CN103788454A - 一种防霉抗菌聚乙烯泡沫材料及其制备方法 - Google Patents

一种防霉抗菌聚乙烯泡沫材料及其制备方法 Download PDF

Info

Publication number
CN103788454A
CN103788454A CN201410028029.0A CN201410028029A CN103788454A CN 103788454 A CN103788454 A CN 103788454A CN 201410028029 A CN201410028029 A CN 201410028029A CN 103788454 A CN103788454 A CN 103788454A
Authority
CN
China
Prior art keywords
parts
weight
polyethylene foam
antimildew
antibacterial polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201410028029.0A
Other languages
English (en)
Inventor
曹伟
葛锦妹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Haiou Lift-Saving & Protection Equipment Co Ltd
Original Assignee
Nantong Haiou Lift-Saving & Protection Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Haiou Lift-Saving & Protection Equipment Co Ltd filed Critical Nantong Haiou Lift-Saving & Protection Equipment Co Ltd
Priority to CN201410028029.0A priority Critical patent/CN103788454A/zh
Publication of CN103788454A publication Critical patent/CN103788454A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/06—CO2, N2 or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)

Abstract

本发明涉及一种防霉抗菌聚乙烯泡沫材料及其制备方法，属于高分子材料技术领域。该聚乙烯泡沫材料包括按照重量份数计的如下组分：低密度聚乙烯100~120份、成核剂0.5~1.5份、纳米氧化锌0.5~2份、α-溴代肉桂醛1~3份、发泡剂1~5份、单甘脂1~2份、甲基硫酸（3-月桂酰胺基丙基）三甲基铵1~2份。本发明产品质量轻，透明性好，减震性能和抗冲击性能良好，且具有良好的防霉和抗菌作用；同时，本发明优选以二氧化碳为发泡剂，避免了使用丁烷为发泡剂时带来的安全隐患。此外，本发明制备方法简单，易于推广应用。

Description

一种防霉抗菌聚乙烯泡沬材料及其制备方法
技术领域
[0001] 本发明属于高分子材料技术领域，具体涉及一种防霉抗菌聚乙烯泡沫材料及其制备方法。
背景技术
[0002] 救生衣是一种救护生命的服装，设计类似背心，采用尼龙面料、氯丁橡胶、浮力材料、可充气的材料或反光材料等制作而成，穿在身上具有足够浮力，使落水者头部能露出水面，是船上、飞机上的救生设备之一。
[0003]目前市场上最常见的救生衣为背心式，采用聚乙烯泡沫塑料外包尼龙面料制成，其使用年限为5-7年。正是由于救生衣的贮存使用环境，决定了救生衣很容易霉变。现有市场上大部分救生衣没有防霉杀菌功能，因此如何克服现有技术的不足是目前高分子材料技术领域亟需解决的问题。
发明内容
[0004] 本发明的目的是为了解决现有技术的不足，提供一种防霉抗菌聚乙烯泡沫材料及其制备方法，该制备方法简单，制得的防霉抗菌聚乙烯泡沫材料质量轻，透明性好，具有良好的减震和抗冲击性能。
[0005] 本发明采用的技术方案如下:
一种防霉抗菌聚乙烯泡沫材料，包括按照重量份数计的如下组分:低密度聚乙烯100^120份、成核剂0.5^1.5份、纳米氧化锌0.5^2份、α -溴代肉桂醛f 3份、发泡剂f 5份、单甘脂广2份、甲基硫酸(3-月桂酰胺基丙基)三甲基铵f 2份。
[0006] 所述的发泡剂为二氧化碳。
[0007] 所述的成核剂为碳酸钙。
[0008] 本发明还提供一种防霉抗菌聚乙烯泡沫材料的制备方法，包括如下步骤:
步骤(1):将低密度聚乙烯、成核剂、纳米氧化锌、α-溴代肉桂醛和甲基硫酸(3-月桂酰胺基丙基)三甲基铵混合均匀，得到混合物料；
步骤(2):将步骤(1)得到的混合物料用挤出机挤出发泡，同时通过计量泵向挤出机中注入发泡剂和单甘脂，挤出温度为14(T230°C，然后再定型，分切，展平，牵引，卷曲，包装，即得到本发明的防霉抗菌聚乙烯泡沫材料。
[0009] 本发明与现有技术相比，其有益效果为:(1)本发明产品质量轻，透明性好，减震性能和抗冲击性能良好，且具有良好的防霉和抗菌作用，可广泛用于制造救生衣；(2)本发明优选以二氧化碳为发泡剂，避免了使用丁烷为发泡剂时带来的安全隐患；(3)本发明产品制备方法简单，易于推广应用。
具体实施例
[0010] 下面结合实施例对本发明作进一步的详细描述。[0011] 实施例1
一种防霉抗菌聚乙烯泡沫材料，包括按照重量份数计的如下组分:低密度聚乙烯100份、碳酸钙0.5份、纳米氧化锌0.5份、α -溴代肉桂醛1份、二氧化碳1份、单甘脂1份、甲
基硫酸(3-月桂酰胺基丙基)三甲基铵1份。
[0012] 本实施例防霉抗菌聚乙烯泡沫材料的制备方法，包括如下步骤:
步骤(1):将低密度聚乙烯、碳酸钙、纳米氧化锌、α-溴代肉桂醛和甲基硫酸(3-月桂酰胺基丙基)三甲基铵混合均匀，得到混合物料；
步骤(2):将步骤(1)得到的混合物料用挤出机挤出发泡，同时通过计量泵向挤出机中注入二氧化碳和单甘脂，挤出温度为14(T230°C，然后再定型，分切，展平，牵引，卷曲，包装，即得到本发明的防霉抗菌聚乙烯泡沫材料。实施例2
一种防霉抗菌聚乙烯泡沫材料，包括按照重量份数计的如下组分:低密度聚乙烯120份、碳酸钙1.5份、纳米氧化锌2份、α -溴代肉桂醛3份、二氧化碳5份、单甘脂2份、甲基硫酸(3-月桂酰胺基丙基)三甲基铵2份。
[0013] 本实施例的防霉抗菌聚乙烯泡沫材料的制备方法与实施例1的相同。
[0014] 实施例3
一种防霉抗菌聚乙烯泡沫材料，包括按照重量份数计的如下组分:低密度聚乙烯110份、碳酸钙1份、纳米氧化锌1.3份、α -溴代肉桂醛2.1份、二氧化碳3份、单甘脂1.4份、甲基硫酸(3-月桂酰胺基丙基)三甲基铵1.5份。
[0015] 本实施例的防霉抗菌聚乙烯泡沫材料的制备方法与实施例1的相同。
[0016] 对本发明实施例3所得产品的进行性能测试，结果如表1所示。
[0017] 表1本发明实施例3产品性能测试数据
Figure CN103788454AD00041
同时对实施例3产品的抗菌性能进行测试:
采用常规微生物抗菌效果检测，其抗菌力结果为:金黄色葡萄球菌92%，大肠杆菌90%。

