CN103483808A - 复合热塑性树脂模具材料及其制备方法和模具及制造方法 - Google Patents
复合热塑性树脂模具材料及其制备方法和模具及制造方法 Download PDFInfo
- Publication number
- CN103483808A CN103483808A CN201210190114.8A CN201210190114A CN103483808A CN 103483808 A CN103483808 A CN 103483808A CN 201210190114 A CN201210190114 A CN 201210190114A CN 103483808 A CN103483808 A CN 103483808A
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- Prior art keywords
- thermoplastic resin
- die
- mould
- composite thermoplastic
- continuous
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 67
- 239000000463 material Substances 0.000 title claims abstract description 60
- 239000002131 composite material Substances 0.000 title claims abstract description 57
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000003365 glass fiber Substances 0.000 claims abstract description 39
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 16
- 239000004952 Polyamide Substances 0.000 claims abstract description 8
- 229920002647 polyamide Polymers 0.000 claims abstract description 8
- 239000011528 polyamide (building material) Substances 0.000 claims abstract description 8
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 5
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims description 28
- 238000001816 cooling Methods 0.000 claims description 26
- 238000003825 pressing Methods 0.000 claims description 25
- 239000003513 alkali Substances 0.000 claims description 24
- 238000001125 extrusion Methods 0.000 claims description 21
- 238000007598 dipping method Methods 0.000 claims description 14
- 239000004576 sand Substances 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000007731 hot pressing Methods 0.000 claims description 7
- 239000004417 polycarbonate Substances 0.000 claims description 7
- 229920000515 polycarbonate Polymers 0.000 claims description 7
- 238000009736 wetting Methods 0.000 claims description 7
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 6
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 5
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound 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O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 4
