CN103537164A - Environment-friendly nanometer formaldehyde purification scavenger - Google Patents

Environment-friendly nanometer formaldehyde purification scavenger Download PDF

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Publication number
CN103537164A
CN103537164A CN201310454623.1A CN201310454623A CN103537164A CN 103537164 A CN103537164 A CN 103537164A CN 201310454623 A CN201310454623 A CN 201310454623A CN 103537164 A CN103537164 A CN 103537164A
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China
Prior art keywords
environment
formaldehyde scavenger
purifying formaldehyde
amino acid
scavenger
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310454623.1A
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Chinese (zh)
Inventor
姚旻
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Anhui Huayin Mechanical and Electrical Co Ltd
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Anhui Huayin Mechanical and Electrical Co Ltd
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Priority to CN201310454623.1A priority Critical patent/CN103537164A/en
Publication of CN103537164A publication Critical patent/CN103537164A/en
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Abstract

The invention discloses an environment-friendly nanometer formaldehyde purification scavenger which comprises the following components in percentage by weight: 1-3 percent of natural plant extract, 15-30 percent of nanometer TIO2 sol, 1-3 percent of sodium dodecyl benzene sulfonate and the balance of deionized water. The natural plant extract is amino acids which are extracted from powder mixture of more than two of tea, aloe, chlorophytum comosum and hedera helix through a supercritical method. The natural plants are used in the components of the environment-friendly nanometer formaldehyde purification scavenger; therefore, the percentage of other chemical materials is correspondingly reduced and secondary pollution caused by the air purifying agent can be reduced. The environment-friendly nanometer formaldehyde purification scavenger has strong absorption, good purifying effect and high clearance rate for harmful gas such as benzene series substances with weak polarity or non-polarity. When the environment-friendly nanometer formaldehyde purification scavenger is prepared, the production process is simple, and the production cost is low.

