CN103626366B - 一种油田含油污泥资源化的处理方法 - Google Patents
一种油田含油污泥资源化的处理方法 Download PDFInfo
- Publication number
- CN103626366B CN103626366B CN201310703139.8A CN201310703139A CN103626366B CN 103626366 B CN103626366 B CN 103626366B CN 201310703139 A CN201310703139 A CN 201310703139A CN 103626366 B CN103626366 B CN 103626366B
- Authority
- CN
- China
- Prior art keywords
- oil
- treatment
- extraction
- sludge
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000010802 sludge Substances 0.000 title claims abstract description 65
- 238000004064 recycling Methods 0.000 title abstract description 6
- 238000000605 extraction Methods 0.000 claims abstract description 67
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 35
- 239000002904 solvent Substances 0.000 claims abstract description 24
- 238000001914 filtration Methods 0.000 claims abstract description 13
- 238000004821 distillation Methods 0.000 claims abstract description 10
- 238000007873 sieving Methods 0.000 claims abstract description 3
- 239000003921 oil Substances 0.000 claims description 72
- 239000003795 chemical substances by application Substances 0.000 claims description 54
- 239000000203 mixture Substances 0.000 claims description 34
- 241000894006 Bacteria Species 0.000 claims description 24
- 239000012071 phase Substances 0.000 claims description 22
- 238000005188 flotation Methods 0.000 claims description 17
- 238000005191 phase separation Methods 0.000 claims description 16
- 239000008346 aqueous phase Substances 0.000 claims description 15
- 239000010779 crude oil Substances 0.000 claims description 14
- 235000016709 nutrition Nutrition 0.000 claims description 12
- 230000035764 nutrition Effects 0.000 claims description 12
- 244000005700 microbiome Species 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000007790 solid phase Substances 0.000 claims description 8
- 238000000638 solvent extraction Methods 0.000 claims description 7
- VSCWAEJMTAWNJL-UHFFFAOYSA-K Aluminium chloride Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 6
- 241000589516 Pseudomonas Species 0.000 claims description 6
- 241000589517 Pseudomonas aeruginosa Species 0.000 claims description 6
