CN103898806B - Preventing atomization three-dimensional is cold mounts composite sheet - Google Patents

Preventing atomization three-dimensional is cold mounts composite sheet Download PDF

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Publication number
CN103898806B
CN103898806B CN201410139424.6A CN201410139424A CN103898806B CN 103898806 B CN103898806 B CN 103898806B CN 201410139424 A CN201410139424 A CN 201410139424A CN 103898806 B CN103898806 B CN 103898806B
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China
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layer
consumption
dimensional
rubberised
paper
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CN201410139424.6A
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Chinese (zh)
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CN103898806A (en
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聂志平
聂博
刘会萍
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湖北富狮材料科技股份有限公司
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Abstract

The invention belongs to field of packaging material, be specifically related to a kind of composite sheet.Preventing atomization three-dimensional is cold mounts composite sheet and preparation method thereof, it is characterized in that: it is made up of gloss oil layer (10), antifog oxidant layer (11), three-dimensional cold lamination film layer (9), glue-line (6), ply of paper (7) and back of the body rubberised layer (8), gloss oil layer (10), antifog oxidant layer (11), three-dimensional cold lamination film layer (9), glue-line (6), ply of paper (7), back of the body rubberised layer (8) are combined into one successively.The stereoeffect of this composite sheet is good, have atomization-preventing function.