Claims (4)

1.一种防霉抗菌聚乙烯泡沫材料，其特征在于包括按照重量份数计的如下组分:低密度聚乙烯100-120份、成核剂0.5^1.5份、纳米氧化锌0.5^2份、α -溴代肉桂醛f 3份、发泡剂广5份、单甘脂f 2份、甲基硫酸(3-月桂酰胺基丙基)三甲基铵f 2份。
2.根据权利要求1所述的防霉抗菌聚乙烯泡沫材料，其特征在于所述的发泡剂为二氧化碳。
3.根据权利要求1所述的防霉抗菌聚乙烯泡沫材料，其特征在于所述的成核剂为碳酸钙。
4.权利要求1所述的防霉抗菌聚乙烯泡沫材料的制备方法，其特征在于包括如下步骤: 步骤(1):将低密 度聚乙烯、成核剂、纳米氧化锌、α-溴代肉桂醛和甲基硫酸(3-月桂酰胺基丙基)三甲基铵混合均匀，得到混合物料； 步骤(2):将步骤(1)得到的混合物料用挤出机挤出发泡，同时通过计量泵向挤出机中注入发泡剂和单甘脂，挤出温度为14(T230°C，然后再定型，分切，展平，牵引，卷曲，包装，即得到本发明的防霉抗菌聚乙烯泡沫材料。
CN201410028029.0A 2014-01-22 2014-01-22 一种防霉抗菌聚乙烯泡沫材料及其制备方法 Withdrawn CN103788454A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410028029.0A CN103788454A (zh) 2014-01-22 2014-01-22 一种防霉抗菌聚乙烯泡沫材料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410028029.0A CN103788454A (zh) 2014-01-22 2014-01-22 一种防霉抗菌聚乙烯泡沫材料及其制备方法

Publications (1)

Publication Number Publication Date
CN103788454A true CN103788454A (zh) 2014-05-14

Family

ID=50664537

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410028029.0A Withdrawn CN103788454A (zh) 2014-01-22 2014-01-22 一种防霉抗菌聚乙烯泡沫材料及其制备方法

Country Status (1)

