CN104099592A - Surface treating agent for smooth foamless aluminum alloy - Google Patents

Surface treating agent for smooth foamless aluminum alloy Download PDF

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Publication number
CN104099592A
CN104099592A CN201410276861.2A CN201410276861A CN104099592A CN 104099592 A CN104099592 A CN 104099592A CN 201410276861 A CN201410276861 A CN 201410276861A CN 104099592 A CN104099592 A CN 104099592A
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China
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parts
aluminum alloy
raw material
mixed
stirring
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CN201410276861.2A
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Chinese (zh)
Inventor
徐泽军
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Sharp Exhibition Tongling Technology Co Ltd
Ruizhan Tongling Technologies Co Ltd
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Ruizhan Tongling Technologies Co Ltd
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Priority to CN201410276861.2A priority Critical patent/CN104099592A/en
Publication of CN104099592A publication Critical patent/CN104099592A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a surface treating agent for smooth foamless aluminum alloy. The surface treating agent comprises the following raw materials in parts by weight: 0.8-2 parts of hydroxyethyl oleic imidazoline betaine, 1-2 parts of locust bean gum, 0.1-0.2 part of neodymium acetate, 1-2 parts of ethylene diamine tetraacetic acid, 0.3-1 part of antimony oxide, 1-2 parts of sodium tungstate, 2-3 parts of magnesium nitrate, 0.3-1 part of graphite powder, 0.1-0.2 part of dioctyl sebacate, 2-3 parts of 1, 4-cyclohexanedimethanol, 2-3 parts of a coalescing agent, 8-12 parts of 3-amino propyl trimethoxy silane, 6-10 parts of silane coupling agent KH570, and 110-140 parts of de-ionized water. The surface treating agent can form a stable and even coating film on the surface of the aluminum alloy; and the coating film is foamless and smooth, and has the advantages of strong compactness, good leakage resistance, strong corrosion and bacterial resistance and good easy cleanness.

