CN103709835B - Resin combination and false proof type matrix material for false proof type matrix material protection layer - Google Patents

Abstract

The invention provides a kind of false proof type matrix material protection layer resin combination and false proof type matrix material; this false proof type matrix material comprises plane materiel, patterned layer, protective layer, ink layer, dielectric layer, adhesive layer and release liners successively, and described protective layer is solidify to form through isocyanate-based curing agent by resin combination. Compared with prior art, protective layer of the present invention is taking acrylic resin as main film forming substance, acrylic resin has good physical and mechanical properties, weatherability, chemical-resistant and resistance to water excellence, and guarantor's light colour retention is high, can play good protective effect to patterned layer; Meanwhile, the present invention adds cellulose ester type resin additive promoter the most, and its hydroxyl and isocyanate-based curing agent generation polyaddition reaction film-forming, can make resin combination fast filming; In addition, cellulose esters resin has good hydrophilic and oleophilic performance, can make protective layer have good printing adaptability energy.

Description

Resin combination and false proof type matrix material for false proof type matrix material protection layer

Technical field

The invention belongs to anti-fake material technical field, relate in particular to false proof type matrix material protection layer resin groupCompound and false proof type matrix material.

Background technology

Fake just have from ancient times, thereby false proof be an ancient topic, equally remote with the mankind's civilization.Along with commodity economy become increasingly prosperous and scientific and technical development, false proof become one also brand-newThe field changing at development.

False proof science and technology refers to the measure of taking in order to reach false proof object, and it within the specific limits can be accurateDiscern the false from the genuine, and be difficult for the technology that is imitated and copies. Be exactly briefly prevent from copying, counterfeit skillArt. The one taked in order to protect brand names, protection market, protection consumers in general's legitimate rights and interestsPrecaution technical measures.

Enterprise is in making full use of anti-counterfeiting technology and hitting fake and forged commodity, rectify and standardize market, moreBe external enterprise of modern enterprise and products thereof image, show business to consumer, society is taken responsibilityA kind of necessary means.

Enterprise should be taking false proof as opportunity simultaneously, a kind of strategic investment using effective false proof measure as enterprise,And in a planned way formulate and progressively realize false proof target, and by false proof through production, marketThe overall process of marketing, business administration, using false proof as enterprise's right-safeguarding, crack down on counterfeit goods, synergy, brandImportant means.

At present, using more general anti-counterfeiting technology is to stick anti-fake material on regular qualified product, withPrevent low-quality goods counterfeit. The structure of anti-fake material is generally anti-forgery ink, anti-forge paper, is a kind of baseMaterial is the revealing type adhesive sticker anti-fake material of plastic sheeting, art paper, synthetic paper, opens layered abilityShow and lie in the content of interlayer, thereby reach false proof effect.

Protective layer in false proof type matrix material is a kind of coating based on patterned layer and ink layer, and it can not onlyEnough hide all information of patterned layer, and can accept ink layer, played the work of protection patterned layer informationWith, therefore it is indispensable part in anti-counterfeiting technology. Protective layer need have high rigidity and chemicals-resistantEtc. performance, in order to reach above-mentioned requirements, many enterprise developments many moneys protecting layer compositions: one is treeThe reaction of oil/fat composition and curing agent, this kind of protecting layer compositions not only can at a lower temperature can be quickReaction, and at room temperature also can automatically react, when in the time of coating protective layer, process drying tunnel is only at surface dryingJust can rolling, then own slaking under room temperature, fully reacts completely, and can reach result of use, butThe method material resin composition mostly is import raw material, and cost is higher; Another kind is in matrix resinAccording to the composition of amino resins ratio, due to amino crosslinked will be at high temperature just can fast reaction,Inefficiency, cost is higher.

Summary of the invention

In view of this, the technical problem to be solved in the present invention is to provide a kind of false proof type matrix material protection layerWith resin combination and false proof type matrix material, this false proof type matrix material protection layer cost is lower.

The invention provides a kind of false proof type matrix material, comprise successively plane materiel, patterned layer, protective layer, oilChina ink layer, dielectric layer, adhesive layer and release liners, described protective layer by resin combination through isocyanate-basedCuring agent solidify to form, and described resin combination comprises host and additive promoter;

Described host comprises:

Acrylic resin 50～80 weight portions;

The first auxiliary agent 0.5～3 weight portion;

The first organic solvent 20～50 weight portions;

Described additive promoter comprises:

The first cellulose ester type resin 50～80 weight portions;

The second organic solvent 30～50 weight portions;

Described the first auxiliary agent is one or more in wetting agent, levelling agent, coupling agent and drier.

