CN103725890A - 一种从富锌锰钴渣中多重控制分步回收有价金属的方法 - Google Patents
一种从富锌锰钴渣中多重控制分步回收有价金属的方法 Download PDFInfo
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- CN103725890A CN103725890A CN201410006522.2A CN201410006522A CN103725890A CN 103725890 A CN103725890 A CN 103725890A CN 201410006522 A CN201410006522 A CN 201410006522A CN 103725890 A CN103725890 A CN 103725890A
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- zinc
- cobalt
- manganese
- solution
- slag
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- 238000000034 method Methods 0.000 title claims abstract description 60
- 239000002893 slag Substances 0.000 title claims abstract description 47
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 30
- 239000002184 metal Substances 0.000 title claims abstract description 28
- HCOGAZTYXMWOMJ-UHFFFAOYSA-N [Mn].[Co].[Zn] Chemical compound [Mn].[Co].[Zn] HCOGAZTYXMWOMJ-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 150000002739 metals Chemical class 0.000 title abstract description 3
- 238000004064 recycling Methods 0.000 title abstract 5
- 238000006243 chemical reaction Methods 0.000 claims abstract description 50
- 239000010941 cobalt Substances 0.000 claims abstract description 39
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 39
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 39
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 37
- 239000011701 zinc Substances 0.000 claims abstract description 37
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 23
- HSSJULAPNNGXFW-UHFFFAOYSA-N [Co].[Zn] Chemical compound [Co].[Zn] HSSJULAPNNGXFW-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000011572 manganese Substances 0.000 claims abstract description 21
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 18
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 13
- 238000000926 separation method Methods 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 10
- 238000004070 electrodeposition Methods 0.000 claims abstract description 9
- 229910001429 cobalt ion Inorganic materials 0.000 claims abstract description 7
- 238000001914 filtration Methods 0.000 claims abstract description 7
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000002386 leaching Methods 0.000 claims abstract description 6
- 238000003723 Smelting Methods 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 20
- 230000003647 oxidation Effects 0.000 claims description 18
- 150000002500 ions Chemical class 0.000 claims description 16
- 238000001514 detection method Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 230000002378 acidificating effect Effects 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 6
- 238000000605 extraction Methods 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 abstract description 5
- 238000012545 processing Methods 0.000 abstract description 5
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 abstract description 3
- 230000003749 cleanliness Effects 0.000 abstract description 3
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 229910001437 manganese ion Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 82
- 238000011084 recovery Methods 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 238000001556 precipitation Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 230000003301 hydrolyzing effect Effects 0.000 description 4
- DLHSXQSAISCVNN-UHFFFAOYSA-M hydroxy(oxo)cobalt Chemical compound O[Co]=O DLHSXQSAISCVNN-UHFFFAOYSA-M 0.000 description 4
- 241001062472 Stokellia anisodon Species 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical compound [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000010310 metallurgical process Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical class [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003978 infusion fluid Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- -1 iron ion Chemical class 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000010295 mobile communication Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
Images
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
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CN201410006522.2A CN103725890B (zh) | 2014-01-07 | 2014-01-07 | 一种从富锌锰钴渣中多重控制分步回收有价金属的方法 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104480316A (zh) * | 2014-12-24 | 2015-04-01 | 连云港市兆昱新材料实业有限公司 | 一种从钕铁硼磁材废料中回收Co元素的简便化工业方法 |
CN105274345A (zh) * | 2015-11-27 | 2016-01-27 | 江苏理工学院 | 分离回收钴锰废料中钴和锰的方法 |
CN105950875A (zh) * | 2016-05-09 | 2016-09-21 | 钟庆文 | 一种湿法炼锌、锰的净化钴渣的处理方法 |
CN107619945A (zh) * | 2017-09-12 | 2018-01-23 | 贵州省冶金科学研究室 | 一种高钴冶锌废渣除钴的方法 |
CN113512649A (zh) * | 2021-05-27 | 2021-10-19 | 金川集团股份有限公司 | 一种混酸体系下利用臭氧实现镍钴分离的生产方法 |
CN114755283A (zh) * | 2022-05-17 | 2022-07-15 | 安徽大学 | 一种区分锰的不同价态七价锰MnO4-和二价锰Mn2+的方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101020962A (zh) * | 2007-02-07 | 2007-08-22 | 北京矿冶研究总院 | 深海多金属结核氨-氯化铵体系自催化还原氨浸的方法 |
-
2014
- 2014-01-07 CN CN201410006522.2A patent/CN103725890B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101020962A (zh) * | 2007-02-07 | 2007-08-22 | 北京矿冶研究总院 | 深海多金属结核氨-氯化铵体系自催化还原氨浸的方法 |
Non-Patent Citations (1)
Title |
---|
夏晓梅: "湿法炼锌净化渣中回收钴的工艺研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104480316A (zh) * | 2014-12-24 | 2015-04-01 | 连云港市兆昱新材料实业有限公司 | 一种从钕铁硼磁材废料中回收Co元素的简便化工业方法 |
CN104480316B (zh) * | 2014-12-24 | 2016-12-07 | 连云港市兆昱新材料实业有限公司 | 一种从钕铁硼磁材废料中回收Co元素的简便化工业方法 |
CN105274345A (zh) * | 2015-11-27 | 2016-01-27 | 江苏理工学院 | 分离回收钴锰废料中钴和锰的方法 |
CN105274345B (zh) * | 2015-11-27 | 2017-09-29 | 江苏理工学院 | 分离回收钴锰废料中钴和锰的方法 |
CN107828965A (zh) * | 2015-11-27 | 2018-03-23 | 江苏理工学院 | 一种分离回收钴锰废料中钴和锰的方法 |
CN107828965B (zh) * | 2015-11-27 | 2019-04-23 | 江苏理工学院 | 一种分离回收钴锰废料中钴和锰的方法 |
CN105950875A (zh) * | 2016-05-09 | 2016-09-21 | 钟庆文 | 一种湿法炼锌、锰的净化钴渣的处理方法 |
CN107619945A (zh) * | 2017-09-12 | 2018-01-23 | 贵州省冶金科学研究室 | 一种高钴冶锌废渣除钴的方法 |
CN113512649A (zh) * | 2021-05-27 | 2021-10-19 | 金川集团股份有限公司 | 一种混酸体系下利用臭氧实现镍钴分离的生产方法 |
CN114755283A (zh) * | 2022-05-17 | 2022-07-15 | 安徽大学 | 一种区分锰的不同价态七价锰MnO4-和二价锰Mn2+的方法 |
CN114755283B (zh) * | 2022-05-17 | 2024-04-02 | 安徽大学 | 一种区分锰的不同价态七价锰MnO4-和二价锰Mn2+的方法 |
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Address after: 410000 room 402, 4th floor, building A1, lingzhi Industrial Park, No. 128 Jinhai Road, Yuhua District, Changsha City, Hunan Province Patentee after: Zhongke Boyi Environmental Protection Technology Co.,Ltd. Address before: 410116 room 402, 4 / F, building A1, lingzhi Industrial Park, No. 128 Jinhai Road, Yuhua District, Changsha City, Hunan Province Patentee before: HUNAN BOE ENVIRONMENT PROTECTION TECHNOLOGY CO.,LTD. |
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