CN104044331A - Plastic-aluminum plate with PVC color-pattern facing and preparation method thereof - Google Patents
Plastic-aluminum plate with PVC color-pattern facing and preparation method thereof Download PDFInfo
- Publication number
- CN104044331A CN104044331A CN201410214550.3A CN201410214550A CN104044331A CN 104044331 A CN104044331 A CN 104044331A CN 201410214550 A CN201410214550 A CN 201410214550A CN 104044331 A CN104044331 A CN 104044331A
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- China
- Prior art keywords
- plastic
- pvc
- lathe work
- mass percent
- curing agent
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 19
- 238000001035 drying Methods 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 238000003475 lamination Methods 0.000 claims description 27
- 239000000084 colloidal system Substances 0.000 claims description 18
- 125000004494 ethyl ester group Chemical group 0.000 claims description 17
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 10
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 10
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 9
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 9
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 claims description 2
- 239000002344 surface layer Substances 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- 238000010276 construction Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention provides a preparation method for a plastic-aluminum plate with a PVC color-pattern facing. The method comprises the following steps: coating the surface of a plastic-aluminum plate with a binder; then carrying out drying; and subjecting the dried plastic-aluminum plate and a PVC color-pattern film to rolling at a temperature of 160 to 200 DEG C so as to obtain the plastic-aluminum plate with the PVC color-pattern facing. The invention also provides the plastic-aluminum plate with the PVC color-pattern facing prepared by using the method. The plastic-aluminum plate with the PVC color-pattern facing prepared by using the method has rich and colorful appearance and good fire resistance, corrosion resistance and thermal insulation performance. Moreover, the plastic-aluminum plate with the PVC color-pattern facing appears to be smooth and beautiful; the PVC color-pattern film is tightly bonded with the plastic-aluminum plate, hardly falls off and has good quality, so good practicality is realized.
Description
Technical field
The present invention relates to architectural decoration material field, specifically a kind of PVC lathe work decorative lamination plastic-aluminum panel and preparation method thereof.
Background technology
The development of more than ten years of aluminium-plastic panel industry, has become among the external and internal wall of domestic building, landmark building and senior house building at present, and technical maturity, production scale are greatly, construction is simple, outward appearance is various, and market prospects are more and more prosperous, inestimable.
Along with the development in epoch, the large step leap of urban construction paces, consumption of resident level rises in step with life taste, and tradition simple outward appearance, solid color, the aluminium-plastic panel that makes us dull have been difficult to meet the demand of people for the comfortable life of high-quality.People are looking forward to warm leisurely and carefree but do not lose graceful living environment, seek consumingly unfolding of individual character.
PVC plate outward appearance is rich and varied, has good fire prevention, wear-resisting, heat-insulating property simultaneously, is a kind of conventional building and ornament materials.But existing PVC plate and metal material are difficult to bonding preferably, and PVC plate not only easily comes off, and easily foaming of surface, performance attractive in appearance affected.
Summary of the invention
The object of the invention is provides a kind of PVC lathe work decorative lamination plastic-aluminum panel and preparation method thereof according to the deficiencies in the prior art, the PVC lathe work decorative lamination plastic-aluminum panel appearance looks elegant preparing by the inventive method, and PVC colour grain board and aluminium-plastic panel bonding closely, appearance is smooth, and quality is good.
The present invention is achieved through the following technical solutions: a kind of method of preparing PVC lathe work decorative lamination plastic-aluminum panel, its step comprises: first binding agent post-drying is coated in aluminium-plastic panel surface, then obtain PVC lathe work decorative lamination plastic-aluminum panel with the roll-in at 160-200 DEG C of PVC jump lathe work film; Colloid and curing agent that described binding agent is 3-6:1 by mass ratio form, and the mass percent of the each component of described colloid part is: polyethers 10-12%, and polyester 30-35%, phthalic anhydride 4.8-5.5%, MDI7-8%, cyclohexane 10-20%, surplus is solvent.
Described solvent is ethyl ester.
Described curing agent is the mixture of TDI, MDI, trimethylolpropane and ethyl ester, wherein to account for the mass percent of curing agent be 30-40% to TDI, the mass percent that MDI accounts for curing agent is 10-18%, the mass percent that trimethylolpropane accounts for curing agent is 10-18%, and the mass percent that ethyl ester accounts for curing agent is 26-45%.
Preparing the preferred method of above-mentioned PVC lathe work decorative lamination plastic-aluminum panel is: first binding agent post-drying is coated in aluminium-plastic panel surface, then obtain PVC lathe work decorative lamination plastic-aluminum panel with the roll-in at 160-200 DEG C of PVC jump lathe work film; Colloid and curing agent that described binding agent is 3-6:1 by mass ratio form, and the mass percent of the each component of described colloid part is: polyethers 10-12%, and polyester 30-35%, phthalic anhydride 4.8-5.5%, MDI7-8%, cyclohexane 10-20%, surplus is ethyl ester; Described curing agent is the mixture of TDI, MDI, trimethylolpropane and ethyl ester, wherein to account for the mass percent of curing agent be 30-40% to TDI, the mass percent that MDI accounts for curing agent is 10-18%, the mass percent that trimethylolpropane accounts for curing agent is 10-18%, and the mass percent that ethyl ester accounts for curing agent is 26-45%.