Description

A kind of environment-friendly type nano purifying formaldehyde scavenger
Technical field
The invention belongs to air purifying process field, be specifically related to a kind of environment-friendly type nano purifying formaldehyde scavenger.
Background technology
Raising along with living standards of the people, the kind of building and ornament materials and household chemical product and quantity all constantly increase, these materials or product all can cause room air severe contamination to indoor release harmful chemical component, and health has been brought to great harm.Therefore pollution, how to eliminate room air obtains people's attention day by day.
Air purifying preparation refers to absorption, the decomposition principle of utilizing natural material itself to have, through modern science and technology, processes, the formed product that has pernicious gas in elimination air, dispels various odor functions.
After generally adopting organic solvent extraction, current commercially available natural plant extraction formaldehyde scavenger adds number of chemical stable reagent, too much chemical substance can may cause potential injury to human body after human body Long Term Contact, and organic solvent can be to environment after extraction is reclaimed simultaneously.Simultaneously existing product is containing active group, need to free formaldehyde Long contact time after just can remove formaldehyde, can not initiatively catch and remove fast free formaldehyde.As disclosing, Chinese patent CN1431258 a kind ofly applies natural canella extract as the method for formaldehyde eliminating agent, natural canella is made to volatile oil through steam distillation extraction process, again crude oil is made to the preparation method that different dosage form becomes formaldehyde eliminating agent, the shortcoming of the method is that distillation extraction technique extraction crude oil efficiency is low, wastage of material is many, has distilled waste discharge and has easily caused water pollution.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, the environment-friendly type nano purifying formaldehyde scavenger of a kind of safety and environmental protection, good air purification effect is provided.
Above-mentioned purpose of the present invention is achieved by the following scheme:
A purifying formaldehyde scavenger, described nanometer purifying formaldehyde scavenger comprises the component of following percentage by weight:
Natural plant extracts 1～3%
Nano-TiO 2colloidal sol 15～30%
Neopelex 1～3%
Remainder is deionized water;
Described natural plant extracts is to think that the two or more mixture of powders of tealeaves, aloe, bracketplant and ivy is raw material, the amino acid extracting by supercritical methanol technology.
On the basis of technique scheme, above-mentioned nanometer purifying formaldehyde scavenger comprises the component of following percentage by weight:
Natural plant extracts 2%
Nano-TiO 2colloidal sol 20%
Neopelex 2%
Remainder is deionized water.
The amino acid of above-mentioned extraction is the mixture of aspartic acid, threonine, serine, glutamic acid, glycine and alanine.
In above-mentioned amino acid, the percentage by weight of each amino acid composition in purifying formaldehyde scavenger is: aspartic acid 0.1～0.2%, threonine 0.01～0.2%, serine 0.01～0.2%, glutamic acid 0.01～0.2%, glycine 0.01～0.2%, alanine 0.01～0.2%, cysteine 0.01～0.2%.
Above-mentioned nano-TiO 2the gum concentration of colloidal sol is 7 * 10 -4～10 * 10 -4mol/L, decentralized medium is polyethylene glycol.
Above-mentioned natural plant extracts supercritical extraction method is specially: at supercritical extract machine, be controlled under 20～30 ℃ of temperature, pressure 6～8MP state, with the liquid CO of supercriticality 2as solvent, natural plants is pulverized and mixed by proportioning, then is added in supercritical extract machine and extracts 2h, isolate natural amino acid.
Compared with prior art, the beneficial effect that the present invention has is:
In the component of environment-friendly type nano purifying formaldehyde scavenger of the present invention owing to having used natural plants, thereby the corresponding ratio that reduces other chemical raw material thereby can reduce the secondary pollution that air purifying preparation causes; Suction-operated of the present invention is strong, and good purification can have higher clearance rate to pernicious gases such as low pole or nonpolar benzene homologues.When prepared by the present invention, production technology is simple, and manufacturing cost is cheap.
Environment-friendly type nano purifying formaldehyde scavenger of the present invention is water white transparency or pale yellow solution, deposit-free and suspension, and the air pollution that is applicable to family, public place and workplace is removed.During use, environmental protection formaldehyde scavenger is directly sprayed on to furniture or plate surface, or environmental protection formaldehyde scavenger is directly placed or is sprayed on active absorption in air and catch free formaldehyde.
The present invention, compared with market existing formaldehyde scavenger class technological invention, has extraction efficiency high, and raw material availability is high, environmental protection extractant CO 2itself is to around human body and environmental nonpollution, and natural extraction is to human body without injury, and extraction process is with short production cycle, is easy to the advantage of continuous and stable production.
The specific embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art should understand, described embodiment only, for helping to understand the present invention, should not be considered as concrete restriction of the present invention.
Embodiment 1
A purifying formaldehyde scavenger, comprises the component of following percentage by weight:
Natural plants (tealeaves is 4:1 with the ratio of the powder of aloe) extract 2%
Nano-TiO 2colloidal sol 20%
Neopelex 2%
Remainder is deionized water;
Described nano-TiO 2the gum concentration of colloidal sol is 8 * 10 -4mol/L, decentralized medium is polyethylene glycol.
Process for preparation is as follows:
First, at supercritical extract machine, be controlled under 30 ℃ of temperature, pressure 7MP state the liquid CO of supercriticality 2as solvent, natural plants is pulverized and mixed by proportioning, then is added in supercritical extract machine and extracts 2h, isolate natural amino acid;
Under stirring at normal temperature condition, the natural amino acid of above-mentioned extraction gained is added to deionized water solution and the nano-TiO that is dissolved with neopelex by proportioning again 2colloidal sol, is prepared into environment-friendly type nano purifying formaldehyde scavenger of the present invention after stirring.
