CN104095288A - Additive for preparing cigarette paper for paper filter tip - Google Patents
Additive for preparing cigarette paper for paper filter tip Download PDFInfo
- Publication number
- CN104095288A CN104095288A CN201410314176.4A CN201410314176A CN104095288A CN 104095288 A CN104095288 A CN 104095288A CN 201410314176 A CN201410314176 A CN 201410314176A CN 104095288 A CN104095288 A CN 104095288A
- Authority
- CN
- China
- Prior art keywords
- starch
- additive
- paper
- filter tip
- gum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
An additive for preparing cigarette paper for a paper filter tip is characterized in that the additive is prepared by taking natural gelatine and cellulose or starch as raw materials through esterification reaction under the effect of a catalyst; the method comprises the specific steps of adding the raw materials into glacial acetaic acid, wherein the mass ratio of the raw materials to the glacial acetaic acid is 0.1-0.5; adding an esterifying agent with the weigh being 2-5 times that of the raw materials into the reaction system within 1 hour, then adding the catalyst with the weight being 0.05-0.5% that of the raw materials, heating to 60-90 DEG C, reacting for 3-10 hours, and performing suction filtration, washing with water and drying after the reaction is finished, thus obtaining the additive product. The additive has the advantages that the additive takes the natural gelatine, cellulose and starch as the raw materials, the raw materials are wide in source, the preparation is simple, and green and environment-friendly effects are realized. The additive is used in the papermaking production of filter tip paper, the operation is simple and convenient, and the smoking flavor and the sensory quality of paper filter tip cigarettes can be effectively improved due to the use of the additive.
Description
technical fieldthe invention belongs to technical field of cigarettes, a kind of for the preparation of the additive of cigarette paper for paper filter tip specifically, this additive is the production with cigarette paper for paper filter tip, can effectively improve paper filter tip type cigarette suction taste, improve aesthetic quality, and such additive raw material wide material sources, preparation are simple, environmental protection.
Background technology
Existing cigarette filter is mainly that acetate fiber prepares, and still, along with the increase of domestic cigarette output, the supply of acetate fiber starts to occur anxiety to a certain extent.Therefore, be necessary that exploitation can substitute the new filter tip material of cellulose acetate filter rod, and paper filter tip is a kind of filter tip material with huge applications potentiality, in the twenties in 20th century, there is in the world the filter tip with wadding or wadding and cellulose soft packing manufacture, to 20th century six the seventies, all cigarette that Britain produces all adopt binary combined filter tip, i.e. one end of filter tip contact pipe tobacco is one section of filter tip of being made by embossed paper.To the end of the seventies, along with the appearance of KDF2 filter rod forming machine, most of companies start oneself and produce acetate fiber filter tip, have now just greatly reduced the use of embossed paper filter tip.At the end of the eighties and the beginning of the nineties, also there is analogue in China.Compare with acetate fiber filter tip, paper filter tip has good tar filter capacity and lower price.Paper filter tip exists some very large shortcomings also: " the paper taste " of paper filter tip is heavier, can exert an influence to cigarette smoke, affects the suction taste of cigarette, particularly more obvious in low-coke tar cigarette.Paper filter tip cigarette is in aspiration procedure in addition, and the easy deliquescing of paper produces obvious heat and subsides, and stain variable color is serious.
For paper filter tip, patent CN 1279586 A have reported a kind of wooden fiber paper adhesive-applied filter rod for cigarettes and preparation method thereof, and it is to adopt wood fibre paper as filtering material, in filter stick formation process, applies polyvinyl acetate adhesive, improve cigarette jealous, improved the hardness of filter stick.Patent CN2909863Y has reported a kind of paper and the fine binary compound filter candle of vinegar, it consists of paper and the fine binary composite filter element of vinegar, interior integument and outer wrapping layer, paper is by paper filter element section the engage round clava that form alternate with acetate fiber filter core section with the fine binary composite filter element of vinegar, interior integument is wrapped on paper and the fine binary composite filter element of vinegar, and outer wrapping layer is wrapped on interior integument.It has advantages of the good filtration effect of its made cigarette filter.The people such as Yao Ermin have reported fine two composite filter tips of a kind of tea matter paper-vinegar, and this composite filter tip can reduce cigarette smoke tar, nicotine, optionally reduces flue gas free radical, TSNAs, PAHs, phenols component, and does not affect the organoleptic quality of cigarette.Changde Furong Daya Chemical Fibre Co., Ltd. develops the fine binary compound filter candle of a kind of paper/vinegar, this filter stick application to some extent on white sand cigarette at present.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of additive is provided, in production at paper filter tip with cigarette paper, add use, the use of such additive can effectively improve suction taste, the raising aesthetic quality of paper filter tip type cigarette, and such additive preparation is simple, environmental protection, with low cost.