- 229920000299 Nylon 12 Polymers 0.000 claims description 4
- 229920001721 Polyimide Polymers 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 125000004203 4-hydroxyphenyl group Chemical group 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[H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
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- KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound 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- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound 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[Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000005712 crystallization Effects 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000001105 regulatory Effects 0.000 description 1
- 230000000630 rising Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
- B29B15/10—Coating or impregnating independently of the moulding or shaping step
- B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
- B29B15/14—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length of filaments or wires
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/58—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
Abstract
本发明公开了一种复合热塑性树脂模具材料及其制备方法和模具及制造方法，该种模具材料由包含以下重量份的组分制成，连续玻璃纤维55-60份，热塑性树脂40-45份，较优的，连续玻璃纤维可选用连续无碱玻璃纤维，热塑性树脂选自聚酰胺类树脂或聚碳酸酯类树脂。本发明的复合热塑性树脂模具材料成本低廉，所制造的模具使用寿命长，磨损修复快，本模具材料和模具的制造过程及方法具有设备简单，周期短，工艺要求不高的优点，本发明是一项打破传统机械加工工艺的新技术、新材料和新工艺。
Description
复合热塑性树脂模具材料及其制备方法和模具及制造方法
技术领域
[0001] 本发明属于高分子材料技术领域，具体涉及一种复合热塑性树脂模具材料及其制备方法和模具及制造方法。
背景技术
[0002] 模具作为现代工业生产不可缺少的工装，在生产中起着决定性的作用，目前的模具大多采用金属材质，金属模具的质量和寿命都很高，但其制作成本昂贵，尤其是一些外形复杂、难成形的金属模具，制作过程极为复杂，很多金属材质同时还存在加工困难，加工周期长，而且模具磨损后修复时间较长的缺陷。这使得选择使用它的商家在竞争中没有取得时间上的有利时机，而且其成本较高使得利润下降。
[0003] 随着工业的飞速发展，聚合物复合材料强度和精度等方面的不断提高，使其制品的应用范围也在不断扩大，聚合物复合材料制品所占的比例正迅猛增加，由于一个设计合理的复合材料能代替多个传统金属材料，因而其用量也在不断上升。相对于金属材料而言，聚合物复合材料制作成本低廉，易成型，加工周期短，修复时间短，这些优点使得它在模具领域具有巨大的潜力。
发明内容
[0004] 针对上述现有技术的不足，本发明的第一目的是提供一种复合热塑性树脂模具材料，该模具材料可用于制造模具，其具有成本低，加工易，加工周期短，可快速修复等优点。
[0005] 本发明的第二目的是提供上述复合热塑性树脂模具材料的制备方法。
[0006] 本发明的第三目 的是提供一种由上述复合热塑性树脂模具材料制备的模具。
[0007] 本发明的第四目的是提供一种上述模具的制造方法。
[0008] 本发明的技术方案如下:
