CN103740089A - High-strength modified polyphenyl ether - Google Patents
High-strength modified polyphenyl ether Download PDFInfo
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- CN103740089A CN103740089A CN201410024581.2A CN201410024581A CN103740089A CN 103740089 A CN103740089 A CN 103740089A CN 201410024581 A CN201410024581 A CN 201410024581A CN 103740089 A CN103740089 A CN 103740089A
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- noryl
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Abstract
The invention discloses a high-strength modified polyphenyl ether, which is prepared from polydiphenyl ether plastic and an additive, wherein the additive comprises a light stabilizer, an anti-impact modifier, a filler, a lubricating agent and a dispersing agent, wherein the light stabilizer is 2,2'-sulpho-bi(4-tert-octylphenol ether) nickel; the anti-impact modifier is chlorinated polyethylene; the filler is attapulgite; the lubricating agent is microcrystalline wax; the dispersing agent is cellulose acetate butyrate. The prepared high-strength modified polyphenyl ether has the characteristics of being good in light resistance, invariant in color, high in mechanical strength, good in mobility, large in hardness, easy to process, good in quality and low in production cost by adding a plurality of additives to the polyphenyl ether plastic.
Description
Technical field
The present invention relates to plastics, particularly relate to a kind of high strength Noryl.
Background technology
Polyphenylene oxide is the high-strength engineering plastic growing up 1960's, and chemical name, for poly-2,6-dimethyl-Isosorbide-5-Nitrae-phenylate, is called for short PPO or PPE, is called again polyphenylene oxide or polyhenylene ether.Auto industry field is applicable to instrument plate, window frame, vibroshock, pump screen etc., mechanical industry field is as gear, bearing, pump impeller, blower wheel sheet etc., and chemical field is used for making the corrosion-resistant component such as pipeline, valve, filter disc and submersible pump.Polyphenylene oxide photostabilization is poor, and melt fluidity is poor, machine-shaping difficulty, and itself physical strength, hardness, quality are all general, are accompanied by high production cost in use toward contact.
Summary of the invention
The high strength Noryl that the technical problem that the present invention mainly solves is to provide that a kind of photostabilization is good, nondiscoloration, physical strength are high, good fluidity, hardness are large, be easy to processing, quality is good, production cost is low.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of high strength Noryl is provided, by polydiphenyl ether plastics and additive, made, described additive comprises photostabilizer, shock resistance modification agent, weighting agent, lubricant and dispersion agent, described photostabilizer is 2, 2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel, described shock resistance modification agent is chlorinatedpolyethylene, described weighting agent is attapulgite clay, described lubricant is microcrystalline wax, described dispersion agent is cellulose acetate butyrate, the shared weight percent of described each composition of high strength Noryl is respectively polydiphenyl ether plastics and accounts for 84.9%-89.4%, 2, 2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel accounts for 0.4%-1.3%, chlorinatedpolyethylene accounts for 6.8%-7.7%, attapulgite clay accounts for 1.5%-2.4%, microcrystalline wax accounts for 0.7%-1.6%, cellulose acetate butyrate accounts for 1.2%-2.1%.
In a preferred embodiment of the present invention, the described shared weight percent of each composition of high strength Noryl is specially polydiphenyl ether plastics and accounts for 88.9%, 2,2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel accounts for 0.5%, chlorinatedpolyethylene accounts for 6.9%, attapulgite clay accounts for 1.6%, and microcrystalline wax accounts for 0.8%, and cellulose acetate butyrate accounts for 1.3%.
In a preferred embodiment of the present invention, the described shared weight percent of each composition of high strength Noryl is specially polydiphenyl ether plastics and accounts for 85.5%, 2,2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel accounts for 1.2%, chlorinatedpolyethylene accounts for 7.6%, attapulgite clay accounts for 2.3%, and microcrystalline wax accounts for 1.5%, and cellulose acetate butyrate accounts for 1.9%.
The invention has the beneficial effects as follows: high strength Noryl of the present invention by adding multiple additives in polydiphenyl ether plastics, the high strength Noryl that makes to make has that photostabilization is good, nondiscoloration, physical strength are high, good fluidity, hardness are large, be easy to processing, the measured feature of matter, and production cost is low.
Embodiment
Below the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiment.Embodiment based in the present invention, those of ordinary skills, not making all other embodiment that obtain under creative work prerequisite, belong to the scope of protection of the invention.
A kind of high strength Noryl, by polydiphenyl ether plastics and additive, made, described additive comprises photostabilizer, shock resistance modification agent, weighting agent, lubricant and dispersion agent, described photostabilizer is 2, 2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel, described shock resistance modification agent is chlorinatedpolyethylene, described weighting agent is attapulgite clay, described lubricant is microcrystalline wax, described dispersion agent is cellulose acetate butyrate, the shared weight percent of described each composition of high strength Noryl is respectively polydiphenyl ether plastics and accounts for 84.9%-89.4%, 2, 2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel accounts for 0.4%-1.3%, chlorinatedpolyethylene accounts for 6.8%-7.7%, attapulgite clay accounts for 1.5%-2.4%, microcrystalline wax accounts for 0.7%-1.6%, cellulose acetate butyrate accounts for 1.2%-2.1%.