Country Link
CN (1) CN103788454A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387655A (zh) * 2014-11-24 2015-03-04 苏州市贝克生物科技有限公司 一种医用纳米氧化锌抗菌pe及其制备方法
CN104403172A (zh) * 2014-11-25 2015-03-11 苏州九鼎珍珠棉有限公司 一种ldpe发泡异形材料及其制备方法
CN105646984A (zh) * 2016-01-28 2016-06-08 惠州市环美盛新材料有限公司 一种抗菌聚乙烯泡沫及其制备方法
CN108752734A (zh) * 2018-05-04 2018-11-06 广德祥源新材科技有限公司 一种可降解的抗菌型塑料发泡卷材及制造方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102286164A (zh) * 2010-06-18 2011-12-21 中国石油化工股份有限公司 一种抗菌性聚乙烯泡沫塑料及其制备方法
CN103333392A (zh) * 2013-06-24 2013-10-02 苏州新区佳合塑胶有限公司 一种天然抗菌珍珠棉

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102286164A (zh) * 2010-06-18 2011-12-21 中国石油化工股份有限公司 一种抗菌性聚乙烯泡沫塑料及其制备方法
CN103333392A (zh) * 2013-06-24 2013-10-02 苏州新区佳合塑胶有限公司 一种天然抗菌珍珠棉

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王加龙: "《热塑性塑料挤出生产技术》", 31 August 2003, article ""PE泡沫片材挤出生产技术"", pages: 335 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387655A (zh) * 2014-11-24 2015-03-04 苏州市贝克生物科技有限公司 一种医用纳米氧化锌抗菌pe及其制备方法
CN104403172A (zh) * 2014-11-25 2015-03-11 苏州九鼎珍珠棉有限公司 一种ldpe发泡异形材料及其制备方法
CN105646984A (zh) * 2016-01-28 2016-06-08 惠州市环美盛新材料有限公司 一种抗菌聚乙烯泡沫及其制备方法
CN105646984B (zh) * 2016-01-28 2018-03-27 惠州市环美盛新材料有限公司 一种抗菌聚乙烯泡沬及其制备方法
CN108752734A (zh) * 2018-05-04 2018-11-06 广德祥源新材科技有限公司 一种可降解的抗菌型塑料发泡卷材及制造方法

Similar Documents

Publication Publication Date Title
CN103788454A (zh) 一种防霉抗菌聚乙烯泡沫材料及其制备方法
AU2014101568A4 (en) High filling and high resilience soft foaming polyethylene material and preparation method thereof
CN104877335B (zh) 一种热塑性聚氨酯弹性体发泡珠粒及其制备方法
CN107200879B (zh) 一种丁腈橡胶微孔发泡材料及其制备方法
CN104672427B (zh) 一种用于汽车内饰件的高硬度聚氨酯软泡及其制备方法
CN104479331A (zh) 汽车坐垫塑料配方
CN103435886B (zh) 一种阻燃气相防锈珍珠棉及其制备方法
CA2929472C (en) Mixtures of polyether carbonate polyols and polyether polyols for producing polyurethane soft foams
CN103788468A (zh) 一种eva/pe复合发泡材料及其制备方法
CN103289412B (zh) 硅橡胶闭孔发泡材料及其制备方法
EA201590308A1 (ru) Природный каучук, содержащий наноуглерод
CN108610621A (zh) 一种高吸声性低密度聚氨酯半硬质泡沫及其制备方法
CN104558492B (zh) 一种低气味高阻燃的车用聚氨酯内饰泡沫及其制备方法
JP2014521798A5 (zh)
CN103387699A (zh) 一种低蠕变减振橡胶及其挤出成型方法
CN105860329A (zh) 抑菌型软质聚氯乙烯人造革发泡层材料及其制备方法
MX2017003347A (es) Espumas hidrofilas de celda abierta.
CN103788579A (zh) 一种耐高温城轨电缆护套材料
CN105368015A (zh) 一种汽车座椅的发泡材料及其制备方法和应用
CN108084506A (zh) 一种耐老化天然橡胶复合材料
CN105133320A (zh) 一种轻质抗菌吸音棉及其制备方法
CN103214645B (zh) 一种聚氨酯泡沫的制备方法
CN104072822A (zh) 一种用于椅背连接的弹性橡胶件及其加工工艺
CN103724686A (zh) 一种高分子橡胶混合物
CN103709368A (zh) 一种软质pu泡沫塑料及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C04 Withdrawal of patent application after publication (patent law 2001)
WW01 Invention patent application withdrawn after publication

Application publication date: 20140514