CN104039760B - 肟的气相和液相催化贝克曼重排以制备内酰胺 - Google Patents

肟的气相和液相催化贝克曼重排以制备内酰胺 Download PDF

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Publication number
CN104039760B
CN104039760B CN201280052939.1A CN201280052939A CN104039760B CN 104039760 B CN104039760 B CN 104039760B CN 201280052939 A CN201280052939 A CN 201280052939A CN 104039760 B CN104039760 B CN 104039760B
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China
Prior art keywords
oxime
sapo
catalyst
lactams
selectivity
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CN201280052939.1A
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Chinese (zh)
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CN104039760A (zh
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A.B.利维
R.拉贾
M.E.波特
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Ed Vance Chemical Co
University of Southampton
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University of Southampton
Honeywell International Inc
Advansix Resins and Chemicals LLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54—Phosphates, e.g. APO or SAPO compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/04—Preparation of lactams from or via oximes by Beckmann rearrangement
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C07D223/10—Oxygen atoms attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D225/00—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom
    • C07D225/02—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
CN201280052939.1A 2011-10-28 2012-10-25 肟的气相和液相催化贝克曼重排以制备内酰胺 Active CN104039760B (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201161628419P 2011-10-28 2011-10-28
US61/628419 2011-10-28
US61/628,419 2011-10-28
US13/658,495 US8772476B2 (en) 2011-10-28 2012-10-23 Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams
US13/658,495 2012-10-23
US13/658495 2012-10-23
PCT/US2012/061876 WO2013063244A1 (en) 2011-10-28 2012-10-25 Gas and liquid phase catalytic beckmann rearrangement of oximes to produce lactams

Publications (2)

Publication Number Publication Date
CN104039760A CN104039760A (zh) 2014-09-10
CN104039760B true CN104039760B (zh) 2018-03-09

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Country Link
US (3) US8772476B2 (https=)
EP (1) EP2771317B1 (https=)
JP (2) JP6243340B2 (https=)
KR (1) KR102002197B1 (https=)
CN (1) CN104039760B (https=)
CO (1) CO6950487A2 (https=)
ES (1) ES2856699T3 (https=)
IN (1) IN2014DN03074A (https=)
MX (1) MX354802B (https=)
RU (1) RU2609779C2 (https=)
WO (1) WO2013063244A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4136000B2 (ja) * 1994-06-03 2008-08-20 三井化学株式会社 殺虫性テトラヒドロフラン系化合物
US8772476B2 (en) * 2011-10-28 2014-07-08 Honeywell International Inc. Gas and liquid phase catalytic Beckmann rearrangement of oximes to produce lactams
US20160167030A1 (en) * 2014-12-16 2016-06-16 University Of Southampton Hierarchical aluminophosphates as catalysts for the beckmann rearrangement

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WO1998054092A1 (en) * 1997-05-29 1998-12-03 Exxon Chemical Patents Inc. Preparation of zeolite-bound fau structure type zeolite and use thereof
WO1999010277A1 (en) * 1997-08-25 1999-03-04 California Institute Of Technology Functionalized molecular sieves
WO2005035118A1 (en) * 2003-09-25 2005-04-21 Exxonmobil Chemical Patents Inc. Multi component catalyst and its use in catalytic cracking
WO2011064666A2 (en) * 2009-11-30 2011-06-03 Johnson Matthey Public Limited Company Catalysts for treating transient nox emissions

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US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
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Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5312915A (en) * 1993-03-04 1994-05-17 Sumitomo Chemical Company, Limited Process for producing epsilon-caprolactam
WO1998054092A1 (en) * 1997-05-29 1998-12-03 Exxon Chemical Patents Inc. Preparation of zeolite-bound fau structure type zeolite and use thereof
WO1999010277A1 (en) * 1997-08-25 1999-03-04 California Institute Of Technology Functionalized molecular sieves
WO2005035118A1 (en) * 2003-09-25 2005-04-21 Exxonmobil Chemical Patents Inc. Multi component catalyst and its use in catalytic cracking
WO2011064666A2 (en) * 2009-11-30 2011-06-03 Johnson Matthey Public Limited Company Catalysts for treating transient nox emissions

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IN2014DN03074A (https=) 2015-05-15
WO2013063244A1 (en) 2013-05-02
RU2609779C2 (ru) 2017-02-03
US20150126732A1 (en) 2015-05-07
EP2771317B1 (en) 2020-12-09
BR112014010194A2 (pt) 2017-06-13
JP6243340B2 (ja) 2017-12-06
EP2771317A1 (en) 2014-09-03
US20150306586A1 (en) 2015-10-29
US20160279622A9 (en) 2016-09-29
US9221762B2 (en) 2015-12-29
CN104039760A (zh) 2014-09-10
JP2017200906A (ja) 2017-11-09
KR102002197B1 (ko) 2019-07-19
US8772476B2 (en) 2014-07-08
ES2856699T3 (es) 2021-09-28
MX354802B (es) 2018-03-22
JP2015501321A (ja) 2015-01-15
EP2771317A4 (en) 2015-10-07
MX2014005018A (es) 2014-07-09
US20130109851A1 (en) 2013-05-02
KR20150000863A (ko) 2015-01-05
RU2014121157A (ru) 2015-12-10
CO6950487A2 (es) 2014-05-20
US9662643B2 (en) 2017-05-30
BR112014010194A8 (pt) 2017-06-20

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