Preferably, the thickness of described protective layer is 8～20 μ m.

Preferably, described the first organic solvent and the second organic solvent be selected from independently of one another acetone, butanone,One or more in butyl acetate, ethyl acetate, toluene and dimethylbenzene.

Preferably, described the first cellulose ester type resin is selected from cellulose acetate resin, propyl acetate fiberOne or more in element resin, butyl acetate celluosic resin and cellulose nitrate resin.

Preferably, described patterned layer is formed by the second resin combination; Described the second resin combination comprises:

The second cellulose ester type resin 5～30 weight portions;

The 3rd organic solvent 60～90 weight portions.

Preferably, the thickness of described ink layer is 0.5～1.5 μ m.

Preferably, described ink layer is Halogen, the ink that does not contain heavy metal.

Preferably, described dielectric layer is formed by the 3rd resin combination, and described the 3rd resin combination comprises:

Described the 4th organic solvent is alcohols solvent and/or alcohol ether solvent;

Described the second auxiliary agent is one or more in wetting agent, levelling agent, defoamer and dispersant.

The present invention also provides a kind of false proof type matrix material protection layer resin combination, comprises host and addsAdd agent promoter;

Described host comprises:

Acrylic resin 50～80 weight portions;

The first auxiliary agent 0.5～3 weight portion;

The first organic solvent 20～50 weight portions;

Described additive promoter comprises:

The first cellulose ester type resin 50～80 weight portions;

The second organic solvent 30～50 weight portions;

Described the first auxiliary agent is one or more in wetting agent, levelling agent, coupling agent and drier.

The present invention also provides a kind of preparation method of false proof type matrix material protection layer resin combination, bagDraw together following steps:

By the first auxiliary agent of the acrylic resin of 50～80 weight portions, 0.5～3 weight portion and 20～50 weight portionsFirst organic solvent mix, stir, obtain host; Described the first auxiliary agent is wetting agent, levellingOne or more in agent, coupling agent and drier;

By the first cellulose ester type resin of 50～80 weight portions and the second organic solvent of 30～50 weight portionsMix, stir, obtain additive promoter;

Described host is mixed with additive promoter, obtains false proof type matrix material protection layer resin groupCompound.

The invention provides a kind of false proof type matrix material protection layer resin combination and false proof type matrix material,This false proof type matrix material comprises plane materiel, patterned layer, protective layer, ink layer, dielectric layer, adhesive successivelyLayer and release liners, described protective layer is solidify to form through isocyanate-based curing agent by resin combination, described inResin combination comprises host and additive promoter; Described host comprises: acrylic resin 50～80 weightsAmount part; The first auxiliary agent 0.5～3 weight portion; The first organic solvent 20～40 weight portions; Described additive promotesAgent comprises: the first cellulose ester type resin 60～80 weight portions; The second organic solvent 30～50 weight portions;Described the first auxiliary agent is one or more in wetting agent, levelling agent, coupling agent and drier. With existingTechnology is compared, and protective layer of the present invention is taking acrylic resin as main film forming substance, and acrylic resin hasGood physical and mechanical properties, weatherability, chemical-resistant and resistance to water excellence, guarantor's light colour retention is high, canPatterned layer is played to good protective effect; Meanwhile, the present invention adds cellulose ester type resin and adds the mostAgent promoter, its hydroxyl and isocyanate-based curing agent generation polyaddition reaction film-forming, can make treeOil/fat composition fast filming; In addition, cellulose esters resin has good hydrophilic and oleophilic performance, can makeProtective layer has good printing adaptability energy.

Brief description of the drawings

Fig. 1 is the schematic diagram of the false proof type matrix material of the present invention.

Detailed description of the invention

The invention provides a kind of false proof type matrix material protection layer resin combination, comprise host and interpolationAgent promoter;

Described host comprises:

Acrylic resin 50～80 weight portions;

The first auxiliary agent 0.5～3 weight portion;

The first organic solvent 20～50 weight portions;

Described additive promoter comprises:

The first cellulose ester type resin 50～80 weight portions;

The second organic solvent 30～50 weight portions;

Described the first auxiliary agent is one or more in wetting agent, levelling agent, coupling agent and drier.

The present invention does not have special restriction to the source of all raw materials, for commercially available.

Wherein, described acrylic resin is preferably 50～70 weight portions, more preferably 55～65 weight portions;Described acrylic resin is acrylic resin well known to those skilled in the art, and it can be a kind of monomerOr the homopolymers that several monomer polymerizations form or copolymer, there is no special restriction, described in the present inventionAcrylic resin polymerization monomer used is preferably methyl methacrylate, EMA, methylOne or more in butyl acrylate, methyl acrylate, ethyl acrylate and butyl acrylate; DescribedThe weight average molecular weight of acrylic resin is preferably 50,000～300,000, and more preferably 100,000～200,000.