The object of the invention is to be achieved through the following technical solutions and obtain:
An additive for the preparation of paper filter tip with cigarette paper, is to take natural plant, cellulose or starch as raw material, under catalyst action, by esterification, is prepared from, and concrete grammar is as follows:
Raw material is joined in glacial acetic acid, the mass ratio of raw material and glacial acetic acid is 0.1-0.5, the esterifying agent of in 1h, raw material weight 2-5 doubly being measured joins in reaction system, then the catalyst that adds raw material weight 0.05-0.5%, and be warming up to 60-90 ℃ reaction 3-10h, after reaction finishes, suction filtration, wash with water, the dry additive product that is.
Described catalyst is methanesulfonic acid or p-methyl benzenesulfonic acid.
Described esterifying agent is acetic anhydride or vinylacetate.
Described natural plant comprises pectin, gelatin, xanthans, agar, sodium alginate, carragheen, guar gum, casein, locust bean gum, tamarind gum, linseed glue, Arabic gum, Sunset Abelmoschus Root glue, Karaya Gum, artemisia seed gum, trigonella bean gum, sesbania gum, the sub-glue of pawpaw, thorn kidney bean glue, ghatti gum, loose glue, curdlan.
Described starch comprises that farina, starch from sweet potato, tapioca, green starch, pea starch, sorghum starch, bajiao banana starch, sago starch, wheaten starch, barley starch, cornstarch, rice starch and waxy starch are as waxy corn starch, Waxy Rice Starch, wax sorghum starch.
Invention mechanism of the present invention is that cellulose acetate filter is to take cellulose and acetic anhydride as raw material obtains cellulose acetate by reaction, then prepares through spinning; And in natural plant and starch molecular structure, all contain a large amount of hydroxyls, there is same or analogous basic structural unit with cellulose, by natural plant, cellulose and starch are carried out to preparing acetic acid esterified modified, obtained having with cellulose acetate filter the modified product of similar molecular characterization, be applied to filter tip paper using, this is conducive to promote the aesthetic quality of paper filter tip cigarette.
Additive in the present invention is generally in the copy paper stage, and along with other additive adds together, addition is the 0.5%-5% that paper is heavy.
Advantage of the present invention is that to take natural plant, cellulose, starch be raw material to such additive, raw material sources are extensive, preparation is simple, and such additive is to use in the paper production of filter tip paper using, easy and simple to handle, and the use of such additive can effectively improve suction taste, the raising aesthetic quality of paper filter tip type cigarette.
the specific embodiment
Below in conjunction with embodiment, this is described further invention, but the scope of the invention is not limited to these embodiment.
embodiment 1100g guar gum is joined in 550g glacial acetic acid, in 1h, 300g acetic anhydride is joined in reaction system, then add 0.1g methanesulfonic acid and be warmed up to 75 ℃ of reaction 4h, after reaction finishes, suction filtration, wash with water, dry can obtain product.
embodiment 2100g carragheen is joined in 350g glacial acetic acid, in 1h, 450g vinylacetate is joined in reaction system, then add 0.2g p-methyl benzenesulfonic acid and be warmed up to 80 ℃ of reaction 6h, after reaction finishes, suction filtration, wash with water, dry can obtain product.
embodiment 3100g cellulose is joined in 420g glacial acetic acid, in 1h, 390g vinylacetate is joined in reaction system, then add 0.15g methanesulfonic acid and be warmed up to 70 ℃ of reaction 8h, after reaction finishes, suction filtration, wash with water, dry can obtain product.
embodiment 4100g wheaten starch is joined in 400g glacial acetic acid, in 1h, 400g acetic anhydride is joined in reaction system, then add 0.3g p-methyl benzenesulfonic acid and be warmed up to 70 ℃ of reaction 7h, after reaction finishes, suction filtration, wash with water, dry can obtain product.
embodiment 5100g rice starch is joined in 330g glacial acetic acid, in 1h, 450g vinylacetate is joined in reaction system, then add 0.45g methanesulfonic acid and be warmed up to 70 ℃ of reaction 9h, after reaction finishes, suction filtration, wash with water, dry can obtain product.
Applicant is applied to paper filter tip type cigarette (add in the copy paper stage, addition accounts for paper and weighs 2%) by 5 kinds of embodiment provided by the present invention, and has carried out contrast with plain pape filter tip type cigarette and the fine type cigarette of normal vinegar and smoked panel test, and the results are shown in Table 1.
