CN103910513A - White or colored cement-based composite material used for art wares - Google Patents
White or colored cement-based composite material used for art wares Download PDFInfo
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- CN103910513A CN103910513A CN201410093727.9A CN201410093727A CN103910513A CN 103910513 A CN103910513 A CN 103910513A CN 201410093727 A CN201410093727 A CN 201410093727A CN 103910513 A CN103910513 A CN 103910513A
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- white
- cement
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- artwork
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- 239000004568 cement Substances 0.000 title claims abstract description 33
- 239000002131 composite material Substances 0.000 title claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003638 reducing agent Substances 0.000 claims abstract description 15
- 239000006004 Quartz sand Substances 0.000 claims abstract description 14
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 14
- 239000011398 Portland cement Substances 0.000 claims description 12
- 229920005646 polycarboxylate Polymers 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910052904 quartz Inorganic materials 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003292 glue Substances 0.000 abstract 2
- 239000003086 colorant Substances 0.000 abstract 1
- 239000003469 silicate cement Substances 0.000 abstract 1
- 241001465754 Metazoa Species 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N Iron(III) oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 229910000460 iron oxide Inorganic materials 0.000 description 4
- -1 metakaolin Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 241000282693 Cercopithecidae Species 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000001052 yellow pigment Substances 0.000 description 2
- 235000015655 Crocus sativus Nutrition 0.000 description 1
- 240000004229 Crocus sativus Species 0.000 description 1
- 241001115479 Opheodrys Species 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003000 nontoxic Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004248 saffron Substances 0.000 description 1
- 235000013974 saffron Nutrition 0.000 description 1
Abstract
The invention relates to a white or colored cement-based composite material used for art wares. The cement-based composite material is prepared by compounding 21.5-55.8% by weight of white cement, 5-45.9% by weight of metakaolin, 16.5-47.7% by weight of quartz sand, 0.8-2% of a water reducer, less than 0.1-4.5% by weight of fiber, less than 0.1-10% by weight of pigments, and water, wherein the water-glue ratio is 0.22-0.4, and the water-glue ratio is the ratio of the weight of the water to the sum of the weight of the white silicate cement and the weight of the metakaolin. The cement-based composite material has characteristics of high performance, diverse colors and diverse varieties, and can achieve long artistic effects.
Description
Technical field
The present invention relates to a kind of cement-base composite material field, especially polychrome high performance cement-based composites.
Background technology
Current various ornameutal handiwork adopts organic materials as resin, and to be main raw material(s) a lot of, but the shortcomings such as the artwork that adopts organic materials to make exists that material cost is high, making processes can produce a large amount of obnoxious flavoures, inflammable, not environmental protection.Certainly the artwork that also useful lithotome is made, this artwork mainly relies on the feature of stone material own, and manifestation is limited, also needs relatively consumptive material of cutting processing, cause cost high, and part stone material exists the defects such as intensity of radioactivity height.Also useful gypsum is starting material handicraft, and this artwork relative intensity is lower, frangible.Find that there is people and adopt Portland cement and sandstone mixing manufacture artwork, but substantially all gray or grey blacks of the artwork of making.Along with the raising of people's living standard, people's aesthetic standards also improve day by day, wish that each series of handicraft articles has the multiple color of being permitted available, rather than machine-made grey or grey black.
Summary of the invention
Technical problem: the problems such as the various material costs that the object of the invention is to be just used at present artwork are high, intensity is low, color is dull, making processes can produce a large amount of obnoxious flavoures, inflammable, not environmental protection, provide a kind of white or colored high-performance cement-based advanced composite material as artwork.
Technical scheme: a kind of white or colored high performance cement-based composites, is characterized in that: it is composited by comprising white cement, metakaolin, quartz sand, water reducer, fiber, pigment and water; It is characterized in that: its composition and mass percent are:
The quality that wherein water-cement ratio is water and white portland cement and metakaolin quality and ratio.
Described cement performance index meets GB/T2015-2005 regulation, and cement whiteness is not less than 87.
Described metakaolin is take kaolin as raw material, the anhydrous aluminium silicate at high temperature forming through dehydration.
Described water reducer is polycarboxylate water-reducer.
Described water performance index meet JGJ63-2006 regulation.
The particle diameter of described quartz sand, between 4 order～400 orders, also can account for by allotment quartz sand different-grain diameter the percentage ratio of total quartz sand: 4 order～30 orders 25%～63% according to white cement or colored cement base composite-material product desirable strength or degree of mobilization difference; 30 order～100 orders 5%～40%; 100 order～400 orders 2%～30%, can need to adopt colorful quartz sands according to color in addition.
Described pigment is inorganic serial pigment.
Described fiber is synthon and inorganic fibre.