Described the first auxiliary agent is one or more in wetting agent, levelling agent, coupling agent and drier, containsAmount is preferably 0.5～2 weight portion, more preferably 0.5～1 weight portion. Wherein, described wetting agent is this areaWetting agent known by the technical staff, there is no special restriction, is preferably polyoxyethylene groups in the present inventionOne or more in alkane ether, acetylene ethylene glycol and polyoxyethylene glycol Arrcostab; Described levelling agent isLevelling agent well known to those skilled in the art, there is no special restriction, is preferably modification in the present inventionPolysiloxanes and/or modified silicone; Described coupling agent is preferably silane, titanate esters, phosphate and chromium complexingOne or more in thing; Described drier is preferably dibutyl tin laurate and/or hydramine drier.

Described the first organic solvent is preferably 30～45 weight portions, more preferably 30～40 weight portions; DescribedThe first organic solvent is organic solvent well known to those skilled in the art, there is no special restriction, thisIn invention, be preferably a kind of in acetone, butanone, butyl acetate, ethyl acetate, toluene and dimethylbenzene orMultiple.

Described the first cellulose ester type resin is preferably 50～70 weight portions, more preferably 50～60 weight portions;Described the first cellulose ester type resin is cellulose ester type resin well known to those skilled in the art, andWithout special restriction, in the present invention, be preferably cellulose acetate resin, propyl acetate celluosic resin, vinegarOne or more in acid butyl ester celluosic resin and cellulose nitrate resin.

Described the second organic solvent is preferably 40～50 weight portions; Described the second organic solvent is this area skillThe organic solvent that art personnel know, there is no special restriction, in the present invention, be preferably acetone, butanone,One or more in butyl acetate, ethyl acetate, toluene and dimethylbenzene. According to the present invention, describedOne organic solvent can be identical with the second organic solvent, also can be different, there is no special restriction.

The present invention also provides a kind of preparation side of above-mentioned false proof type matrix material protection layer resin combinationMethod, comprises the following steps: by the first auxiliary agent of the acrylic resin of 50～80 weight portions, 0.5～3 weight portionMix with the first organic solvent of 20～50 weight portions, stir, obtain host; Described the first auxiliary agentFor one or more in wetting agent, levelling agent, coupling agent and drier; By of 50～80 weight portionsOne cellulose ester type resin mixes with the second organic solvent of 30～50 weight portions, stirs, and is addedAdd agent promoter; Described host is mixed with additive promoter, obtains false proof type matrix material protection layerUse resin combination.

Wherein, described acrylic resin, the first auxiliary agent, the first organic solvent, the first cellulose esters type treeFat and the second organic solvent are all same as above, do not repeat them here.

By the first auxiliary agent of the acrylic resin of 50～80 weight portions, 0.5～3 weight portion and 20～50 weight portionsFirst organic solvent mix, in the present invention, this step is preferably according to carrying out below: by 20～50 weightFirst organic solvent of part mixes with the acrylic resin of 50～80 weight portions, stirs for the first time, soAfter add the first auxiliary agent of 0.5～3 weight portion, stir for the second time, filter, obtain host. Wherein,The described speed stirring is for the first time preferably 500～600rpm; The described time of stirring is for the first time preferably10～20min, dissolves completely to acrylic resin; The described speed stirring is for the second time preferably 600～700Rpm; The described time of stirring is for the second time preferably 5～10min.

By the first cellulose ester type resin of 50～80 weight portions and the second organic solvent of 30～50 weight portionsMix, stir, obtain additive promoter. The speed stirring described in this step is preferably 800～900Rpm; The time of described stirring is preferably 10～20min, dissolves completely to the first cellulose ester type resin.

According to the present invention, the preparation process of described host and additive promoter in no particular order, can first be preparedHost, also can first prepare additive promoter, there is no special restriction.

Described host is mixed with additive promoter, can obtain false proof type matrix material protection layer resinComposition.

The false proof type matrix material protection of the present invention layer is simple by resin combination preparation method, and cost is lower.

The present invention also provides a kind of false proof type matrix material, comprise successively plane materiel, patterned layer, protective layer,Ink layer, dielectric layer, adhesive layer and release layer, wherein, described protective layer by resin combination through differentCyanate type curing agent solidify to form, and described resin combination comprises host and additive promoter;

Described host comprises:

Acrylic resin 50～80 weight portions;

The first auxiliary agent 0.5～3 weight portion;

The first organic solvent 20～50 weight portions;

Described additive promoter comprises:

The first cellulose ester type resin 50～80 weight portions;

The second organic solvent 30～50 weight portions;

Described the first auxiliary agent is one or more in wetting agent, levelling agent, coupling agent and drier.

