CN103723820A - Solar aeration-plant bed supported device with biological membrane - Google Patents

Solar aeration-plant bed supported device with biological membrane Download PDF

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Publication number
CN103723820A
CN103723820A CN201310756465.5A CN201310756465A CN103723820A CN 103723820 A CN103723820 A CN 103723820A CN 201310756465 A CN201310756465 A CN 201310756465A CN 103723820 A CN103723820 A CN 103723820A
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China
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filler
water
aeration
river
plant bed
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CN201310756465.5A
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Chinese (zh)
Inventor
孙井梅
杨晓杰
李檬
吴卿
席兆胜
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Tianjin University
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Tianjin University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

Abstract

The invention discloses a solar aeration-plant bed supported device with a biological membrane. The device is characterized in that a solar cell, a supporting connecting device, an air pump, an aeration pipe and an air distribution pipe are combined to form an aeration system, a strong buoyancy carrier and an emergent aquatic plant form an ecological floating bed system; a filler system provides a place for lots of microbial floras, phytoplanktons, protozoa and micro-metazoons to attach and live; all the systems are co-built to form a biological membrane capable of effectively and quickly purifying contaminants. The solar aeration-plant bed supported device with the biological membrane is capable of effectively removing organic matters and other pollutants such as COD (Chemical Oxygen Demand), nitrogen and phosphorus in water, purifying water, improving the ecological system of the river, helping recovering the self-cleaning ability of water and also achieving certain environment beautifying effect.

