CN103720026A - Reconstituted tobacco chlorine ion regulation and control method - Google Patents
Reconstituted tobacco chlorine ion regulation and control method Download PDFInfo
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- CN103720026A CN103720026A CN201310677366.8A CN201310677366A CN103720026A CN 103720026 A CN103720026 A CN 103720026A CN 201310677366 A CN201310677366 A CN 201310677366A CN 103720026 A CN103720026 A CN 103720026A
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- reconstituted tobacco
- extract
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- anion
- chlorion
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Abstract
The invention provides a reconstituted tobacco chlorine ion regulation and control method. The method includes the steps that suspended solids in extracting solution generated in an extraction section in the reconstituted tobacco production process are removed through separation and purification; ion exchange is conducted on 10-100% of the total mass of the purified extracting solution through an anion exchanger, and then chlorine ions in the solution are removed; the anion exchanger is used for regeneration through vinyl benzene anion resin and sodium hydroxide; the pH value of the extracting solution after ion exchange is adjusted to be in the range from 5.5 to 8 through malic acid, the extracting solution after ion exchange is mixed with the 0-90% of the extracting solution before ion exchange according to the 10-100% mass, coating production is conducted after the mixed solution is concentrated and mixed, the reconstituted tobacco product coating weight is counted according to product oven dry amount and controlled to be 40%, and then the chlorine ion content of reconstituted tobacco is regulated and controlled within the range from 0.1% to 0.8% by mass. According to the reconstituted tobacco chlorine ion regulation and control method, the problems that the chlorine ion content of the reconstituted tobacco is high and difficult to control can be solved.
Description
Technical field
The invention belongs to papermaking-method reconstituted tobaccos production technical field.
Background technology
Domestic papermaking-method reconstituted tobaccos manufacturing technology is started late, and realizes industrialization and is less than the time of 10 years, because the improvement of its consumption reduction, reducing tar and reducing harm and cigarette quality to cigarette industry has broad application prospects, progressively receives increasing concern.The production method of papermaking-method reconstituted tobaccos at present, mainly using the tobacco leaf fragment producing in Cigarette processing process and offal and other non-baccy fibers as mixed material, through solvent extraction, extract, through concentrated, as the solid content after coating fluid, extraction, utilize the production procedures such as the making beating of papermaking ratio juris, the moulding of manufacturing paper with pulp, coating fluid return painting, are dried and cut, acquisition can be for the reconstituted tobacco of cigarette industry.In recent years, along with the rising of tobacco material chloride ion content and the progressively raising of reconstituted tobacco coating weight, reconstituted tobacco product chloride ion content increases, and reaches 1.0-1.2%, is difficult to meet the requirement of tobacco business standard YC/T16.3 product chloride ion content≤0.8%.
Ion exchange technique is the characteristic that can be dissociated into cation or anion according to some solute, utilize the difference of ion-exchanger and different ions adhesion power, solute is temporarily exchanged on ion-exchanger, then with applicable eluant, eluent, solute ions is eluted to the operating technology that makes solute separate, concentrate or purify from original solution.Ion-exchanger is divided into cation exchanger (demineralizer), anion exchanger, mixed ion exchanger etc.Ion exchange technique is widely used in the fields such as food and drink, pharmacy, surface treatment, industrial pure water and preparation of high-purity water.Domestic publication CN101589845 has reported a kind of method that reduces content of chloride ions in paper-making method sheet tobacco, its method is: in papermaking-method reconstituted tobaccos is produced, utilize solvent to carry out multitple extraction to offal, the first order extracts the part extract obtaining and discharges after sewage disposal; The extract obtaining after the extraction of the second level all goes to concentrate; Again through dehydration for the first time, third level extraction, dehydration for the second time or subsequently after third level extraction and twice dehydration, carry out Separation of Solid and Liquid subsequently, the extract obtaining is sent into offal second level extraction use, and offal is sent into pulping section.Domestic publication CN103082394A has reported a kind of papermaking-method reconstituted tobaccos extract anionic group regulate and control method, by ionic membrane isolation technics, process the extract of the papermaking-method reconstituted tobaccos raw materials such as offal, offal and discarded tobacco leaf, regulate the inorganic anion content of reconstituted tobacco extract, improve the quality of papermaking-method reconstituted tobaccos, reduce flue gas of papermaking-method reconstituted tobaccos Harmful ingredient content.So far, also do not apply the technology that ion-exchange regulates and controls reconstituted tobacco chloride ion content.
Summary of the invention
The deficiency that object of the present invention exists in order to solve prior art just, provides a kind of method that ion-exchange regulates and controls reconstituted tobacco chloride ion content of applying, to solve reconstituted tobacco chloride ion content height and unmanageable problem.
