CN103614646A - Alloy steel material used for concrete pump conveyer pipes and preparation method of the alloy steel material - Google Patents
Alloy steel material used for concrete pump conveyer pipes and preparation method of the alloy steel material Download PDFInfo
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- CN103614646A CN103614646A CN201310506140.1A CN201310506140A CN103614646A CN 103614646 A CN103614646 A CN 103614646A CN 201310506140 A CN201310506140 A CN 201310506140A CN 103614646 A CN103614646 A CN 103614646A
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- 229910000851 Alloy steel Inorganic materials 0.000 title claims abstract description 20
- 239000000463 material Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000007670 refining Methods 0.000 claims abstract description 17
- 238000005266 casting Methods 0.000 claims abstract description 13
- 229910052742 iron Inorganic materials 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 9
- 239000011651 chromium Substances 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052729 chemical element Inorganic materials 0.000 claims abstract description 7
- 229910052802 copper Inorganic materials 0.000 claims abstract description 7
- 239000010949 copper Substances 0.000 claims abstract description 7
- 239000010703 silicon Substances 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 7
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 18
- 238000010792 warming Methods 0.000 claims description 18
- 238000009413 insulation Methods 0.000 claims description 14
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 12
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 12
- 238000005275 alloying Methods 0.000 claims description 12
- 239000004571 lime Substances 0.000 claims description 12
- 229910000805 Pig iron Inorganic materials 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 239000011572 manganese Substances 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 238000006477 desulfuration reaction Methods 0.000 claims description 3
- 230000023556 desulfurization Effects 0.000 claims description 3
- 238000001514 detection method Methods 0.000 claims description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
- 229910000514 dolomite Inorganic materials 0.000 claims description 3
- 239000010459 dolomite Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 239000010977 jade Substances 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 3
- 238000010791 quenching Methods 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229940001516 sodium nitrate Drugs 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 3
- 239000000956 alloy Substances 0.000 abstract description 3
- 229910052692 Dysprosium Inorganic materials 0.000 abstract description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 2
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 238000007669 thermal treatment Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
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- Curing Cements, Concrete, And Artificial Stone (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Abstract
The invention discloses an alloy steel material used for concrete pump conveyer pipes. The alloy steel material comprises following chemical elements by weight: 0.2-0.4% of carbon, 0.8-1.1% of silicon, 1.9-2.3% of manganese, 1.5-1.7% of chromium, 0.4-0.7% of vanadium, 0.07-0.1% of copper, 0.04-0.07% of Dy, S not more than 0.05% and P not more than 0.05%, with the balance being iron. By utilization of the chromium, the manganese, the rare earth element dysprosium, and other elements, and by adding the raw materials in batches and reasonably controlling the thermal treatment temperature after casting, an alloy formed has characteristics of high yield strength, high tensile strength, high specific elongation, and wear resistance. The alloy steel is suitable for various delivery pipes and is especially suitable for the concrete delivery pump pipes. The alloy steel material has good wear resistance and long service lifetime. A refining agent provided by the invention is used for casting production. The porosity degree in castings is reduced by 1-2 degrees. Oxide inclusion is at about the 2 level.
Description
Technical field
The present invention relates to metallic substance preparation field, relate in particular to alloy steel material and preparation method thereof for a kind of concrete pump transfer lime.
background technology
The environment of pump valve work is various, badly, very high to the requirement of material, the steel alloy that pump valve is used at present has varied, technology has very much progress, but still have a lot of problems to exist, as wear resistance, hardness, rustless property, corrosion resistance nature, high and low temperature resistance, fragility, toughness etc., in a lot of occasions, can't meet the requirement of production, also require further improvement, to enhance productivity, reduce costs, improve security, for high-quality precision and sophisticated technology development provides safeguard, for social development provides power, task is also very arduous.
Summary of the invention
The object of the present invention is to provide alloy steel material and preparation method thereof for a kind of concrete pump transfer lime, this alloy material has advantages of high-yield strength, high-tensile, high-elongation, wear-resisting.