Description

Solar energy aeration oxygenation-plant bed carrier band microbial film device
Technical field
The invention relates to city river water pollution control and environment restoring method, the device that particularly a kind of river water body restoration of the ecosystem and water quality keep.
Background technology
City river, as important resources and environment carrier, is related to the existence in city, is restricting the development in city, is the Source of life in city.City river can improve the ecotope in city, regulates the climate, and moulds urban look, offers the better living space of resident, and energy investment promotion, promotes the flourish of related industries, drives the overall progress in city.Visible, city river has very important effect in development, construction and the ecotope in city.But along with the development of economic society, city river pollutes also in progressively aggravation, and due to long-term negligence of management, the phenomenon ubiquity such as river course is dirty, random, black, smelly, this has all seriously fettered the development in city, destroyed urban environment, the existence of aquatic animals and plants has also been formed to threat.The ecological management of city river is extremely urgent.
At present, river channel ecology improvement technology has more array configuration, as Hu Mengchun (CN102491586A) has designed a set of black smelly river course water purification treatment facility including floatation type scene electric energy service, floatation type BAF, flocculation agent spray agent, the techniques such as the method comprehensive utilization flocculation, filtration, microbiological treatment, the water quality in the black smelly river course for the treatment of and purification.In the design of Pang Pengyuan (CN201099644Y), relate to a kind of floatation type solar energy aeration system, can easily, to oxygenation in water, solve the problems such as aeration energy consumption height, can be used for the places such as lake, larger area river.The auspicious grade of kingdom (CN101544424A) has designed a kind of combined biological floating bed device for purification of water quality, this is biological floating bed eight function divisions, can plant multiple plant, can not only remove preferably the pollutent such as nitrogen phosphorus in water, also have certain beautification function.But these methods exist certain limitation and deficiency: mainly in containing the black and odorous water of trade effluent, range of application is narrow; Biological filtering tank process is applied in river course and is not easy to control the operations such as water inlet flow velocity, backwash, is an impediment to river course flood function; Simply, to aeration aerating in river course, effect is not clearly, takes effect slow, is unfavorable for that river course is attractive in appearance yet; The microbe species of assembling on root system of plant is abundant not, and quantity is also large not, so not good to polluting more serious river course treatment effect.
In sum, the Ecological Disposal aspect of city river lack a kind of regulation effect comprehensively, the treatment unit of applied range and easy handling.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, a kind of purification of water quality for river course polluted water body and recovery be provided, improve water quality, progressively recover water body self-purification ability, regulation effect comprehensively, a kind of solar energy aeration oxygenation for the city river ecological management-plant bed carrier band microbial film device of easy handling.
The present invention is achieved by following technical solution.
A kind of solar energy aeration oxygenation-plant bed carrier band microbial film device, comprise solar panel, air pump, emergent, aeration tube and gas distribution pipe, it is characterized in that, the by-level position of this device is provided with strong buoyancy carrier (5), strong buoyancy carrier (5) is circular, on bubbling through the water column; Solar panel (1) is arranged on strong buoyancy carrier (5) central part above, and be connected with air pump (4) by the support connection device (3) below it, the air outlet of air pump (4) is connected with aeration tube (7), aeration tube (7) vertically through strong buoyancy carrier (5) and be horizontally set on this device gas distribution pipe (8) below and be connected, for even gas distribution; At solar panel (1), support connection device (3), be provided with emergent (2) with around air pump (4); Below strong buoyancy carrier (5), be vertically installed with filler (6), filler (6) connects bunchiness, evenly hangs on below strong buoyancy carrier (5); Strong buoyancy carrier (5) central position below is also provided with deadman (9), with the stability of assurance device;
The upper aerobic denitrifying bacteria of cultivating of described filler (6) can complete denitrification process under the higher condition of Dissolved Oxygen in Water, effectively reduces total nitrogen concentration in water.
Described filler (6) also can Selection and Constitute filler, this filler be fiber yarn take hard as skeleton, the weighting material using filamentary fibers as skeleton hollow part, quality is light, easy to assembly, biofilm area is large, is beneficial to administer the river course that pollution condition is more serious.
Described filler (6) also can be selected active bio filler, and this filler has merged the multiple trace element that is conducive to the quick apposition growth of microorganism, good hydrophilic property in macromolecular material, extension mould is fast, oxygen transfer efficiency is high, and specific surface area is large, is beneficial to administer the river course that eutrophication is serious.
Described solar panel (1) is 3~5, is arranged into fold-line-shaped, orientation Chao Nan, and spend with level orientation angle 10~20.
Described emergent is the emergent with good water body purification effect and landscape effect, as wilson iris, Canna generalis Bailey, reed, Scirpus tabernaemontani, cattail etc.
The plantation density of described emergent is 2~10 strains/m 2.
