CN103972564A - Generating device provided with hydrogen storage tank adopting stainless steel composite material - Google Patents

Generating device provided with hydrogen storage tank adopting stainless steel composite material Download PDF

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Publication number
CN103972564A
CN103972564A CN201410132615.XA CN201410132615A CN103972564A CN 103972564 A CN103972564 A CN 103972564A CN 201410132615 A CN201410132615 A CN 201410132615A CN 103972564 A CN103972564 A CN 103972564A
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CN
China
Prior art keywords
hydrogen
solid state
trt
blast furnace
gas recovery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410132615.XA
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Chinese (zh)
Inventor
黄晓东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Huapeng Explosion Proof Technology Co Ltd
Original Assignee
Shanghai Huapeng Explosion Proof Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Huapeng Explosion Proof Technology Co Ltd filed Critical Shanghai Huapeng Explosion Proof Technology Co Ltd
Priority to CN201410132615.XA priority Critical patent/CN103972564A/en
Publication of CN103972564A publication Critical patent/CN103972564A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01BASIC ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201Reactant storage and supply, e.g. means for feeding, pipes
    • H01M8/04216Reactant storage and supply, e.g. means for feeding, pipes characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00Use of gas-solvents or gas-sorbents in vessels
    • F17C11/005Use of gas-solvents or gas-sorbents in vessels for hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602Wall structures; Special features thereof
    • F17C2203/0612Wall structures
    • F17C2203/0614Single wall
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602Wall structures; Special features thereof
    • F17C2203/0612Wall structures
    • F17C2203/0614Single wall
    • F17C2203/0617Single wall with one layer
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0639Steels
    • F17C2203/0643Stainless steels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/01Pure fluids
    • F17C2221/012Hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/01Applications for fluid transport or storage
    • F17C2270/0165Applications for fluid transport or storage on the road
    • F17C2270/0168Applications for fluid transport or storage on the road by vehicles
    • F17C2270/0178Cars
    • HELECTRICITY
    • H01BASIC ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The utility model provides a generating device provided with a hydrogen storage tank adopting a stainless steel composite material. The solid hydrogen generating device comprises a hydrogen storage device, a hydrogen supply device, a generating battery device and the like, wherein the hydrogen storage device comprises the hydrogen storage tank containing hydrogen storage particles, the average diameter of each hydrogen storage particle ranges from 20 mu m to 200 mu m, and each hydrogen storage particle is provided with an internal cavity surrounded by a porous wall; an air hole is formed in one end of the hydrogen storage tank, and a filter is arranged in the air hole; and the hydrogen storage tank comprises a stainless steel liner and a carbon fiber enhancement layer.

