CN103724883B - A kind of polyvinyl chloride wire cable material of halogen-free flameproof of crosslinked with silicane - Google Patents
A kind of polyvinyl chloride wire cable material of halogen-free flameproof of crosslinked with silicane Download PDFInfo
- Publication number
- CN103724883B CN103724883B CN201410013136.6A CN201410013136A CN103724883B CN 103724883 B CN103724883 B CN 103724883B CN 201410013136 A CN201410013136 A CN 201410013136A CN 103724883 B CN103724883 B CN 103724883B
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- China
- Prior art keywords
- polyvinyl chloride
- crosslinked
- halogen
- silicane
- wire cable
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- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 24
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title claims abstract description 22
- BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims abstract description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 7
- 239000003607 modifier Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- CJZGTCYPCWQAJB-UHFFFAOYSA-L Calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N Phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 4
- KUAZQDVKQLNFPE-UHFFFAOYSA-N Thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 210000003135 Vibrissae Anatomy 0.000 claims abstract description 4
- 230000003712 anti-aging Effects 0.000 claims abstract description 4
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 4
- 239000008116 calcium stearate Substances 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011591 potassium Substances 0.000 claims abstract description 4
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 4
- 239000000779 smoke Substances 0.000 claims abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011593 sulfur Substances 0.000 claims abstract description 4
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000004073 vulcanization Methods 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 12
- WNROFYMDJYEPJX-UHFFFAOYSA-K Aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 6
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 6
- 241001330002 Bambuseae Species 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- 239000011425 bamboo Substances 0.000 claims description 6
- 239000003610 charcoal Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 5
- HPSUPGAVFFFPMQ-UHFFFAOYSA-N 1,2,3,4,6,7,10-heptachlorododecane Chemical compound CCC(Cl)CCC(Cl)C(Cl)CC(Cl)C(Cl)C(Cl)CCl HPSUPGAVFFFPMQ-UHFFFAOYSA-N 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L Magnesium hydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 210000003205 Muscles Anatomy 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000010304 firing Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N tributyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene (PE) Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
Abstract
The invention discloses a kind of polyvinyl chloride wire cable material of halogen-free flameproof of crosslinked with silicane, it is obtained by the raw material of following weight parts: SG-5 polyvinyl chloride 80-90, Silane coupling agent KH550? 1-2, zinc oxide 1.5-3, magnesium oxide 0.9-1.2, anti-aging agent 4040? 0.8-1.5, Vulcanization accelerator TMTD? 1-2, Sulfur 1-2, heat-proof modifier NR-188? 0.8-1.5, crystal whisker of hexa potassium titanate 1-2, phthalic acid polyester 1-2, smoke sheet rubber 2-4, calcium stearate 3-5, compounded mix 50-60.
Description
Technical field
The present invention relates to CABLE MATERIALS field, is exactly a kind of polyvinyl chloride wire cable material of halogen-free flameproof of crosslinked with silicane.
Background technology
Electric wire is resin dedicated comprises cable insulating material and cable jacket material, raw materials usedly mainly contains polyethylene and polyvinyl chloride.
The quality of polyvinyl chloride cable material and PVC cable material quality is fundamentally to be filled a prescription by PVC cable material and selected raw material decides.Along with the various auxiliary agent of PVC and the continuous renewal of weighting material and development, the formula of PVC cable material is also made constantly to improve and improve.
Summary of the invention
The object of the present invention is to provide a kind of polyvinyl chloride wire cable material of halogen-free flameproof of crosslinked with silicane.
Above-mentioned purpose is realized by following scheme:
A polyvinyl chloride wire cable material for the halogen-free flameproof of crosslinked with silicane, is characterized in that: it is obtained by the raw material of following weight parts:
SG-5 polyvinyl chloride 80-90, Silane coupling agent KH550 1-2, zinc oxide 1.5-3, magnesium oxide 0.9-1.2, anti-aging agent 40400.8-1.5, Vulcanization accelerator TMTD 1-2, Sulfur 1-2, heat-proof modifier NR-1880.8-1.5, crystal whisker of hexa potassium titanate 1-2, phthalic acid polyester 1-2, smoke sheet rubber 2-4, calcium stearate 3-5, compounded mix 50-60;
Compounded mix is made up of the raw material of following weight part:
Carclazyte 20-25, bamboo charcoal powder 2-3, zinc oxide 1-2, magnesium hydroxide 10-12, clorafin 1-2, diatomite 4-5, tributyl citrate 2-3, aluminium hydroxide 8-10;
Carclazyte, bamboo charcoal powder dodge to burn 6-8 second by the preparation method of compounded mix at 700-750 DEG C in sudden strain of a muscle firing, take out, add in suitable quantity of water in the lump with aluminium hydroxide and grind, adding 10-15% hydrochloric acid soln adjusts PH to be 4.5-5.5, after ground slurry to 400-500 order, repeated hydrogenation sodium oxide is adjusted to neutrality, and spraying dry obtains powder; Mixed with other remaining component by gained powder, ground and mixed evenly and get final product.