Wherein, described resin combination false proof type matrix material protection layer resin combination same as above,This repeats no more. As shown in Figure 1, wherein 1 is plane materiel to the schematic diagram of this false proof type matrix material, and 2 is patternLayer, 3 is protective layer, and 4 is ink layer, and 5 is dielectric layer, and 6 is adhesive layer, 7 is release layer.

In the false proof type matrix material of the present invention, described plane materiel is plane materiel well known to those skilled in the art,There is no special restriction, in the present invention, preferably the thickness of plane materiel is 25～50 μ m; The kind of described plane materiel is excellentElect poly terephthalic acid ethanol ester (PET), bidirectional stretching polypropylene film (BOPP) and polyvinyl chloride as(PVC) one in, more preferably PET.

Described patterned layer is patterned layer well known to those skilled in the art, there is no special restriction. FigureCase layer is mainly security pattern, word or other information of printing protection. Preferred pattern layer in the present inventionFormed by the second resin combination, described the second resin combination comprises the second cellulose of 5～30 weight portionsThe 3rd organic solvent of ester type resin and 60～90 weight portions. Cellulose ester type resin is owing to having preferablyThe good combination of the performances such as toughness, hardness, intensity, surface gloss, transparency and feel are soft and showingClaim, and it is also the high material of a kind of chemical resistance, its mechanical performance changes with plasticizer consumption,Plasticizer consumption is low, and product surface hardness is high, heat resistance is high, harder, hot strength is high and haveBetter dimensional stability, plasticizer consumption is high, and goods impact strength can increase, and it also has in additionNatural colour, water white transparency, amber, smoky gray is transparent and black is translucent etc. selective, also can be at itMiddle interpolation mill base concentrate, to change its color. Described in the present invention, the second cellulose ester type resin is preferredFor a kind of in cellulose acetate, cellulose propionate, cellulose butyrate, cellulose nitrate or wherein;Described the 3rd organic solvent be preferably toluene, dimethylbenzene, butyl acetate, butanone, acetone, cyclohexanone,One or more in DAA; According to the present invention, described the second resin combination preferably also comprises that mill base is denseContracting thing; Described mill base concentrate according to the ratio 40 of its celluosic resin and organic solvent gross weight/One to 1/10th ratio is added.

Described protective layer it be mainly the anti-counterfeiting information of protection patterned layer and accept ink layer. In the present inventionThe thickness of described protective layer is preferably 8～20 μ m, more preferably 8～15 μ m. Described protective layer is by resin groupCompound solidify to form through isocyanate-based curing agent, and described resin combination is same as above, no longer superfluous at thisState; Described isocyanate-based curing agent is preferably; TDI PIC, TDI addition product and TDI tri-One in aggressiveness curing agent. The mass ratio of described resin combination and isocyanate-based curing agent is(2～6): 1, more preferably (3～5): 1, then be preferably 4:1.

Described ink layer is ink layer well known to those skilled in the art, there is no special restriction; ThisIn invention, its thickness is preferably 0.5～1.5 μ m. Ink layer is can be versicolor according to client's requirement printingInk, ink layer described in the present invention is preferably Halogen, does not contain the ink of heavy metal.

Dielectric layer is formed by the 3rd resin combination, its between ink layer and adhesive layer, each coatingBetween be closely connected, influence each other. Wherein, the effect of dielectric layer is for accepting ink layer and glueAdhensive layer is bonding better, the solvent corrosion ink layer can not make to be coated with adhesive time, thereby to inkLayer has certain protective effect; In the time that the structure of false proof type matrix material occurs to destroy, dielectric layer can be wellSeparate with ink layer, meanwhile, it also can remain in the surface of affixed object with being combined with adhesive layer well,Clearly demonstrate the type matrix effect in false proof type matrix material, thereby reach false proof material.

Described the 3rd resin combination comprises:

Described the 4th organic solvent is alcohols solvent and/or alcohol ether solvent;

Described the second auxiliary agent is one or more in wetting agent, levelling agent, defoamer and dispersant.

Wherein, described aqueous polymer emulsion is preferably 60～90 weight portions, more preferably 70～90 weightPart; Described aqueous polymer emulsion is preferably aqueous acrylic emulsion and/or aqueous polyurethane emulsion.