The aluminium-plastic panel that a kind of said method prepares, it is characterized in that: described PVC lathe work decorative lamination plastic-aluminum panel is composited by bonding by upper strata PVC jump lathe work film and lower floor's aluminium-plastic panel, preparation method first coats binding agent post-drying by aluminium-plastic panel surface, then obtains PVC lathe work decorative lamination plastic-aluminum panel with the roll-in at 160-200 DEG C of PVC jump lathe work film; Colloid and curing agent that described binding agent is 3-6:1 by mass ratio form, and the mass percent of the each component of described colloid part is: polyethers 10-12%, and polyester 30-35%, phthalic anhydride 4.8-5.5%, MDI7-8%, cyclohexane 10-20%, surplus is solvent.
Described aluminium-plastic panel is taking aluminium alloy plate as upper and lower surface layer, the composite plate that plastic basis material plate is sandwich layer.
Described aluminium-plastic panel thickness is 2-4mm.
Described PVC jump lathe work film thickness is 0.1-0.3mm.
The PVC lathe work decorative lamination plastic-aluminum panel outward appearance preparing by the inventive method is rich and varied, and can have good fire-resistant corrosion-resistant and heat-insulating property.And PVC lathe work decorative lamination plastic-aluminum panel flat appearance is attractive in appearance, PVC jump lathe work film and aluminium-plastic panel bonding are closely not easy to come off, and quality is good, has very strong practicality.
Detailed description of the invention
By the following specific examples further illustrate the invention:
Embodiment 1
Binding agent post-drying is coated on the aluminium-plastic panel surface that is 4mm by thickness, then with the thickness PVC jump lathe work film that is 0.3mm at 200 DEG C, 6kg/m
3lower roll-in obtains PVC lathe work decorative lamination plastic-aluminum panel 1.Colloid and curing agent that described binding agent is 3:1 by mass ratio form, and the mass percent of the each component of described colloid part is: polyethers 10%, and polyester 35%, phthalic anhydride 4.8%, MDI7%, cyclohexane 20%, surplus is ethyl ester.The mixture of the ethyl ester that the trimethylolpropane that described curing agent is mass percent is 35% TDI, mass percent is 18% MDI, mass percent is 18% and mass percent are 29%.
Embodiment 2
Binding agent post-drying is coated on the aluminium-plastic panel surface that is 2mm by thickness, then with the thickness PVC jump lathe work film that is 0.1mm at 160 DEG C, 4kg/m
3lower roll-in obtains PVC lathe work decorative lamination plastic-aluminum panel 2.Colloid and curing agent that described binding agent is 4:1 by mass ratio form, and the mass percent of the each component of described colloid part is: polyethers 12%, and polyester 30%, phthalic anhydride 5.5%, MDI8%, cyclohexane 10%, surplus is ethyl ester.The mixture of the ethyl ester that the trimethylolpropane that described curing agent is mass percent is 38% TDI, mass percent is 10% MDI, mass percent is 10% and mass percent are 42%.
Embodiment 3
Binding agent post-drying is coated on the aluminium-plastic panel surface that is 3mm by thickness, then with the thickness PVC jump lathe work film that is 0.1mm at 180 DEG C, 4kg/m
3lower roll-in obtains PVC lathe work decorative lamination plastic-aluminum panel 3.Colloid and curing agent that described binding agent is 4:1 by mass ratio form, and the mass percent of the each component of described colloid part is: polyethers 11%, and polyester 32%, phthalic anhydride 5%, MDI7.5%, cyclohexane 15%, surplus is ethyl ester.The mixture of the ethyl ester that the trimethylolpropane that described curing agent is mass percent is 30% TDI, mass percent is 13% MDI, mass percent is 12% and mass percent are 45%.
Embodiment 4
Binding agent post-drying is coated on the aluminium-plastic panel surface that is 4mm by thickness, then with the thickness PVC jump lathe work film that is 0.2mm at 190 DEG C, 6kg/m
3lower roll-in obtains PVC lathe work decorative lamination plastic-aluminum panel 4.Colloid and curing agent that described binding agent is 6:1 by mass ratio form, and the mass percent of the each component of described colloid part is: polyethers 10%, and polyester 30%, phthalic anhydride 5%, MDI7.5%, cyclohexane 20%, surplus is ethyl ester.The mixture of the ethyl ester that the trimethylolpropane that described curing agent is mass percent is 40% TDI, mass percent is 16% MDI, mass percent is 18% and mass percent are 26%.
Closely, surfacing is without foaming for the PVC jump lathe work film of PVC lathe work decorative lamination plastic-aluminum panel 1-4 of the present invention and aluminium-plastic panel bonding, and outward appearance is various, has very strong practicality.
