal foam
- hollow continuous
- carbon nano
- continuous skeleton
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Abstract
The invention relates to a metal foam carrier CO2 adsorbent. The metal foam carrier CO2 adsorbent comprises a hollow continuous skeleton, wherein the hollow continuous skeleton is made of metal foam, and CO2 adsorbents with a heat conductivity coefficient of 0.06 to 0.12 W/m.K grow or fill in holes in the metal foam. According to the metal foam carrier CO2 adsorbent, the CO2 adsorbent with low heat conductivity coefficient fills in the metal foam, and because the metal foam is a heat transfer medium with good heat-conducting property, the CO2 adsorbent disclosed by the invention adsorbs heat generated by CO2, so that the heat can be dissipated in time, and the CO2 adsorption capacity is increased, thereby overcoming the defect of low adsorption capacity and even adsorbent failure caused by the low heat conductivity coefficient of the CO2 adsorbent. In addition, because the specific surface area of the metal foam is large, more CO2 adsorbents can grow or fill in the limited volume, and therefore, the metal foam carrier CO2 adsorbent can efficiently adsorb CO2.
Description
Technical field
The present invention relates to a kind of CO
2adsorbent, relates in particular to a kind of metallic foam support CO
2adsorbent.
Background technology
In man-machine confined space, because the reasons such as personnel's breathing, plant equipment operation and material oxidation burning all can produce CO
2, and the CO of concentration over-standard
2can upset human normal metabolism and even can threaten personnel's life security, therefore develop efficient CO
2absorption has very important significance.
From existing document and patent, in physical absorption, adopt the homogenous materials such as zeolite, carbon nano rod as adsorbent more.In this absorption, emit heat.According to equilibrium principle is known, when in time reducing or shifting heat of adsorption, be conducive to more CO
2be adsorbed on carbon nano rod.But in existing patent and document, do not consider the impact of heat on absorption, do not solve and in limited bulk, can have large area carbon nano rod CO absorption simultaneously
2problem.
Patent US2005040090-A1 and patent US2005040090-B1 have introduced respectively distribution carbon nano rod in metal foam, do not eliminate the impact of vapour lock on heat conductivility between carbon nano rod and metal foam, thereby affect adsorbance, and do not make full use of the feature of metal foam structures feature and carbon nano adsorption, adopt rational carbon nano rod space to arrange, thereby affect adsorbance.
Summary of the invention
The object of the present invention is to provide the metallic foam support CO that a kind of adsorbance is large
2adsorbent.
In order to achieve the above object, the technical solution used in the present invention is: comprise the hollow continuous skeleton consisting of metal foam, grow or be filled with thermal conductivity factor at the CO of 0.06～0.12W/mK in the hole of described metal foam
2adsorbent.
Described CO
2adsorbent is one or both in carbon nano rod, solid amine particle, metallic organic framework compound, and solid amine is particles filled in the hole of metal foam, carbon nano rod and metallic organic framework compound are all grown in the hole of metal foam, and the hole inwall angle of carbon nano rod and metal foam is 30 °～150 °.
Described CO
2when adsorbent is carbon nano rod, hollow continuous skeleton is divided into some sections in the axial direction, in each section of hollow continuous skeleton, in the hole of metal foam, the length of the carbon nano rod of growth is identical, and from the entrance of hollow continuous skeleton, the mode that some sections of hollow continuous skeletons increase successively with carbon nano rod length is arranged.
The porosity of described metal foam is 0.90%～0.97%, and aperture is at 0.7 μ m～3mm, and the length of carbon nano rod is 0.2 μ m～200 μ m, and diameter is 50～100nm.
Described CO
2when adsorbent is two kinds in carbon nano rod, solid amine particle, metallic organic framework compound, hollow continuous skeleton is divided into leading portion hollow continuous skeleton and back segment hollow continuous skeleton in the axial direction, grows or fill a kind of CO in each hole of metal foam
2adsorbent, and leading portion hollow continuous skeleton and back segment hollow continuous skeleton start to arrange successively from the entrance of hollow continuous skeleton, is arranged in the hole growth of the intraskeletal metal foam of leading portion hollow continuous or fills a kind of CO
2adsorbent, the hole that is arranged in the intraskeletal metal foam of back segment hollow continuous is filled another kind of CO
2adsorbent.