The object of the invention is to be achieved through the following technical solutions.
A kind of reconstituted tobacco chlorion regulate and control method, the method is used ion exchange technique to process reconstituted tobacco extract, removes the chlorion in extract, realizes the regulation and control of reconstituted tobacco chloride ion content, and method step is as follows:
1) extract that extracts section output in reconstituted tobacco production process is removed to solid suspension through isolation of purified;
2) 10-100% of the extract gross mass after purified treatment is passed through to anion exchanger, carry out ion-exchange, remove the chlorion in liquid; Anion exchanger uses styrene resin anion (R.A.), regenerates with NaOH;
3) will with malic acid, adjust pH value to 5.5-8 through anion exchanger extract after treatment;
4) by adjust extract after pH value by mass percentage 10-100% mix with the extract 0-90% that does not pass through ion-exchange treatment;
5) will after mixed extract concentrates and allocates, enter coating and produce, it is 40% that reconstituted tobacco product coating weight is controlled by product oven-dry weight, realizes reconstituted tobacco chloride ion content and within the scope of 0.1-0.8%, regulates and controls by mass percentage.
The present invention is that a kind of production technology is simple, controllability is strong, selective height, stay-in-grade anion removal method, can be widely used in the removal of inorganic anion in papermaking-method reconstituted tobaccos extract, to improve combustibility, aesthetic quality and the harmful ingredients in flue gas burst size of papermaking-method reconstituted tobaccos.
Adopt reconstituted tobacco fragrance exquisiteness that the present invention produces, assorted gas is few, pleasant impression is clean, chloride ion content can be realized within the scope of 0.1-0.8%, product flammability is good, grey is white, availability is higher, can increase the use amount in the cigarette composition of reconstituted tobacco, reduce the cost of material of cigarette, also can improve the suction quality of cigarette.
Below in conjunction with Figure of description, further set forth content of the present invention.
Accompanying drawing explanation
Fig. 1 is the inventive method process chart.
The specific embodiment
Embodiment 1
As shown in Figure 1, a kind of reconstituted tobacco chlorion of the present invention regulate and control method is to use ion exchange technique to process reconstituted tobacco extract, removes the chlorion in extract, realizes the regulation and control of reconstituted tobacco chloride ion content, and method step is as follows:
1) after removing solid suspension, isolation of purified deposits the extract that extracts section output in reconstituted tobacco production process in fluid reservoir;
2) extract after purified treatment in fluid reservoir is passed through to anion exchanger in the ratio of gross mass 90%, carry out ion-exchange, remove the chlorion in liquid; Anion exchanger uses styrene resin anion (R.A.), regenerates with NaOH;
3) through anion, hand over device to change extract after treatment malic acid and adjust pH value to 6;
5) will after mixed extract concentrates and allocates, enter coating and produce, prepare reconstituted tobacco; It is 40% that reconstituted tobacco product coating weight is controlled by product oven-dry weight, realizes reconstituted tobacco chloride ion content and within the scope of 0.1-0.15%, regulates and controls by mass percentage.
Embodiment 2
A kind of reconstituted tobacco chlorion regulate and control method, method step is as follows:
1) extract that extracts section output in reconstituted tobacco production process is removed to solid suspension through isolation of purified;
2) by 20% of the extract gross mass after purified treatment, pass through anion exchanger, carry out ion-exchange, remove the chlorion in liquid; Anion exchanger uses styrene resin anion (R.A.), regenerates with NaOH;
3) through anion, hand over device to change extract after treatment malic acid and adjust pH value to 8;
4) extract of adjusting after pH value is mixed with the extract 80% that does not pass through ion-exchange treatment by 20%;
5) will after mixed extract concentrates and allocates, enter coating and produce, and prepare reconstituted tobacco, the control of reconstituted tobacco product coating weight is 40%, and reconstituted tobacco chloride ion content is 0.75-0.8%.
Embodiment 3
A kind of reconstituted tobacco chlorion regulate and control method, method step is as follows:
1) extract that extracts section output in reconstituted tobacco production process is removed to solid suspension through isolation of purified;
2) by 30% of the extract gross mass after purified treatment, pass through anion exchanger, carry out ion-exchange, remove the chlorion in liquid; Anion exchanger uses styrene resin anion (R.A.), regenerates with NaOH;
3) through anion, hand over device to change extract after treatment malic acid and adjust pH value to 7.5;
4) extract of adjusting after pH value is mixed with the extract 70% that does not pass through ion-exchange treatment by 30%;
5) will after mixed extract concentrates and allocates, enter coating and produce, and prepare reconstituted tobacco, the control of reconstituted tobacco product coating weight is 40%, and reconstituted tobacco chloride ion content is 0.7-0.75%.