Beneficial effect:
1. a kind of white as artwork of the present invention or colored cement based composites have the characteristic of high fluidity, and degree of mobilization, up to being 300mm, can pour in the mould of various fine textures.
2. a kind of white as artwork of the present invention or the product that colored cement based composites makes can reach higher-strength, and ultimate compression strength is not less than 60MPa, and folding strength is not less than 10MPa, and intensity will be higher than general artwork, good endurance.
3. in a kind of white as artwork of the present invention or colored cement based composites, can meet the vision requirement of people to artwork color effect adding of pigment.
4. a kind of white as artwork of the present invention or colored cement based composites also have that cost is low, technique is simple, making processes is pollution-free, nontoxic gas is discharged and the beneficial effect such as environmental protection.
Embodiment
By the following examples the present invention is carried out to concrete careful description, but content of the present invention is not only confined to the present embodiment.
Embodiment 1
According to following quality weighing starting material: white portland cement 42.5MPa(strength grade is not less than the white portland cement of 32.5MPa) 900g, metakaolin 100g, quartz sand 800g is 8 order-16 order: 241g wherein, 16 order-30 order: 187g, 30 order-50 order: 153g, 50-100 order: 122g, 100 order-200 order: 97g; Water 300g; Polycarboxylate water-reducer 16.5g; The green pigment 2g of ferric oxide; Synthon 2g; First white portland cement, metakaolin, quartz sand, pigment are put into stirrer, mix is to even (stirring 5～10 minutes); Then add load weighted fiber, continue mix (3～8 minutes), add the half water that weighed and half water reducer mix 2 minutes, then add remaining water and water reducer mix about 3 minutes to evenly, the slurry that obtains being stirred; This proportioning degree of mobilization is: 305mm, the slurry mixing is poured in the mould of one of 12 symbolic animals associated with a 12 year cycle snake, and the goods of moulding are put into temperature at 20 ± 2 ℃, in more than 95% standard curing room of humidity, carry out maintenance; Maintenance after 24 hours the demoulding just obtained one of a kind of high strength cement based composites artwork 12 symbolic animals associated with a 12 year cycle of green snake.The standard specimen ultimate compression strength and the folding strength that record this proportioning moulding with reference to GB/T17671-1999 standard are respectively: 80.3MPa, 12MPa.
Embodiment 2
According to following quality weighing starting material: white portland cement (strength grade is not less than the white portland cement of 32.5MPa) 900g, metakaolin 100g, quartz sand 800g is 8 order-16 order: 282g wherein, 16 order-30 order: 216g, 30 order-50 order: 134g, 50-100 order: 102g, 100 order-200 order: 66g; Water 300g; Polycarboxylate water-reducer 16.5g; The yellow pigment 15.36g of ferric oxide; Synthon 18g; First white portland cement, metakaolin, quartz sand, pigment are put into stirrer, mix is to even (stirring 5～10 minutes); Then add load weighted fiber, continue mix (3～8 minutes), add the half water that weighed and half water reducer mix 2 minutes, then add remaining water and water reducer mix about 3 minutes to evenly, this proportioning degree of mobilization is: the slurry that 310mm obtains being stirred; The slurry mixing is poured in the mould of one of 12 symbolic animals associated with a 12 year cycle monkey, the goods of moulding are put into temperature at 20 ± 2 ℃, in more than 95% standard curing room of humidity, carry out maintenance; Maintenance after 24 hours the demoulding just obtained one of a kind of high strength cement based composites artwork 12 symbolic animals associated with a 12 year cycle of yellow monkey.The standard specimen ultimate compression strength and the folding strength value that record this proportioning moulding with reference to GB/T17671-1999 standard are respectively: 86.2MPa, 10.9MPa.
Embodiment 3
According to following quality weighing starting material: white portland cement (strength grade is not less than the white portland cement of 32.5MPa) 800g, wherein 8 order-16 order: 241g of metakaolin 200g quartz sand 800g, 16 order-30 order: 187g, 30 order-50 order: 153g, 50-100 order: 122g, 100 order-200 order: 97g; Water 300g; Polycarboxylate water-reducer 16.5g; The red pigment 7.68g of ferric oxide; The yellow pigment 7.68g of ferric oxide synthon 18g, first puts into stirrer by white portland cement, metakaolin, quartz sand, pigment, and mix is to even (stirring 5～10 minutes); Then add load weighted fiber, continue mix (3～8 minutes), add the half water that weighed and half water reducer mix 2 minutes, add again remaining water and water reducer mix extremely even about 3 minutes, the slurry that obtains being stirred, this proportioning degree of mobilization is: 300mm, pours the slurry mixing in the mould of one of 12 symbolic animals associated with a 12 year cycle mouse, the goods of moulding are put into temperature at 20 ± 2 ℃, in more than 95% standard curing room of humidity, carry out maintenance; Maintenance after 24 hours the demoulding just obtained one of a kind of saffron high strength cement based composites artwork 12 symbolic animals associated with a 12 year cycle mouse.The standard specimen ultimate compression strength and the folding strength that record this proportioning moulding with reference to GB/T17671-1999 standard are respectively: 93.2MPa, 11.7MPa.