Described the 4th organic solvent is preferably 8～12 weight portions, more preferably 9～12 weight portions; The present inventionIn the kind of the 4th organic solvent used be that alcohols solvent well known to those skilled in the art and/or alcohol ethers are moltenAgent, there is no special restriction, is preferably in ethanol, isopropyl alcohol and ethylene glycol monobutyl ether in the present inventionOne or more.

Described the second auxiliary agent is preferably 1～4 weight portion; Described the second auxiliary agent is wetting agent, levelling agent, disappearsOne or more in infusion and dispersant; Wherein, described wetting agent is well known to those skilled in the artWetting agent, there is no special restriction, is preferably polyoxyethylene groups alkane ether, acetylene second two in the present inventionOne or more in alcohol and polyoxyethylene glycol Arrcostab; Described levelling agent is those skilled in the artThe levelling agent of knowing, there is no special restriction, is preferably modified polyorganosiloxane and/or changes in the present inventionProperty silicone; Described defoamer is defoamer well known to those skilled in the art, there is no special restriction,In the present invention, be preferably the one in polyethers defoamer, silicon defoamer and polyether-modified silicon defoamerOr multiple; Described dispersant is dispersant well known to those skilled in the art, there is no special restriction,In the present invention, be preferably one in fatty acid dispersant, aliphatic amide type dispersant and ester class dispersantKind or multiple.

Described filler is preferably 1～3 weight portion; The kind of described filler is well known to those skilled in the artFiller, there is no special restriction, is preferably calcium carbonate, talcum powder, alumina silicate, sulphur in the present inventionOne or more in acid calcium, silica, calcium silicates and flatting silica, more preferably TS-100 flatting silica.

According to the present invention, the thickness of described dielectric layer is preferably 8～15 μ m, more preferably 8～10 μ m.

Dielectric layer is accepted ink layer and adhesive layer, and the thickness of described adhesive layer is preferably 16～20 μ m;Its adhesive used is selected the reasonable adhesive of tack, and being preferably 180 degree peeling forces is 0.8～1.5The adhesive of N/inch.

Protective layer of the present invention is taking acrylic resin as main film forming substance, and acrylic resin has good thingReason mechanical performance, weatherability, chemical-resistant and resistance to water excellence, guarantor's light colour retention is high, can be to patternLayer plays good protective effect; Meanwhile, the present invention adds the additive promotion the most of cellulose ester type resinAgent, its hydroxyl and isocyanate-based curing agent generation polyaddition reaction film-forming, can make resin combinationThing fast filming; In addition, cellulose esters resin has good hydrophilic and oleophilic performance, can make protective layerThere is good printing adaptability energy.

In order to further illustrate the present invention, below in conjunction with embodiment to the false proof type matrix of one provided by the inventionMaterial protection layer is described in detail with resin combination and false proof type matrix material.

In following examples, reagent used is commercially available.

Embodiment 1

1.1 taking the thick poly terephthalic acid ethanol ester (PET) of 25 μ m as plane materiel; By the vinegar of 10 weight portionsAcid cellulose mixes with the toluene of 70 weight portions, stirs 50min, to completely molten with the speed of 500rpmSeparate, filter, the coating obtaining is coated on PET plane materiel, after being dried, obtain patterned layer.

1.2 add to 16.5 weight portion butyl acetates and 23 parts by weight of toluene in reactor, stir, then addEnter the acrylic resin of 60.5 weight portions, continue to be stirred to evenly, then add 0.1 weight portion 1051 evenThe BYK-065 defoamer of connection agent, 0.1 weight portion DBTDL drier and 0.3 weight portion stirs,Obtain coating major ingredient; The toluene of the butyl acetate of 25 weight portions and 25 weight portions is added in reactor,Stir, then add the cellulose nitro-resin of 50 weight portions, continue to be stirred to evenly, filter and obtain coatingPromoter; Coating major ingredient, additive promoter are mixed with TDI tripolymer, obtain protection layer for paint,The trimerical quality of TDI is 1/4th of coating major ingredient and additive promoter gross mass, by protective layerCoating is coated in patterned layer, after solidifying, obtains the protective layer that thickness is 10 μ m.

On 1.3 protective layers that the ink printing of G02 system is obtained in 1.2, obtaining thickness is 1 μ mInk layer.

The aqueous polyurethane emulsion of 90 weight portions is placed in reactor by 1.4, and 200rpm stirs 5min,Mix, then add the absolute ethyl alcohol of 7 weight portions, 250rpm stirs 10min, makes it to disperse allThe slightly emulsion of blue light of even formation milky; Again by the auxiliary agent of 1 weight portion 140 wetting agents and 1 weight portionAuxiliary agent TEGO4100 add in reactor, 300rpm stirs 2min; Finally filling out 1 weight portionMaterial TS-100 is added in reactor, accelerates the rotating speed of mixer, and 500rpm stirs 40min, makes itBe uniformly dispersed, stablized, without precipitation slightly albescent resin combination; Resin combination is coated inOn the ink layer obtaining in 1.3, obtain the dielectric layer that thickness is 8 μ m.