- 229940055023 Pseudomonas aeruginosa Drugs 0.000 claims description 6
- 241000316848 Rhodococcus <scale insect> Species 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000011084 recovery Methods 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 5
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 239000006004 Quartz sand Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive Effects 0.000 claims description 4
- 239000010428 baryte Substances 0.000 claims description 4
- 229910052601 baryte Inorganic materials 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- -1 aluminium iron Chemical compound 0.000 claims description 3
- 239000011257 shell material Substances 0.000 claims description 2
- 238000007667 floating Methods 0.000 abstract description 8
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 3
- 238000004062 sedimentation Methods 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 238000005194 fractionation Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 238000009287 sand filtration Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative Effects 0.000 description 1
- 230000004059 degradation Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010909 process residue Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004642 transportation engineering Methods 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Abstract
本发明涉及油田含油污泥的处理，特别涉及一种油田含油污泥资源化的处理方法，处理设备包括污油污泥提升装置、振动筛、萃取罐、三相分离罐、蒸馏塔、电气浮与过滤装置；包括机械筛除、溶剂萃取、三相分离、溶剂回收以及油渣处理等步骤。本发明的萃取过程为水辅助的溶剂萃取过程，使萃取更充分，更易于后期的相分离回收，溶剂可回收循环利用，辅助水可通过电气浮-过滤处理后循环利用，不造成二次污染，泥渣生物处理后有效利用，从而充分利用了含油污泥这一废弃的资源，节约石油资源，消除环境污染，产生经济与社会双重效益。
Description
技术领域
[0001] 本发明涉及油田含油污泥的处理，特别涉及一种油田含油污泥资源化的处理方法。
背景技术
[0002] 油田含油污泥的来源主要是原油开采、集输过程产生的含油污泥。这些含油污泥除含有原油外，还含有采出液中携带的地层泥沙，油田污水处理站污水处理过程中形成的含油浮渣，管道与储罐的腐蚀产物，以及胶质、浙青质等，和一定的水份。
[0003] 原油开采过程中产生的含油污泥主要来源于采出液的地面处理系统，采油污水处理过程中产生的含油污泥，再加上污水净化处理中投加的净水剂形成的絮体等组成了油田含油污泥。
[0004] 油田集输过程产生含油污泥主要来源于接转站、联合站的油罐、沉降罐、污水罐、隔油池底泥、油品储罐在储存油品时，油品中的少量机械杂质、沙粒、泥土、重金属盐类以及石蜡和胶质浙青质等重质组分沉积在油罐底部，形成罐底油泥。此外一次沉降罐、二次沉降罐、酸化压裂作业也可产生含油污泥。
[0005] 经分析这些含油污泥组成各异，通常含油率在10%〜60%之间，泥沙等固体物10-60%，含水15-60%。在石油资源日益紧张、环境污染日趋严峻的形势下，有效回收污油泥中的原油、无害化的处理残渣，不仅可节约宝贵的石油资源、消除环境污染，同时可产生经济与社会双重效益。