The one-tenth string length of described filler (6), in the situation that taking into full account the suffered buoyancy of filler, is set as 1/3~1/2 of the river course depth of water, but is generally no more than 1.2 meters, and on filler string, adjacent filler spacing is set as 5~8cm, and filler string density is 40~60 strings/m 2.
The diameter of this device, depending on river cross-section width, is set to 1/5~1/4 of river cross-section width, but general maximum is no more than 2 meters; In river course, the spacing of adjacent stream oriented device is 5~10 meters.
The present invention on the basis of existing technology, is mainly the use that has increased filler, utilizes the advantages such as the high-specific surface area of filler, assembles a large amount of microorganisms, zooplankton etc., has greatly improved biomass; Meanwhile, under the condition of aeration aerating, increased oxygen in water concentration, biological degradation has been played to obvious booster action.The present invention can combine the advantage of aeration aerating and microbiological deterioration, effectively reduce pollution load, remove efficiently organism and other pollutents such as COD in water, nitrogen, phosphorus, purifying water body water quality, the progressively river training ecosystem, can make contaminated serious river water body water quality change gradually V class into by bad V class, even return to IV class water quality level.
Accompanying drawing explanation
Fig. 1 is the structural representation of solar energy aeration oxygenation-plant bed carrier band microbial film device;
Fig. 2 is the vertical view of Fig. 1.
1---solar panel 2---emergent
3---support connection device 4---air pump
5---strong buoyancy carrier 6---filler
7---aeration tube 8---gas distribution pipe
9---deadman.
Embodiment
Below in conjunction with accompanying drawing, the invention will be further described.
Solar energy aeration oxygenation of the present invention-plant bed carrier band microbial film device, as shown in Figure 1, the by-level position of this device is provided with strong buoyancy carrier 5, strong buoyancy carrier 5 is circular, on bubbling through the water column, its diameter, depending on river cross-section width, is set to 1/5~1/4 of river cross-section width, but general maximum is no more than 2 meters; Solar panel 1 is arranged on strong buoyancy carrier 5 central part above, and is connected with air pump 4 by the support connection device 3 below it, and solar panel 1 is 3~5, is arranged into fold-line-shaped, orientation Chao Nan, and spend with level orientation angle 10~20; The air outlet of air pump 4 is connected with aeration tube 7, aeration tube 7 vertical through strong buoyancy carrier 5 and be horizontally set on this device gas distribution pipe 8 below and be connected, for even gas distribution.
At solar panel 1, support connection device 3, be provided with emergent 2 with around air pump 4, referring to Fig. 2; Described emergent is the emergent with good water body purification effect and landscape effect, and as wilson iris, Canna generalis Bailey, reed, Scirpus tabernaemontani, cattail etc., the plantation density of emergent is 2~10 strains/m 2.
Below strong buoyancy carrier 5, be vertically installed with filler 6, filler 6 connects bunchiness, evenly hang on below strong buoyancy carrier (5), the one-tenth string length of described filler 6 is in the situation that taking into full account the suffered buoyancy of filler, be set as 1/3~1/2 of the river course depth of water, but be generally no more than 1.2 meters, on filler string, adjacent filler spacing is set as 5~8cm, and filler string density is 40~60 strings/m 2.
Strong buoyancy carrier 5 central position below is also provided with deadman 9, with the stability of assurance device.
The present invention combines solar energy aeration aeration system and biological floating bed, filler, is combined into one formula device.Be directed to aerating system and biological floating bed separated method, the present invention has simplified technique; Solar energy aeration aeration system and biological and ecological improvement method are combined, improved water body micro-ecological environment, not only Dissolved Oxygen in Water concentration improves, the ecological management such as plant, microorganism also plays very large effect, integrated device has improved the effect that water ecology is repaired, overall regulation effect is effective a lot of compared with two kinds of independent techniques, and the clearance of nitrogen can reach or can reach or higher than 40%~60% higher than 30%~60%, COD clearance.
Solar panel 1, support connection device 3, air pump 4, aeration tube 7 and gas distribution pipe 8 form aeration oxygen replenishing system.
Solar panel is arranged on support connection device, converts solar energy into electrical energy, for aeration in the situation that weather is good.During due to sunny weather, solar panel can constantly be converted into electric energy by sun power, for aerator aeration oxygen replenishing, the oxygen producing has made the dissolved oxygen content in water enough high, enough for the oxygen that breathing, the Degradation of plant, microorganism etc. are required.In the situation that overcast and rainy and evening there is no sunlight, the content of oxygen in water can't affect the physiological activity of plant and microorganism in a short time.Existing aeration process, be no matter aeration or surface aeration under water, all have the problems such as aerator power consumption is high, maintenance management difficulty is large, particularly require to have supporting power system supply of electrical energy, these problems have seriously been dwindled the range of application of aerating apparatus, have fettered the application of aeration oxygen replenishing.The present invention converts solar energy into electrical energy, and has first saved and has required supporting power system, has greatly expanded range of application, has reduced running cost, has reduced the operational administrative difficulty of equipment; And this method application clean energy-sun power, greatly reduces energy consumption, and meets the theory of environment protection; Simultaneously, the quantity of solar panel should meet the demand of aeration, can not form too greatly waste by area again, the present invention arranges 3~5 solar panels, solar panel is broken-line type arranges, and the certain angle that tilts, and can Efficient Conversion sun power be electric energy, meet the electrical energy demands of aeration aerating, the normal operation of holdout device.Selecting with solar panel of air pump and gas distribution pipe matches, the object of aeration is to recover oxygen in water level, improve the degrading activity of carrier biofilm, aeration tube length setting, than the long 10~15cm of filler string, can be realized this two kinds of effects simultaneously simultaneously.
