CN104070052B - 含氰废渣的处理方法 - Google Patents
含氰废渣的处理方法 Download PDFInfo
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- CN104070052B CN104070052B CN201410296106.0A CN201410296106A CN104070052B CN 104070052 B CN104070052 B CN 104070052B CN 201410296106 A CN201410296106 A CN 201410296106A CN 104070052 B CN104070052 B CN 104070052B
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- Prior art keywords
- waste residue
- powder
- cyanogen
- stirring
- broken cyanide
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- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 title claims abstract description 104
- 239000002699 waste material Substances 0.000 title claims abstract description 90
- 238000000034 method Methods 0.000 title abstract description 67
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims abstract description 61
- 238000003756 stirring Methods 0.000 claims abstract description 43
- 239000000843 powder Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000002245 particle Substances 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003513 alkali Substances 0.000 claims abstract description 10
- 239000000460 chlorine Substances 0.000 claims abstract description 10
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 10
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract 2
- 235000011116 calcium hydroxide Nutrition 0.000 claims abstract 2
- 239000000920 calcium hydroxide Substances 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 22
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 16
- 239000007844 bleaching agent Substances 0.000 claims description 16
- 239000003814 drug Substances 0.000 claims description 16
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 15
- 238000004061 bleaching Methods 0.000 claims description 13
- 238000003672 processing method Methods 0.000 claims description 12
- 239000004155 Chlorine dioxide Substances 0.000 claims description 11
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 11
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 11
- 238000007711 solidification Methods 0.000 claims description 11
- 230000008023 solidification Effects 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 239000008187 granular material Substances 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 abstract description 12
- 239000002351 wastewater Substances 0.000 abstract description 8
- 238000002156 mixing Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract 2
- 229910052602 gypsum Inorganic materials 0.000 abstract 2
- 239000010440 gypsum Substances 0.000 abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 238000005660 chlorination reaction Methods 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 239000012798 spherical particle Substances 0.000 abstract 1
- 238000002386 leaching Methods 0.000 description 25
- 150000003839 salts Chemical class 0.000 description 22
- 239000002910 solid waste Substances 0.000 description 15
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 102000004316 Oxidoreductases Human genes 0.000 description 2
- 108090000854 Oxidoreductases Proteins 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000004643 cyanate ester Substances 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- MGHREQTXGWWBMU-UHFFFAOYSA-N O=Cl=O.O=Cl=O Chemical compound O=Cl=O.O=Cl=O MGHREQTXGWWBMU-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 231100000570 acute poisoning Toxicity 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- ZIUSEGSNTOUIPT-UHFFFAOYSA-N ethyl 2-cyanoacetate Chemical compound CCOC(=O)CC#N ZIUSEGSNTOUIPT-UHFFFAOYSA-N 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000006385 ozonation reaction Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
Abstract
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CN201611134213.9A CN106734071B (zh) | 2014-06-27 | 2014-06-27 | 用漂白粉处理含氰废渣的方法 |
CN201410296106.0A CN104070052B (zh) | 2014-06-27 | 2014-06-27 | 含氰废渣的处理方法 |
CN201611133980.8A CN106730569B (zh) | 2014-06-27 | 2014-06-27 | 用二氧化氯水溶液处理含氰废渣的方法 |