1.5 to select MH-101 be adhesive, is coated on the dielectric layer obtaining in 1.4, obtains glueAdhensive layer.

1.6 taking 80g lattice Racine as release liners, by itself and 1.5 in the adhesive layer that obtains compound, preventedPseudo-type matrix material.

The protective layer obtaining in 1.2 is analyzed, its at ambient temperature 3min be curable film-forming.

The ink layer obtaining in 1.3 is analyzed, and itself and protective layer associativity are better, and are heated to60 DEG C, protective layer and ink layer all do not come off.

Embodiment 2

2.1 taking the thick poly terephthalic acid ethanol ester (PET) of 25 μ m as plane materiel; By the vinegar of 10 weight portionsAcid cellulose mixes with the toluene of 70 weight portions, stirs 50min, to completely molten with the speed of 500rpmSeparate, filter, the coating obtaining is coated on PET plane materiel, after being dried, obtain patterned layer.

2.2 add to 23 weight portion butyl acetates and 13 parts by weight of toluene in reactor, stir, then addThe acrylic resin of 63.5 weight portions, continues to be stirred to evenly, then adds 0.1 weight portion 1051 couplingsThe BYK-065 defoamer of agent, 0.1 weight portion DBTDL drier and 0.3 weight portion stirs,To coating major ingredient; The toluene of the butyl acetate of 27.8 weight portions and 17.8 weight portions is added in reactor,Stir, then add the cellulose nitro-resin of 54.40 weight portions, continue to be stirred to evenly, filter and be coated withMaterial promoter; Coating major ingredient, additive promoter are mixed with TDI tripolymer, obtain protection layer for paint,The trimerical quality of TDI is 1/4th of coating major ingredient and additive promoter gross mass, by protective layerCoating is coated in patterned layer, after solidifying, obtains the protective layer that thickness is 10 μ m.

On 2.3 protective layers that the ink printing of G02 system is obtained in 2.2, obtaining thickness is 1 μ mInk layer.

The aqueous acrylic emulsion of 80 weight portions is placed in reactor by 2.4, and 200rpm stirs 5min,Mix, then add the absolute ethyl alcohol of 12 weight portions, 250rpm stirs 10min, makes it to disperseEvenly form the slightly emulsion of blue light of milky; Again by the auxiliary agent of 2 weight portions 140 wetting agents and 2 weightThe auxiliary agent TEGO4100 of part adds in reactor, and 300rpm stirs 2min; Finally by 4 weight portionsFiller TS-100 is added in reactor, accelerates the rotating speed of mixer, and 500rpm stirs 40min, makesIt is uniformly dispersed, stablized, without precipitation slightly albescent resin combination; Resin combination is appliedOn the ink layer obtaining, obtain the dielectric layer that thickness is 8 μ m in 2.3.

2.5 to select MH-101 be adhesive, is coated on the dielectric layer obtaining in 2.4, obtains glueAdhensive layer.

2.6 taking 80g lattice Racine as release liners, by itself and 2.5 in the adhesive layer that obtains compound, preventedPseudo-type matrix material.

The protective layer obtaining in 2.2 is analyzed, its at ambient temperature 2min be curable film-forming.

The ink layer obtaining in 2.3 is analyzed, and itself and protective layer associativity are better, and are heated to60 DEG C, protective layer and ink layer all do not come off.

Embodiment 3

3.1 taking the thick poly terephthalic acid ethanol ester (PET) of 25 μ m as plane materiel; By the vinegar of 10 weight portionsAcid cellulose mixes with the toluene of 70 weight portions, stirs 50min, to completely molten with the speed of 500rpmSeparate, filter, the coating obtaining is coated on PET plane materiel, after being dried, obtain patterned layer.

3.2 add to 49.5 weight portion butyl acetates in reactor, stir, then add third of 50 weight portionsOlefin(e) acid resin, continues to be stirred to evenly, then adds 0.1 weight portion 1051 coupling agents, 0.1 weight portionThe BYK-065 defoamer of DBTDL drier and 0.3 weight portion stirs, and obtains coating major ingredient; WillThe toluene of the butyl acetate of 25 weight portions and 25 weight portions adds in reactor, stirs, then adds 50 weightsThe cellulose nitro-resin of amount part, continues to be stirred to evenly, filters and obtains coating promoter; By coating masterMaterial, additive promoter are mixed with TDI tripolymer, obtain protection layer for paint, the trimerical quality of TDIFor 1/4th of coating major ingredient and additive promoter gross mass, protection layer for paint is coated in to patterned layerUpper, after solidifying, obtain the protective layer that thickness is 10 μ m.