[0006]目前，比较常见的含油污泥的处理方法有:掩埋，焚烧，活性水热洗涤法、溶剂萃取法、生物法、热解法等。但其中多数方法都存在着一些问题，不适合实际应用。如焚烧法能耗大、且易产生二次污染，并浪费宝贵的原油资源；生物处理法需历时长，原油资源不仅得不到回收利用，关键是通常仅适宜于含油小于5%的含油污泥；活性水热洗涤法需另加破乳剂和加热，而且后处理较困难，同时也产生二次污染；热解法设备投资高，污油泥需预脱水干化处理，且存在较大的安全隐患。
[0007] 溶剂萃取法是回收原油较有效的方法，萃取后泥渣的含油量较易达到填埋或堆放的国家标准，并且萃取深度可通过萃剂的选择与操作参数的调整进行有效控制。该方法除可有效回收宝贵的原油资源外，还易与其它处理工艺，如焚烧、生物降解法联合，达到完全无害化的处理。
[0008] 专利CN1526797A，应用萃取法从含油污泥中回收燃料油。该专利采用通用的萃取塔，在含油污泥分层较慢时，需加入I 一 3%的稀酸进行破乳，会造成设备的腐蚀与环境的二次污染。
[0009] 专利CN 102092907 A 一种含油污泥资源化处理的方法。用电气浮处理的污水冲洗污油泥，再用电气浮法气浮分理出原油，冲洗后的含油污泥至流幕式萃取塔萃取，萃取混合液入沉降罐自然沉降分离出油相与水相，油相入分馏塔分馏出原油与萃取剂。该专利所采用的从污水中分理原油的电气浮法，没有对电气浮的极板、操作条件等加以限制，恐难得到合格的原油。
[0010] 专利CN 101734834 A砂质含油污泥回收方法。依次将萃取剂与砂质含有污泥按0.5:1至10:1的体积比混合，进行间歇式萃取，萃取溶剂层、水、泥沙三相分离，萃取溶剂层经减压或常压蒸馏分出溶剂与原油。所用溶剂为6#溶剂油、120 #溶剂油、芳烃、凝析油、石油醚中的一种或几种混合物。该专利存在油分与泥沙不易剥离及萃取相与泥沙不易分离的问题，同时，没有对电气浮的极板以及浸洗水中的机械杂质加以限制，这恐造成萃取中间层的增加与乳化油的形成，而最终无法运行。
发明内容
[0011] 本发明针对现有技术中的不足，提供一种油田含油污泥资源化的处理方法。
[0012] 本发明的技术方案是:
[0013] 一种油田含油污泥资源化的处理方法，处理设备包括含油污泥提升装置，振动筛，萃取罐、三相分离罐、蒸馏塔、电气浮、过滤装置；
[0014] 具体步骤:
[0015] I)筛除含油污泥中的粒径大于0.5cm的块状物；
[0016] 2)过筛后的含油污泥进入溶剂萃取过程，并进行油相、水相、固相的三相分离；所述溶剂萃取过程为水辅助的溶剂萃取过程，含油污泥与萃取剂混合搅拌10-90min后，再注入0.5-2倍于萃取剂体积的辅助水并搅拌5-30min ;萃取剂为以6#溶剂油、芳烃、油田凝析油、石油醚为主剂的混合物，采用间歇式的萃取方式，萃取剂与含油污泥体积比为0.5:1-5:1，萃取温度为 15-800C ；
[0017] 3)经过步骤2)得到的油相通过蒸馏回收原油与溶剂；
[0018] 4)经过步骤2)水相经电气浮-过滤处理后循环利用，其中，电气浮的极板为非溶解性的，同时兼具电凝聚-电气浮功能；过滤为核桃壳、石英砂或重晶石过滤；
[0019] 5)经过步骤2)得到的含油小于5%的泥渣与添加剂混合，并将微生物混合菌剂及营养剂的水液均匀喷洒在含油泥沙中进行生物处理；所述微生物混合菌剂从原油污染土壤中筛选培育，包括铜绿假单胞菌、假单胞菌和枯草芽孢杆菌、红球菌的混合菌，所述以上四种菌按照1:1:1:1的重量比混合。
[0020] 在以上方案的基础上，所述步骤2)在三相分离时萃取混合物不易分层时，加入0.05-0.1%辅助水质量的聚合氯化铝、聚合氯化铝铁中的一种或两种。
[0021] 在以上方案的基础上，所述步骤2)所述步骤2)的辅助水为油田采出水，采出水的矿化度最好是大于10000mg/L。
[0022] 在以上方案的基础上，所述步骤4)电气浮-过滤处理，其中，电气浮为一至二级，过滤为一至二级。
[0023] 在以上方案的基础上，所述步骤5)的营养剂为KNOjP K 2ΗΡ04,保持含油泥沙中C:N:P 为 100:10:1-100:15:5。
[0024] 在以上方案的基础上，所述步骤5)添加剂为锯末，其加入量为5-15%的泥沙体积，生物处理过程中泥沙的含水量在35-55%。
[0025] 本发明的有益效果是:
[0026] 本发明的萃取过程为水辅助的溶剂萃取过程，辅助水促进油分与泥沙的剥离、萃取相与泥沙的相分离、以及萃取泥渣中萃取剂的替出，使萃取更充分，更易于后期的分离回收，溶剂可回收循环利用，辅助水可通过电气浮-过滤处理后循环利用，不造成二次污染，萃取泥渣生物处理后有效利用，从而充分利用了含油污泥这一废弃的资源，节约石油资源，消除环境污染，产生经济与社会双重效益。
附图说明
[0027] 附图1为本发明的工艺流程图。
具体实施方式
[0028] 本发明的具体实施方式如下:
[0029] 实施例1
[0030] 一种油田含油污泥资源化的处理方法，处理设备包括油污泥提升装置，振动筛，萃取罐、三相分离罐、蒸馏塔、电气浮装置；
[0031] 具体步骤:
[0032] I)含油污泥提升装置将含油污泥提升至振动筛，在振动筛中将含油污泥中的粒径大于0.5cm的块状物；