Embodiment 4
A kind of reconstituted tobacco chlorion regulate and control method, method step is as follows:
1) extract that extracts section output in reconstituted tobacco production process is removed to solid suspension through isolation of purified;
2) by 50% of the extract gross mass after purified treatment, pass through anion exchanger, carry out ion-exchange, remove the chlorion in liquid; Anion exchanger uses styrene resin anion (R.A.), regenerates with NaOH;
3) through anion, hand over device to change extract after treatment malic acid and adjust pH value to 7;
4) extract of adjusting after pH value is mixed with the extract 50% that does not pass through ion-exchange treatment by 50%;
5) will after mixed extract concentrates and allocates, enter coating and produce, and prepare reconstituted tobacco, the control of reconstituted tobacco product coating weight is 40%, and reconstituted tobacco chloride ion content is 0.5-0.55%.
Embodiment 5
A kind of reconstituted tobacco chlorion regulate and control method, method step is as follows:
1) extract that extracts section output in reconstituted tobacco production process is removed to solid suspension through isolation of purified;
2) by 70% of the extract gross mass after purified treatment, pass through anion exchanger, carry out ion-exchange, remove the chlorion in liquid; Anion exchanger uses styrene resin anion (R.A.), regenerates with NaOH;
3) through anion, hand over device to change extract after treatment malic acid and adjust pH value to 6.5;
4) extract of adjusting after pH value is mixed with the extract 30% that does not pass through ion-exchange treatment by 70%;
5) will after mixed extract concentrates and allocates, enter coating and produce, and prepare reconstituted tobacco, the control of reconstituted tobacco product coating weight is 40%, and reconstituted tobacco chloride ion content is 0.3-0.35%.
Embodiment 6
A kind of reconstituted tobacco chlorion regulate and control method, method step is as follows:
1) extract that extracts section output in reconstituted tobacco production process is removed to solid suspension through isolation of purified;
2) the whole extracts after purified treatment are passed through to anion exchanger, carry out ion-exchange, remove the chlorion in liquid; Anion exchanger uses styrene resin anion (R.A.), regenerates with NaOH;
3) through anion, hand over device to change extract after treatment malic acid and adjust pH value to 5.5;
4) by adjusting after extract after pH value concentrate and allocate, enter and be coated with production, prepare reconstituted tobacco, the control of reconstituted tobacco product coating weight is 40%, and reconstituted tobacco chloride ion content is 0.05-0.1%.
The reconstituted tobacco of the reconstituted tobacco that adopts the inventive method to produce and the production of the prior art mode of production is made to sample cigarette, through the specialty committee member's sensory evaluation of smokeing panel test, think and utilize the reconstituted tobacco that the technology of the present invention makes to promote qualitatively in suction, fragrance exquisiteness, assorted gas is less, pleasant impression is clean.The reconstituted tobacco that the inventive method is produced carries out the evaluation of physics and chemistry index, to detect data and YC/T16.3-2003(reconstituted tobacco industry standard) compare, result shows, utilize physics, the chemical index of the reconstituted tobacco of the inventive method production to meet the requirement of countries tobacco industry < < reconstituted tobacco industry standard > >, product chloride ion content has been realized adjustable within the scope of 0.1-0.8%, controlled.
The reconstituted tobacco that applicant utilizes the inventive method to make, carries out after chopping it, in 10% ratio, adds in the trade mark cigarette of Yunnan.Through the specialty committee member's sensory evaluation of smokeing panel test, to think and add the cigarette of this reconstituted tobacco when keeping cigarette style, fragrance concentration improves, and stimulates, assorted gas reduces, and pleasant impression improves.Through flue gas analysis, add the cigarette of reconstituted tobacco, releasing content of coke tar is propped up and is reduced to 9.6mg/ and props up by the 12mg/ before not adding.Illustrate and utilize the inventive method production and processing reconstituted tobacco to there is beneficial effect.
