CN103739144A - 一种合成洗涤剂废水处理工艺 - Google Patents
一种合成洗涤剂废水处理工艺 Download PDFInfo
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- CN103739144A CN103739144A CN201310568531.6A CN201310568531A CN103739144A CN 103739144 A CN103739144 A CN 103739144A CN 201310568531 A CN201310568531 A CN 201310568531A CN 103739144 A CN103739144 A CN 103739144A
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- wastewater
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- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 230000002194 synthesizing Effects 0.000 title abstract 2
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- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound 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OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明公开一种合成洗涤剂废水处理工艺，包括以下步骤：车间清洗废水同地面冲洗废水、尾气洗涤废水一起进入格栅井Ⅰ，去除大颗粒杂质后进入集水池，提升至混凝一体化池，加药混凝沉淀去除废水中表面活性剂、悬浮物及有机物，混凝一体化池出水进入预酸化调节池与经过格栅井Ⅱ处理后的生活污水混合均匀，废水提升至EGSB反应器，EGSB反应器出水自流进入生物接触氧化池，接触氧化池出水进入二沉池，二沉池出水进入清水池，最后达标排放。本发明通过混凝沉淀预处理、絮凝聚合作用，去除废水中表面活性剂及大部分有机物；采用外回流工艺，可减少废水中的有害物质对厌氧菌的抑制作用及充分利用出水的碱度。
Description
一种合成洗涤剂废水处理工艺
技术领域
[0001] 本发明涉及洗洁精、洗衣液等产品生产过程产生的高浓度有机废水的处理，具体是一种合成洗涤剂废水处理工艺。
背景技术
[0002] 合成洗涤剂废水中含有大量的阴离子表面活性剂(LAS)、不饱和脂肪酸、磷酸、蛋白质粘滞物、甘油及C1-等，C0D浓度较高，是一种较难处理的有机工业废水。对于合成洗涤剂废水，国内已使用或处于研究阶段的处理方法有:混凝法、生化法、臭氧氧化法等，其中臭氧氧化法、电絮凝法处理成本较高，不适合于大水量废水的处理，而有些方法尚处于研究阶段，还不能工业应用。由于合成洗涤剂厂排放的废水污染物浓度较高，成分复杂，如只依赖单一处理工艺往往难以达标。本发明采用预处理、厌氧生化处理、好氧生化处理、污泥处理多工艺的组合，以充分发挥各种处理工艺的优势。
发明内容
[0003] 本发明的目的在于提供一种合成洗涤剂废水处理工艺。
[0004] 本发明的目的可以通过以下技术方案实现:
一种合成洗涤剂废水处理工艺，其特征在于，包括以下步骤:车间清洗废水同地面冲洗废水、尾气洗涤废水一起进入格栅井I，去除大颗粒杂质后进入集水池，混合均匀，经泵提升至混凝一体化池，加药混凝沉淀去除废水中表面活性剂、悬浮物及有机物，混凝一体化池出水进入预酸化调节池与经过格栅井II处理后的生活污水混合均匀，通过蒸汽加热，起到预酸化的作用，保证EGSB反应器进水温度控制在33-36°C，预酸化调节池综合废水由泵提升至EGSB反应器，通过 厌氧过程去除大部分有机物，EGSB反应器出水自流进入生物接触氧化池，在好氧微生物的作用下去除小分子有机物，接触氧化池出水进入二沉池，二沉池出水进入清水池，最后经规范化排放口达标排放。
[0005] 本发明的有益效果:本发明通过混凝沉淀预处理、絮凝聚合作用，去除废水中表面活性剂及大部分有机物；采用外回流工艺，可减少废水中的有害物质对厌氧菌的抑制作用及充分利用出水的碱度；不需要专门培养菌种，挂膜方便，启动快可以间歇运行；对冲击负荷有较强的适应能力，在间歇运行条件下，仍能够保持良好的处理效果，对排水不均匀的企业，更具有实际意义。
具体实施方式
[0006] 下面结合具体实施例对本发明作进一步详细描述。
[0007] 表1为某合成洗涤剂企业排出的废水水质指标:
一种合成洗涤剂废水处理工艺，包括以下步骤:车间清洗废水同地面冲洗废水、尾气洗涤废水一起进入格栅井I，去除大颗粒杂质后进入集水池，混合均匀，经泵提升至混凝一体化池，投加废碱液调节pH到7-8，以PAC作为絮凝剂产生絮凝反应，产生絮体，再投加助凝剂PAM，使产生絮体形成矾花，后通过沉淀区去除水中表面活性剂、部分C0D及SS ;沉淀池结构采用斜板式，水流方向与颗粒沉淀方向相反，其截留速度与水流上升速度相等，上升速度等于沉降速度的颗粒将悬浮在混合液中形成一层悬浮层，对上升的颗粒进行拦截和过滤，沉淀效率相比平流式沉淀池要高。加药混凝沉淀去除废水中表面活性剂、悬浮物及有机物，混凝一体化池出水进入预酸化调节池与经过格栅井II处理后的生活污水混合均匀，通过蒸汽加热，起到预酸化的作用，保证EGSB反应器进水温度控制在33-36°C，预酸化调节池综合废水由泵提升至EGSB反应器，通过厌氧过程去除大部分有机物，厌氧生化处理常分为预酸化和甲烷化两个过程，在调节酸化池中废水被充分预酸化，在甲烷化EGSB反应器中，有机物被最终转化为甲烷和二氧化碳。EGSB反应器出水自流进入生物接触氧化池，在有氧条件下，废水中的可降解污染物在好氧微生物作用下一部分合成为微生物细胞，另一部分分解为C02、H20，得以彻底去除，部分多余的微生物有机体通过排泥系统中排出，从而使水质得到进一步处理。在好氧微生物的作用下去除小分子有机物，接触氧化池出水进入二沉池，去除沉淀池中沉淀的污泥以及水面表层的漂浮物，一般适用于大中池径沉淀池，周边传动，传动力矩大，而且相对节能；中心支座与旋转桁架以铰接的形式连接，刮泥时产生的扭矩作用于中心支座时即转化为中心旋转轴承的圆周摩擦力，因而受力条件较好；中心进水、排泥，周边出水，对水体的搅动力小，有利于污泥的去除。二沉池出水进入清水池，最后经规范化排放口达标排放。
[0008] 表2为经本发明处理后的出水水质:
表3为本发明各段出水水质指标(单位均以mg/L)
以上内容仅仅是对本发明的工艺所作的举例和说明，所属本技术领域的技术人员对所描述的具体实施例做各种各样的修改或补充或采用类似的方式替代，只要不偏离发明的工艺或者超越本权利要求书所定义的范围，均应属于本发明的保护范围。
Claims (1)
1.一种合成洗涤剂废水处理工艺，其特征在于，包括以下步骤:车间清洗废水同地面冲洗废水、尾气洗涤废水一起进入格栅井I，去除大颗粒杂质后进入集水池，混合均匀，经泵提升至混凝一体化池，加药混凝沉淀去除废水中表面活性剂、悬浮物及有机物，混凝一体化池出水进入预酸化调节池与经过格栅井II处理后的生活污水混合均匀，通过蒸汽加热，起到预酸化的作用，保证EGSB反应器进水温度控制在33-36°C，预酸化调节池综合废水由泵提升至EGSB反应器，通过厌氧过程去除大部分有机物，EGSB反应器出水自流进入生物接触氧化池，在好氧微生物的作用下去除 小分子有机物，接触氧化池出水进入二沉池，二沉池出水进入清水池，最后经规范化排放口达标排放。
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