一种复合热塑性树脂模具材料，由包含以下重量份的组分制成:
连续玻璃纤维 55-60份，
热塑性树脂 40-45份。
[0009] 较佳地，所述的连续玻璃纤维为连续无碱玻璃纤维。
[0010] 较佳地，所述的热塑性树脂选自聚酰胺类树脂或聚碳酸酯类树脂。
[0011] 较佳地，所述的聚酰胺类树脂选自聚酰胺66、聚十二内酰胺或聚酰胺1212中的一种或几种；
所述的聚碳酸酯类树脂选自2，2’-双(4-羟基苯基)丙烷聚碳酸酯、聚碳酸三亚甲基酯中的一种。
[0012] 本发明还提供一种上述的复合热塑性树脂模具材料的制备方法，包含以下步骤:
(1)首先，对连续玻璃纤维进行处理，包括对其进行第一次张力调节和除静电处理，之后进行预加热，预加热后对其进行第二次张力调节；
(2)通过交错可开合双挤出模头组，将步骤(1)处理过的55-60重量份的连续玻璃纤维浸润到40-45重量份的熔融热塑性树脂中，连续玻璃纤维浸溃后导入浸溃压延辊组进行辊压成型使其完全浸润，之后导入冷却辊压装置使其冷却至30-50°C，再经过卷取，得到带状连续纤维预浸料；
(3) 将步骤(2)中得到的带状连续纤维预浸料裁剪至工艺要求的尺寸，然后交叉铺放到热压成型机中预热，之后热压成型，再进行冷压处理冷却至30-50°C取出，成为板状材料，SP得到复合热塑性树脂模具材料。
[0013] 较佳地，所述的步骤(1)中，预加热的温度为140_180°C，预加热方式为电加热或红外辐射加热；
所述的步骤(2)中，所述可开合双挤出模头组中的熔融热塑性树脂是由单一挤出机通过分流道对双挤出模头进行供料，所述冷却辊压装置的冷却方式为自然冷却或通水冷却。
[0014] 较佳地，所述的步骤(3)中，所述裁剪后的带状连续纤维预浸料按照纤维方向0° /±45°或0° /90°的方向交叉铺放到热压成型机中；
所述热压机的预热温度为230-250°C，热压成型的温度为250-270°C，热压压力为l-3MPa，冷压处理的压力为2-4MPa ；
所述冷压处理的冷却方式为自然冷却或通水冷却。
[0015] 本发明还提供一种由上述的复合热塑性树脂模具材料制成的模具。
[0016] 本发明还提供一种上述模具的制造方法，包括将复合热塑性树脂模具材料按照模具设计的图纸放入数控机床进行加工，制成模具，在其表面上喷涂一层树脂砂后包装。
[0017] 较佳地，所述喷涂的树脂砂为热塑性PMMA或聚酰亚胺聚合热固胺中的一种制成的颗粒。
[0018] 与现有技术相比，本发明的有益效果如下:
第一，本发明的复合热塑性树脂模具材料的制备方法，包括预浸料中对连续纤维束的固定、牵引、除静电、复合、冷却，预浸料后进行热压成型及冷却，以及制造模具过程中的数控切割及喷涂处理，均具有设备简单，价格低廉，工艺要求不高的优点；
第二，制造本发明中复合热塑性树脂模具一般只要5-7天就可完成，其成本仅仅是钢模的15-20%左右，而且树脂模具使用寿命很长，磨损了还可以很快修补好，继续使用。
[0019] 综上，本发明的复合树脂模具及其制造是一项打破传统机械加工工艺的新技术、新材料和新工艺。
具体实施方式
[0020] 下面结合具体实施例，进一步阐述本发明。应该理解，这些实施例仅用于说明本发明，而不用于限定本发明的保护范围。在实际应用中技术人员根据本发明做出的改进和调整，仍属于本发明的保护范围。以下实施例中热塑性树脂采用聚酰胺和聚碳酸酯，但本发明也可采用其他热塑性树脂，此处不做限定。本发明中连续玻璃纤维优选连续无碱玻璃纤维，但并不限制其他种类玻璃纤维的使用。
[0021] 实施例1
本实施例采用以下组分及重量份制备复合热塑性树脂模具材料:
连续无碱玻璃纤维 55份
聚酰胺66 45份本实施例的复合热塑性树脂模具材料制备方法包括如下步骤:
(1)将连续无碱玻璃纤维卷置于纱架之上，使连续纤维束平行展开，并通过第一张力调节装置对其进行第一次张力调节，具体为通过调节第一张力调节装置的张力辊的交错角度，来调节纤维的张力；由于在第一次张力调节过程中，纤维会不可避免的因摩擦而产生静电，造成纤维束起毛，影响产品的质量和生产的连续性，为此增加了静电消除装置对纤维进行除静电处理；为了使熔融聚酰胺66与连续无碱玻璃纤维浸润时不会由于树脂表面结晶而影响浸润效果，采取预加热装置(红外烘箱)对上述纤维进行预加热，预加热的温度设定在150°C ;经过预加热后的纤维通过第二张力调节装置进行第二次张力调节，以确保产品最后的均匀性与不变性；
(2)通过交错可开合双挤出模头组，将步骤(1)处理过的55重量份的连续无碱玻璃纤维浸润到45重量份熔融聚酰胺66中，其中挤出模头组中的聚酰胺66是由单一挤出机通过分流道对双挤出模头进行供料；连续无碱玻璃纤维浸溃后导入浸溃压延辊组进行辊压成型使其完全浸润，之后导入冷却辊压装置使其自然冷却至50°C，再经过卷取，得到带状连续纤维预浸料，此时预浸料厚度为0.25-0.27mm ；
(3)将步骤(2)中得到的带状连续纤维预浸料裁剪至工艺要求的尺寸，按照纤维方向0° /90°的方向铺放到热压成型机中预热，预热温度为240°C。之后热压成型，热压温度为270°C，压力2MPa，然后进行冷压处理，冷压压力为3MPa，待自然冷却至50°C后取出，成为板状材料，即得到复合热塑性树脂模具材料。