Strong buoyancy carrier 5 forms biological floating bed system with emergent 2.
On strong buoyancy carrier, plant suitable emergent, can utilize the effect such as sieving, absorption and absorption of root system of plant, removing the pollution substance in water, as nutritive elements such as nitrogen, phosphorus, and enrichment and conversion heavy metal etc., meanwhile, the plantation of emergent can beautify river course environment.In water, the removal of nitrogen needs aerobic and alternately generation of anaerobic environment, and solar energy aeration oxygenation makes oxygen in water abundance, has suppressed the growth metabolism of denitrifying bacteria, can not effectively remove nitrogen; Although microorganism can gather phosphorus under aerobic condition, if in time microorganism is not derived to water body, phosphoric is not removed from water at all, also can be present in water body or be released under certain condition in water body.And only have the sorption by root system of plant, could remove fast and effectively the nutritive substance such as nitrogen, phosphorus in river course, so arranging of plant is essential.Can, according to the water quality that will process river water body, select targetedly the kind of emergent.For example, for the serious river course of eutrophication, can select the emergents such as wilson iris, Canna generalis Bailey, reed, Scirpus tabernaemontani, cattail; Wilson iris can suppress alga eruption, remove solvability nitrogen, phosphorus in water, improves water transparency, suppresses that pH value increases etc.; Canna generalis Bailey root system is more flourishing, to solid matter, colloidalmaterial and NH 4 +-N etc. have certain sedimentation, interception and adsorption; Reed, Scirpus tabernaemontani and cattail also have good removal effect to nutritive substances such as nitrogen phosphorus.The plantation density of plant will fully take into account the growing space of plant, the factors such as lodging not occur, and plantation density is set as 2~10 strains/m 2.
Filler is important component part of the present invention, a large amount of microorganism species, plant plankton, protozoon, micro-metazoas that participate in pollutant purification adhere to, reside in filling surface, common structure forms the microbial film with efficient fast purification pollutent, mainly removes the COD in river water body.Filler can provide larger specific surface area, makes the existence density of microorganism the highest, can make planktonic organism adhere on it simultaneously, herds nutritive substance in drinking water.The use of filler, can be in limited space the huge biomass of enrichment, make microorganism high speed degradation of contaminant, can within the relatively short time, reach good treatment effect.And filler is combined with plant, the secretory product of root system of plant can be strengthened the biochemical degradation effect of filler, and the effect that so just makes filler is more outstanding, treatment effect is more obvious.In present method, on filler, cultivate especially aerobic denitrifying bacteria, this class growth speed is fast, output is high, environmental compatibility is strong, denitrification speed is fast and thorough, the ability mostly with the nitrated and metabolism hardly degraded organic substance of synchronous difference can complete denitrification process under the higher condition of Dissolved Oxygen in Water, reduces fast and effectively in river course total nitrogen concentration in water.Can, according to the water quality that will process river water body, select targetedly the kind of filler.For example, while administering the more serious river course of pollution condition, can Selection and Constitute filler, this filler be fiber yarn take hard as skeleton, the weighting material using filamentary fibers as skeleton hollow part, have that quality is light, easy to assembly, biofilm area large, with root system of plant compatible degree compared with advantages of higher.In filler, filamentary fibers is wound around out tiny space, so that the planktonic organism on it is adhered in protection, provides again higher specific surface area simultaneously, and zooplankton and microorganism can be survived with higher density.Can also select in addition active bio filler, this filler has merged the trace element that multiple types is conducive to the quick apposition growth of microorganism in macromolecular material, and it is fast that good hydrophilic property is hung mould, oxygen transfer efficiency is high, specific surface area is large, and proportion is suitable, fluid effect good, long service life.
When the present invention is applied to river water body purification, can determine according to river course particular case the size of whole device.Device is placed in to center, river course or near the position on bank, during arrangement, both otherwise hinder the functions such as river course flood, plays again the effect that purifies water, improves the ecological environment.The area of strong buoyancy carrier can be determined according to factors such as the ecotope of the length of cross section of river, two sides, river course, river flood passages, strong buoyancy carrier is set to circle, diameter, depending on river cross-section width, is set to 1/5~1/4 of river cross-section width, but general maximum is no more than 2 meters.In river course, the spacing of adjacent stream oriented device is set to 5~10 meters.