Described CO
2adsorbent is carbon nano rod and solid amine particle, and the hole that is arranged in the intraskeletal metal foam of the leading portion hollow continuous carbon nano rod of growing, and the hole that is arranged in the intraskeletal metal foam of back segment hollow continuous is filled solid amine particle.
In described leading portion hollow continuous skeleton and back segment hollow continuous skeleton, the porosity of metal foam is 0.90%～0.97%, and in leading portion hollow continuous skeleton, the aperture of metal foam is 0.7 μ m～2.0mm, and the length of carbon nano rod is 20nm～0.3 μ m; In back segment hollow continuous skeleton, the aperture of metal foam is 3mm～5mm, and the particle diameter of solid amine particle is 0.3～1.5mm, specific area >100m
2/ mg.
Described leading portion hollow continuous skeleton D is divided into some skeleton units in the axial direction, the length of the carbon nano rod of growing in the hole of metal foam in each skeleton unit is identical with density, and from the entrance of hollow continuous skeleton, the mode that some skeleton units increase successively with length and the density of carbon nano rod is arranged.
Described metallic organic framework compound is Cu-BTC, Ni-DOBDC or ZIF-8.
The material of described metal foam is copper, nickel or iron.
Compared with prior art, beneficial effect of the present invention is:
The present invention is by the low CO of thermal conductivity factor
2adsorbent is placed in metal foam, because metal foam is the heat transmission medium that a kind of heat conductivility is good, therefore, CO of the present invention
2adsorbent CO absorption
2the heat producing can scatter and disappear timely, has improved CO
2adsorbance, thereby overcome because of CO
2the defect that the little even adsorbent of the low adsorbance causing of adsorbent thermal conductivity factor lost efficacy.Meanwhile, because the specific area of metal foam is larger, can in limited volume, grow or fill more CO
2adsorbent, therefore, the present invention can efficient adsorption CO
2.
Accompanying drawing explanation
Fig. 1 is the structural representation of the first embodiment of the present invention;
Fig. 2 is the partial enlarged drawing of first paragraph hollow continuous skeleton in Fig. 1,
Fig. 3 is the partial enlarged drawing of second segment hollow continuous skeleton in Fig. 1;
Fig. 4 is the partial enlarged drawing of the 3rd section of hollow continuous skeleton in Fig. 1;
Fig. 5 is the structural representation of the second embodiment of the present invention;
Fig. 6 is the partial enlarged drawing of leading portion hollow continuous skeleton in Fig. 5;
Fig. 7 is the partial enlarged drawing of Fig. 6 posterior segment hollow continuous skeleton;
Wherein, 1-metal foam, A-first paragraph hollow continuous skeleton, B-second segment hollow continuous skeleton, C-three section hollow continuous skeleton, D-leading portion hollow continuous skeleton, E-back segment hollow continuous skeleton.
The specific embodiment
Below in conjunction with accompanying drawing, the present invention is described in further details.
As shown in Figure 1 and Figure 5, the present invention includes the hollow continuous skeleton being formed by metal foam, in the hole of described metal foam, grow or be filled with thermal conductivity factor at the CO of 0.06～0.12W/mK
2adsorbent, and CO
2adsorbent is one or both in carbon nano rod, solid amine particle, metallic organic framework compound, in each hole of metal foam, fills a kind of CO
2adsorbent, metallic organic framework compound is Cu-BTC, Ni-DOBDC or ZIF-8; The material of metal foam is copper, nickel or iron.
(1) as shown in Figure 1, work as CO
2when adsorbent is carbon nano rod, solid amine particle or metallic organic framework compound; the present invention adopts the structure with the first technical scheme; and the porosity of metal foam is 0.90%～0.97%; aperture is at 0.7 μ m～3mm, so growth that can be a large amount of in limited volume in metal foam or filling CO
2adsorbent, increases CO
2adsorption capacity.
Work as CO
2when adsorbent is solid amine particle, solid amine particle is be filled in metal foam intrapore, solid amine particle CO absorption
2it is a kind of chemisorbed process.