On 3.3 protective layers that the ink printing of G02 system is obtained in 3.2, obtaining thickness is 1 μ mInk layer.

The aqueous polyurethane emulsion of 85 weight portions is placed in reactor by 3.4, and 200rpm stirs 5min,Mix, then add the absolute ethyl alcohol of 7 weight portions, 250rpm stirs 10min, makes it to disperse allThe slightly emulsion of blue light of even formation milky; Again by the auxiliary agent of 1 weight portion 140 wetting agents and 1 weight portionAuxiliary agent TEGO4100 add in reactor, 500rpm stirs 40min, and it is uniformly dispersed,To stable, the slightly albescent resin combination of nothing precipitation; Resin combination is coated in to the oil obtaining in 3.3China ink layer is upper, obtains the dielectric layer that thickness is 8 μ m.

3.5 to select MH-101 be adhesive, is coated on the dielectric layer obtaining in 3.4, obtains glueAdhensive layer.

3.6 taking 80g lattice Racine as release liners, by itself and 3.5 in the adhesive layer that obtains compound, preventedPseudo-type matrix material.

The protective layer obtaining in 3.2 is analyzed, its at ambient temperature 3min be curable film-forming.

The ink layer obtaining in 3.3 is analyzed, and itself and protective layer associativity are better, and are heated to60 DEG C, protective layer and ink layer all do not come off.

Embodiment 4

4.1 taking the thick poly terephthalic acid ethanol ester (PET) of 25 μ m as plane materiel; By the vinegar of 10 weight portionsAcid cellulose mixes with the toluene of 70 weight portions, stirs 50min, to completely molten with the speed of 500rpmSeparate, filter, the coating obtaining is coated on PET plane materiel, after being dried, obtain patterned layer.

4.2 add to 44.5 weight portion butyl acetates in reactor, stir, then add third of 55 weight portionsOlefin(e) acid resin, continues to be stirred to evenly, then adds 0.1 weight portion 1051 coupling agents, 0.1 weight portionThe BYK-065 defoamer of DBTDL drier and 0.3 weight portion stirs, and obtains coating major ingredient; WillThe toluene of the butyl acetate of 25 weight portions and 25 weight portions adds in reactor, stirs, then adds 50 weightsThe cellulose nitro-resin of amount part, continues to be stirred to evenly, filters and obtains coating promoter; By coating masterMaterial, additive promoter are mixed with TDI tripolymer, obtain protection layer for paint, the trimerical quality of TDIFor 1/4th of coating major ingredient and additive promoter gross mass, protection layer for paint is coated in to patterned layerUpper, after solidifying, obtain the protective layer that thickness is 10 μ m.

On 4.3 protective layers that the ink printing of G02 system is obtained in 4.2, obtaining thickness is 1 μ mInk layer.

The aqueous polyurethane emulsion of 85 weight portions is placed in reactor by 4.4, and 200rpm stirs 5min,Mix, then add the absolute ethyl alcohol of 7 weight portions, 250rpm stirs 10min, makes it to disperse allThe slightly emulsion of blue light of even formation milky; Again by the auxiliary agent of 1 weight portion 140 wetting agents and 1 weight portionAuxiliary agent TEGO4100 add in reactor, 500rpm stirs 40min, and it is uniformly dispersed,To stable, the slightly albescent resin combination of nothing precipitation; Resin combination is coated in to the oil obtaining in 4.3China ink layer is upper, obtains the dielectric layer that thickness is 8 μ m.

4.5 to select MH-101 be adhesive, is coated on the dielectric layer obtaining in 4.4, obtains glueAdhensive layer.

4.6 taking 80g lattice Racine as release liners, by itself and 4.5 in the adhesive layer that obtains compound, preventedPseudo-type matrix material.

The protective layer obtaining in 4.2 is analyzed, its at ambient temperature 3min be curable film-forming.

The ink layer obtaining in 4.3 is analyzed, and itself and protective layer associativity are better, and are heated to60 DEG C, protective layer and ink layer all do not come off.

Embodiment 5

5.1 taking the thick poly terephthalic acid ethanol ester (PET) of 25 μ m as plane materiel; By the vinegar of 10 weight portionsAcid cellulose mixes with the toluene of 70 weight portions, stirs 50min, to completely molten with the speed of 500rpmSeparate, filter, the coating obtaining is coated on PET plane materiel, after being dried, obtain patterned layer.