Description

Preventing atomization three-dimensional is cold mounts composite sheet
Technical field
The invention belongs to field of packaging material, be specifically related to a kind of three-dimensional coldly mount composite sheet and preparation method thereof.
Background technology
Three-dimensional (3D) cold composite sheet of mounting is environmental protection packaging material emerging over the past two years, with the convex lens visual impact of its uniqueness and anti-counterfeiting performance, and environmental protection, attractive in appearance, high-grade characteristic, be day by day widely applied at stationery packaging fields such as drinks, daily use chemicals, medicines and health protection, exquisite gifts.Three-dimensional cold composite sheet of mounting, as the performance of environment-friendly products with its brilliance, finally certainly will will replace compound package material, promote the development of packaging, printing industry.Current three-dimensional is cold mounts composite sheet, and visual effect, stereoeffect, preventing atomization effect are not ideal.
Summary of the invention
The object of the present invention is to provide that a kind of preventing atomization is three-dimensional coldly mounts composite sheet and preparation method thereof, the stereoeffect of this composite sheet is good, there is atomization-preventing function.
To achieve these goals, the technical solution used in the present invention is: preventing atomization three-dimensional is cold mounts composite sheet, it is characterized in that: it is made up of gloss oil layer 10, antifog oxidant layer 11, three-dimensional cold lamination film layer 9, glue-line 6, ply of paper 7 and back of the body rubberised layer 8, gloss oil layer 10, antifog oxidant layer 11, three-dimensional cold lamination film layer 9, glue-line 6, ply of paper 7, back of the body rubberised layer 8 are combined into one successively.
Described three-dimensional cold lamination film layer 9 is made up of rubberised layer 1, aluminium lamination 2, mold pressing Information Level 3, coating layer 4 and bidirectional stretching polypropylene film 5, and rubberised layer 1, aluminium lamination 2, mold pressing Information Level 3, coating layer 4, bidirectional stretching polypropylene film 5 are combined into one successively.
The material of antifog oxidant layer 11 is antifoggant, and consumption is 3g/m 2; Antifoggant can adopt glycerin mono-fatty acid ester, sorbitan monopalmitate, sorbitan monostearate or poly(ethylene oxide) (20) glyceryl monostearate; The material of described gloss oil layer 10 is acrylic resin, and consumption is 3g/m 2; The material of described glue-line 6 is acrylate adhesive, and consumption is 3g/m 2; The material of described ply of paper 7 is paper, and consumption is 225g/m 2; The material of described back of the body rubberised layer 8 is polyvinyl alcohol, and consumption is 3g/m 2; The consumption of described three-dimensional cold lamination film layer 9 is 17-27g/m 2.
The material of described rubberised layer 1 is acrylate adhesive, and consumption is 3g/m 2; The material of described aluminium lamination 2 is aluminium, and consumption is 1-5g/m 2; Described mold pressing Information Level 3 is: holographic for metal laser version be directly pressed on coating layer, fringe depths requires 5 ~ 8 microns, forms mold pressing Information Level; The material of described coating layer 4 is gloss oil, and consumption is 3g/m 2; The consumption of described bidirectional stretching polypropylene film 5 is 10-16g/m 2.
The three-dimensional cold preparation method mounting composite sheet of preventing atomization, is characterized in that it comprises the steps:
1) preparation of three-dimensional cold lamination film;
2) below ply of paper 7, be coated with layer of polyethylene alcohol, form back of the body rubberised layer 8; At coated thereon one deck acrylate adhesive of ply of paper 7, form glue-line 6;
3) contact below the bidirectional stretching polypropylene film 5 of three-dimensional cold lamination film layer 9 with glue-line 6; At coated thereon one deck antifoggant of the rubberised layer 1 of three-dimensional cold lamination film layer 9, form antifog oxidant layer 11, at coated thereon one deck acrylic resin of antifog oxidant layer 11, form gloss oil layer 10; Then be combined into one by compounding machine.
The preparation of above-mentioned three-dimensional cold lamination film layer 9, it comprises the steps:
1) at coated thereon one deck gloss oil of bidirectional stretching polypropylene film 5, coating layer 4 is formed;
2) be directly pressed on coating layer 4 by holographic for metal laser version, fringe depths requires 5 ~ 8 microns, forms mold pressing Information Level 3;
3) utilize equipment of aluminizing, aluminium wire is heated to about 1500 DEG C melting evaporations, and the condensation that distils, evenly steam one deck aluminium lamination on an information layer, form aluminium lamination 2;
4) at coated thereon one deck acrylate adhesive of aluminium lamination 2, rubberised layer 1 is formed.
The invention has the beneficial effects as follows: adopt said structure, the stereoeffect of composite sheet of the present invention is good, there is atomization-preventing function.Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Fig. 2 is outward appearance photo figure of the present invention.
In figure: 1-rubberised layer, 2-aluminium lamination, 3-mold pressing Information Level, 4-coating layer, 5-bidirectional stretching polypropylene film, 6-glue-line, 7-ply of paper, 8-carries on the back rubberised layer, the three-dimensional cold lamination film layer of 9-, 10-gloss oil layer, the antifog oxidant layer of 11-.
Detailed description of the invention