A kind of white as artwork of the present invention or colored cement based composites can be prepared the artwork of various good and cheap, different modeling, differ and repeat, within all should being included in the present invention's scope required for protection at this.
Claims (6)
1. as white or the colored cement based composites of artwork, it is characterized in that: its composition and mass percent are:
The quality that wherein water-cement ratio is water and white portland cement and metakaolin quality and ratio.
2. a kind of white or colored cement based composites as artwork according to claim 1, is characterized in that described cement performance index meets GB/T2015-2005 regulation.
3. a kind of white or colored cement based composites as artwork according to claim 1, is characterized in that described metakaolin is take kaolin as raw material, the anhydrous aluminium silicate at high temperature forming through dehydration.
4. a kind of white or colored cement based composites as artwork according to claim 1, the particle diameter of described quartz sand, between 4 order～400 orders, also can account for total quartz sand percentage ratio by allotment quartz sand different-grain diameter according to white cement or colored cement base composite-material product desirable strength or degree of mobilization difference: 4 order～30 orders 25%～60%; 30 order～100 orders 5%～40%; 100 order～400 orders 2%～30%.Can need to adopt colorful quartz sands according to color in addition.
5. a kind of white or colored cement based composites as artwork according to claim 1, is characterized in that wherein said pigment is inorganic serial pigment, and described fiber is synthon and inorganic fibre.
6. a kind of white or colored cement based composites as artwork according to claim 1, is characterized in that described water reducer is polycarboxylate water-reducer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410093727.9A CN103910513A (en) | 2014-03-13 | 2014-03-13 | White or colored cement-based composite material used for art wares |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410093727.9A CN103910513A (en) | 2014-03-13 | 2014-03-13 | White or colored cement-based composite material used for art wares |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103910513A true CN103910513A (en) | 2014-07-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410093727.9A Pending CN103910513A (en) | 2014-03-13 | 2014-03-13 | White or colored cement-based composite material used for art wares |
Country Status (1)
| Country | Link |
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| CN (1) | CN103910513A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106082879A (en) * | 2016-06-27 | 2016-11-09 | 中建商品混凝土西安有限公司 | A kind of cement based colour artware prepare material and preparation method thereof |
| CN110117175A (en) * | 2019-05-15 | 2019-08-13 | 华南理工大学 | A kind of production method of concrete making technology product of the surface with dumb light texture |
| CN111321730A (en) * | 2020-03-03 | 2020-06-23 | 云南建投第一勘察设计有限公司 | Foundation reinforcing method in superfluid cement soil pit |
| CN112979235A (en) * | 2019-12-18 | 2021-06-18 | 武汉夸克新材料有限公司 | Inorganic artificial stone with colored cement stone as coarse aggregate and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102531493A (en) * | 2011-12-30 | 2012-07-04 | 重庆暄洁环保产业（集团）股份有限公司 | White or colored cement-based composite material plate with super-high strength and preparation method thereof |
| CN103313953A (en) * | 2011-01-13 | 2013-09-18 | 乐金华奥斯株式会社 | Artificial stone and manufacturing method thereof |
-
2014
- 2014-03-13 CN CN201410093727.9A patent/CN103910513A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103313953A (en) * | 2011-01-13 | 2013-09-18 | 乐金华奥斯株式会社 | Artificial stone and manufacturing method thereof |
| CN102531493A (en) * | 2011-12-30 | 2012-07-04 | 重庆暄洁环保产业（集团）股份有限公司 | White or colored cement-based composite material plate with super-high strength and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106082879A (en) * | 2016-06-27 | 2016-11-09 | 中建商品混凝土西安有限公司 | A kind of cement based colour artware prepare material and preparation method thereof |
| CN106082879B (en) * | 2016-06-27 | 2018-06-19 | 中建商品混凝土西安有限公司 | A kind of cement base colour craftwork prepares material and preparation method thereof |
| CN110117175A (en) * | 2019-05-15 | 2019-08-13 | 华南理工大学 | A kind of production method of concrete making technology product of the surface with dumb light texture |
| CN112979235A (en) * | 2019-12-18 | 2021-06-18 | 武汉夸克新材料有限公司 | Inorganic artificial stone with colored cement stone as coarse aggregate and preparation method thereof |
| CN111321730A (en) * | 2020-03-03 | 2020-06-23 | 云南建投第一勘察设计有限公司 | Foundation reinforcing method in superfluid cement soil pit |
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Application publication date: 20140709 |