CN201611136212.8A CN106734072B (zh) | 2014-06-27 | 2014-06-27 | 一种含氰废渣的处理方法 |
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CN201410296106.0A CN104070052B (zh) | 2014-06-27 | 2014-06-27 | 含氰废渣的处理方法 |
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CN201611133980.8A Division CN106730569B (zh) | 2014-06-27 | 2014-06-27 | 用二氧化氯水溶液处理含氰废渣的方法 |
CN201611136212.8A Division CN106734072B (zh) | 2014-06-27 | 2014-06-27 | 一种含氰废渣的处理方法 |
CN201611134213.9A Division CN106734071B (zh) | 2014-06-27 | 2014-06-27 | 用漂白粉处理含氰废渣的方法 |
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CN104070052B true CN104070052B (zh) | 2017-02-15 |
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CN201611133980.8A Active CN106730569B (zh) | 2014-06-27 | 2014-06-27 | 用二氧化氯水溶液处理含氰废渣的方法 |
CN201611136212.8A Active CN106734072B (zh) | 2014-06-27 | 2014-06-27 | 一种含氰废渣的处理方法 |
CN201410296106.0A Active CN104070052B (zh) | 2014-06-27 | 2014-06-27 | 含氰废渣的处理方法 |
CN201611134213.9A Active CN106734071B (zh) | 2014-06-27 | 2014-06-27 | 用漂白粉处理含氰废渣的方法 |
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CN201611133980.8A Active CN106730569B (zh) | 2014-06-27 | 2014-06-27 | 用二氧化氯水溶液处理含氰废渣的方法 |
CN201611136212.8A Active CN106734072B (zh) | 2014-06-27 | 2014-06-27 | 一种含氰废渣的处理方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111545554A (zh) * | 2020-05-24 | 2020-08-18 | 东阳市琰安建筑工程有限公司 | 一种含氰废渣处理工艺 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104475431B (zh) * | 2015-01-01 | 2017-09-29 | 扬州杰嘉工业固废处置有限公司 | 一种高毒废渣的稳定化固化方法 |
CN105149319B (zh) * | 2015-08-23 | 2017-04-05 | 长春黄金研究院 | 黄金尾矿库原位修复方法 |
CN106391674A (zh) * | 2016-12-07 | 2017-02-15 | 云南大地绿坤环保科技有限公司 | 一种含氰废渣的无害化处理方法 |
CN107243505A (zh) * | 2017-07-25 | 2017-10-13 | 云南大地绿坤环保科技有限公司 | 一种含腈废渣的焚烧处理方法 |
CN107716516A (zh) * | 2017-10-31 | 2018-02-23 | 长春黄金研究院 | 一种氰化尾渣的氰化物去除方法 |
CN108217896A (zh) * | 2018-01-24 | 2018-06-29 | 东莞市升佳净水材料有限公司 | 一种聚合碱及其制备方法 |
CN108298718B (zh) * | 2018-01-31 | 2021-09-14 | 辽宁工程技术大学 | 一种含氰尾矿浆的综合处理方法 |
CN110576028A (zh) * | 2019-09-16 | 2019-12-17 | 营口忠旺铝业有限公司 | 一种新型铝合金电解大修渣危废处理工艺 |
CN111184977A (zh) * | 2020-01-03 | 2020-05-22 | 常州工学院 | 一种含氰废盐渣的稳固化处理方法 |
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CN86108699A (zh) * | 1986-12-27 | 1988-04-13 | 王连弟 | 含氰、钡工业废渣的处理工艺 |
CN1493537A (zh) * | 2002-10-31 | 2004-05-05 | 赵文俊 | 双氰胺废渣的处理方法 |
CN102115271A (zh) * | 2009-12-30 | 2011-07-06 | 川化股份有限公司 | 一种高浓度含氰或腈有机废水的处理方法 |
CN102311183A (zh) * | 2010-07-06 | 2012-01-11 | 上海瑞勇实业有限公司 | 含氰废水处理方法及处理系统 |
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CN1044567C (zh) * | 1989-07-05 | 1999-08-11 | 广州市珠峰研究所 | 铬渣除毒综合利用法 |
US5630785A (en) * | 1995-03-15 | 1997-05-20 | Hydromex Inc. | Process for the treatment of waste products |
GB0112216D0 (en) * | 2001-05-21 | 2001-07-11 | Secr Defence Brit | Method of treatment |
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- 2014-06-27 CN CN201611133980.8A patent/CN106730569B/zh active Active
- 2014-06-27 CN CN201611136212.8A patent/CN106734072B/zh active Active
- 2014-06-27 CN CN201410296106.0A patent/CN104070052B/zh active Active
- 2014-06-27 CN CN201611134213.9A patent/CN106734071B/zh active Active
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CN86108699A (zh) * | 1986-12-27 | 1988-04-13 | 王连弟 | 含氰、钡工业废渣的处理工艺 |
CN1493537A (zh) * | 2002-10-31 | 2004-05-05 | 赵文俊 | 双氰胺废渣的处理方法 |
CN102115271A (zh) * | 2009-12-30 | 2011-07-06 | 川化股份有限公司 | 一种高浓度含氰或腈有机废水的处理方法 |
CN102311183A (zh) * | 2010-07-06 | 2012-01-11 | 上海瑞勇实业有限公司 | 含氰废水处理方法及处理系统 |
CN103553468A (zh) * | 2013-10-31 | 2014-02-05 | 洛阳氟钾科技有限公司 | 利用金矿尾矿和萤石尾矿制作加气砖的方法 |
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CN111545554A (zh) * | 2020-05-24 | 2020-08-18 | 东阳市琰安建筑工程有限公司 | 一种含氰废渣处理工艺 |
Also Published As
Publication number | Publication date |
---|---|
CN106730569B (zh) | 2019-05-28 |
CN106734071A (zh) | 2017-05-31 |
CN106734072B (zh) | 2019-04-23 |
CN104070052A (zh) | 2014-10-01 |
CN106734071B (zh) | 2019-05-28 |
CN106734072A (zh) | 2017-05-31 |
CN106730569A (zh) | 2017-05-31 |
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