Claims (6)

1. solar energy aeration oxygenation-plant bed carrier band microbial film device, comprise solar panel, air pump, emergent, aeration tube and gas distribution pipe, it is characterized in that, the by-level position of this device is provided with strong buoyancy carrier (5), strong buoyancy carrier (5) is circular, on bubbling through the water column; Solar panel (1) is arranged on strong buoyancy carrier (5) central part above, and be connected with air pump (4) by the support connection device (3) below it, the air outlet of air pump (4) is connected with aeration tube (7), aeration tube (7) vertically through strong buoyancy carrier (5) and be horizontally set on this device gas distribution pipe (8) below and be connected, for even gas distribution; At solar panel (1), support connection device (3), be provided with emergent (2) with around air pump (4); Below strong buoyancy carrier (5), be vertically installed with filler (6), filler (6) connects bunchiness, evenly hangs on below strong buoyancy carrier (5); Strong buoyancy carrier (5) central position below is also provided with deadman (9), with the stability of assurance device;
The upper aerobic denitrifying bacteria of cultivating of described filler (6) can complete denitrification process under the higher condition of Dissolved Oxygen in Water, effectively reduces total nitrogen concentration in water;
Described filler (6) also can Selection and Constitute filler, this filler be fiber yarn take hard as skeleton, the weighting material using filamentary fibers as skeleton hollow part, quality is light, easy to assembly, biofilm area is large, is beneficial to administer the river course that pollution condition is more serious;
Described filler (6) also can be selected active bio filler, and this filler has merged the multiple trace element that is conducive to the quick apposition growth of microorganism, good hydrophilic property in macromolecular material, extension mould is fast, oxygen transfer efficiency is high, and specific surface area is large, is beneficial to administer the river course that eutrophication is serious.
2. solar energy aeration oxygenation according to claim 1-plant bed carrier band microbial film device, is characterized in that, described solar panel (1) is 3~5, is arranged into fold-line-shaped, orientation Chao Nan, and spend with level orientation angle 10~20.
3. solar energy aeration oxygenation according to claim 1-plant bed carrier band microbial film device, it is characterized in that, described emergent is selected the emergent with good water body purification effect and landscape effect, is wilson iris, Canna generalis Bailey, reed, Scirpus tabernaemontani or cattail.
4. solar energy aeration oxygenation according to claim 1-plant bed carrier band microbial film device, is characterized in that, the plantation density of described emergent is 2~10 strains/m 2.
5. solar energy aeration oxygenation according to claim 1-plant bed carrier band microbial film device, it is characterized in that, the one-tenth string length of described filler (6) is in the situation that taking into full account the suffered buoyancy of filler, be set as 1/3~1/2 of the river course depth of water, but be generally no more than 1.2 meters, on filler string, adjacent filler spacing is set as 5~8cm, and filler string density is 40~60 strings/m 2.
6. solar energy aeration oxygenation according to claim 1-plant bed carrier band microbial film device, is characterized in that, the diameter of this device, depending on river cross-section width, is set to 1/5~1/4 of river cross-section width, but general maximum is no more than 2 meters; In river course, the spacing of adjacent stream oriented device is 5~10 meters.
CN201310756465.5A 2013-12-31 2013-12-31 Solar aeration-plant bed supported device with biological membrane Pending CN103723820A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104250057A (en) * 2014-08-29 2014-12-31 天津大学 Photocatalytic oxidation and ecological remediation combined integrated water body restoration device
CN104261566A (en) * 2014-10-17 2015-01-07 西南交通大学 Micro-aeration enhanced ecological floating bed sewage treatment device
CN105827181A (en) * 2016-05-31 2016-08-03 大工(青岛)新能源材料技术研究院有限公司 Photovoltaic power generation station for water surface planting
CN105948268A (en) * 2016-06-27 2016-09-21 中冶华天工程技术有限公司 Plant ecological floating bed
CN106045054A (en) * 2016-07-07 2016-10-26 河北新天地环保工程有限公司 Acquiring method of ecological enzymes and water purifying system formed by using ecological enzymes
CN106745766A (en) * 2016-12-01 2017-05-31 黄鑫 A kind of aquatic plant floating bed system of dependence solar energy aeration oxygenation
CN107162208A (en) * 2017-05-17 2017-09-15 南京鼎盛合力水利技术有限公司 Floating-island type biomembrane Water Ecological Recovery controlling device and apply its method
CN107176687A (en) * 2017-05-17 2017-09-19 东南大学 A kind of three-dimensional partition conbination is biological floating bed and its applies
CN108217957A (en) * 2018-01-15 2018-06-29 中冶华天工程技术有限公司 River black and odorous water comprehensive treatment device and method
CN109205800A (en) * 2018-11-16 2019-01-15 上海理工大学 It is a kind of that water quality emergency on duty and ensuring equipment are exempted from based on microbiological media