Work as CO
2when adsorbent is carbon nano rod or metallic organic framework compound, carbon nano rod or metallic organic framework compound are to adopt intrapore at metal foam of ALD technology growth, and carbon nano rod or metallic organic framework compound CO absorption
2be a kind of physical adsorption process, there is adsorbance large, be easy to the advantage of resolving simultaneously.
Further, work as CO
2when adsorbent is carbon nano rod, the length of carbon nano rod is 0.2 μ m～200 μ m, and diameter is 50～100nm.
In order to prevent to adsorb clogging, hollow continuous skeleton is divided into some sections in the axial direction, take three sections as example (as Figure 1-4), first, two, metal foam A in three sections of hollow continuous skeletons, B, identical (that is to say of length of the carbon nano rod of growth in the hole of C, in same section of hollow continuous skeleton, in the hole of metal foam, the length of the carbon nano rod of growth is identical), in each section of hollow continuous skeleton, in the hole of metal foam, the length of the carbon nano rod of growth is different (that is to say, in the hollow continuous skeleton of different sections, in the hole of metal foam, the carbon nano rod length of growth is different), and from the entrance of hollow continuous skeleton, first, second and third section of hollow continuous skeleton A, B, the mode that C increases successively with carbon nano rod length is arranged.Carbon nano rod has not only prevented at the arrangement of the short rear length of axially going forward of hollow continuous skeleton the phenomenon that absorption is stopped up, and can also eliminate air thermal resistance, therefore, the present invention can be in adsorption process in time by transfer of heat in metallic framework, thereby be lost in air, strengthen adsorption capacity.
(2) as shown in Figure 5, work as CO
2when adsorbent is two kinds in carbon nano rod, solid amine particle, metallic organic framework compound, the present invention adopts the structure with the second technical scheme.
Hollow continuous skeleton is divided into leading portion hollow continuous skeleton D and back segment hollow continuous skeleton E in the axial direction, grows or fill a kind of CO in each hole of metal foam
2adsorbent, and leading portion hollow continuous skeleton D and back segment hollow continuous skeleton E start to arrange successively from the entrance of hollow continuous skeleton, be arranged in leading portion hollow continuous skeleton D metal foam hole growth or fill a kind of CO
2adsorbent, the hole that is arranged in the metal foam of back segment hollow continuous skeleton E is filled another kind of CO
2adsorbent.Wherein, in leading portion hollow continuous skeleton D and back segment hollow continuous skeleton E, the porosity of metal foam is 0.90%～0.97%, in leading portion hollow continuous skeleton D metal foam aperture be 0.7 μ m～2.0mm, in back segment hollow continuous skeleton E, the aperture of metal foam is 3mm～5mm, therefore growth that, can be a large amount of in limited volume in metal foam or filling CO
2adsorbent, increases CO
2adsorption capacity.
Work as CO
2when adsorbent is carbon nano rod and metallic organic framework compound, the hole that is arranged in the metal foam of leading portion hollow continuous skeleton D and back segment hollow continuous skeleton E can adopt ALD technology growth carbon nano rod or metallic organic framework compound, and carbon nano rod and metallic organic framework compound CO absorption
2it is a kind of physical adsorption process.Take copper metal foam as example, and the technique of carbon nano tube growth on copper foam is that metal foam copper is coated with the thick titanium of the about 60nm of one deck, protection copper.And then it is thick to be coated with 2～3nm with nickel as catalyst, then passing into gas is 200～300 ℃ of reactions or ALD method in room temperature or temperature; Long Cu-BTC on copper foam, first carries out oxidation processes by copper foam, and washing 15min places 4 days in baking oven, 100 degree oxidations, and there is yellow green metallic luster in surface then, the copper foam surface growth Cu-BTC after oxidation.Solid amine particle can adopt direct filling.
