CN103981546A - Chloride galvanized composite material and preparation method thereof - Google Patents
Chloride galvanized composite material and preparation method thereof Download PDFInfo
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- CN103981546A CN103981546A CN201410173892.5A CN201410173892A CN103981546A CN 103981546 A CN103981546 A CN 103981546A CN 201410173892 A CN201410173892 A CN 201410173892A CN 103981546 A CN103981546 A CN 103981546A
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- chloride
- boric acid
- composite material
- matrix material
- zinc chloride
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Abstract
The invention relates to the technical field of chloride galvanized materials, in particular to a chloride galvanized composite material. The chloride galvanized composite material is characterized by comprising potassium chloride, zinc chloride and boric acid, wherein the ratio of potassium chloride to zinc chloride to boric acid is 210: 55: 35; and the proportional materials are fully and evenly stirred by a mixer to prepare the composite material. As the materials of potassium chloride, zinc chloride and boric acid for preparing the composite material are adopted in the production process, various technical errors caused by unbalanced raw material addition and raw material quality problem in the production process can be prevented.
Description
Technical field
The present invention relates to chloride galvanizing material technology field, especially relate to a kind of chloride galvanizing matrix material and preparation method thereof.
Background technology
Potassium Chloride Zinc Plating is due to nontoxic; be conducive to environment protection; cost is low, cleaner production, and steady quality is reliable; firmly get favorable comment; just by traditional electroplate liquid proportioning and specific operation process, often go out that raw materials quality is difficult to guarantee and many proportioning examples of raw material variety are difficult to grasp, often break down; waste raw material, cause cost improve and can not normally produce.In prior art, there is no the synthetic compound use raw material of existing raw material yet, thus the various technical errors of always producing because adding raw material imbalance and raw materials quality problem in production process.
Summary of the invention
The object of the invention is to avoid the deficiencies in the prior art that a kind of chloride galvanizing matrix material and preparation method thereof is provided, thereby effectively solve the defect existing in prior art.
For achieving the above object, the technical scheme that the present invention takes is: described a kind of chloride galvanizing matrix material, is characterized in containing Repone K 180-230 gram, zinc chloride 45-70 gram, boric acid 25-45 gram in every liter of plating solution.
The proportioning of Repone K, zinc chloride and boric acid in every liter of described plating solution is 210: 55: 35.
The preparation method of described a kind of chloride galvanizing matrix material, is characterized in comprising the steps:
(1), zinc chloride is added in stainless steel or plastic containers by proportioning content;
(2), by proportioning content, add boric acid, fully stir naturally cooling 15-25 minute after 5-10 minute;
(3), by proportioning content, add Repone K, uniform stirring 5-15 minute;
(4), packing.
The invention has the beneficial effects as follows: described a kind of chloride galvanizing matrix material, it is by adopting Repone K, zinc chloride, the materials such as boric acid are made matrix material and are used in process of production, can avoid in process of production because adding the various technical errors that raw material is uneven and raw materials quality problem is produced.
Embodiment
Below in conjunction with principle of the present invention and feature, be described, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Described a kind of chloride galvanizing matrix material, described a kind of chloride galvanizing matrix material, is characterized in containing Repone K 180-230 gram, zinc chloride 45-70 gram, boric acid 25-45 gram in every liter of plating solution.
Further, the optimum ratio of Repone K, zinc chloride and the boric acid in every liter of described plating solution is 210: 55: 35.
The preparation method of described a kind of chloride galvanizing matrix material, is characterized in comprising the steps:
(1), zinc chloride is added in stainless steel or plastic containers by proportioning content;
(2), by proportioning content, add boric acid, fully stir naturally cooling 15-25 minute after 5-10 minute;
(3), by proportioning content, add Repone K, uniform stirring 5-15 minute;
(4), packing.
Repone K is weak coordination agent and conductive agent, its mass concentration affects plating solution electroconductibility, too much or the very few specific conductivity that all can reduce plating solution, thereby affect dispersive ability and the dark plating touch of plating solution, the existence of a large amount of chlorions can increase cathodic polarization and promote negative electrode recklessly to change, when if the concentration of Repone K is higher or on the low side, easily make coating produce dark-coloured, black streaking or drum eye, when too high, brightening agent may be separated out and can not normally produce because salting-out phenomenon is oily matter, so chloride containing potassium is 210g in every liter of electric liquid liquid; Dispersive ability and covering power sedimentation velocity that every liter of content of zinc chloride crosses liquid at 60g are best, because when the quality degree of depth of plating ion is higher, easily burn high current density region, the workpiece that plates becomes black shape, cause and scrap, anti-plating, when zine ion is lower, coating deposition rate is slower, useless power when electric current is opened little giving up; Boric acid every kind of content in electroplate liquid is 35g, because at this moment can play bath pH value, is stabilized in 5 left and right, can obtain the luminance brightness of high coating and expand bright current density range and crystallization of refinement.