The sensory evaluation of the different filter tip type of table 1 cigarette
| Cigarette | Sensory evaluation |
| Contrast cigarette 1 | Paper taste is heavier, and xylon gas and assorted gas are heavier, and flue gas is more coarse, stimulates, and pleasant impression is unclean |
| Contrast cigarette 2 | Fragrance is plentiful, fine and smooth, and flue gas is coordinated, and micro-have assorted gas, and non-stimulated, pleasant impression is comfortable, cleaner |
| Test cigarette 1 | Fragrance is sufficient, and flue gas is coordinated, and micro-have assorted gas, slightly stimulate, pleasant impression more only, more comfortable |
| Test cigarette 2 | Fragrance is sufficient, finer and smoother, and flue gas is coordinated, and micro-have assorted gas, slightly stimulate, pleasant impression more only, more comfortable |
| Test cigarette 3 | Fragrance is sufficient, and flue gas is coordinated, and micro-have assorted gas, slightly stimulate, pleasant impression more only, more comfortable |
| Test cigarette 4 | Fragrance is sufficient, finer and smoother, and flue gas is coordinated, and micro-have assorted gas, slightly stimulate, pleasant impression more only, more comfortable |
| Test cigarette 5 | Fragrance is plentiful, fine and smooth, and flue gas is coordinated, and micro-have assorted gas, slightly stimulate, pleasant impression more only, more comfortable |
Note: contrast cigarette 1 is plain pape filter tip cigarette, contrast cigarette 2 is normal cellulose acetate filter cigarette, test cigarette 1 is for being added with the paper filter tip cigarette of additive in embodiment 1, test cigarette 2 is for being added with the paper filter tip cigarette of additive in embodiment 2, test cigarette 3 is for being added with the paper filter tip cigarette of additive in embodiment 3, test cigarette 4 is for being added with the paper filter tip cigarette of additive in embodiment 4, and test cigarette 5 is for being added with the paper filter tip cigarette of additive in embodiment 5
As can be seen from Table 1, compare with plain pape filter tip cigarette, its sensory evaluation of paper filter tip test cigarette that is added with additive has clear improvement, and very close with common cellulose acetate filter Sensory Quality of Cigarette.
Claims (5)
1. for the preparation of paper filter tip, use an additive for cigarette paper, it is characterized in that: be to take natural plant, cellulose or starch as raw material, under catalyst action, by esterification, be prepared from, concrete grammar is as follows:
Raw material is joined in glacial acetic acid, the mass ratio of raw material and glacial acetic acid is 0.1-0.5, the esterifying agent of in 1h, raw material weight 2-5 doubly being measured joins in reaction system, then the catalyst that adds raw material weight 0.05-0.5%, and be warming up to 60-90 ℃ reaction 3-10h, after reaction finishes, suction filtration, wash with water, the dry additive product that is.
2. the additive of using cigarette paper for the preparation of paper filter tip according to claim 1, is characterized in that: described catalyst is methanesulfonic acid or p-methyl benzenesulfonic acid.
3. the additive of using cigarette paper for the preparation of paper filter tip according to claim 1, is characterized in that: described esterifying agent is acetic anhydride or vinylacetate.
4. the additive of using cigarette paper for the preparation of paper filter tip according to claim 1, is characterized in that: described natural plant comprises pectin, gelatin, xanthans, agar, sodium alginate, carragheen, guar gum, casein, locust bean gum, tamarind gum, linseed glue, Arabic gum, Sunset Abelmoschus Root glue, Karaya Gum, artemisia seed gum, trigonella bean gum, sesbania gum, the sub-glue of pawpaw, thorn kidney bean glue, ghatti gum, loose glue, curdlan.
