CN103917508A - 由异丁醇制造叔丁醇的方法、由异丁醇制造异丁烯醛和甲基丙烯酸的方法以及这些方法的制造装置 - Google Patents

由异丁醇制造叔丁醇的方法、由异丁醇制造异丁烯醛和甲基丙烯酸的方法以及这些方法的制造装置 Download PDF

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Publication number
CN103917508A
CN103917508A CN201280054318.7A CN201280054318A CN103917508A CN 103917508 A CN103917508 A CN 103917508A CN 201280054318 A CN201280054318 A CN 201280054318A CN 103917508 A CN103917508 A CN 103917508A
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CN
China
Prior art keywords
isobutanol
butanol
tert
methacrylic acid
methacrolein
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Pending
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CN201280054318.7A
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English (en)
Chinese (zh)
Inventor
大谷内健
安川隼也
秋原秀治
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Mitsubishi Chemical Corp
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Mitsubishi Rayon Co Ltd
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Publication of CN103917508A publication Critical patent/CN103917508A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0046—Sequential or parallel reactions, e.g. for the synthesis of polypeptides or polynucleotides; Apparatus and devices for combinatorial chemistry or for making molecular arrays
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00277—Apparatus
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280054318.7A 2011-11-07 2012-11-06 由异丁醇制造叔丁醇的方法、由异丁醇制造异丁烯醛和甲基丙烯酸的方法以及这些方法的制造装置 Pending CN103917508A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2011243518 2011-11-07
JP2011-243518 2011-11-07
PCT/JP2012/078714 WO2013069630A1 (ja) 2011-11-07 2012-11-06 イソブタノールからｔ－ブタノールを製造する方法、イソブタノールからメタクロレイン及びメタクリル酸を製造する方法、並びにそれらの製造装置

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Publication Number Publication Date
CN103917508A true CN103917508A (zh) 2014-07-09

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CN201280054318.7A Pending CN103917508A (zh) 2011-11-07 2012-11-06 由异丁醇制造叔丁醇的方法、由异丁醇制造异丁烯醛和甲基丙烯酸的方法以及这些方法的制造装置

Country Status (7)

Country Link
US (1) US9346735B2 (https=)
JP (1) JP6107139B2 (https=)
KR (1) KR101979475B1 (https=)
CN (1) CN103917508A (https=)
IN (1) IN2014KN00748A (https=)
MY (1) MY167695A (https=)
WO (1) WO2013069630A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111004116A (zh) * 2019-12-19 2020-04-14 湖北美和科技有限公司 一种用于制备结焦抑制剂组份的甲基丙烯酸酯单体

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6081950B2 (ja) * 2014-03-25 2017-02-15 Ｊｘエネルギー株式会社 脱水触媒、及び共役ジエンの製造方法
JP6081949B2 (ja) * 2014-03-25 2017-02-15 Ｊｘエネルギー株式会社 脱水触媒、及び共役ジエンの製造方法
US9840453B2 (en) * 2014-07-02 2017-12-12 Mitsubishi Chemical Corporation Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate
EP4129962B1 (en) 2020-03-31 2025-04-30 Mitsubishi Chemical Corporation Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate
EP4480941A4 (en) 2022-02-17 2025-08-27 Mitsubishi Chem Corp PROCESS FOR PRODUCING METHACROLEIN AND/OR METHACRYLIC ACID AND PROCESS FOR PRODUCING METHACRYLIC ACID ESTER
WO2025226576A1 (en) * 2024-04-25 2025-10-30 ExxonMobil Technology and Engineering Company Processes for producing isobutylene and isobutylene-based polymers

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JP2000044502A (ja) * 1998-07-30 2000-02-15 Asahi Chem Ind Co Ltd オレフィン混合物より第３級ブチルアルコールの回収方法
CN1283174A (zh) * 1997-12-26 2001-02-07 三菱丽阳株式会社 生产叔丁醇的方法
CN1596149A (zh) * 2001-12-21 2005-03-16 旭化成化学株式会社 氧化物催化剂组合物

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JPS5112605B2 (https=) 1971-09-01 1976-04-21
JPS5324403B2 (https=) 1973-06-11 1978-07-20
JPS6130538A (ja) 1984-07-20 1986-02-12 Mitsubishi Rayon Co Ltd メタクロレイン及びメタクリル酸の製造法
ATE255554T1 (de) * 1997-06-30 2003-12-15 Takara Bio Inc Cyclopentenonderivate
CN1108283C (zh) * 2000-09-28 2003-05-14 中国石油天然气股份有限公司兰州石化分公司 一种异丁烯水合制叔丁醇的方法
CN1511815A (zh) * 2002-12-31 2004-07-14 中国石化集团齐鲁石油化工公司 一种叔丁醇的制备方法

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CN1283174A (zh) * 1997-12-26 2001-02-07 三菱丽阳株式会社 生产叔丁醇的方法
JP2000044502A (ja) * 1998-07-30 2000-02-15 Asahi Chem Ind Co Ltd オレフィン混合物より第３級ブチルアルコールの回収方法
CN1596149A (zh) * 2001-12-21 2005-03-16 旭化成化学株式会社 氧化物催化剂组合物

Non-Patent Citations (1)

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Title
JOSHUA D. TAYLOR ET AL: "Dehydration of Fermented Isobutanol for the Production of Renewable Chemicals and Fuels", 《TOPICS IN CATALYSIS》, vol. 53, no. 1518, 30 September 2010 (2010-09-30), pages 1224 - 1230 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111004116A (zh) * 2019-12-19 2020-04-14 湖北美和科技有限公司 一种用于制备结焦抑制剂组份的甲基丙烯酸酯单体

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US20140357890A1 (en) 2014-12-04
US9346735B2 (en) 2016-05-24
JP6107139B2 (ja) 2017-04-05
JPWO2013069630A1 (ja) 2015-04-02
KR20140090650A (ko) 2014-07-17
WO2013069630A1 (ja) 2013-05-16
MY167695A (en) 2018-09-21
KR101979475B1 (ko) 2019-05-16
IN2014KN00748A (https=) 2015-10-02

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