Embodiment 2
Described natural plant extracts is to think that the two or more mixture of powders of tealeaves, aloe, bracketplant and ivy is raw material, the amino acid extracting by supercritical methanol technology.
A purifying formaldehyde scavenger, comprises the component of following percentage by weight:
Natural plants (tealeaves is 4:1 with the ratio of the powder of bracketplant) extract 2%
Nanometer TIO 2colloidal sol 20%
Neopelex 2%
Remainder is deionized water;
Described nano-TiO 2the gum concentration of colloidal sol is 8 * 10 -4mol/L, decentralized medium is polyethylene glycol.
Process for preparation is as follows:
First, at supercritical extract machine, be controlled under 30 ℃ of temperature, pressure 7MP state the liquid CO of supercriticality 2as solvent, natural plants is pulverized and mixed by proportioning, then is added in supercritical extract machine and extracts 2h, isolate natural amino acid;
Under stirring at normal temperature condition, the natural amino acid of above-mentioned extraction gained is added to deionized water solution and the nano-TiO that is dissolved with neopelex by proportioning again 2colloidal sol, is prepared into environment-friendly type nano purifying formaldehyde scavenger of the present invention after stirring.
Embodiment 3
Described natural plant extracts is to think that the two or more mixture of powders of tealeaves, aloe, bracketplant and ivy is raw material, the amino acid extracting by supercritical methanol technology.
A purifying formaldehyde scavenger, comprises the component of following percentage by weight:
Natural plants (tealeaves is 4:1:1 with the ratio of the powder of aloe, bracketplant) extract 2%
Nano-TiO 2colloidal sol 20%
Neopelex 2%
Remainder is deionized water;
Described nanometer TIO 2the gum concentration of colloidal sol is 8 * 10 -4mol/L, decentralized medium is polyethylene glycol.
Process for preparation is as follows:
First, at supercritical extract machine, be controlled under 30 ℃ of temperature, pressure 7MP state the liquid CO of supercriticality 2as solvent, natural plants is pulverized and mixed by proportioning, then is added in supercritical extract machine and extracts 2h, isolate natural amino acid;
Under stirring at normal temperature condition, the natural amino acid of above-mentioned extraction gained is added to deionized water solution and the nano-TiO that is dissolved with neopelex by proportioning again 2colloidal sol, is prepared into environment-friendly type nano purifying formaldehyde scavenger of the present invention after stirring.
Embodiment 4
Described natural plant extracts is to think that the two or more mixture of powders of tealeaves, aloe, bracketplant and ivy is raw material, the amino acid extracting by supercritical methanol technology.
A purifying formaldehyde scavenger, comprises the component of following percentage by weight:
Natural plants (tealeaves is 2:1:1:1 with the ratio of the powder of aloe, bracketplant and ivy) extract 2%
Nano-TiO 2colloidal sol 20%
Neopelex 2%
Remainder is deionized water;
Described nanometer TI O 2the gum concentration of colloidal sol is 8 * 10 -4mol/L, decentralized medium is polyethylene glycol.
Process for preparation is as follows:
First, at supercritical extract machine, be controlled under 30 ℃ of temperature, pressure 7MP state the liquid CO of supercriticality 2as solvent, natural plants is pulverized and mixed by proportioning, then is added in supercritical extract machine and extracts 2h, isolate natural amino acid;
Under stirring at normal temperature condition, the natural amino acid of above-mentioned extraction gained is added to deionized water solution and the nano-TiO that is dissolved with neopelex by proportioning again 2colloidal sol, is prepared into environment-friendly type nano purifying formaldehyde scavenger of the present invention after stirring.
Embodiment 5
Described natural plant extracts is to think that the two or more mixture of powders of tealeaves, aloe, bracketplant and ivy is raw material, the amino acid extracting by supercritical methanol technology.
A purifying formaldehyde scavenger, comprises the component of following percentage by weight:
Natural plants (tealeaves is 4:1 with the ratio of the powder of aloe) extract 1%
Nanometer TIO 2colloidal sol 15%
Neopelex 1%
Remainder is deionized water;
Described nano-TiO 2the gum concentration of colloidal sol is 7 * 10 -4mol/L, decentralized medium is polyethylene glycol.
Process for preparation is as follows:
First, at supercritical extract machine, be controlled under 30 ℃ of temperature, pressure 7MP state the liquid CO of supercriticality 2as solvent, natural plants is pulverized and mixed by proportioning, then is added in supercritical extract machine and extracts 2h, isolate natural amino acid;
Under stirring at normal temperature condition, the natural amino acid of above-mentioned extraction gained is added to deionized water solution and the nano-TiO that is dissolved with neopelex by proportioning again 2colloidal sol, is prepared into environment-friendly type nano purifying formaldehyde scavenger of the present invention after stirring.
Embodiment 6
Described natural plant extracts is to think that the two or more mixture of powders of tealeaves, aloe, bracketplant and ivy is raw material, the amino acid extracting by supercritical methanol technology.
A purifying formaldehyde scavenger, comprises the component of following percentage by weight:
Natural plants (tealeaves is 4:1 with the ratio of the powder of aloe) extract 3%
Nano-TiO 2colloidal sol 30%
Neopelex 3%
Remainder is deionized water;
Described nanometer TIO 2the gum concentration of colloidal sol is 10 * 10 -4mol/L, decentralized medium is polyethylene glycol.
Process for preparation is as follows:
First, at supercritical extract machine, be controlled under 30 ℃ of temperature, pressure 7MP state the liquid CO of supercriticality 2as solvent, natural plants is pulverized and mixed by proportioning, then is added in supercritical extract machine and extracts 2h, isolate natural amino acid;
Under stirring at normal temperature condition, the natural amino acid of above-mentioned extraction gained is added to deionized water solution and the nano-TiO that is dissolved with neopelex by proportioning again 2colloidal sol, is prepared into environment-friendly type nano purifying formaldehyde scavenger of the present invention after stirring.
Yang Sheng is raw, and newly-decorated area is 100m 2house, the concentration that detects formaldehyde by relevant department is 0.8mg/m 3, at the corner in indoor each room, place the environment-friendly type nano purifying formaldehyde scavenger 100mlg making by the formula of embodiment 1, after the use of 10 days, that detect this indoor formaldehyde is 0.3mg/m 3, clearance is greater than 50%.

