CN103764268B - 使用集成膜反应器的烯烃水合方法 - Google Patents

使用集成膜反应器的烯烃水合方法 Download PDF

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Publication number
CN103764268B
CN103764268B CN201280039107.6A CN201280039107A CN103764268B CN 103764268 B CN103764268 B CN 103764268B CN 201280039107 A CN201280039107 A CN 201280039107A CN 103764268 B CN103764268 B CN 103764268B
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CN
China
Prior art keywords
reaction zone
alcohol
permeable membrane
hydration
catalyst
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Expired - Fee Related
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CN201280039107.6A
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English (en)
Chinese (zh)
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CN103764268A (zh
Inventor
易卜拉欣·阿巴
阿代什·哈拉利
斯蒂芬·拉尔夫·福格尔
W·徐
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Saudi Arabian Oil Co
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Saudi Arabian Oil Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/006—Separating solid material from the gas/liquid stream by filtration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1893—Membrane reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/0257—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278—Feeding reactive fluids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Catalysts (AREA)
CN201280039107.6A 2011-08-10 2012-07-17 使用集成膜反应器的烯烃水合方法 Expired - Fee Related CN103764268B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/207,122 US8865950B2 (en) 2011-08-10 2011-08-10 Olefin hydration process with an integrated membrane reactor
US13/207,122 2011-08-10
PCT/US2012/047003 WO2013022565A1 (en) 2011-08-10 2012-07-17 Olefin hydration process with and integrated membrane reactor

Publications (2)

Publication Number Publication Date
CN103764268A CN103764268A (zh) 2014-04-30
CN103764268B true CN103764268B (zh) 2017-03-29

Family

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Family Applications (1)

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CN201280039107.6A Expired - Fee Related CN103764268B (zh) 2011-08-10 2012-07-17 使用集成膜反应器的烯烃水合方法

Country Status (6)

Country Link
US (2) US8865950B2 (https=)
EP (1) EP2741848B1 (https=)
JP (2) JP2014534163A (https=)
KR (1) KR101854955B1 (https=)
CN (1) CN103764268B (https=)
WO (1) WO2013022565A1 (https=)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8865950B2 (en) * 2011-08-10 2014-10-21 Saudi Arabian Oil Company Olefin hydration process with an integrated membrane reactor
KR101876612B1 (ko) * 2011-12-05 2018-07-09 사우디 아라비안 오일 컴퍼니 친수성 멤브레인 통합형 올레핀 수화 공정
DE102014209413A1 (de) * 2014-05-19 2015-11-19 Evonik Degussa Gmbh Membrangestützte Katalysatorabtrennung bei der Epoxidierung von Fettsäurealkylestern
CN105498646B (zh) * 2015-12-31 2019-04-05 成都易态科技有限公司 反应釜和应用该反应釜的三相流催化反应方法
US10570071B1 (en) 2018-12-12 2020-02-25 Saudi Arabian Oil Company Membrane-based process for butanols production from mixed butenes
CN110227331B (zh) * 2019-06-13 2020-07-17 中国石油大学(北京) 一种水合物-膜法耦合分离混合气体的方法和装置
CN112705116B (zh) * 2019-10-25 2021-10-08 中国石油化工股份有限公司 一种重油加氢反应器及加氢方法
KR102383657B1 (ko) * 2020-07-15 2022-04-05 한국화학연구원 고투과성 거터층을 포함하는 복합막 및 이의 제조방법
CN118765212A (zh) * 2022-02-28 2024-10-11 日本碍子株式会社 反应器组件和分离膜组件

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WO1988005768A1 (en) * 1987-02-02 1988-08-11 Exxon Chemical Patents, Inc. Process for the recovery of alcohols using an organic acid-modified polymer membrane
EP0579153A2 (en) * 1992-07-13 1994-01-19 Tosoh Corporation Process for producing tertiary alcohol, and for preparing catalyst therefor
CN1092757A (zh) * 1992-12-25 1994-09-28 旭化成工业株式会社 环烯烃水合法
WO1994021377A1 (en) * 1993-03-16 1994-09-29 Exxon Chemical Patents Inc. A method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
CN1230169A (zh) * 1996-09-10 1999-09-29 旭化成工业株式会社 甲基丙烯酸酯或丙烯酸酯的方法
JP2007055970A (ja) * 2005-08-26 2007-03-08 Mitsui Eng & Shipbuild Co Ltd メタノール製造用反応器及びメタノール製造方法

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WO1988005768A1 (en) * 1987-02-02 1988-08-11 Exxon Chemical Patents, Inc. Process for the recovery of alcohols using an organic acid-modified polymer membrane
EP0579153A2 (en) * 1992-07-13 1994-01-19 Tosoh Corporation Process for producing tertiary alcohol, and for preparing catalyst therefor
CN1092757A (zh) * 1992-12-25 1994-09-28 旭化成工业株式会社 环烯烃水合法
WO1994021377A1 (en) * 1993-03-16 1994-09-29 Exxon Chemical Patents Inc. A method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
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JP2007055970A (ja) * 2005-08-26 2007-03-08 Mitsui Eng & Shipbuild Co Ltd メタノール製造用反応器及びメタノール製造方法

Also Published As

Publication number Publication date
US20130041186A1 (en) 2013-02-14
US8865950B2 (en) 2014-10-21
KR20140054198A (ko) 2014-05-08
WO2013022565A8 (en) 2014-03-13
EP2741848B1 (en) 2018-12-26
EP2741848A1 (en) 2014-06-18
US20150004073A1 (en) 2015-01-01
US9233349B2 (en) 2016-01-12
WO2013022565A1 (en) 2013-02-14
JP6464105B2 (ja) 2019-02-06
JP2016153392A (ja) 2016-08-25
CN103764268A (zh) 2014-04-30
JP2014534163A (ja) 2014-12-18
KR101854955B1 (ko) 2018-05-04

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