Work as CO
2when adsorbent is solid amine particle and metallic organic framework compound, the hole that is arranged in the metal foam of leading portion hollow continuous skeleton D can also can be filled solid amine particle by growing metal organic backbone compound; The hole that is arranged in the metal foam of back segment hollow continuous skeleton E can be filled solid amine particle also can growing metal organic backbone compound, and metallic organic framework compound is to adopt ALD technology growth in the hole of metal foam, solid amine particle CO absorption
2a kind of chemisorbed process, metallic organic framework compound CO absorption
2it is a kind of physical adsorption process.
Work as CO
2when adsorbent is carbon nano rod and solid amine particle, the hole that is arranged in the metal foam of the leading portion hollow continuous skeleton D carbon nano rod of can growing also can be filled solid amine particle; The hole that is arranged in the metal foam of back segment hollow continuous skeleton E can be filled the solid amine particle carbon nano rod of also can growing, and metallic organic framework compound is to adopt ALD technology growth in the hole of metal foam, solid amine particle CO absorption
2a kind of chemisorbed process, carbon nano rod CO absorption
2it is a kind of physical adsorption process.
Work as CO
2adsorbent is solid amine particle and metallic organic framework compound and works as CO
2adsorbent is carbon nano rod and solid amine particle both of these case, and every kind of situation all exists chemisorbed and physical absorption, for these two kinds of adsorption processes are coupled together in best mode, further, works as CO
2when adsorbent is solid amine particle and metallic organic framework compound, be arranged in the hole growing metal organic backbone compound of the metal foam of leading portion hollow continuous skeleton D, the hole that is arranged in the metal foam of back segment hollow continuous skeleton E is filled solid amine particle, work as CO
2when adsorbent is carbon nano rod and solid amine particle (referring to Fig. 6 and Fig. 7), in leading portion hollow continuous skeleton D and back segment hollow continuous skeleton E, the porosity of metal foam is 0.90%～0.97%, in leading portion hollow continuous skeleton D, the aperture of metal foam is 0.7 μ m～2.0mm, in back segment hollow continuous skeleton E, the aperture of metal foam is 3mm～5mm, the hole growth length that is arranged in the metal foam of leading portion hollow continuous skeleton D is the carbon nano rod of 20nm～0.3 μ m, it is definite that the length of carbon nano rod makes solid amine particle issue biochemical absorption in Optimal Temperature according to its absorption liberated heat, the hole that is arranged in the metal foam of back segment hollow continuous skeleton E is filled solid amine particle, and the particle diameter of solid amine particle is 0.3～1.5mm, specific area >100m
2/ mg.
The reason arranging is like this: containing CO
2fluid while entering from the entrance of hollow continuous skeleton, first there is physical absorption, the metal foam that the heat of adsorption that physical absorption is emitted is good by heat conductivility and specific area is large pass to be positioned at back segment hollow continuous skeleton E solid amine particle with preheating solid amine particle, make it at more rational activation energy, issue biochemical absorption, thereby strengthen its adsorption capacity.
Further, leading portion hollow continuous skeleton D of the present invention is divided into some skeleton units in the axial direction, (that is to say identical with density of length of the carbon nano rod of growing in the hole of metal foam in each skeleton unit, the length of the carbon nano rod of growing in the hole of metal foam in same skeleton unit is identical with density), (that is to say different with density of length of the carbon nano rod of growing in the hole of metal foam in each skeleton unit, the length of the carbon nano rod of growing in the hole of metal foam in different skeleton units is different with density), and from the entrance of hollow continuous skeleton, the mode that some skeleton units increase successively with length and the density of carbon nano rod is arranged, such setting can prevent the generation that absorption is stopped up, and eliminate thermal resistance.
Finally, CO
2adsorbent is no matter be a kind of or two kinds, as long as selected carbon nano rod, will consider the angle of carbon nano rod and metal foam mesopore inwall, this is because longitudinal heat conductivility of carbon nano rod and metal foam is relatively good, can in time the transfer of heat producing in adsorption process be lost in air, be conducive to CO absorption
2that is to say that the hole inwall angle heat-conducting effect in 90 ° of carbon nano rod and metal foam is best in theory, but generally the hole inwall angle of carbon nano rod and metal foam is made as to 30 °～150 ° in reality, in this angular range, it is best that longitudinal heat-conducting effect of carbon nano rod can be brought into play.