[0022] 复合热塑性树脂模具的制造例:将上述得到的复合热塑性树脂模具材料按照模具设计的图纸放入数控机床进行加工，制成模具，在模具表面上喷涂一层热塑性PMMA树脂砂包装，即可完成模具制作。
[0023] 对本实施例所制得的复合热塑性树脂模具材料及模具进行性能测试，测试结果如表1:
表1
实施例2
本实施例采用以下组分及重量份制备复合热塑性树脂模具材料:
连续无碱玻璃纤维 60份
聚十二内酰胺 40份
本实施例的复合热塑性树脂模具材料制备方法包括如下步骤:
(1)首先，对连续无碱玻璃纤维进行处理，包括对其进行第一次张力调节和除静电处理如实施例1，之后采用电加热方式预加热，预加热温度140°C，预加热后对其进行第二次张力调节；
(2)通过交错可开合双挤出模头组，将步骤(1)处理过的60重量份的连续无碱玻璃纤维浸润到40重量份的熔融聚十二内酰胺中，其中挤出模头组中的熔融聚十二内酰胺由单一挤出机通过分流道对双挤出模头进行供料，连续无碱玻璃纤维浸溃后导入浸溃压延辊组进行辊压成型使其完全浸润，之后导入冷却辊压装置使其自然冷却至30°C，再经过卷取，得到带状连续纤维预浸料，此时预浸料厚度为0.20、.22mm ；
(3)将步骤(2)中得到的带状连续纤维预浸料裁剪至工艺要求的尺寸，按照纤维方向0° /±45°的方向铺放到热压成型机中在230°C下预热后，在250°C下热压成型，热压压力3MPa，然后在冷压压力4Mpa条件下进行冷压处理使其自然冷却至30°C后取出，成为板状材料，即得到复合热塑性树脂模具材料。
[0024]复合热塑性树脂模具的制造例:将上述得到的复合热塑性树脂模具材料按照模具设计的图纸放入数控机床进行加工，制成模具，在其表面上喷涂一层热塑性PMMA树脂砂后包装，即可完成模具制作。
[0025]
实施例3
本实施例采用以下组分及重量份制备复合热塑性树脂模具材料:
连续无碱玻璃纤维 57份
聚酰胺1212 43份
本实施例的复合热塑性树脂模具材料制备方法如下:
(1)首先，对连续无碱玻璃纤维进行处理，包括对其进行第一次张力调节和除静电处理如实施例1，之后采用红外辐射加热方式进行预加热，预加热温度180°C，预加热后对其进行第二次张力调节；
(2)通过交错可开合双挤出模头组，将步骤(1)处理过的57重量份的连续无碱玻璃纤维浸润到43重量份的熔融聚酰胺1212中，其中挤出模头组中的熔融聚酰胺1212由单一挤出机通过分流道对双挤出模头进行供料，连续无碱玻璃纤维浸溃后导入浸溃压延辊组进行辊压成型使其完全浸润，之后导入冷却辊压装置，通水冷却至40°C，再经过卷取，得到带状连续纤维预浸料，此时预浸料厚度为0.23、.25mm ；
(3)将步骤(2)中得到的带状连续纤维预浸料裁剪至工艺要求的尺寸，按照纤维方向0° /90°的方向铺放到热压成型机中在250°C下预热后，在270°C下热压成型，热压压力IMPa,然后进行冷压处理，冷压压力2Mpa，通水冷却至45°C后取出，成为板状材料，即得到复合热塑性树脂模具材料。
[0026] 复合热塑性树脂模具的制造例:将上述得到的复合热塑性树脂模具材料按照模具设计的图纸放入数控机床进行加工，制成模具，在其表面上喷涂一层聚酰亚胺聚合热固胺树脂砂后包装，即可完成模具制作。
[0027]
实施例4
本实施例采用以下组分及重量份制备复合热塑性树脂模具材料:
连续无碱玻璃纤维 58份
2，2’ -双(4-羟基苯基)丙烷聚碳酸酯 42份
本实施例的复合热塑性树脂模具材料制备方法如下:
(I)首先，对连续无碱玻璃纤维进行处理，包括对其进行第一次张力调节和除静电处理如实施例1，之后采用电加热方式进行预加热，预加热温度160°C，预加热后对其进行第二次张力调节；(2)通过交错可开合双挤出模头组，将步骤(1)处理过的58重量份的连续无碱玻璃纤维浸润到42重量份的熔融2，2’ -双(4-羟基苯基)丙烷聚碳酸酯中，其中挤出模头组中的熔融聚碳酸酯由单一挤出机通过分流道对双挤出模头进行供料，连续无碱玻璃纤维浸溃后导入浸溃压延辊组进行辊压成型使其完全浸润，之后导入冷却辊压装置，自然冷却至50°C，再经过卷取，得到带状连续纤维预浸料，此时预浸料厚度为0.27、.30mm ；
(3)将步骤(2)中得到的带状连续纤维预浸料裁剪至工艺要求的尺寸，按照纤维方向0° /±45°的方向铺放到热压成型机中在240°C下预热后，在260°C下热压成型，热压压力
1.5MPa，然后进行冷压处理，冷压压力3Mpa，自然冷却至50°C后取出，成为板状材料，即得到复合热塑性树脂模具材料。
[0028] 复合热塑性树脂模具的制造例:将上述得到的复合热塑性树脂模具材料按照模具设计的图纸放入数控机床进行加工，制成模具，在其表面上喷涂一层热塑性PMMA树脂砂后包装，即可完成模具制作。
[0029]
实施例5
本实施例采用以下组分及重量份制备复合热塑性树脂模具材料:
连续无碱玻璃纤维 55份