Technical scheme of the present invention is as follows:
A concrete pump transfer lime alloy steel material, is characterized in that: chemical element composition and mass percent thereof that it contains are: carbon 0.2-0.4, silicon 0.8-1.1, manganese 1.9-2.3, chromium 1.5-1.7, vanadium 0.4-0.7, copper 0.07-0.1, Dy0.04-0.07, S≤0.05, P≤0.05, surplus are iron.
The production method of alloy steel material for described concrete pump transfer lime, is characterized in that:
(1), preparing the pig iron and scrap iron originates as ferrous substrate in 1:1-2 ratio, the pig iron is added to drop in stove and melt, carry out desulfurization, deoxidation, employing refining agent initial refining, add alloying constituent and carry out alloying, then add scrap iron fusing, add refining agent secondary refining, detection and adjust chemical element component content to qualified, casting, casting postheat treatment etc.;
(2) in alloying process, to the lot sequence that drops into alloying element in stove, be: (1) silicon, manganese, Dy; (2) chromium, vanadium, copper; The timed interval that each batch drops into element is 21-25 minute, after feeding intake, stirs.
Described casting postheat treatment is: first by room temperature, with 200-220 ℃/h of speed, be warming up to 500-510 ℃, with 160-170 ℃/h of speed, be cooled to 400-410 ℃ again, with 200-220 ℃/h of speed, be warming up to 650-660 ℃ again, insulation 60-70 minute, with 200-220 ℃/h of speed, be warming up to 930-940 ℃ again, insulation 3-4 hour; With 150-160 ℃/h of speed, be cooled to 600-620 ℃ again, then be warming up to 710-730 ℃ with 200-220 ℃/h of speed, then be cooled to 500-510 ℃ with 130-140 ℃/h of speed, insulation 60-80 minute; With 130-140 ℃/h of speed, be cooled to 200-220 ℃ again, insulation 2-3 hour; With 180-200 ℃/h of speed, be warming up to 380-400 ℃ again, insulation 40-60 minute, then be cooled to 300-310 ℃ with 130-140 ℃/h of speed, insulation 40-60 minute, with 180-200 ℃/h of speed, be warming up to 540-550 ℃ again, insulation 2-3 hour, takes out air cooling and get final product.
Described refining agent is made by the raw material of following weight part: instrument comminuted steel shot 3-4, zinc oxide 1-2, aluminium powder 1-2, SODIUMNITRATE 3-5, ground dolomite 3-4, kaolin 2-3, Zirconium tetrafluoride 1-2, jade powder 3-4, montmorillonite 1-2, Sodium Silicofluoride 2-3; Preparation method mixes each raw material, is heated to molten state, then, is poured into Quench in pure water, then is ground into 100-200 order powder; Gained powder is added and is equivalent to the silane resin acceptor kh-550 of powder weight 2-3%, the nano-carbon powder of 1-2%, after mixing, under 8-15Mpa, be pressed into base, then, at 900-950 ℃, calcine 3-4 hour, cooling after, be ground into again 150-250 order powder, obtain.
Beneficial effect of the present invention
The present invention, by using the multiple elements such as chromium, manganese and dysprosium doping, by gradation throwing raw materials, rationally controls casting postheat treatment temperature, and the alloy of formation has high-yield strength, high-tensile, high-elongation, wear-resisting feature; Use part scrap iron as raw material, and through secondary refining, make more stable uniform of quality.Steel alloy of the present invention is applicable to various transport pipes, is particularly useful for concrete delivery pump pipe road, and wear resistance is good, long service life.Refining agent of the present invention is for Foundry Production, and the degree of porosity obviously improving in yield rate, particularly foundry goods reduces 1-2 degree, can not produce pore at cast(ing) surface, and trapped oxide also obviously reduces, and oxide inclusion is 2 grades of left and right.
Embodiment
A concrete pump transfer lime alloy steel material, chemical element composition and mass percent thereof that it contains are: carbon 0.2-0.4, silicon 0.8-1.1, manganese 1.9-2.3, chromium 1.5-1.7, vanadium 0.4-0.7, copper 0.07-0.1, Dy0.04-0.07, S≤0.05, P≤0.05, surplus are iron.