Claims (10)
1. a metallic foam support CO
2adsorbent, is characterized in that: comprise the hollow continuous skeleton consisting of metal foam, grow or be filled with thermal conductivity factor at the CO of 0.06～0.12W/mK in the hole of described metal foam
2adsorbent.
2. metallic foam support CO according to claim 1
2adsorbent, is characterized in that: described CO
2adsorbent is one or both in carbon nano rod, solid amine particle, metallic organic framework compound, and solid amine is particles filled in the hole of metal foam, carbon nano rod and metallic organic framework compound are all grown in the hole of metal foam, and the hole inwall angle of carbon nano rod and metal foam is 30 °～150 °.
3. metallic foam support CO according to claim 2
2adsorbent, is characterized in that: described CO
2when adsorbent is carbon nano rod, hollow continuous skeleton is divided into some sections in the axial direction, in each section of hollow continuous skeleton, in the hole of metal foam, the length of the carbon nano rod of growth is identical, and from the entrance of hollow continuous skeleton, the mode that some sections of hollow continuous skeletons increase successively with carbon nano rod length is arranged.
4. metallic foam support CO according to claim 3
2adsorbent, is characterized in that: the porosity of described metal foam is 0.90%～0.97%, and aperture is at 0.7 μ m～3mm, and the length of carbon nano rod is 0.2 μ m～200 μ m, and diameter is 50～100nm.
5. metallic foam support CO according to claim 2
2adsorbent, is characterized in that: described CO
2when adsorbent is two kinds in carbon nano rod, solid amine particle, metallic organic framework compound, hollow continuous skeleton is divided into leading portion hollow continuous skeleton (D) and back segment hollow continuous skeleton (E) in the axial direction, grows or fill a kind of CO in each hole of metal foam
2adsorbent, and leading portion hollow continuous skeleton (D) and back segment hollow continuous skeleton (E) start to arrange successively from the entrance of hollow continuous skeleton, be arranged in leading portion hollow continuous skeleton (D) metal foam hole growth or fill a kind of CO
2adsorbent, the hole that is arranged in the metal foam of back segment hollow continuous skeleton (E) is filled another kind of CO
2adsorbent.
6. metallic foam support CO according to claim 5
2adsorbent, is characterized in that: described CO
2adsorbent is carbon nano rod and solid amine particle, and the hole that is arranged in the intraskeletal metal foam of the leading portion hollow continuous carbon nano rod of growing, and the hole that is arranged in the metal foam of back segment hollow continuous skeleton (E) is filled solid amine particle.
7. metallic foam support CO according to claim 6
2adsorbent, it is characterized in that: the porosity of described leading portion hollow continuous skeleton (D) and the interior metal foam of back segment hollow continuous skeleton (E) is 0.90%～0.97%, the aperture of the interior metal foam of leading portion hollow continuous skeleton (D) is 0.7 μ m～2.0mm, and the length of carbon nano rod is 20nm～0.3 μ m; The aperture of the interior metal foam of back segment hollow continuous skeleton (E) is 3mm～5mm, and the particle diameter of solid amine particle is 0.3～1.5mm, specific area >100m
2/ mg.
8. according to the metallic foam support CO described in claim 6 or 7
2adsorbent, it is characterized in that: described leading portion hollow continuous skeleton D is divided into some skeleton units in the axial direction, the length of the carbon nano rod of growing in the hole of metal foam in each skeleton unit is identical with density, and from the entrance of hollow continuous skeleton, the mode that some skeleton units increase successively with length and the density of carbon nano rod is arranged.
9. metallic foam support CO according to claim 2
2adsorbent, is characterized in that: described metallic organic framework compound is Cu-BTC, Ni-DOBDC or ZIF-8.
10. metallic foam support CO according to claim 1
2adsorbent, is characterized in that: the material of described metal foam is copper, nickel or iron.