Description

A kind of smooth still aluminum alloy surface treatment agent
?
Technical field
The present invention relates generally to field of surface treatment, relates in particular to a kind of smooth still aluminum alloy surface treatment agent.
Background technology
The surface treatment method of aluminium alloy has a lot, as Physical, chemical method, physico-chemical processes and synthetic method.Conventional method is anonizing now, form conversion film by electrochemical method in aluminum alloy surface, although this method can improve the smooth still performance of aluminium alloy, but the ability that it conforms, transform rete even not, easily come off, wear resisting property does not improve, and although traditional phosphate conversion and chromating process for treating surface can obtain good effect, but contain zinc in the waste liquid of discharging in treating processes, manganese, nickel, the heavy metal ion such as chromium and the sub-smooth still carcinogenic substance that waits, environmental pollution is very serious, and metallic surface silanization treatment technology is due to the material of hurm involved environment not, energy consumption in production process is low, technical applications is extensive, being considered to be expected to replace phosphate conversion processes and chromating processing, that recent development direction is protected separately in metallic surface.
Summary of the invention
The object of the invention is just to provide a kind of smooth still aluminum alloy surface treatment agent.
The present invention is achieved by the following technical solutions:
A kind of smooth still aluminum alloy surface treatment agent, it is made up of the raw material of following weight parts:
Hydroxyethyl oleic imidazolinone trimethyl-glycine 0.8-2, Viscogum BE 1-2, acetic acid neodymium 0.1-0.2, disodium ethylene diamine tetraacetate 1-2, weisspiessglanz 0.3-1, sodium wolframate 1-2, magnesium nitrate 2-3, Graphite Powder 99 0.3-1, SA dioctyl ester 0.1-0.2,1,4 cyclohexane dimethanol 2-3, film coalescence aid 2-3,3-TSL 8330 8-12, silane coupling agent KH570 6-10, deionized water 110-140;
Described film coalescence aid is made up of the raw material of following weight parts:
Acrylate and vinyl acetate emulsion 25-30, tea saponin 1-2, pyrrolidone hydroxy acid sodium 1-2, hydroxy silicon oil 0.1-0.3, trimethylene phosphonic 2-3, allyl polyglycol 0.7-1, Zinic stearas 0.3-0.4,1,2 dimethylimidazole 0.2-0.3, deionized water 80-90;
Pyrrolidone hydroxy acid sodium is joined in acrylate and vinyl acetate emulsion, add hydroxy silicon oil, 100-200 rev/min of dispersed with stirring 3-5 minute;
Tea saponin is mixed with allyl polyglycol, add the 40-60% of above-mentioned deionized water weight, at 60-70 DEG C, be uniformly mixed 6-10 minute, add Zinic stearas, 100-200 rev/min of dispersed with stirring 4-6 minute;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 400-600 rev/min of dispersed with stirring 20-30 minute, obtains described film coalescence aid.
A preparation method for smooth still aluminum alloy surface treatment agent, comprises the following steps:
Weisspiessglanz, sodium wolframate, magnesium nitrate, Graphite Powder 99 are mixed, and ball milling adds SA dioctyl ester after evenly, stirs 10-13 minute at 60-70 DEG C;
Viscogum BE is mixed with disodium ethylene diamine tetraacetate, join in above-mentioned deionized water, after stirring, add hydroxyethyl oleic imidazolinone trimethyl-glycine, stir;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 400-600 rev/min of dispersed with stirring 1-2 hour, obtains described smooth still aluminum alloy surface treatment agent.
Advantage of the present invention is:
Surface treatment agent of the present invention can form stable uniform film in aluminum alloy surface, and film is still smooth, and compactness is strong, and leakage resistance is good, and anti-corrosive antibacterial is strong, and property easy to clean is good.
Embodiment
Embodiment 1
A kind of smooth still aluminum alloy surface treatment agent, it is made up of the raw material of following weight parts:
Hydroxyethyl oleic imidazolinone trimethyl-glycine 0.8, Viscogum BE 2, acetic acid neodymium 0.2, disodium ethylene diamine tetraacetate 2, weisspiessglanz 0.3-1, sodium wolframate 1-2, magnesium nitrate 2-3, Graphite Powder 99 0.3, SA dioctyl ester 0.2,1,4 cyclohexane dimethanol 2, film coalescence aid 2,3-TSL 8330 12, silane coupling agent KH570 10, deionized water 140;
Described film coalescence aid is made up of the raw material of following weight parts:
Acrylate and vinyl acetate emulsion 30, tea saponin 1, pyrrolidone hydroxy acid sodium 2, hydroxy silicon oil 0.3, trimethylene phosphonic 2, allyl polyglycol 0.7, Zinic stearas 0.4,1,2 dimethylimidazole 0.3, deionized water 90;
Pyrrolidone hydroxy acid sodium is joined in acrylate and vinyl acetate emulsion, add hydroxy silicon oil, 200 revs/min of dispersed with stirring 3-5 minute;
Tea saponin is mixed with allyl polyglycol, add 60% of above-mentioned deionized water weight, at 70 DEG C, be uniformly mixed 10 minutes, add Zinic stearas, 200 revs/min of dispersed with stirring 6 minutes;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 600 revs/min of dispersed with stirring 30 minutes, obtain described film coalescence aid.
A preparation method for smooth still aluminum alloy surface treatment agent, comprises the following steps:
Weisspiessglanz, sodium wolframate, magnesium nitrate, Graphite Powder 99 are mixed, and ball milling adds SA dioctyl ester after evenly, stirs 13 minutes at 70 DEG C;
Viscogum BE is mixed with disodium ethylene diamine tetraacetate, join in above-mentioned deionized water, after stirring, add hydroxyethyl oleic imidazolinone trimethyl-glycine, stir;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 600 revs/min of dispersed with stirring 2 hours, obtain described smooth still aluminum alloy surface treatment agent.
Using method:
The Al alloy parts carrying out after degreasing, washing is placed in to surface treatment agent of the present invention and floods, working temperature 20-40 DEG C, working hour 0.5-1min.
Performance test:
Getting the aluminum alloy plate materials of surface treatment agent processing of the present invention tests, the specification of this sheet material is 80mm × 100mm × 4mm, by this sheet material lateral dissection, carry out spray test, agents useful for same is that concentration is 5% sodium chloride solution, test period 300 hours, measures the bubbling width forming in line of cut one side, and result bubbling width is 0;
Salt tolerance:
It is in 5% sodium chloride solution that this sheet material is immersed in to concentration, soaks 300 hours, and material surface is substantially unchanged, soaks 300 hours, occurs without rust staining;
Acid resistance:
This sheet material is sprayed to experiment with the 0.05mol/l sulfuric acid that temperature is 23 DEG C, and experimental period 20 hours, cleans with clear water, and indoor placement 2 hours, coating surface was unchanged, and nothing is bubbled, nothing comes off, nothing is damaged;
Stripper-resistance:
The paste that this plate surface is coated with to last layer 2-3mm, being put into temperature is 50 DEG C, and in the watertight chest that relative humidity is 90-96%, experimental period 24 hours, cleans with clear water after taking-up, and coating surface is without bubbling, without coming off, without damaged.

Claims (2)