Described concrete pump transfer lime is as follows by the production method of alloy steel material:
(1), preparing the pig iron and scrap iron originates as ferrous substrate in 1:1.5 ratio, the pig iron is added to drop in stove and melt, carry out desulfurization, deoxidation, employing refining agent initial refining, add alloying constituent and carry out alloying, then add scrap iron fusing, add refining agent secondary refining, detection and adjust chemical element component content to qualified, casting, casting postheat treatment etc.;
(2) in alloying process, to the lot sequence that drops into alloying element in stove, be: (1) silicon, manganese, Dy; (2) chromium, vanadium, copper; The timed interval that each batch drops into element is 23 minutes, after feeding intake, stirs.
Described casting postheat treatment is: first by room temperature, with 210 ℃/h of speed, be warming up to 505 ℃, with 165 ℃/h of speed, be cooled to 405 ℃ again, then be warming up to 655 ℃ with 210 ℃/h of speed, be incubated 65 minutes, with 210 ℃/h of speed, be warming up to 935 ℃ again, be incubated 3.5 hours; With 155 ℃/h of speed, be cooled to 610 ℃ again, then be warming up to 720 ℃ with 210 ℃/h of speed, then be cooled to 505 ℃ with 135 ℃/h of speed, be incubated 70 minutes; With 135 ℃/h of speed, be cooled to 210 ℃ again, be incubated 2.5 hours; With 190 ℃/h of speed, be warming up to 390 ℃ again, be incubated 50 minutes, then be cooled to 305 ℃ with 135 ℃/h of speed, be incubated 50 minutes, then be warming up to 545 ℃ with 190 ℃/h of speed, be incubated 2.5 hours, take out air cooling and get final product.
Described refining agent by following weight part (kilogram) raw material make: instrument comminuted steel shot 3.5, zinc oxide 1.5, aluminium powder 1.5, SODIUMNITRATE 4, ground dolomite 3.5, kaolin 2.5 Zirconium tetrafluorides 1.5, jade powder 3.5, montmorillonite 1.5, Sodium Silicofluoride 2.5; Preparation method mixes each raw material, is heated to molten state, then, is poured into Quench in pure water, then is ground into 150 order powder; Gained powder is added and is equivalent to the silane resin acceptor kh-550 of powder weight 2.5%, 1.5% nano-carbon powder, after mixing, under 11Mpa, be pressed into base, then, at 930 ℃, calcine 3.5 hours, cooling after, then be ground into 200 order powder, obtain.
Concrete pump transfer lime of the present invention by the mechanical property of alloy steel material is: tensile strength 1362MPa, yield strength 969MPa, unit elongation 15.6%, relative reduction in area 25.1%, impact absorbing energy 54.8J, impelling strength 65.7J/cm2, hardness 269.4HB.
Claims (4)
1. a concrete pump transfer lime alloy steel material, is characterized in that: chemical element composition and mass percent thereof that it contains are: carbon 0.2-0.4, silicon 0.8-1.1, manganese 1.9-2.3, chromium 1.5-1.7, vanadium 0.4-0.7, copper 0.07-0.1, Dy0.04-0.07, S≤0.05, P≤0.05, surplus are iron.
2. the production method of alloy steel material for concrete pump transfer lime according to claim 1, is characterized in that:
(1), preparing the pig iron and scrap iron originates as ferrous substrate in 1:1-2 ratio, the pig iron is added to drop in stove and melt, carry out desulfurization, deoxidation, employing refining agent initial refining, add alloying constituent and carry out alloying, then add scrap iron fusing, add refining agent secondary refining, detection and adjust chemical element component content to qualified, casting, casting postheat treatment etc.;
(2) in alloying process, to the lot sequence that drops into alloying element in stove, be: (1) silicon, manganese, Dy; (2) chromium, vanadium, copper; The timed interval that each batch drops into element is 21-25 minute, after feeding intake, stirs.