[0033] 2)将含油污泥I m3置于5 m3萃取罐中，泵入Im 3的萃取剂，搅拌90min使油份完全溶解后，注入Im3油田采出水搅拌并沉降1min后，将萃取相泵入三相分离罐分离出固相、水相、油相；萃取剂为以6#溶剂油为主剂的混合物，采用间歇式的萃取方式萃取温度为35 0C ；
[0034] 3)油相泵入溶剂分馏塔分出萃取剂与原油，萃取剂经塔顶冷凝器冷凝后循环使用；
[0035] 4)经过步骤2)水相经电气浮-过滤处理后循环利用，其中，电气浮的极板为非溶解性的，同时兼具电凝聚-电气浮功能；过滤为核桃壳过滤+石英砂过滤；
[0036] 5)过步骤2)得到的固相泥渣加入其10%体积的锯末并混均后，喷洒含有微生物混合菌剂与营养剂的水，所述微生物混合菌剂从原油污染土壤中筛选培育，包括铜绿假单胞菌、假单胞菌和枯草芽孢杆菌、红球菌的混合菌，所述以上四种菌按照1:1:1:1的重量比混合；营养剂为謂03和K 2ΗΡ04;堆放进行生物处理6-12月。
[0037] 实施例2
[0038] 一种油田含油污泥资源化的处理方法，处理设备包括油污泥提升装置，振动筛，萃取罐、三相分离罐、蒸馏塔、电气浮装置；
[0039] 具体步骤如下:
[0040] I)含油污泥提升装置将含油污泥提升至振动筛，在振动筛中将含油污泥中的粒径大于0.5cm的块状物；
[0041] 2)将含油污泥Im3置于I #萃取罐中，泵入2m 3的萃取剂，搅拌使油份完全溶解后，注入I Hi3油田采出水并搅拌沉降1min后，将萃取相泵入三相分离罐分离出固相、水相、油相；萃取剂为以油田凝析油、石油醚为主剂的混合物萃取过程采用间歇式的萃取方式，萃取温度为55°C。
[0042] 3)油相泵入溶剂分馏塔分出萃取剂与原油，萃取剂经塔顶冷凝器冷凝后循环使用；
[0043] 4)水相经电气浮，核桃壳+石英砂过滤处理后循环使用；
[0044] 5)经过步骤2)得到的含油小于5%的泥渣加入其15%体积的锯末并混均后，喷洒含有混合菌剂与营养剂的水，所述微生物混合菌剂从原油污染土壤中筛选培育，包括铜绿假单胞菌、假单胞菌和枯草芽孢杆菌、红球菌的混合菌，所述以上四种菌按照1:1:1:1的重量比混合；营养剂为謂03和K 2ΗΡ04;堆放进行生物处理6-12月。
[0045] 实施例3
[0046] —种油田含油污泥资源化的处理方法，处理设备包括油污泥提升装置，振动筛，萃取罐、三相分离罐、蒸馏塔、电气浮装置；
[0047] 具体步骤如下:
[0048] I)含油污泥提升装置将含油污泥提升至振动筛，在振动筛中将含油污泥中的粒径大于0.5cm的块状物；
[0049] 2)将含油污泥I m3置于1#萃取罐中，泵入3m 3的萃取剂，搅拌50min使油份完全溶解后，注入3 m3的油田采出水，并沉降60min后，将萃取相泵入三相分离罐分离出固相、水相、油相；萃取剂为以6#溶剂油、芳烃、油田凝析油为主剂的混合物，萃取过程采用间歇式的萃取方式，萃取温度为65°C。
[0050] 3)油相泵入溶剂分馏塔分出萃取剂与原油，萃取剂经塔顶冷凝器冷凝后循环使用；
[0051] 4)水相经电气浮，重晶石过滤处理后循环使用；
[0052] 5)过步骤2)得到的含油小于5%的泥渣加入其5%体积的锯末并混均后，喷洒含有混合菌剂与营养剂的水，所述微生物混合菌剂从原油污染土壤中筛选培育，包括铜绿假单胞菌、假单胞菌和枯草芽孢杆菌、红球菌的混合菌，所述以上四种菌按照1:1:1:1的重量比混合；营养剂为謂03和K 2ΗΡ04;堆放进行生物处理6-12月。
[0053] 实施例4
[0054] 一种油田含油污泥资源化的处理方法，处理设备包括油污泥提升装置，振动筛，萃取罐、三相分离罐、蒸馏塔、电气浮装置；
[0055] 具体步骤如下:
[0056] I)含油污泥提升装置将含油污泥提升至振动筛，在振动筛中将含油污泥中的粒径大于0.5cm的块状物；
[0057] 2)将含油污泥I m3置于I #萃取罐中，泵入5m 3的萃取剂，搅拌20min使油份完全溶解后，注入3m3油田采出水，再注入6.4kg的聚合氯化铝和聚合氯化铝铁的混合物，并沉降60min后，将萃取相泵入三相分离罐分离出固相、水相、油相；萃取剂为以6#溶剂油、芳烃、油田凝析油为主剂的混合物，萃取过程采用间歇式的萃取方式，萃取温度为65°C。
[0058] 3)油相泵入溶剂分馏塔分出萃取剂与原油，萃取剂经塔顶冷凝器冷凝后循环使用；
[0059] 4)水相经电气浮，重晶石过滤处理后循环使用；
[0060] 5)过步骤2)得到的含油小于5%的泥渣加入其5%体积的锯末并混均后，喷洒含有混合菌剂与营养剂的水，所述微生物混合菌剂从原油污染土壤中筛选培育，包括铜绿假单胞菌、假单胞菌和枯草芽孢杆菌、红球菌的混合菌，所述以上四种菌按照1:1:1:1的重量比混合；营养剂为謂03和K 2ΗΡ04;堆放进行生物处理6-12月。
[0061] 实施例5
[0062] 将含油污泥I m3置于萃取I#罐中，泵入2 m3的萃取剂，搅拌30min使油份完全溶解后，注入Im3油田采出水并搅拌沉降20min后，将混合物泵入三相分离罐分离出固相、水相、油相，油相泵入萃取罐中在进行萃取；水相经电气浮、过滤处理后循环使用；二次萃取后的残渣排出萃取罐，并进行生物处理。