As shown in Figure 1, preventing atomization three-dimensional is cold mounts composite sheet, it is made up of gloss oil layer 10, antifog oxidant layer 11, three-dimensional cold lamination film layer 9, glue-line 6, ply of paper 7 and back of the body rubberised layer 8, and gloss oil layer 10, antifog oxidant layer 11, three-dimensional cold lamination film layer 9, glue-line 6, ply of paper 7, back of the body rubberised layer 8 are combined into one successively.
Described three-dimensional cold lamination film layer 9 is made up of rubberised layer 1, aluminium lamination 2, mold pressing Information Level 3, coating layer 4 and bidirectional stretching polypropylene film 5, and rubberised layer 1, aluminium lamination 2, mold pressing Information Level 3, coating layer 4, bidirectional stretching polypropylene film 5 are combined into one successively.
The material of antifog oxidant layer 11 is antifoggant, and consumption is 3g/m 2.The partial esterification thing of the chemical composition of antifoggant mainly aliphatic acid and polyalcohol.Conventional polyalcohol is glycerine (glycerin mono-fatty acid ester), D-sorbite and acid anhydrides thereof, and the aliphatic acid that conventional aliphatic acid is the saturated acid of C11, C12 or unsaturated acids, carbon number is more than 24 also can use.In general, the ester initial stage good antifogging effect of medium chain fatty acid; The lasting good antifogging effect of fat of LCFA.In fact the mixed ester of antifoggant multiple acid often, the fatty acid ester of many polyalcohols lacks hydrophily, by ethyleneoxide addition, can improve hydrophily, and the initial stage that increases is anti-fog properties and low temperature is anti-fog properties.
Antifoggant can adopt glycerin mono-fatty acid ester, sorbitan monopalmitate, sorbitan monostearate or poly(ethylene oxide) (20) glyceryl monostearate.
The material of described gloss oil layer 10 is acrylic resin, and consumption is 3g/m 2.The material of described glue-line 6 is acrylate adhesive, and consumption is 3g/m 2.The material of described ply of paper 7 is paper (string is made), and consumption is 225g/m 2.The material of described back of the body rubberised layer 8 is polyvinyl alcohol, and consumption is 3g/m 2.The consumption of described three-dimensional cold lamination film layer 9 is 17-27g/m 2.
The material of described rubberised layer 1 is acrylate adhesive, and consumption is 3g/m 2.The material of described aluminium lamination 2 is aluminium, and consumption is 1-5g/m 2.
Described mold pressing Information Level 3 is: control molding temperature (170-190 DEG C), molding pressure (15-20kg/cm2), utilize the thermoplastic deformation behavior of coating layer, holographic for metal laser version is directly pressed on coating layer that [candy strip in the holographic version of metal laser is transferred on coating layer, and (traditional fringe depths is 1 ~ 2 micron, the fringe depths making three-dimensional cold lamination film requires 5 ~ 8 microns)], form mold pressing Information Level.
The material of described coating layer 4 is gloss oil, and consumption is 3g/m 2.The consumption of described bidirectional stretching polypropylene film (adopting existing) 5 is 10-16g/m 2.
The preparation of above-mentioned three-dimensional cold lamination film layer 9, it comprises the steps:
1) at coated thereon one deck gloss oil of bidirectional stretching polypropylene film (adopting existing) 5, coating layer 4 is formed;
2) molding temperature (170-190 DEG C) is controlled, molding pressure (15-20kg/cm2), utilize the thermoplastic deformation behavior of coating layer, holographic for metal laser version is directly pressed on coating layer 4 that [candy strip in the holographic version of metal laser is transferred on coating layer, and (traditional fringe depths is 1 ~ 2 micron, the fringe depths making three-dimensional cold lamination film requires 5 ~ 8 microns)], form mold pressing Information Level 3;
3) utilize equipment of aluminizing, aluminium wire is heated to about 1500 DEG C melting evaporations, and the condensation that distils, evenly steam one deck aluminium lamination on an information layer, form aluminium lamination 2;
4) at coated thereon one deck acrylate adhesive of aluminium lamination 2, rubberised layer 1 is formed.
The three-dimensional cold preparation method mounting composite sheet of preventing atomization, it comprises the steps:
1) preparation (see above-mentioned) of three-dimensional cold lamination film;
2) below paper (ply of paper 7), (i.e. the back side) is coated with layer of polyethylene alcohol, forms back of the body rubberised layer 8; At coated thereon one deck acrylate adhesive of paper (ply of paper 7), form glue-line 6;
3) contact below the bidirectional stretching polypropylene film 5 of three-dimensional cold lamination film layer 9 with glue-line 6; At coated thereon one deck antifoggant of the rubberised layer 1 of three-dimensional cold lamination film layer 9, form antifog oxidant layer 11, at coated thereon one deck acrylic resin of antifog oxidant layer 11, form gloss oil layer 10; Then be combined into one by compounding machine.Combined temp is 80 ~ 130 DEG C, pressure 3-5 kilogram.
Preventing atomization three-dimensional of the present invention is cold mounts composite sheet (for a kind of optical lens array imaging film), third dimension is strong, transparency is high, there is lens wide-angle effect, downscaled images, broaden one's vision, reflection can observe the several image reduced of thing, very novel, because of the extremely similar opal of viewing effect, therefore claim 3D opal composite sheet.The three-dimensional special efficacy of this composite sheet is very strong, and hold the film less than 1 millimeters thick, eyes can be become 4-5 cm thick by illusion.As shown in Figure 2, the stereoeffect that picture shows composite sheet of the present invention is good for the outward appearance photo of product.
The three-dimensional cold composite sheet of mounting of preventing atomization of the present invention does not haze, and mist degree (%) :≤0.3, has atomization-preventing function.