1. a smooth still aluminum alloy surface treatment agent, is characterized in that what it was made up of the raw material of following weight parts:
Hydroxyethyl oleic imidazolinone trimethyl-glycine 0.8-2, Viscogum BE 1-2, acetic acid neodymium 0.1-0.2, disodium ethylene diamine tetraacetate 1-2, weisspiessglanz 0.3-1, sodium wolframate 1-2, magnesium nitrate 2-3, Graphite Powder 99 0.3-1, SA dioctyl ester 0.1-0.2,1,4 cyclohexane dimethanol 2-3, film coalescence aid 2-3,3-TSL 8330 8-12, silane coupling agent KH570 6-10, deionized water 110-140;
Described film coalescence aid is made up of the raw material of following weight parts:
Acrylate and vinyl acetate emulsion 25-30, tea saponin 1-2, pyrrolidone hydroxy acid sodium 1-2, hydroxy silicon oil 0.1-0.3, trimethylene phosphonic 2-3, allyl polyglycol 0.7-1, Zinic stearas 0.3-0.4,1,2 dimethylimidazole 0.2-0.3, deionized water 80-90;
Pyrrolidone hydroxy acid sodium is joined in acrylate and vinyl acetate emulsion, add hydroxy silicon oil, 100-200 rev/min of dispersed with stirring 3-5 minute;
Tea saponin is mixed with allyl polyglycol, add the 40-60% of above-mentioned deionized water weight, at 60-70 DEG C, be uniformly mixed 6-10 minute, add Zinic stearas, 100-200 rev/min of dispersed with stirring 4-6 minute;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 400-600 rev/min of dispersed with stirring 20-30 minute, obtains described film coalescence aid.
2. a preparation method for smooth still aluminum alloy surface treatment agent as claimed in claim 1, is characterized in that comprising the following steps:
Weisspiessglanz, sodium wolframate, magnesium nitrate, Graphite Powder 99 are mixed, and ball milling adds SA dioctyl ester after evenly, stirs 10-13 minute at 60-70 DEG C;
Viscogum BE is mixed with disodium ethylene diamine tetraacetate, join in above-mentioned deionized water, after stirring, add hydroxyethyl oleic imidazolinone trimethyl-glycine, stir;
Above-mentioned each raw material after treatment is mixed with the each raw material of residue, and 400-600 rev/min of dispersed with stirring 1-2 hour, obtains described smooth still aluminum alloy surface treatment agent.
CN201410276861.2A 2014-06-19 2014-06-19 Surface treating agent for smooth foamless aluminum alloy Pending CN104099592A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410276861.2A CN104099592A (en) 2014-06-19 2014-06-19 Surface treating agent for smooth foamless aluminum alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410276861.2A CN104099592A (en) 2014-06-19 2014-06-19 Surface treating agent for smooth foamless aluminum alloy

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CN104099592A true CN104099592A (en) 2014-10-15

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086720A (en) * 2015-07-11 2015-11-25 合肥正浩机械科技有限公司 Anticorrosive metal surface treating agent and preparation method thereof
CN105274516A (en) * 2015-11-04 2016-01-27 合肥海源机械有限公司 Micro-emulsified forming liquid for cured film of aluminum alloy and preparation method of micro-emulsified forming liquid
CN107829086A (en) * 2017-11-08 2018-03-23 安徽腾龙泵阀制造有限公司 A kind of anticorrosion treatment technology of pump aluminium alloy part

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Publication number Priority date Publication date Assignee Title
JP2001288580A (en) * 2000-03-31 2001-10-19 Nippon Parkerizing Co Ltd Surface treating method for magnesium alloy and magnesium alloy member
JP2002322570A (en) * 2001-04-25 2002-11-08 Hitachi Ltd Highly corrosion resistant aluminum material and surface treatment method therefor
CN1733970A (en) * 1997-10-31 2006-02-15 铃木株式会社 Sliding memberss
WO2006126394A1 (en) * 2005-05-23 2006-11-30 Nihon Parkerizing Co., Ltd. Aqueous surface treating agent for precoated metal material, surface treatment method and method for producing precoated metal material
CN101476118A (en) * 2009-01-21 2009-07-08 湖南大学 Universal metallic surface silanization treating agent, preparation and use thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1733970A (en) * 1997-10-31 2006-02-15 铃木株式会社 Sliding memberss
JP2001288580A (en) * 2000-03-31 2001-10-19 Nippon Parkerizing Co Ltd Surface treating method for magnesium alloy and magnesium alloy member
JP2002322570A (en) * 2001-04-25 2002-11-08 Hitachi Ltd Highly corrosion resistant aluminum material and surface treatment method therefor
WO2006126394A1 (en) * 2005-05-23 2006-11-30 Nihon Parkerizing Co., Ltd. Aqueous surface treating agent for precoated metal material, surface treatment method and method for producing precoated metal material
CN101476118A (en) * 2009-01-21 2009-07-08 湖南大学 Universal metallic surface silanization treating agent, preparation and use thereof

Non-Patent Citations (1)

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Title
王雷等: "镀锌层无机物与有机物复合无铬钝化研究进展", 《电镀与精饰》, vol. 33, no. 3, 31 March 2011 (2011-03-31), pages 22 - 26 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086720A (en) * 2015-07-11 2015-11-25 合肥正浩机械科技有限公司 Anticorrosive metal surface treating agent and preparation method thereof
CN105274516A (en) * 2015-11-04 2016-01-27 合肥海源机械有限公司 Micro-emulsified forming liquid for cured film of aluminum alloy and preparation method of micro-emulsified forming liquid
CN107829086A (en) * 2017-11-08 2018-03-23 安徽腾龙泵阀制造有限公司 A kind of anticorrosion treatment technology of pump aluminium alloy part

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Application publication date: 20141015