The polyvinyl chloride wire cable material of the halogen-free flameproof of described a kind of crosslinked with silicane, is characterized in that:
Preparation method is:
(1) get SG-5 polyvinyl chloride, zinc oxide, magnesium oxide, solid paraffin, heat-proof modifier NR-188 mix by weight, mediate 8-10 minute at 160-170 DEG C in kneader after, take out cooling;
(2) by the cooled material of step (1) gained and each raw material blending of residue, mixing in twin screw extruder, granulation, control temperature, at 165-175 DEG C, obtains finished product.
Beneficial effect of the present invention is:
Wire cable material provided by the invention has soft feel, good flame retardant resistance, is applicable to producing the cord such as supply lead and transmission line series products.
Embodiment
A polyvinyl chloride wire cable material for the halogen-free flameproof of crosslinked with silicane, it is obtained by the raw material of following weight parts (kg):
SG-5 polyvinyl chloride 85, Silane coupling agent KH550 1, zinc oxide 1.8, magnesium oxide 1.2, anti-aging agent 40401.5, Vulcanization accelerator TMTD 1.2, Sulfur 2, heat-proof modifier NR-1881.2, crystal whisker of hexa potassium titanate 2, phthalic acid polyester 2, smoke sheet rubber 4, calcium stearate 5, compounded mix 57;
Compounded mix is made up of the raw material of following weight part:
Carclazyte 25, bamboo charcoal powder 3, zinc oxide 2, magnesium hydroxide 10, clorafin 1, diatomite 5, tributyl citrate 2, aluminium hydroxide 10;
Carclazyte, bamboo charcoal powder are dodged burning 8 seconds by the preparation method of compounded mix at 750 DEG C in sudden strain of a muscle firing, take out, add in suitable quantity of water in the lump grind with aluminium hydroxide, adding 12% hydrochloric acid soln adjusts PH to be 4.5, and after ground slurry to 400 order, repeated hydrogenation sodium oxide is adjusted to neutrality, spraying dry, obtains powder; Mixed with other remaining component by gained powder, ground and mixed evenly and get final product.
The polyvinyl chloride wire cable material of the halogen-free flameproof of described a kind of crosslinked with silicane, preparation method is:
(1) get SG-5 polyvinyl chloride, zinc oxide, magnesium oxide, solid paraffin, heat-proof modifier NR-188 mix by weight, mediate at 165 DEG C after 10 minutes in kneader, take out cooling;
(2) by the cooled material of step (1) gained and each raw material blending of residue, mixing in twin screw extruder, granulation, control temperature, at 169 DEG C, obtains finished product.
The present embodiment is carried out performance test, and the data obtained is as follows:
From the present embodiment test result, product of the present invention is through the aging of 100 DEG C × 168h and 80 DEG C × 6h Apparatus for Pressure at high-temp, the change of its mechanical and physical performance meets corresponding mark requirement, has good physical and mechanical properties, meets the demand of differing temps environmental change.
Claims (2)
1. a polyvinyl chloride wire cable material for the halogen-free flameproof of crosslinked with silicane, is characterized in that: it is obtained by the raw material of following weight parts: SG-5 polyvinyl chloride 80-90, Silane coupling agent KH550 1-2, zinc oxide 1.5-3, magnesium oxide 0.9-1.2, anti-aging agent 40400.8-1.5, Vulcanization accelerator TMTD 1-2, Sulfur 1-2, heat-proof modifier NR-1880.8-1.5, crystal whisker of hexa potassium titanate 1-2, phthalic acid polyester 1-2, smoke sheet rubber 2-4, calcium stearate 3-5, compounded mix 50-60; Compounded mix is made up of the raw material of following weight part: carclazyte 20-25, bamboo charcoal powder 2-3, zinc oxide 1-2, magnesium hydroxide 10-12, clorafin 1-2, diatomite 4-5, tributyl citrate 2-3, aluminium hydroxide 8-10; Carclazyte, bamboo charcoal powder dodge to burn 6-8 second by the preparation method of compounded mix at 700-750 DEG C in sudden strain of a muscle firing, take out, add in suitable quantity of water in the lump with aluminium hydroxide and grind, adding 10-15% hydrochloric acid soln adjusts pH to be 4.5-5.5, after ground slurry to 400-500 order, repeated hydrogenation sodium oxide is adjusted to neutrality, and spraying dry obtains powder; Mixed with other remaining component by gained powder, ground and mixed evenly and get final product.