Claims (6)

1. an environment-friendly type nano purifying formaldehyde scavenger, is characterized in that, described nanometer purifying formaldehyde scavenger comprises the component of following percentage by weight:
Natural plant extracts 1～3%
Nano-TiO 2colloidal sol 15～30%
Neopelex 1～3%
Remainder is deionized water;
Described natural plant extracts is to think that the two or more mixture of powders of tealeaves, aloe, bracketplant and ivy is raw material, the amino acid extracting by supercritical methanol technology.
2. a kind of environment-friendly type nano purifying formaldehyde scavenger according to claim 1, is characterized in that, described nanometer purifying formaldehyde scavenger comprises the component of following percentage by weight:
Natural plant extracts 2%
Nano-TiO 2colloidal sol 20%
Neopelex 2%
Remainder is deionized water.
3. a kind of environment-friendly type nano purifying formaldehyde scavenger according to claim 1, is characterized in that: the amino acid of described extraction is the mixture of aspartic acid, threonine, serine, glutamic acid, glycine and alanine.
4. a kind of environment-friendly type nano purifying formaldehyde scavenger according to claim 1, is characterized in that: in described amino acid, the percentage by weight of each amino acid composition in purifying formaldehyde scavenger is: aspartic acid 0.1～0.2%, threonine 0.01～0.2%, serine 0.01～0.2%, glutamic acid 0.01～0.2%, glycine 0.01～0.2%, alanine 0.01～0.2%, cysteine 0.01～0.2%.
5. a kind of environment-friendly type nano purifying formaldehyde scavenger according to claim 1, is characterized in that: described nano-TiO 2the gum concentration of colloidal sol is 7 * 10 -4～10 * 10 -4mol/L, decentralized medium is polyethylene glycol.
6. a kind of environment-friendly type nano purifying formaldehyde scavenger according to claim 1, it is characterized in that, described natural plant extracts supercritical extraction method is specially: supercritical extract machine is controlled under 20～30 ℃ of temperature, pressure 6～8MP state, with the liquid CO of supercriticality 2as solvent, natural plants is pulverized and mixed by proportioning, then is added in supercritical extract machine and extracts 2h, isolate natural amino acid.
CN201310454623.1A 2013-09-29 2013-09-29 Environment-friendly nanometer formaldehyde purification scavenger Pending CN103537164A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105251341A (en) * 2015-11-10 2016-01-20 南京润中生物技术有限公司 Air purification spray for removing indoor fitment pollution and preparation method thereof
CN105270968A (en) * 2015-11-27 2016-01-27 佛山住友富士电梯有限公司 Elevator with air self-purification function
CN105344225A (en) * 2015-11-27 2016-02-24 佛山住友富士电梯有限公司 Special air purification liquid and air purification mechanism for elevators
CN105920774A (en) * 2016-04-26 2016-09-07 国家海洋局第二海洋研究所 Pollution scavenging agent containing seaweed extracts and preparation method of pollution scavenging agent containing seaweed extracts
CN106731597A (en) * 2016-11-28 2017-05-31 汕头市绿康生物科技有限公司 A kind of methanal disintegrant
CN107486005A (en) * 2017-09-06 2017-12-19 福州光启环保科技有限公司 A kind of indoor formaldehyde odor scavenging agent
CN107511059A (en) * 2017-09-22 2017-12-26 太仓弘杉环保科技有限公司 A kind of nano titanium oxide herb extract aldehyde remover
CN107569999A (en) * 2017-09-22 2018-01-12 昆明理工大学 A kind of preparation method of green formaldehyde scavenger
CN107638788A (en) * 2017-10-10 2018-01-30 丁玉琴 A kind of preparation method of formaldehyde scavenger
CN108201786A (en) * 2018-03-16 2018-06-26 扬州工业职业技术学院 A kind of environment protective agent and preparation method thereof
WO2019000586A1 (en) * 2017-06-29 2019-01-03 季春柳 Formaldehyde remover
CN109260946A (en) * 2018-11-19 2019-01-25 芜湖格丰环保科技研究院有限公司 A kind of safety-type indoor formaldehyde agent for capturing and its preparation and application
CN109432979A (en) * 2018-10-12 2019-03-08 福建省居乐康环保科技有限公司 A kind of scavenger with efficient formaldehyde purification function
CN110449008A (en) * 2019-08-21 2019-11-15 舍用环境科技(宁波)有限公司 A kind of plant type formaldehyde scavenger and preparation method
CN110559794A (en) * 2019-10-21 2019-12-13 沈鸿裕 Formula of preparation for purifying indoor air