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CN201245510Y (en) * 2008-07-24 2009-05-27 李�杰 Natural energy water control ecological bed
CN103058383A (en) * 2013-01-16 2013-04-24 中国环境科学研究院 Multifunctional modularized floating island for in-situ restoration of polluted rivers and lakes
CN203668098U (en) * 2013-12-31 2014-06-25 天津大学 Solar aeration oxygenation-plant bed carrying biofilm device

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Publication number Priority date Publication date Assignee Title
CN201245510Y (en) * 2008-07-24 2009-05-27 李�杰 Natural energy water control ecological bed
CN103058383A (en) * 2013-01-16 2013-04-24 中国环境科学研究院 Multifunctional modularized floating island for in-situ restoration of polluted rivers and lakes
CN203668098U (en) * 2013-12-31 2014-06-25 天津大学 Solar aeration oxygenation-plant bed carrying biofilm device

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104250057A (en) * 2014-08-29 2014-12-31 天津大学 Photocatalytic oxidation and ecological remediation combined integrated water body restoration device
CN104261566A (en) * 2014-10-17 2015-01-07 西南交通大学 Micro-aeration enhanced ecological floating bed sewage treatment device
CN105827181A (en) * 2016-05-31 2016-08-03 大工(青岛)新能源材料技术研究院有限公司 Photovoltaic power generation station for water surface planting
CN105948268A (en) * 2016-06-27 2016-09-21 中冶华天工程技术有限公司 Plant ecological floating bed
CN106045054A (en) * 2016-07-07 2016-10-26 河北新天地环保工程有限公司 Acquiring method of ecological enzymes and water purifying system formed by using ecological enzymes
CN106745766A (en) * 2016-12-01 2017-05-31 黄鑫 A kind of aquatic plant floating bed system of dependence solar energy aeration oxygenation
CN107162208A (en) * 2017-05-17 2017-09-15 南京鼎盛合力水利技术有限公司 Floating-island type biomembrane Water Ecological Recovery controlling device and apply its method
CN107176687A (en) * 2017-05-17 2017-09-19 东南大学 A kind of three-dimensional partition conbination is biological floating bed and its applies
CN107162208B (en) * 2017-05-17 2018-05-15 南京鼎盛合力水利技术有限公司 Floating-island type biomembrane Water Ecological Recovery controlling device and apply its method
CN107176687B (en) * 2017-05-17 2020-05-19 东南大学 Three-dimensional partition combined ecological floating bed and application thereof
CN108217957A (en) * 2018-01-15 2018-06-29 中冶华天工程技术有限公司 River black and odorous water comprehensive treatment device and method
CN109205800A (en) * 2018-11-16 2019-01-15 上海理工大学 It is a kind of that water quality emergency on duty and ensuring equipment are exempted from based on microbiological media

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Application publication date: 20140416