Claims (7)
1. prepare a method for PVC lathe work decorative lamination plastic-aluminum panel, its step comprises: first binding agent post-drying is coated in aluminium-plastic panel surface, then obtain PVC lathe work decorative lamination plastic-aluminum panel with the roll-in at 160-200 DEG C of PVC jump lathe work film; Colloid and curing agent that described binding agent is 3-6:1 by mass ratio form, and the mass percent of the each component of described colloid part is: polyethers 10-12%, and polyester 30-35%, phthalic anhydride 4.8-5.5%, MDI7-8%, cyclohexane 10-20%, surplus is solvent.
2. the preparation method of PVC lathe work decorative lamination plastic-aluminum panel according to claim 1, is characterized in that: described solvent is ethyl ester.
3. the preparation method of PVC lathe work decorative lamination plastic-aluminum panel according to claim 1, it is characterized in that: described curing agent is the mixture of TDI, MDI, trimethylolpropane and ethyl ester, wherein to account for the mass percent of curing agent be 30-40% to TDI, the mass percent that MDI accounts for curing agent is 10-18%, the mass percent that trimethylolpropane accounts for curing agent is 10-18%, and the mass percent that ethyl ester accounts for curing agent is 26-45%.
4. a PVC lathe work decorative lamination plastic-aluminum panel of preparing by the method for claim 1, it is characterized in that: described PVC lathe work decorative lamination plastic-aluminum panel is composited by bonding by upper strata PVC jump lathe work film and lower floor's aluminium-plastic panel, preparation method first coats binding agent post-drying by aluminium-plastic panel surface, then obtains PVC lathe work decorative lamination plastic-aluminum panel with the roll-in at 160-200 DEG C of PVC jump lathe work film; Colloid and curing agent that described binding agent is 3-6:1 by mass ratio form, and the mass percent of the each component of described colloid part is: polyethers 10-12%, and polyester 30-35%, phthalic anhydride 4.8-5.5%, MDI7-8%, cyclohexane 10-20%, surplus is solvent.
5. described PVC lathe work decorative lamination plastic-aluminum panel according to claim 4, is characterized in that: described aluminium-plastic panel is taking aluminium alloy plate as upper and lower surface layer, the composite plate that plastic basis material plate is sandwich layer.
6. described PVC lathe work decorative lamination plastic-aluminum panel according to claim 4, is characterized in that: described aluminium-plastic panel thickness is 2-4mm.
7. described PVC lathe work decorative lamination plastic-aluminum panel according to claim 4, is characterized in that: described PVC jump lathe work film thickness is 0.1-0.3mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410214550.3A CN104044331B (en) | 2014-05-21 | 2014-05-21 | A kind of PVC lathe work decorative lamination plastic-aluminum panel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410214550.3A CN104044331B (en) | 2014-05-21 | 2014-05-21 | A kind of PVC lathe work decorative lamination plastic-aluminum panel and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104044331A true CN104044331A (en) | 2014-09-17 |
| CN104044331B CN104044331B (en) | 2016-09-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410214550.3A Active CN104044331B (en) | 2014-05-21 | 2014-05-21 | A kind of PVC lathe work decorative lamination plastic-aluminum panel and preparation method thereof |
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| Country | Link |
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| CN (1) | CN104044331B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108128019A (en) * | 2017-12-20 | 2018-06-08 | 揭阳市运泰装饰材料有限公司 | A kind of method for preparing PE lathe work decorative lamination plastic-aluminum panels |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202106619U (en) * | 2011-05-13 | 2012-01-11 | 北京市物佳攀士科技贸易有限公司 | Metal plate |
| CN103342978A (en) * | 2013-06-27 | 2013-10-09 | 天长市京发铝业有限公司 | High-gloss coated aluminum sheet using polyurethane adhesive |
-
2014
- 2014-05-21 CN CN201410214550.3A patent/CN104044331B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202106619U (en) * | 2011-05-13 | 2012-01-11 | 北京市物佳攀士科技贸易有限公司 | Metal plate |
| CN103342978A (en) * | 2013-06-27 | 2013-10-09 | 天长市京发铝业有限公司 | High-gloss coated aluminum sheet using polyurethane adhesive |
Non-Patent Citations (5)
| Title |
|---|
| 张玉龙主编: "《胶黏剂配方精选2000-2003》", 30 November 2003, 化学工业出版社 * |
| 李东光主编: "《胶黏剂配方与生产》", 31 July 2013, 化学工业出版社 * |
| 李和平主编: "《胶黏剂配方工艺手册》", 28 February 2006, 化学工业出版社 * |
| 王慎敏主编: "《胶黏剂合成、配方设计与配方实例》", 30 June 2003, 化学工业出版社 * |
| 马晓燕主编: "《塑料装饰》", 31 March 2004, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108128019A (en) * | 2017-12-20 | 2018-06-08 | 揭阳市运泰装饰材料有限公司 | A kind of method for preparing PE lathe work decorative lamination plastic-aluminum panels |
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| Publication number | Publication date |
|---|---|
| CN104044331B (en) | 2016-09-07 |
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