Description

Blast Furnace Top Gas Recovery Turbine Unit (TRT) with stainless steel composite material storage hydrogen bottle
Technical field
The present invention relates to a kind of novel energy, especially a kind of solid state hydrogen battery, is specifically related to hydrogen-storing device.
Background technology
The power of automobile is generally used fuel oil at present, and because petroleum resources are limited, people have to seek new alternative energy source, for example electric energy, solar energy etc.As the substitute of vehicle fuel, comprise known liquefied petroleum gas and liquefied natural gas.Use the pernicious gas of motor vehicle emission of these substitutes relatively less, but still fail fundamentally to solve the problem of the energy and pollution.
Hydrogen more and more comes into one's own as the application of fuel, and the hydrogen of gaseous state is very easy to blast.In hydrogen powered vehicle field, hydrogen can be stored in the on-board high-voltage container of the vehicles.Such storage system efficiency in volume level is not high, and for example, due to storage hypertonia, 5,000-10, the about 350-700 Bar of 000psi() air pressure, thereby there is potential safety hazard.
Summary of the invention
In order to realize above object, the present invention proposes a kind of solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT), usings solid state hydrogen as the energy, and solid state hydrogen is converted into electric energy, with the acting of electric energy drive motors.This solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT), by supporting relevant servicing unit, as hydrogen-storing device, hydrogen feeding mechanism, generating battery device etc., realizes the object of saving fuel oil and reducing toxic emission.
Described hydrogen-storing device comprises storage hydrogen bottle, and storage hydrogen bottle contains storage hydrogen particle, and this storage hydrogen particle can store the hydrogen after activation with solid-state form, and disengages the hydrogen of storage when heat absorption.Described storage hydrogen particle have by porous wall around internal cavities.One end of storage hydrogen bottle is provided with pore, is provided with filter in pore.Filter is made by metal powder sintered moulding or by the micro-close net of stainless steel, can allow hydrogen circulation and filters and stop other gas and impurity to enter in storage hydrogen bottle.When hydrogen being injected to storage hydrogen bottle, it is inner that hydrogen enters storage hydrogen bottle through filter, now store up the storage hydrogen particle that hydrogen bottle contains and absorb rapidly hydrogen, after overactivation, a large amount of hydrogen molecules are changed into solid state hydrogen and be stored in hydrogen bottle inside, hydrogen is no longer stored with the form of high-pressure gaseous, thereby reach safety in transportation and storage object.
The solid state hydrogen that described hydrogen feeding mechanism can store storage hydrogen particle by the wireway at storage hydrogen bottle pore place divides submode to disengage with Gaseous Hydrogen, sends into generating battery device.
Described generating battery device and general battery structure are similar, are that adopted material is different.
Hydrogen storage technology provided by the invention and Blast Furnace Top Gas Recovery Turbine Unit (TRT) have solved the existing series of problems of gaseous state storing mode effectively, have replenished the blank of this technical field, have novelty.This hydrogen storage technology and Blast Furnace Top Gas Recovery Turbine Unit (TRT) can be used for the various vehicles, and the features such as, transitory efficient safe and reliable with it, economic convenient, environmental protection and energy saving, have vast potential for future development.Use solid state hydrogen can solve as the energy environmental pollution that oil discharging waste gas causes, and use solid state hydrogen can reduce costs as the energy.
The said storage hydrogen of above-mentioned hydrogen-storing device bottle contains storage hydrogen particle, and the average diameter of this storage hydrogen particle is 20 microns to 200 microns, have by porous wall around internal cavities.One end at storage hydrogen bottle is provided with pore, is provided with filter in pore.The housing of described storage hydrogen bottle comprises stainless steel inner container and carbon fiber enhancement layer, the chemical element that described stainless steel contains following quality %: carbon≤0.025, silicon≤1.00, manganese≤1.00, phosphorus≤0.040, sulphur≤0.030, nickel≤1.00, nitrogen≤0.035, chromium 18.0-20.0, molybdenum 2.10-3.00.
Further, the average diameter of described storage hydrogen particle is 50 microns to 80 microns.
Further, described storage hydrogen particle is CNT (carbon nano-tube), nano-glass ball, nano ceramics.The mixture of nano zeolite, nanofiber or these materials.
Further, described storage hydrogen particle has the wall thickness of 1 to 30 micron, preferably the wall thickness of 1 to 10 micron.
Further, the wall of described storage hydrogen particle is porous wall, and the aperture in described porous wall is 50 dust-1000 dusts, and preferably the aperture in porous wall is 200 dust-500 dusts.
Further, described filter is made by metal powder sintered moulding, or is made by the micro-close net of stainless steel, and contains Metal Palladium.
Further, the stainless steel inner container wall thickness of described storage hydrogen bottle housing is 2-6 millimeter.
Further, the carbon fiber enhancement layer thickness of described storage hydrogen bottle housing is 0.5-5mm.
Accompanying drawing explanation