Claims (1)
1. a reconstituted tobacco chlorion regulate and control method, is characterized in that, the method is used ion exchange technique to process reconstituted tobacco extract, removes the chlorion in extract, realizes the regulation and control of reconstituted tobacco chloride ion content, and method step is as follows:
1) extract that extracts section output in reconstituted tobacco production process is removed to solid suspension through isolation of purified;
2) 10-100% of the extract gross mass after purified treatment is passed through to anion exchanger, carry out ion-exchange, remove the chlorion in liquid; Anion exchanger uses styrene resin anion (R.A.), regenerates with NaOH;
3) will with malic acid, adjust pH value to 5.5-8 through anion exchanger extract after treatment;
4) by adjust extract after pH value by mass percentage 10-100% mix with the extract 0-90% that does not pass through ion-exchange treatment;
5) will after mixed extract concentrates and allocates, enter coating and produce, it is 40% that reconstituted tobacco product coating weight is controlled by product oven-dry weight, realizes reconstituted tobacco chloride ion content and within the scope of 0.1-0.8%, regulates and controls by mass percentage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310677366.8A CN103720026A (en) | 2013-12-13 | 2013-12-13 | Reconstituted tobacco chlorine ion regulation and control method |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310677366.8A CN103720026A (en) | 2013-12-13 | 2013-12-13 | Reconstituted tobacco chlorine ion regulation and control method |
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| CN103720026A true CN103720026A (en) | 2014-04-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310677366.8A Pending CN103720026A (en) | 2013-12-13 | 2013-12-13 | Reconstituted tobacco chlorine ion regulation and control method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104824822A (en) * | 2015-03-13 | 2015-08-12 | 广东中烟工业有限责任公司 | Method for improving sensory quality of reconstituted tobacco |
| CN106366110A (en) * | 2016-08-30 | 2017-02-01 | 唐山三友硅业有限责任公司 | Method for removing residual chloridion from hydrolysate |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3616801A (en) * | 1968-10-28 | 1971-11-02 | Philip Morris Inc | Process for the treatment of tobacco to effect ion removal |
| US20060231496A1 (en) * | 2005-04-01 | 2006-10-19 | Akzo Nobel N.V. | Method of treating polyaluminium compounds |
| CN101641291A (en) * | 2006-11-16 | 2010-02-03 | 雅宝荷兰有限责任公司 | By molybdenum glance purified molybdenum technical oxide |
| CN103082394A (en) * | 2013-01-25 | 2013-05-08 | 安徽中烟工业有限责任公司 | Regulation and control method for paper-making method reproducing tobacco leaf extract liquor negative ion components |
| CN103330278A (en) * | 2013-07-02 | 2013-10-02 | 云南烟草科学研究院 | Method for controlling chlorine content of paper-making process reconstituted tobacco |
| CN103371429A (en) * | 2012-04-22 | 2013-10-30 | 朱大恒 | Tobacco dechlorinating method, application of tobacco dechlorinating method and tobacco dechlorinating device |
-
2013
- 2013-12-13 CN CN201310677366.8A patent/CN103720026A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3616801A (en) * | 1968-10-28 | 1971-11-02 | Philip Morris Inc | Process for the treatment of tobacco to effect ion removal |
| US20060231496A1 (en) * | 2005-04-01 | 2006-10-19 | Akzo Nobel N.V. | Method of treating polyaluminium compounds |
| CN101641291A (en) * | 2006-11-16 | 2010-02-03 | 雅宝荷兰有限责任公司 | By molybdenum glance purified molybdenum technical oxide |
| CN103371429A (en) * | 2012-04-22 | 2013-10-30 | 朱大恒 | Tobacco dechlorinating method, application of tobacco dechlorinating method and tobacco dechlorinating device |
| CN103082394A (en) * | 2013-01-25 | 2013-05-08 | 安徽中烟工业有限责任公司 | Regulation and control method for paper-making method reproducing tobacco leaf extract liquor negative ion components |
| CN103330278A (en) * | 2013-07-02 | 2013-10-02 | 云南烟草科学研究院 | Method for controlling chlorine content of paper-making process reconstituted tobacco |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104824822A (en) * | 2015-03-13 | 2015-08-12 | 广东中烟工业有限责任公司 | Method for improving sensory quality of reconstituted tobacco |
| CN106366110A (en) * | 2016-08-30 | 2017-02-01 | 唐山三友硅业有限责任公司 | Method for removing residual chloridion from hydrolysate |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 650106 No. 41, medical Road, hi tech Zone, Yunnan, Kunming Applicant after: Yunnan Zhongyan Reconstituted Tobacco Co., Ltd. Address before: 650106 No. 41, medical Road, hi tech Zone, Yunnan, Kunming Applicant before: Yunnan Zhongyan Kunchuan Ruisheng Technology Co., Ltd. |
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| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: YUNNAN ZHONGYAN KUNCHUAN RUISHENG TECHNOLOGY CO., LTD. TO: YUNNAN ZHONGYAN RECONSTITUTED TOBACCO CO., LTD. |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Application publication date: 20140416 |