Further, the described shared weight percent of each composition of high strength Noryl is specially polydiphenyl ether plastics and accounts for 88.9%, 2,2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel accounts for 0.5%, chlorinatedpolyethylene accounts for 6.9%, attapulgite clay accounts for 1.6%, and microcrystalline wax accounts for 0.8%, and cellulose acetate butyrate accounts for 1.3%.
Further, the described shared weight percent of each composition of high strength Noryl is specially polydiphenyl ether plastics and accounts for 85.5%, 2,2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel accounts for 1.2%, chlorinatedpolyethylene accounts for 7.6%, attapulgite clay accounts for 2.3%, and microcrystalline wax accounts for 1.5%, and cellulose acetate butyrate accounts for 1.9%.
The beneficial effect of high strength Noryl of the present invention is: high strength Noryl of the present invention by adding multiple additives in polydiphenyl ether plastics, the high strength Noryl that makes to make has that photostabilization is good, nondiscoloration, physical strength are high, good fluidity, hardness are large, be easy to processing, the measured feature of matter, and production cost is low.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes description of the present invention to do; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.
Claims (3)
1. a high strength Noryl, by polydiphenyl ether plastics and additive, made, it is characterized in that: described additive comprises photostabilizer, shock resistance modification agent, weighting agent, lubricant and dispersion agent, described photostabilizer is 2, 2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel, described shock resistance modification agent is chlorinatedpolyethylene, described weighting agent is attapulgite clay, described lubricant is microcrystalline wax, described dispersion agent is cellulose acetate butyrate, the shared weight percent of described each composition of high strength Noryl is respectively polydiphenyl ether plastics and accounts for 84.9%-89.4%, 2, 2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel accounts for 0.4%-1.3%, chlorinatedpolyethylene accounts for 6.8%-7.7%, attapulgite clay accounts for 1.5%-2.4%, microcrystalline wax accounts for 0.7%-1.6%, cellulose acetate butyrate accounts for 1.2%-2.1%.
2. high strength Noryl according to claim 1, it is characterized in that, the described shared weight percent of each composition of high strength Noryl is specially polydiphenyl ether plastics and accounts for 88.9%, 2,2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel accounts for 0.5%, and chlorinatedpolyethylene accounts for 6.9%, and attapulgite clay accounts for 1.6%, microcrystalline wax accounts for 0.8%, and cellulose acetate butyrate accounts for 1.3%.
3. high strength Noryl according to claim 1, it is characterized in that, the described shared weight percent of each composition of high strength Noryl is specially polydiphenyl ether plastics and accounts for 85.5%, 2,2 '-thiobis (the tertiary octyl phenol oxygen of 4-base) nickel accounts for 1.2%, and chlorinatedpolyethylene accounts for 7.6%, and attapulgite clay accounts for 2.3%, microcrystalline wax accounts for 1.5%, and cellulose acetate butyrate accounts for 1.9%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410024581.2A CN103740089A (en) | 2014-01-20 | 2014-01-20 | High-strength modified polyphenyl ether |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410024581.2A CN103740089A (en) | 2014-01-20 | 2014-01-20 | High-strength modified polyphenyl ether |
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| CN103740089A true CN103740089A (en) | 2014-04-23 |
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| CN201410024581.2A Pending CN103740089A (en) | 2014-01-20 | 2014-01-20 | High-strength modified polyphenyl ether |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111303610A (en) * | 2020-03-09 | 2020-06-19 | 芮城县诺澜生物科技服务有限公司 | Novel halogen-free flame-retardant master batch and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101410449A (en) * | 2006-03-29 | 2009-04-15 | 三井化学株式会社 | Resin composition containing olefin block polymer and use of the same |
| WO2013015111A1 (en) * | 2011-07-25 | 2013-01-31 | 東レ株式会社 | Thermoplastic resin composition for impact absorbing member and method for producing same |
| CN103509260A (en) * | 2013-09-05 | 2014-01-15 | 安徽省科林电子有限公司 | Acid-base-resistant insulating sheath material for transformer and preparation method thereof |
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2014
- 2014-01-20 CN CN201410024581.2A patent/CN103740089A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101410449A (en) * | 2006-03-29 | 2009-04-15 | 三井化学株式会社 | Resin composition containing olefin block polymer and use of the same |
| WO2013015111A1 (en) * | 2011-07-25 | 2013-01-31 | 東レ株式会社 | Thermoplastic resin composition for impact absorbing member and method for producing same |
| CN103509260A (en) * | 2013-09-05 | 2014-01-15 | 安徽省科林电子有限公司 | Acid-base-resistant insulating sheath material for transformer and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111303610A (en) * | 2020-03-09 | 2020-06-19 | 芮城县诺澜生物科技服务有限公司 | Novel halogen-free flame-retardant master batch and preparation method thereof |
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Application publication date: 20140423 |