Claims (6)
1.一种油田含油污泥资源化的处理方法，其特征在于:处理设备包括油污泥提升装置，振动筛，萃取罐、三相分离罐、蒸馏塔、电气浮、过滤装置； 具体步骤: 1)筛除含油污泥中的粒径大于0.5cm的块状物； 2)过筛后的含油污泥进入溶剂萃取过程，并进行油相、水相、固相的三相分离；所述溶剂萃取过程为水辅助的溶剂萃取过程，含油污泥与萃取剂混合搅拌10-90min后，再注入0.5-2倍于萃取剂体积的辅助水并搅拌5-30min ;萃取剂为以6#溶剂油、芳烃、油田凝析油、石油醚为主剂的混合物，采用间歇式的萃取方式，萃取剂与含油污泥体积比为0.5:1-5:1，萃取温度为15-80°C ； 3)经过步骤2)得到的油相通过蒸馏回收原油与溶剂； 4)经过步骤2)水相经电气浮-过滤处理后循环利用，其中，电气浮的极板为非溶解性的，同时兼具电凝聚-电气浮功能；过滤为核桃壳、石英砂或重晶石过滤； 5)经过步骤2)得到的含油小于5%的泥渣与添加剂混合，并将微生物混合菌剂及营养剂的水液均匀喷洒在含油泥沙中进行生物处理；所述微生物混合菌剂从原油污染土壤中筛选培育，包括铜绿假单胞菌、假单胞菌和枯草芽孢杆菌、红球菌的混合菌，所述以上四种菌按照1:1:1:1的重量比混合。
2.根据权利要求1所述的油田含油污泥资源化的处理方法，其特征在于，所述步骤2)在三相分离时萃取混合物不易分层时，加入0.05-0.1%辅助水质量的聚合氯化铝、聚合氯化铝铁中的一种或两种。
3.根据权利要求1所述的油田含油污泥资源化的处理方法，其特征在于，所述步骤2)的辅助水为油田采出水，所述采出水的矿化度最好是大于10000mg/L。
4.根据权利要求1或2所述的油田含油污泥资源化的处理方法，其特征在于，所述步骤4)电气浮-过滤处理，其中，电气浮为一至二级，过滤为一至二级。
5.根据权利要求1或2所述的油田含油污泥资源化的处理方法，其特征在于，所述步骤5)的营养剂为KNOJP K2HPO4，保持含油泥沙中C:N:P为100:10:1-100:15:5。
6.根据权利要求1所述的油田含油污泥资源化的处理方法，其特征在于，所述步骤5)添加剂为锯末，其加入量为5-15%的泥沙体积，生物处理过程中泥沙的含水量在35-55%。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310703139.8A CN103626366B (zh) | 2013-12-19 | 2013-12-19 | 一种油田含油污泥资源化的处理方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310703139.8A CN103626366B (zh) | 2013-12-19 | 2013-12-19 | 一种油田含油污泥资源化的处理方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103626366A CN103626366A (zh) | 2014-03-12 |
| CN103626366B true CN103626366B (zh) | 2015-04-29 |
Family
ID=50207863
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310703139.8A Expired - Fee Related CN103626366B (zh) | 2013-12-19 | 2013-12-19 | 一种油田含油污泥资源化的处理方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103626366B (zh) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105174669B (zh) * | 2015-09-30 | 2018-07-06 | 四川光隆环保科技有限公司 | 废弃油基泥浆无害化处理工艺 |
| CN105733640A (zh) * | 2016-03-16 | 2016-07-06 | 中国石油大学(华东) | 一种废弃油基钻井液的处理方法 |
| CN107572751A (zh) * | 2016-07-05 | 2018-01-12 | 中国石油化工股份有限公司 | 处理油泥的方法 |
| CN108218164A (zh) * | 2018-03-05 | 2018-06-29 | 四川同步油田技术服务有限公司 | 一种油田废弃泥浆资源化处理的方法 |
| CN108455762A (zh) * | 2018-04-13 | 2018-08-28 | 陈淡宁 | 采用物化、生化技术综合治理油田废弃物的方法 |
| CN109179930B (zh) * | 2018-09-30 | 2020-12-01 | 华东理工大学 | 一种罐底油泥中油、泥、水三相分离以及油泥中油的高效回收的方法 |