Matrix material is easier in joining plating solution use procedure, first the good matrix material of computer is calculated and added in coating bath by every liter of plating solution matrix material 300g, example is joined the coating bath Huaihe River method of calculation of a 100L: 300g * 100L=30000g matrix material, by kilogram equal kilogram to draw calculation namely 300 kilograms of matrix materials accelerate the warm water of 35 ℃～60 ℃ and stir and just can try the end and produced, very simple operations, also very easy when adding at ordinary times, the in use main consumption of plating solution of plating solution is that negative electrode workpiece to be plated is taken plating solution out of and consumed, while therefore adding supply plating solution, must guarantee Repone K in electroplate liquid, zinc chloride, the proportional balancing method of boric acid, so add this point of accomplishing that matrix material could saving of labor saves trouble, brought convenience material benefit to grasp electroplating technology.
The foregoing is only preferred embodiment of the present invention, in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (3)
1. a chloride galvanizing matrix material, is characterized in that containing Repone K 180-230 gram, zinc chloride 45-70 gram, boric acid 25-45 gram in every liter of plating solution.
2. a kind of chloride galvanizing matrix material as claimed in claim 1, is characterized in that: the proportioning of Repone K, zinc chloride and boric acid in every liter of described plating solution is 210: 55: 35.
3. a preparation method for chloride galvanizing matrix material as claimed in claim 1, is characterized in comprising the steps:
(1), zinc chloride is added in stainless steel or plastic containers by proportioning content;
(2), by proportioning content, add boric acid, fully stir naturally cooling 15-25 minute after 5-10 minute;
(3), by proportioning content, add Repone K, uniform stirring 5-15 minute;
(4), packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410173892.5A CN103981546A (en) | 2014-04-29 | 2014-04-29 | Chloride galvanized composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410173892.5A CN103981546A (en) | 2014-04-29 | 2014-04-29 | Chloride galvanized composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103981546A true CN103981546A (en) | 2014-08-13 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410173892.5A Pending CN103981546A (en) | 2014-04-29 | 2014-04-29 | Chloride galvanized composite material and preparation method thereof |
Country Status (1)
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| CN (1) | CN103981546A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105506715A (en) * | 2015-12-15 | 2016-04-20 | 东南大学 | Preparation method of rare earth oxide-graphene composite doping zinc plating layer |
| CN109972067A (en) * | 2019-04-25 | 2019-07-05 | 天津市萧山管业有限公司 | A kind of electrician's conduit and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102618896A (en) * | 2011-11-14 | 2012-08-01 | 天津市聚兴电镀有限公司 | Potassium chloride-type galvanizing plating solution and its preparation method |
| CN102965703A (en) * | 2012-11-23 | 2013-03-13 | 沈阳工业大学 | Method for improving binding force of electro-galvanized layer on surface of neodymium-iron-boron permanent magnet |
| CN103451690A (en) * | 2013-08-13 | 2013-12-18 | 南京飞燕活塞环股份有限公司 | Method for galvanizing treatment of spring lined in piston ring |
-
2014
- 2014-04-29 CN CN201410173892.5A patent/CN103981546A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102618896A (en) * | 2011-11-14 | 2012-08-01 | 天津市聚兴电镀有限公司 | Potassium chloride-type galvanizing plating solution and its preparation method |
| CN102965703A (en) * | 2012-11-23 | 2013-03-13 | 沈阳工业大学 | Method for improving binding force of electro-galvanized layer on surface of neodymium-iron-boron permanent magnet |
| CN103451690A (en) * | 2013-08-13 | 2013-12-18 | 南京飞燕活塞环股份有限公司 | Method for galvanizing treatment of spring lined in piston ring |
Non-Patent Citations (1)
| Title |
|---|
| 张允诚等: "《电镀手册》", 31 May 2008, article "氯化物镀锌" * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105506715A (en) * | 2015-12-15 | 2016-04-20 | 东南大学 | Preparation method of rare earth oxide-graphene composite doping zinc plating layer |
| CN109972067A (en) * | 2019-04-25 | 2019-07-05 | 天津市萧山管业有限公司 | A kind of electrician's conduit and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20140813 |