Fig. 1 is solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT) schematic diagram of the present invention.
Fig. 2 is solid state hydrogen generating battery device schematic diagram of the present invention.
1 storage hydrogen bottle in figure, 2 oxygen-storage devices, 3 generating battery devices, 12 storage hydrogen bottle pores, 13 filters, 22 oxygen-storage device pores, the electric energy delivery outlet of 31 generating battery devices.
Embodiment
Below in conjunction with accompanying drawing, the present invention is described in more detail.
Figure 1 shows that solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT) schematic diagram of the present invention.This device comprises storage hydrogen bottle 1, oxygen-storage device 2 and generating battery device 3.Storage hydrogen bottle 1 is connected with generating battery device 3 with oxygen-storage device pore 22 by storage hydrogen bottle pore 12 respectively with oxygen-storage device 2, the storage hydrogen bottle pore 12 interior filters 13 that arrange, and the electric energy delivery outlet 31 of generating battery device is connected with motor.
Described storage hydrogen bottle 1 contains storage hydrogen particle, and storage hydrogen bottle 1 pore 12 is connected with generating battery device 3.
Described oxygen-storage device 2 internal reservoir oxygen, oxygen-storage device 2 pores 22 are connected with generating battery device 3.
Described generating battery device 3 is built up generating battery device with the Porous hydrogen fuel utmost point (anode) and air pole (negative electrode) and polymer dielectric film, and electric energy is connected with motor by electric energy delivery outlet 31.
The average diameter of described storage hydrogen particle is 20 microns to 200 microns, preferably 50 microns to 80 microns.
Described storage hydrogen particle can be CNT (carbon nano-tube), nano-glass ball, nano ceramics.The mixture of nano zeolite, nanofiber or these materials.This storage hydrogen particle has 1 to 30 micron, preferably the wall thickness of 1 to 10 micron.
The wall of described storage hydrogen particle is porous wall, and the aperture in described porous wall is 50 dust-1000 dusts, preferably 200 dust-500 dusts.
Described filter 13 is made by metal powder sintered moulding or is made by the micro-close net of stainless steel, and described filter contains Metal Palladium.
The housing of described storage hydrogen bottle comprises stainless steel inner container and carbon fiber enhancement layer, described stainless steel inner container wall thickness 2-6 millimeter, and described carbon fiber enhancement layer thickness is 0.5-5mm.
Figure 2 shows that solid state hydrogen generating battery device schematic diagram of the present invention.This device overlaps to form generating battery device with the Porous hydrogen fuel utmost point (anode) and air pole (negative electrode) and polymer dielectric film.At anode, hydrogen is decomposed into hydrogen ion (proton) and electronics, and polymer dielectric film only allows proton to pass and the negative electrode that arrives, and electronics moves on to negative electrode along external circuit, carries out chemical reaction become water (H2O) at negative electrode and oxygen.In electronics moving process, obtain electric energy.
Embodiment 1
The stainless steel that use contains following quality % chemical element is prepared the storage hydrogen bottle inner bag of solid state hydrogen hydrogen-storing device of the present invention, carbon≤0.025, silicon≤1.00, manganese≤1.00, phosphorus≤0.040, sulphur≤0.030, nickel≤1.00, nitrogen≤0.035, chromium 18.00, molybdenum 2.10.The wall thickness of storage hydrogen bottle inner bag is 2 millimeters.Carbon fibre reinforcement is attached to the housing that solidify to form storage hydrogen bottle on inner bag, described carbon fiber enhancement layer thickness is 0.5mm.
Embodiment 2
Repeat the operation of embodiment 1, just the quality % of some chemical element is revised as chromium 18.50, molybdenum 2.75.The wall thickness of storage hydrogen bottle inner bag is revised as 5mm.Described carbon fiber enhancement layer thickness is 2.5mm.
Embodiment 3
Repeat the operation of embodiment 1, just the quality % of some chemical element is revised as chromium 19.00, molybdenum 3.00.The wall thickness of storage hydrogen bottle inner bag is revised as 6mm.Described carbon fiber enhancement layer thickness is 5mm.
Embodiment 4
Repeat the operation of embodiment 2, just the quality % of some chemical element is revised as molybdenum 2.20.The wall thickness of storage hydrogen bottle inner bag is revised as 4mm.
Embodiment 5
Repeat the operation of embodiment 1, just the quality % of some chemical element is revised as chromium 18.50.The wall thickness of storage hydrogen bottle inner bag is revised as 3mm.
Embodiment 6
Repeat the operation of embodiment 4, just the quality % of some chemical element is revised as molybdenum 2.50.The wall thickness of storage hydrogen bottle inner bag is revised as 4.5mm.
Embodiment 7
Repeat the operation of embodiment 2, just the quality % of some chemical element is revised as chromium 19.The wall thickness of storage hydrogen bottle inner bag is revised as 5.2mm.
Embodiment 8
Repeat the operation of embodiment 3, just the quality % of some chemical element is revised as molybdenum 2.50.The thickness of storage hydrogen bottle inner bag is revised as 3.4mm.
Solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT) of the present invention can reduce costs hydrogen as the energy, solves the environmental pollution that oil discharging waste gas causes.Described hydrogen-storing device can reach safety in transportation and storage object, for using hydrogen energy source that technical guarantee is provided.