5. the additive of using cigarette paper for the preparation of paper filter tip according to claim 1, is characterized in that: described starch comprises that farina, starch from sweet potato, tapioca, green starch, pea starch, sorghum starch, bajiao banana starch, sago starch, wheaten starch, barley starch, cornstarch, rice starch and waxy starch are as waxy corn starch, Waxy Rice Starch, wax sorghum starch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410314176.4A CN104095288A (en) | 2014-07-04 | 2014-07-04 | Additive for preparing cigarette paper for paper filter tip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410314176.4A CN104095288A (en) | 2014-07-04 | 2014-07-04 | Additive for preparing cigarette paper for paper filter tip |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104095288A true CN104095288A (en) | 2014-10-15 |
Family
ID=51664121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410314176.4A Pending CN104095288A (en) | 2014-07-04 | 2014-07-04 | Additive for preparing cigarette paper for paper filter tip |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104095288A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109275955A (en) * | 2018-08-10 | 2019-01-29 | 河南中烟工业有限责任公司 | A kind of additives of filter tip and its preparation method and application increasing cigarette filter filter capacity |
| CN113876022A (en) * | 2021-09-20 | 2022-01-04 | 河南中烟工业有限责任公司 | High-molecular latent-fragrance slow-release material and application thereof in heating cigarettes |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009075652A1 (en) * | 2007-12-11 | 2009-06-18 | Nanyang Technological University | Hollow multi-layered microspheres for delivery of hydrophilic active compounds |
| CN102597008A (en) * | 2009-10-09 | 2012-07-18 | 罗盖特兄弟公司 | Method for preparing acetylated derivatives of an amylaceous material |
| CN103720046A (en) * | 2014-01-15 | 2014-04-16 | 湖北金叶玉阳化纤有限公司 | Tobacco filter tip stick of sugar alcohol sweetening agent and production process thereof |
| US20140113826A1 (en) * | 2012-10-24 | 2014-04-24 | Celanese Acetate Llc | Polysaccharide ester microspheres and methods and articles relating thereto |
-
2014
- 2014-07-04 CN CN201410314176.4A patent/CN104095288A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009075652A1 (en) * | 2007-12-11 | 2009-06-18 | Nanyang Technological University | Hollow multi-layered microspheres for delivery of hydrophilic active compounds |
| CN102597008A (en) * | 2009-10-09 | 2012-07-18 | 罗盖特兄弟公司 | Method for preparing acetylated derivatives of an amylaceous material |
| US20140113826A1 (en) * | 2012-10-24 | 2014-04-24 | Celanese Acetate Llc | Polysaccharide ester microspheres and methods and articles relating thereto |
| CN103720046A (en) * | 2014-01-15 | 2014-04-16 | 湖北金叶玉阳化纤有限公司 | Tobacco filter tip stick of sugar alcohol sweetening agent and production process thereof |
Non-Patent Citations (1)
| Title |
|---|
| 朱颖先等: "高取代度淀粉醋酸酯的制备", 《应用化学》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109275955A (en) * | 2018-08-10 | 2019-01-29 | 河南中烟工业有限责任公司 | A kind of additives of filter tip and its preparation method and application increasing cigarette filter filter capacity |
| CN113876022A (en) * | 2021-09-20 | 2022-01-04 | 河南中烟工业有限责任公司 | High-molecular latent-fragrance slow-release material and application thereof in heating cigarettes |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108451001B (en) | Dry-process reconstituted tobacco for heating non-combustible cigarettes and preparation method thereof | |
| WO2017181684A1 (en) | Method for manufacturing heat-not-burn tobacco cigarette | |
| CN102277780B (en) | Production method of tobacco sheet cigarette paper | |
| CN109393543A (en) | A kind of ultra-micro powder plantflakesare and preparation method thereof | |
| WO2017181685A1 (en) | Method for manufacturing heat-not-burn tobacco substrate containing activated carbon | |
| CN102747647B (en) | Paper cigarette filter rod filter media and processing method thereof | |
| CN105167154A (en) | Novel method for preparing reconstituted tobacco by virtue of papermaking process | |
| CN111317166A (en) | Preparation method of bouquet type non-combustion reconstituted tobacco for heating non-combustion cigarettes | |
| CN107594617B (en) | Paper filter tip for reconstituted tobacco and preparation method thereof | |
| CN106617288A (en) | Paper cigarette filter stick and manufacturing method thereof | |
| CN104480774A (en) | Preparation process of cigar coat and cigar sleeve with tobacco leaf texture | |
| CN110150723A (en) | It does not burn the application in cigarette for the tobacco compositions of papermaking-method reconstituted tobaccos and its in heating | |
| CN102499469B (en) | Preparation method of mechanically-wrapped tobacco-coated cigar wrapper | |
| CN110257172A (en) | Coating medium is fragrant, coating fluid and heating are not burnt cigarette | |
| CN103829374A (en) | Tobacco fiber paper filter stick and preparation method thereof | |
| CN102326863A (en) | Preparation method of cigarette paper filter material containing nicotiana tabacum extract | |
| CN103126045A (en) | Treatment process used for improving aromatic tobacco sensory quality | |
| CN108323793B (en) | Core base material for heating non-combustible cigarette and preparation method thereof | |
| CN106522020B (en) | A kind of bamboo base filter stick for cigarettes forming paper and preparation method thereof | |
| CN104095288A (en) | Additive for preparing cigarette paper for paper filter tip | |
| CN102845828B (en) | Method for producing paper cigar cloth and cigar jacket for cigars and cigarettes | |
| CN103284327B (en) | Tobacco paper filter stick combining bamboo fiber and preparation method of tobacco paper filter stick | |
| CN102247013A (en) | Method for preparing low-acetification natural fiber filter stick | |
| CN102763897B (en) | Method for making polylactic acid fiber filter stick | |
| CN104088195B (en) | A kind of coating fluid for paper filter tip |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141015 |
|
| RJ01 | Rejection of invention patent application after publication |