3. the production method of alloy steel material for concrete pump transfer lime according to claim 2, it is characterized in that: described casting postheat treatment is: first by room temperature, with 200-220 ℃/h of speed, be warming up to 500-510 ℃, with 160-170 ℃/h of speed, be cooled to 400-410 ℃ again, with 200-220 ℃/h of speed, be warming up to 650-660 ℃ again, insulation 60-70 minute, with 200-220 ℃/h of speed, be warming up to 930-940 ℃ again, insulation 3-4 hour; With 150-160 ℃/h of speed, be cooled to 600-620 ℃ again, then be warming up to 710-730 ℃ with 200-220 ℃/h of speed, then be cooled to 500-510 ℃ with 130-140 ℃/h of speed, insulation 60-80 minute; With 130-140 ℃/h of speed, be cooled to 200-220 ℃ again, insulation 2-3 hour; With 180-200 ℃/h of speed, be warming up to 380-400 ℃ again, insulation 40-60 minute, then be cooled to 300-310 ℃ with 130-140 ℃/h of speed, insulation 40-60 minute, with 180-200 ℃/h of speed, be warming up to 540-550 ℃ again, insulation 2-3 hour, takes out air cooling and get final product.
4. the production method of alloy steel material for concrete pump transfer lime according to claim 2, is characterized in that: instrument comminuted steel shot 3-4, zinc oxide 1-2, aluminium powder 1-2, SODIUMNITRATE 3-5, ground dolomite 3-4, kaolin 2-3, Zirconium tetrafluoride 1-2, jade powder 3-4, montmorillonite 1-2, Sodium Silicofluoride 2-3; Preparation method mixes each raw material, is heated to molten state, then, is poured into Quench in pure water, then is ground into 100-200 order powder; Gained powder is added and is equivalent to the silane resin acceptor kh-550 of powder weight 2-3%, the nano-carbon powder of 1-2%, after mixing, under 8-15Mpa, be pressed into base, then, at 900-950 ℃, calcine 3-4 hour, cooling after, be ground into again 150-250 order powder, obtain.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310506140.1A CN103614646A (en) | 2013-10-24 | 2013-10-24 | Alloy steel material used for concrete pump conveyer pipes and preparation method of the alloy steel material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310506140.1A CN103614646A (en) | 2013-10-24 | 2013-10-24 | Alloy steel material used for concrete pump conveyer pipes and preparation method of the alloy steel material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107190211A (en) * | 2017-06-15 | 2017-09-22 | 柳州豪祥特科技有限公司 | The preparation method of high rigidity manganeisen material |
| CN115013601A (en) * | 2022-07-01 | 2022-09-06 | 江苏徐工工程机械研究院有限公司 | Concrete conveying pipe, manufacturing method thereof and concrete pump truck |
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| CN102534432A (en) * | 2012-01-10 | 2012-07-04 | 清华大学 | Method for manufacturing and tempering bainite wear-resistant steel and steel pipe |
| CN102776445A (en) * | 2012-07-27 | 2012-11-14 | 攀枝花贝氏体耐磨管道有限公司 | Lower bainite wear-resisting steel tube for slurry transport and production method of steel tube |
| CN103194688A (en) * | 2013-03-28 | 2013-07-10 | 宝山钢铁股份有限公司 | Wear-resistant steel pipe and manufacture method thereof |
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| JP2001355047A (en) * | 2000-06-14 | 2001-12-25 | Kawasaki Steel Corp | High carbon steel pipe excellent in cold workability and induction hardening and method for producing the same |
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| CN107190211A (en) * | 2017-06-15 | 2017-09-22 | 柳州豪祥特科技有限公司 | The preparation method of high rigidity manganeisen material |
| CN115013601A (en) * | 2022-07-01 | 2022-09-06 | 江苏徐工工程机械研究院有限公司 | Concrete conveying pipe, manufacturing method thereof and concrete pump truck |
| CN115013601B (en) * | 2022-07-01 | 2023-11-07 | 江苏徐工工程机械研究院有限公司 | Concrete conveying pipe, manufacturing method thereof and concrete pump truck |
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