| CN110759614A (zh) * | 2019-10-29 | 2020-02-07 | 中国石油化工股份有限公司 | 一种清罐油泥干化前的除油方法 |
| CN110922011A (zh) * | 2019-12-06 | 2020-03-27 | 朱玉波 | 一种用于降解含油污泥及cod的微生物菌剂及其应用方法 |
| CN111253964B (zh) * | 2020-02-12 | 2021-11-05 | 北京矿冶科技集团有限公司 | 一种含聚污油泥的处理方法 |
| CN111718085A (zh) * | 2020-06-11 | 2020-09-29 | 中石大蓝天(青岛)石油技术有限公司 | 一种固体废物的处理方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202898175U (zh) * | 2012-09-18 | 2013-04-24 | 中国石油天然气股份有限公司 | 一种油田含油污泥资源化处理装置 |
-
2013
- 2013-12-19 CN CN201310703139.8A patent/CN103626366B/zh not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202898175U (zh) * | 2012-09-18 | 2013-04-24 | 中国石油天然气股份有限公司 | 一种油田含油污泥资源化处理装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103626366A (zh) | 2014-03-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103626366B (zh) | 一种油田含油污泥资源化的处理方法 | |
| CN102092907B (zh) | 一种含油污泥资源化处理的方法 | |
| CN101734834A (zh) | 砂质含油污泥回收方法 | |
| CN105621823A (zh) | 油田污水处理产生的含油污泥的处理工艺 | |
| CN106014340B (zh) | 一种废弃油基泥浆和油基钻屑的无害化处理工艺 | |
| CN108911447B (zh) | 一种含聚油泥复配处理药剂及其使用方法 | |
| CN103693833B (zh) | 一种含油污泥的综合治理方法 | |
| CN101050049A (zh) | 落地油泥综合处理利用方法 | |
| CN102241998B (zh) | 油泥砂处理装置及工艺 | |
| CN108862954B (zh) | 一种采用开关型混合溶剂体系处理含油废弃物的方法 | |
| CN1303020C (zh) | 利用三相分离技术处理含油污泥的方法 | |
| CN107879572B (zh) | 一种含油污泥的处理方法 | |
| CN103739137A (zh) | 油田污油的无害化处理回收方法及装置 | |
| CN108409077A (zh) | 含油污泥物化耦合处理方法 | |
| CN202898175U (zh) | 一种油田含油污泥资源化处理装置 | |
| CN108558155A (zh) | 一种含油污泥无害资源化的处理方法 | |
| CN202898176U (zh) | 一种砂质含油污泥资源化处理装置 | |
| CN109264946A (zh) | 一种梯级深度分离含油污泥的方法 | |
| CN106316019A (zh) | 一种石油石化含油污泥资源综合利用方法 | |
| CN105967496A (zh) | 一种高盐污泥的无害化处理方法 | |
| CN103626367B (zh) | 一种含聚气浮污油泥资源化回收再利用的方法 | |
| CN104140184A (zh) | 一种炼油厂含油污泥的处理方法 | |
| CN107060671A (zh) | 工业油水废物污染土壤岩屑生态治理技术 | |
| CN110950513B (zh) | 一种利用表面活性剂预处理-水热氧化-热裂解耦合法处理罐底泥的方法 | |
| CN101967033A (zh) | 一种罐底油泥减量化、资源化、无害化的处理方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| C10 | Entry into substantive examination | ||
| GR01 | Patent grant | ||
| C14 | Grant of patent or utility model | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150429 Termination date: 20151219 |
|
| EXPY | Termination of patent right or utility model |