5.2 add to 21 weight portion butyl acetates and 13 parts by weight of toluene in reactor, stir, then addThe acrylic resin of 65.5 weight portions, continues to be stirred to evenly, then adds 0.1 weight portion 1051 couplingsThe BYK-065 defoamer of agent, 0.1 weight portion DBTDL drier and 0.3 weight portion stirs,To coating major ingredient; The toluene of the butyl acetate of 25 weight portions and 25 weight portions is added in reactor, stirMix, then add the cellulose nitro-resin of 50 weight portions, continue to be stirred to evenly, it is short that filtration obtains coatingEnter agent; Coating major ingredient, additive promoter are mixed with TDI tripolymer, obtain protection layer for paint, TDITrimerical quality is 1/4th of coating major ingredient and additive promoter gross mass, by protection layer for paintBe coated in patterned layer, after solidifying, obtain the protective layer that thickness is 10 μ m.

On 5.3 protective layers that the ink printing of G02 system is obtained in 5.2, obtaining thickness is 1 μ mInk layer.

The aqueous polyurethane emulsion of 85 weight portions is placed in reactor by 5.4, and 200rpm stirs 5min,Mix, then add the absolute ethyl alcohol of 7 weight portions, 250rpm stirs 10min, makes it to disperse allThe slightly emulsion of blue light of even formation milky; Again by the auxiliary agent of 1 weight portion 140 wetting agents and 1 weight portionAuxiliary agent TEGO4100 add in reactor, 500rpm stirs 40min, and it is uniformly dispersed,To stable, the slightly albescent resin combination of nothing precipitation; Resin combination is coated in to the oil obtaining in 5.3China ink layer is upper, obtains the dielectric layer that thickness is 8 μ m.

5.5 to select MH-101 be adhesive, is coated on the dielectric layer obtaining in 5.4, obtains glueAdhensive layer.

5.6 taking 80g lattice Racine as release liners, by itself and 3.5 in the adhesive layer that obtains compound, preventedPseudo-type matrix material.

The protective layer obtaining in 5.2 is analyzed, its at ambient temperature 3min be curable film-forming.

The ink layer obtaining in 5.3 is analyzed, and itself and protective layer associativity are better, and are heated to60 DEG C, protective layer and ink layer all do not come off.

The above is only the preferred embodiment of the present invention, it should be pointed out that general for the artLogical technical staff, under the premise without departing from the principles of the invention, can also make some improvement and profitDecorations, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (8)

1. a false proof type matrix material, comprise successively plane materiel, patterned layer, protective layer, ink layer,Dielectric layer, adhesive layer and release liners, is characterized in that, described protective layer is by resin combination warpIsocyanate-based curing agent solidify to form, and described resin combination comprises host and additive promoter;

Described host comprises:

Acrylic resin 50～80 weight portions;

The first auxiliary agent 0.5～3 weight portion;

The first organic solvent 20～50 weight portions;

Described additive promoter comprises:

The first cellulose ester type resin 50～80 weight portions;

The second organic solvent 30～50 weight portions;

Described the first auxiliary agent is one or more in wetting agent, levelling agent, coupling agent and drier.

2. false proof type matrix material according to claim 1, is characterized in that described protective layerThickness be 8～20 μ m.

3. false proof type matrix material according to claim 1, is characterized in that, described first hasMachine solvent and the second organic solvent are selected from acetone, butanone, butyl acetate, acetic acid second independently of one anotherOne or more in ester, toluene and dimethylbenzene.

4. false proof type matrix material according to claim 1, is characterized in that, described the first fibreTie up plain ester type resin and be selected from cellulose acetate resin, propyl acetate celluosic resin, butyl acetate fibreTie up one or more in plain resin and cellulose nitrate resin.

5. false proof type matrix material according to claim 1, is characterized in that described patterned layerFormed by the second resin combination; Described the second resin combination comprises:

The second cellulose ester type resin 5～30 weight portions;

The 3rd organic solvent 60～90 weight portions.

6. false proof type matrix material according to claim 1, is characterized in that described ink layerThickness be 0.5～1.5 μ m.

7. false proof type matrix material according to claim 1, is characterized in that described ink layerFor Halogen, not containing the ink of heavy metal.

8. false proof type matrix material according to claim 1, is characterized in that described dielectric layerFormed by the 3rd resin combination, described the 3rd resin combination comprises:

Described the 4th organic solvent is alcohols solvent and/or alcohol ether solvent;

Described the second auxiliary agent is one or more in wetting agent, levelling agent, defoamer and dispersant.