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CN102500088A (en) * 2011-10-14 2012-06-20 天津创誉科技发展有限公司 Environmental-friendly formaldehyde scavenger and preparation method thereof
CN102658087A (en) * 2012-05-11 2012-09-12 王志勇 Method for preparing formaldehyde scavenging agent

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WO2004110618A1 (en) * 2003-06-10 2004-12-23 Katz International Coasters Gmbh & Co. Kg Composite product made of zeolite as filling material and fibrous cellulose as carrier material and use thereof for the sorption of odours and humidity
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CN102500088A (en) * 2011-10-14 2012-06-20 天津创誉科技发展有限公司 Environmental-friendly formaldehyde scavenger and preparation method thereof
CN102658087A (en) * 2012-05-11 2012-09-12 王志勇 Method for preparing formaldehyde scavenging agent

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105251341A (en) * 2015-11-10 2016-01-20 南京润中生物技术有限公司 Air purification spray for removing indoor fitment pollution and preparation method thereof
CN105251341B (en) * 2015-11-10 2017-09-19 南京润中生物技术有限公司 A kind of air purifying spraying agent for removing indoor decoration pollution and preparation method thereof
CN105270968B (en) * 2015-11-27 2018-05-04 佛山住友富士电梯有限公司 A kind of elevator with air self-purification function
CN105270968A (en) * 2015-11-27 2016-01-27 佛山住友富士电梯有限公司 Elevator with air self-purification function
CN105344225A (en) * 2015-11-27 2016-02-24 佛山住友富士电梯有限公司 Special air purification liquid and air purification mechanism for elevators
CN105344225B (en) * 2015-11-27 2018-10-12 佛山住友富士电梯有限公司 A kind of dedicated air purification liquid of elevator and air purifying mechanism
CN105920774A (en) * 2016-04-26 2016-09-07 国家海洋局第二海洋研究所 Pollution scavenging agent containing seaweed extracts and preparation method of pollution scavenging agent containing seaweed extracts
CN106731597A (en) * 2016-11-28 2017-05-31 汕头市绿康生物科技有限公司 A kind of methanal disintegrant
WO2019000586A1 (en) * 2017-06-29 2019-01-03 季春柳 Formaldehyde remover
CN107486005A (en) * 2017-09-06 2017-12-19 福州光启环保科技有限公司 A kind of indoor formaldehyde odor scavenging agent
CN107569999A (en) * 2017-09-22 2018-01-12 昆明理工大学 A kind of preparation method of green formaldehyde scavenger
CN107511059A (en) * 2017-09-22 2017-12-26 太仓弘杉环保科技有限公司 A kind of nano titanium oxide herb extract aldehyde remover
CN107638788A (en) * 2017-10-10 2018-01-30 丁玉琴 A kind of preparation method of formaldehyde scavenger
CN108201786A (en) * 2018-03-16 2018-06-26 扬州工业职业技术学院 A kind of environment protective agent and preparation method thereof
CN109432979A (en) * 2018-10-12 2019-03-08 福建省居乐康环保科技有限公司 A kind of scavenger with efficient formaldehyde purification function
CN109260946A (en) * 2018-11-19 2019-01-25 芜湖格丰环保科技研究院有限公司 A kind of safety-type indoor formaldehyde agent for capturing and its preparation and application
CN110449008A (en) * 2019-08-21 2019-11-15 舍用环境科技(宁波)有限公司 A kind of plant type formaldehyde scavenger and preparation method
CN110559794A (en) * 2019-10-21 2019-12-13 沈鸿裕 Formula of preparation for purifying indoor air

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Application publication date: 20140129