Claims (10)

1. a solid state hydrogen Blast Furnace Top Gas Recovery Turbine Unit (TRT), comprise hydrogen-storing device, hydrogen feeding mechanism and generating battery device, described hydrogen-storing device comprises storage hydrogen bottle, and storage hydrogen bottle contains storage hydrogen particle, the average diameter of this storage hydrogen particle is 20 microns to 200 microns, have by porous wall around internal cavities; One end at storage hydrogen bottle is provided with pore, is provided with filter in pore; The housing of described storage hydrogen bottle comprises stainless steel inner container and carbon fiber enhancement layer, the chemical element that described stainless steel contains following quality %: carbon≤0.025, silicon≤1.00, manganese≤1.00, phosphorus≤0.040, sulphur≤0.030, nickel≤1.00, nitrogen≤0.035, chromium 18.0-20.0, molybdenum 2.10-3.00.
2. the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of solid state hydrogen according to claim 1, is characterized in that, the average diameter of described storage hydrogen particle is 50 microns to 80 microns.
3. according to the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of solid state hydrogen described in claim 1 or 2, it is characterized in that, described storage hydrogen particle is the mixture of CNT (carbon nano-tube), nano-glass ball, nano ceramics, nano zeolite, nanofiber or these materials.
4. according to the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of solid state hydrogen described in claim 1 or 2, it is characterized in that, described storage hydrogen particle has the wall thickness of 1 to 30 micron.
5. according to the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of solid state hydrogen described in claim 1 or 2, it is characterized in that, the aperture in described porous wall is 50 dust-1000 dusts.
6. according to the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of solid state hydrogen described in claim 1 or 2, it is characterized in that, described filter is made by metal powder sintered moulding.
7. according to the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of solid state hydrogen described in claim 1 or 2, it is characterized in that, described filter is made by the micro-close net of stainless steel.
8. according to the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of solid state hydrogen described in claim 6 or 7, it is characterized in that, described filter contains Metal Palladium.
9. according to the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of solid state hydrogen described in claim 1 or 2, it is characterized in that the stainless steel inner container wall thickness 2-6 millimeter of described storage hydrogen bottle housing.
10. the Blast Furnace Top Gas Recovery Turbine Unit (TRT) of solid state hydrogen according to claim 9, is characterized in that, the carbon fiber enhancement layer thickness of described storage hydrogen bottle housing is 0.5-5mm.
CN201410132615.XA 2014-04-03 2014-04-03 Generating device provided with hydrogen storage tank adopting stainless steel composite material Pending CN103972564A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1277935A (en) * 1999-06-16 2000-12-27 中国科学院金属研究所 Method for preparing single wall nanometer carbon tube hydrogen storage material
CN2534455Y (en) * 2002-03-29 2003-02-05 天津海蓝德能源技术发展有限公司 Hydrogen storage cylinder for fuel cell
EP1950319A1 (en) * 2005-09-22 2008-07-30 The Japan Steel Works, Ltd. Process for producing hydrogen-storage alloy
CN101291874A (en) * 2005-10-21 2008-10-22 华盛顿萨凡纳河有限公司 Hollow porous-wall glass microspheres for hydrogen storage
CN101680601A (en) * 2007-06-06 2010-03-24 株式会社丰田自动织机 Hydrogen storage tank
CN201487536U (en) * 2009-05-19 2010-05-26 无锡尚弗能源科技有限公司 Metal hydride hydrogen storage device with safeguarding structure
CN202807518U (en) * 2012-09-07 2013-03-20 上海华篷防爆科技有限公司 Fiber reinforced container

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1277935A (en) * 1999-06-16 2000-12-27 中国科学院金属研究所 Method for preparing single wall nanometer carbon tube hydrogen storage material
CN2534455Y (en) * 2002-03-29 2003-02-05 天津海蓝德能源技术发展有限公司 Hydrogen storage cylinder for fuel cell
EP1950319A1 (en) * 2005-09-22 2008-07-30 The Japan Steel Works, Ltd. Process for producing hydrogen-storage alloy
CN101291874A (en) * 2005-10-21 2008-10-22 华盛顿萨凡纳河有限公司 Hollow porous-wall glass microspheres for hydrogen storage
CN101680601A (en) * 2007-06-06 2010-03-24 株式会社丰田自动织机 Hydrogen storage tank
CN201487536U (en) * 2009-05-19 2010-05-26 无锡尚弗能源科技有限公司 Metal hydride hydrogen storage device with safeguarding structure
CN202807518U (en) * 2012-09-07 2013-03-20 上海华篷防爆科技有限公司 Fiber reinforced container

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Application publication date: 20140806