聚碳酸三亚甲基酯 45份
本实施例的复合热塑性树脂模具材料制备方法如下:
(1)首先，对连续无碱玻璃纤维 进行处理，包括对其进行第一次张力调节和除静电处理如实施例1，之后采用电加热方式预加热，预加热温度160°C，预加热后对其进行第二次张力调节；
(2)通过交错可开合双挤出模头组，将步骤(1)处理过的55重量份的连续无碱玻璃纤维浸润到45重量份的熔融聚碳酸三亚甲基酯中，其中挤出模头组中的熔融聚碳酸酯由单一挤出机通过分流道对双挤出模头进行供料，连续无碱玻璃纤维浸溃后导入浸溃压延辊组进行辊压成型使其完全浸润，之后导入冷却辊压装置，自然冷却至50°C，再经过卷取，得到带状连续纤维预浸料，此时预浸料厚度为0.25、.27mm ；
(3)将步骤(2)中得到的带状连续纤维预浸料裁剪至工艺要求的尺寸，按照纤维方向0° /±45°的方向铺放到热压成型机中在240°C下预热后，在260°C下热压成型，热压压力
1.5MPa，然后进行冷压处理，冷压压力3Mpa，自然冷却至50°C后取出，成为板状材料，即得到复合热塑性树脂模具材料。
[0030] 复合热塑性树脂模具的制造例:将上述得到的复合热塑性树脂模具材料，按照模具设计的图纸放入数控机床进行加工，制成模具，在其表面上喷涂一层热塑性PMMA树脂砂后包装，即可完成模具制作。
[0031] 本发明的复合热塑性树脂模具材科主要用来制造凹凸模，可以浇注成型，也可以采用低压模压法成形，适合于制作弯曲模、成形模、拉延模、切口模等，实验证明，由此模具材料制成的模具可以冲压或拉延0.8毫米钢板或2毫米以下的铝板，寿命在万次以上且不磨损。此外，它也可以用做吹塑模具、吸塑模具和塑料注射模具等，但由于复合材料的树脂本身为热塑性树脂，只可以做200°C下的模具，这种模具可适用于大多数热固性塑料。
[0032] 本发明的模具材料与常用金属材料相比成本低廉，而且使用寿命很长，磨损了还可以很快修补好，继续使用，其制备方法所需设备简单，造价低廉，工艺要求不高，制作速度快，制造本发明中复合热塑性树脂模具一般只要5~7天就可完成，综上，本发明是一项打破传统机械加工工艺的新技术`、新材料和新工艺。
Claims (10)
1.一种复合热塑性树脂模具材料，其特征在于，由包含以下重量份的组分制成: 连续玻璃纤维 55-60份， 热塑性树脂 40-45份。
2.根据权利要求1所述的复合热塑性树脂模具材料，其特征在于，所述的连续玻璃纤维为连续无碱玻璃纤维。
3.根据权利要求1所述的复合热塑性树脂模具材料，其特征在于，所述的热塑性树脂选自聚酰胺类树脂或聚碳酸酯类树脂。
4.根据权利要求3所述的复合热塑性树脂模具材料，其特征在于，所述的聚酰胺类树脂选自聚酰胺66、聚十二内酰胺或聚酰胺1212中的一种或几种； 所述的聚碳酸酯类树脂选自2，2’ -双(4-羟基苯基)丙烷聚碳酸酯、聚碳酸三亚甲基酯中的一种。
5.—种如权利要求1-4中任一项所述的复合热塑性树脂模具材料的制备方法，其特征在于，包含以下步骤: (1)首先，对连续玻璃纤维进行处理，包括对其进行第一次张力调节和除静电处理，之后进行预加热，预加热后对其进行第二次张力调节； (2)通过交错可开合双挤出模头组，将步骤(1)处理过的55-60重量份的连续玻璃纤维浸润到40-45重量份的熔融热塑性树脂中，连续玻璃纤维浸溃后导入浸溃压延辊组进行辊压成型使其完全浸润，之后导入冷却辊压装置使其冷却至30-50°C，再经过卷取，得到带状连续纤维预浸料； (3)将步骤(2)中得到的带状连续纤维预浸料裁剪至工艺要求的尺寸，然后交叉铺放到热压成型机中预热，之后热压成型，再进行冷压处理冷却至30-50°C取出，成为板状材料，SP得到复合热塑性树脂模具材料。
6.根据权利要求5所述的复合热塑性树脂模具材料的制备方法，其特征在于，所述的步骤(1)中，预加热的温度为140-180°C，预加热方式为电加热或红外辐射加热； 所述的步骤(2)中，所述可开合双挤出模头组中的熔融热塑性树脂是由单一挤出机通过分流道对双挤出模头进行供料，所述冷却辊压装置的冷却方式为自然冷却或通水冷却。
7.根据权利要求5所述的复合热塑性树脂模具材料的制备方法，其特征在于，所述的步骤(3)中， 所述裁剪后的带状连续纤维预浸料按照纤维方向0° /±45°或0° /90°的方向交叉铺放到热压成型机中； 所述热压机的预热温度为230-250°C，热压成型的温度为250-270°C，热压压力为l-3MPa，冷压处理的压力为2-4MPa ； 所述冷压处理的冷却方式为自然冷却或通水冷却。
8.一种由权利要求1-4中任一项所述的复合热塑性树脂模具材料制成的模具。
9.一种如权利要求8所述的模具的制造方法，其特征在于，将复合热塑性树脂模具材料按照模具设计的图纸放入数控机床进行加工，制成模具，在其表面上喷涂一层树脂砂后包装。
10.根据权利要求9所述的模具的制造方法，其特征在于，所述喷涂的树脂砂为热塑性PMMA或聚酰亚胺聚合热固胺中的一种制成的颗粒。
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