Claims (2)

1. preventing atomization three-dimensional is cold mounts composite sheet, it is characterized in that: it is made up of gloss oil layer (10), antifog oxidant layer (11), three-dimensional cold lamination film layer (9), glue-line (6), ply of paper (7) and back of the body rubberised layer (8), gloss oil layer (10), antifog oxidant layer (11), three-dimensional cold lamination film layer (9), glue-line (6), ply of paper (7), back of the body rubberised layer (8) are combined into one successively;
Described three-dimensional cold lamination film layer (9) is made up of rubberised layer (1), aluminium lamination (2), mold pressing Information Level (3), coating layer (4) and bidirectional stretching polypropylene film (5), and rubberised layer (1), aluminium lamination (2), mold pressing Information Level (3), coating layer (4), bidirectional stretching polypropylene film (5) are combined into one successively;
The material of antifog oxidant layer (11) is antifoggant, and consumption is 3g/m 2; Antifoggant can adopt glycerin mono-fatty acid ester, sorbitan monopalmitate, sorbitan monostearate or poly(ethylene oxide) (20) glyceryl monostearate; The material of described gloss oil layer (10) is acrylic resin, and consumption is 3g/m 2; The material of described glue-line (6) is acrylate adhesive, and consumption is 3g/m 2; The material of described ply of paper (7) is paper, and consumption is 225g/m 2; The material of described back of the body rubberised layer (8) is polyvinyl alcohol, and consumption is 3g/m 2; The consumption of described three-dimensional cold lamination film layer (9) is 17-27g/m 2;
The material of described rubberised layer (1) is acrylate adhesive, and consumption is 3g/m 2; The material of described aluminium lamination (2) is aluminium, and consumption is 1-5g/m 2; Described mold pressing Information Level (3) is: holographic for metal laser version be directly pressed on coating layer, fringe depths requires 5 ~ 8 microns, forms mold pressing Information Level; The material of described coating layer (4) is gloss oil, and consumption is 3g/m 2; The consumption of described bidirectional stretching polypropylene film (5) is 10-16g/m 2.
2. the three-dimensional cold preparation method mounting composite sheet of preventing atomization as claimed in claim 1, is characterized in that it comprises the steps:
1) preparation of three-dimensional cold lamination film;
It comprises the steps:
(1) at coated thereon one deck gloss oil of bidirectional stretching polypropylene film (5), coating layer (4) is formed;
(2) be directly pressed on coating layer (4) by holographic for metal laser version, fringe depths requires 5 ~ 8 microns, forms mold pressing Information Level (3);
(3) utilize equipment of aluminizing, aluminium wire is heated to about 1500 DEG C melting evaporations, and the condensation that distils, evenly steam one deck aluminium lamination on an information layer, form aluminium lamination (2);
(4) at coated thereon one deck acrylate adhesive of aluminium lamination (2), rubberised layer (1) is formed;
2) below ply of paper (7), be coated with layer of polyethylene alcohol, form back of the body rubberised layer (8); At coated thereon one deck acrylate adhesive of ply of paper (7), form glue-line (6);
3) contact below the bidirectional stretching polypropylene film (5) of three-dimensional cold lamination film layer (9) with glue-line (6); At coated thereon one deck antifoggant of the rubberised layer (1) of three-dimensional cold lamination film layer (9), form antifog oxidant layer (11), at coated thereon one deck acrylic resin of antifog oxidant layer (11), form gloss oil layer (10); Then be combined into one by compounding machine.
CN201410139424.6A 2014-04-06 2014-04-06 Preventing atomization three-dimensional is cold mounts composite sheet CN103898806B (en)

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Publication number Priority date Publication date Assignee Title
CN104260525A (en) * 2014-09-25 2015-01-07 海南赛诺实业有限公司 Biaxially-oriented polypropylene anti-mist film with five-layer coextrusion and manufacturing method thereof
CN108166327A (en) * 2017-12-22 2018-06-15 湖北富狮材料科技股份有限公司 Durable aluminum imitates foil transfer paper and preparation method thereof
CN108166329A (en) * 2017-12-22 2018-06-15 湖北富狮材料科技股份有限公司 Preventing atomization aluminium imitates foil transfer paper and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN201542556U (en) * 2009-11-26 2010-08-11 张良臣 Antifog paper towel used for automobile
CN102442098A (en) * 2011-09-30 2012-05-09 绍兴虎彩激光材料科技有限公司 Cold-hot film process
CN102535258A (en) * 2011-12-22 2012-07-04 博源科技材料(烟台)有限公司 Transfer hollow-out-out sprayed metallic paper or card paper and production process thereof
CN102535253A (en) * 2011-12-29 2012-07-04 绍兴京昇光信息科技有限公司 Production process of aluminum-foil-imitated direct plating paper

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103578349B (en) * 2012-08-02 2015-12-09 李华容 A kind of anti-counterfeiting mark and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201542556U (en) * 2009-11-26 2010-08-11 张良臣 Antifog paper towel used for automobile
CN102442098A (en) * 2011-09-30 2012-05-09 绍兴虎彩激光材料科技有限公司 Cold-hot film process
CN102535258A (en) * 2011-12-22 2012-07-04 博源科技材料(烟台)有限公司 Transfer hollow-out-out sprayed metallic paper or card paper and production process thereof
CN102535253A (en) * 2011-12-29 2012-07-04 绍兴京昇光信息科技有限公司 Production process of aluminum-foil-imitated direct plating paper

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