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| CN201410359743.8A CN104148036B (en) | 2014-07-25 | 2014-07-25 | A kind of metallic foam support CO2Adsorbent |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104959115A (en) * | 2015-06-11 | 2015-10-07 | 中国科学院山西煤炭化学研究所 | Preparation method of nanoscale metal-organic framework compound |
| CN107754766A (en) * | 2017-11-28 | 2018-03-06 | 广西大学 | A kind of MOF perforated foams and preparation method thereof |
| CN108993414A (en) * | 2018-07-25 | 2018-12-14 | 南京工业大学 | A kind of preparation method of MOFs- foam metal compound adsorbent |
| CN109012162A (en) * | 2018-08-29 | 2018-12-18 | 西北工业大学 | A kind of multistage removal indoor formaldehyde device of band sterilization |
| CN111871007A (en) * | 2020-07-24 | 2020-11-03 | 北方工业大学 | Preparation method of sponge aluminum-based composite material for oil-gas separation |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000107595A (en) * | 1998-10-06 | 2000-04-18 | Matsushita Refrig Co Ltd | Carbon dioxide adsorbent, foamed heat insulating material and heat insulating box body |
| US7011760B2 (en) * | 2001-12-21 | 2006-03-14 | Battelle Memorial Institute | Carbon nanotube-containing structures, methods of making, and processes using same |
| CN102198360A (en) * | 2011-05-26 | 2011-09-28 | 清华大学 | Process and equipment for removing CO2 in flue gas by utilizing amine solid adsorbent |
| US20120006193A1 (en) * | 2010-07-09 | 2012-01-12 | Subir Roychoudhury | Adsorption-desorption apparatus and process |
| CN102964365A (en) * | 2012-03-16 | 2013-03-13 | 长春工业大学 | Zinc furandicarboxylic acid metal-organic framework material with pore structure and preparation method thereof |
| CN103372420A (en) * | 2012-04-20 | 2013-10-30 | 南京理工大学 | Metal organic frameworks (MOFs)-amine modified/oxidized graphite composite material and preparation method thereof |
-
2014
- 2014-07-25 CN CN201410359743.8A patent/CN104148036B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000107595A (en) * | 1998-10-06 | 2000-04-18 | Matsushita Refrig Co Ltd | Carbon dioxide adsorbent, foamed heat insulating material and heat insulating box body |
| US7011760B2 (en) * | 2001-12-21 | 2006-03-14 | Battelle Memorial Institute | Carbon nanotube-containing structures, methods of making, and processes using same |
| US20120006193A1 (en) * | 2010-07-09 | 2012-01-12 | Subir Roychoudhury | Adsorption-desorption apparatus and process |
| CN102198360A (en) * | 2011-05-26 | 2011-09-28 | 清华大学 | Process and equipment for removing CO2 in flue gas by utilizing amine solid adsorbent |
| CN102964365A (en) * | 2012-03-16 | 2013-03-13 | 长春工业大学 | Zinc furandicarboxylic acid metal-organic framework material with pore structure and preparation method thereof |
| CN103372420A (en) * | 2012-04-20 | 2013-10-30 | 南京理工大学 | Metal organic frameworks (MOFs)-amine modified/oxidized graphite composite material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| ZHIGUO QU 等: "Experimental study of air natural convection on metallic foam-sintered plate", 《INTERNATIONAL JOURNAL OF HEAT AND FLUID FLOW》, 31 December 2012 (2012-12-31) * |
| 黄小兵 等: "泡沫镍负载碳纳米管的工艺研究", 《电镀与环保》, vol. 33, no. 3, 31 May 2013 (2013-05-31) * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104959115A (en) * | 2015-06-11 | 2015-10-07 | 中国科学院山西煤炭化学研究所 | Preparation method of nanoscale metal-organic framework compound |
| CN107754766A (en) * | 2017-11-28 | 2018-03-06 | 广西大学 | A kind of MOF perforated foams and preparation method thereof |
| CN108993414A (en) * | 2018-07-25 | 2018-12-14 | 南京工业大学 | A kind of preparation method of MOFs- foam metal compound adsorbent |
| CN109012162A (en) * | 2018-08-29 | 2018-12-18 | 西北工业大学 | A kind of multistage removal indoor formaldehyde device of band sterilization |
| CN111871007A (en) * | 2020-07-24 | 2020-11-03 | 北方工业大学 | Preparation method of sponge aluminum-based composite material for oil-gas separation |
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