2. the polyvinyl chloride wire cable material of the halogen-free flameproof of a kind of crosslinked with silicane according to claim 1, it is characterized in that: preparation method is: (1) gets SG-5 polyvinyl chloride, zinc oxide, magnesium oxide, solid paraffin, heat-proof modifier NR-188 mix by weight, mediate 8-10 minute at 160-170 DEG C in kneader after, take out cooling; (2) by the cooled material of step (1) gained and each raw material blending of residue, mixing in twin screw extruder, granulation, control temperature, at 165-175 DEG C, obtains finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410013136.6A CN103724883B (en) | 2014-01-10 | 2014-01-10 | A kind of polyvinyl chloride wire cable material of halogen-free flameproof of crosslinked with silicane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410013136.6A CN103724883B (en) | 2014-01-10 | 2014-01-10 | A kind of polyvinyl chloride wire cable material of halogen-free flameproof of crosslinked with silicane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103724883A CN103724883A (en) | 2014-04-16 |
| CN103724883B true CN103724883B (en) | 2016-03-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410013136.6A Active CN103724883B (en) | 2014-01-10 | 2014-01-10 | A kind of polyvinyl chloride wire cable material of halogen-free flameproof of crosslinked with silicane |
Country Status (1)
| Country | Link |
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| CN (1) | CN103724883B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194223A (en) * | 2014-09-17 | 2014-12-10 | 朱忠良 | Formula for improving flame retardation of PVC insulating material and processing process of formula |
| CN104194227A (en) * | 2014-09-17 | 2014-12-10 | 朱忠良 | Formula for improving insulation performance of PVC insulating material and processing process of formula |
| CN108976490A (en) * | 2018-07-02 | 2018-12-11 | 芜湖航天特种电缆厂股份有限公司 | Cold-resistant cable and preparation method thereof |
| CN108976492A (en) * | 2018-07-02 | 2018-12-11 | 芜湖航天特种电缆厂股份有限公司 | Cold resistance cable insulation and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101891949A (en) * | 2010-08-09 | 2010-11-24 | 常州天晟新材料股份有限公司 | Halogen free flame retardant liquid and method for preparing flame retardant sponge using same |
| CN103059440A (en) * | 2011-10-20 | 2013-04-24 | 常熟市筑紫机械有限公司 | Flame retardant silane cross-linked polyvinyl chloride wire and cable material |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5167931B2 (en) * | 2008-04-30 | 2013-03-21 | 日立電線株式会社 | Non-halogen flame retardant resin composition and electric wire / cable using the same |
| JP5526164B2 (en) * | 2012-01-19 | 2014-06-18 | 昭和電線ケーブルシステム株式会社 | Flame retardant wire / cable |
-
2014
- 2014-01-10 CN CN201410013136.6A patent/CN103724883B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101891949A (en) * | 2010-08-09 | 2010-11-24 | 常州天晟新材料股份有限公司 | Halogen free flame retardant liquid and method for preparing flame retardant sponge using same |
| CN103059440A (en) * | 2011-10-20 | 2013-04-24 | 常熟市筑紫机械有限公司 | Flame retardant silane cross-linked polyvinyl chloride wire and cable material |
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| Publication number | Publication date |
|---|---|
| CN103724883A (en) | 2014-04-16 |
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Effective date of registration: 20210430 Address after: 710000 No.10 zijianfang, South District, Longshou village, Lianhu District, Xi'an City, Shaanxi Province Patentee after: Zhang Boqiang Address before: 239300 intersection of Jingqi road and Weisi Road, Tianchang Development Zone, Chuzhou City, Anhui Province Patentee before: ANHUI RISE ELECTRIC TECHNOLOGY Co.,Ltd. |