Summary of the invention
The purpose of this invention is to provide a kind of heat-resisting full Eucalyptus lamination decoration panel, can under the environment of hot and humid degree, use and nonhygroscopic distortion for a long time for a long time, the present invention discloses the production method of this full Eucalyptus lamination decoration panel equally, being to have solved the drum problem on the one hand, is to reduce burst size of methanal on the one hand.
Technical scheme of the present invention is as follows:
In the production process of base material, adopt cold pressing for three times, three hot pressing, twice standing health of thermostatic chamber overcome bulging phenomenon with the method for heat radiation health.Concrete production technology is as follows:
Manually select Eucalyptus veneer of the same size, coat above-mentioned adhesive, resin added is generally 200~300g/m
2, assembly (3~15 layers), cold pressing for the first time, and temperature is normal temperature, and pressure is 0.5~0.8MPa, hot pressing for the first time, temperature is 115~120 ℃, pressure is 0.8~1.0MPa; 60~80 ℃ of standing healths of thermostatic chamber 5~8 hours, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the second time, temperature is normal temperature, and pressure is 0.5~0.8MPa, hot pressing for the second time, and temperature is 110~115 ℃, pressure is 0.8~1.0MPa; The standing health of thermostatic chamber for the second time, the thermostatic chamber temperature is 60~80 ℃, time 90~120min, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the third time, temperature is normal temperature, and pressure is 0.5~0.8MPa, hot pressing for the third time, temperature is 120~125 ℃, pressure is 0.8~1.0MPa, fixed thick with coarse sand and fine sandpaper polishing, paste low face side, the polishing face side, face side sticks the melamine gum dipped paper, hot pressing, and temperature is 120 ℃, pressure is 1.5MPa, heat radiation arranges, and beats limit, obtains heat-resisting full Eucalyptus lamination decoration panel.
Reduce the burst size of formaldehyde, at first will from improving adhesive-preparing technology, by improving adhesive-preparing technology, make raw material formaldehyde almost or complete reaction, reduce the residual quantity of formaldehyde.This adhesive-preparing technology adopts the disposable formaldehyde that adds, and adds at twice urea, and the method for a melamine promotes the complete reaction of formaldehyde.Add formaldehyde in reactor, with the first acid for adjusting pH value, be 2~2.5, the polyvinyl alcohol that adds formaldehyde weight 0.5~0.6%, the urea that adds formaldehyde weight 10%, be warming up to 50 ℃, insulation reaction 30min, the pH value of conditioned reaction liquid is 8~8.5, the urea that adds formaldehyde weight 25%, the melamine that adds formaldehyde weight 1%, be warming up to 90~95 ℃, insulation reaction 90min, reaction checks after finishing, if also contain formaldehyde, add appropriate urea or melamine to continue reaction, until detect the content<5mg/L of formaldehyde, the pH value that adds the alkali conditioned reaction to finish liquid is 7.2~7.5.Amino generation polycondensation reaction on aldehyde radical on formaldehyde molecule and urea or melamine molecule, generate macromolecular compound, along with constantly carrying out of condensation reaction, the molecular weight of the material that polycondensation reaction generates constantly increases, cause reactant liquor viscosity to increase, the mobility variation, reduced the probability of the collision of the formaldehyde that do not react and urea, and the high polymer embedding formaldehyde and the urea that generate, cause the outer formaldehyde of high polymer and urea effectively not to supplement to inside, cause the inner polymer molecular weight generated low.Polymer molecular weight is low, easily degraded, release formaldehyde.Therefore the one-step technology before, disposable formaldehyde and the urea of adding, easily cause the reaction in early stage violent, and the embedding phenomenon is very serious.So-called embedding phenomenon is exactly in polymerisation, the high molecular polymer generated encases polymerization single polymerization monomer, and the monomer of high molecular polymer the inside is polymerization reaction take place also, but because the monomer of outside can't give the reaction of the inside supplementary, therefore, the polymer molecular weight that high molecular polymer wraps is very little.The polymer substance molecular weight distribution that this phenomenon causes polymerisation to obtain is very wide, and level of residual monomers is very large.Because one-step method is reacted acutely in earlier stage, reaction polymer molecular weight in early stage is very large, and the later stage molecular weight is little, the formaldehyde of complete reaction is not many, the adhesive molecular weight distribution of making is very wide, and the artificial board formaldehyde burst size made from this adhesive is very large, has greatly endangered the healthy of user.The new technology that adds urea by gradation, avoided in earlier stage reaction too violent, adds for the first time the polymer molecular weight that reaction generates after urea can be very not large, because add for the first time the amount of urea seldom, the polymer generated is few, and viscosity is low, the good fluidity of material, do not have the phenomenon of embedding, therefore the molecular weight distribution of polymer is more even, adds for the second time urea, because the concentration of formaldehyde in reactant liquor has reduced much, react more steady, so the embedding phenomenon not very serious yet.
Formaldehyde almost completely reacts, the molecular weight of polycondensates narrowly distributing, and molecular weight is high, difficult degradation, as the adhesive of veneer, burst size of methanal is naturally low.
The good effect that the present invention produces is:
Office furniture of the present invention by full Eucalyptus lamination decoration panel production technology, adopt cold pressing for three times, three hot pressing, the production technology of twice standing health of thermostatic chamber and twice heat radiation health, can eliminate the stress of Eucalyptus intralamellar part, expand with heat and contract with cold after avoiding finished product to be heated to act on and hold yielding situation generation, and reduced the possibility that finished product chance water, the moisture absorption play drum, are out of shape.Use the technique in the present invention, can also reduce the finished product burst size of methanal, protected consumer's health.
2. the urea-formaldehyde resin adhesive that office furniture of the present invention adopts with full Eucalyptus lamination decoration panel is to adopt gradation to add the technique of urea, the formaldehyde monomers less residue, the repeatedly cold, hot pressure technique adopted in conjunction with the present invention, the burst size of methanal of finished product still less, more environmental protection.
The specific embodiment
Embodiment 1
At first prepare adhesive: add formaldehyde in reactor, with the first acid for adjusting pH value, be 2~2.5, the polyvinyl alcohol that adds formaldehyde weight 0.5~0.6%, the urea that adds formaldehyde weight 10%, be warming up to 50 ℃, insulation reaction 30min, the pH value of conditioned reaction liquid is 8~8.5, the urea that adds formaldehyde weight 25%, the melamine that adds formaldehyde weight 1%, be warming up to 90~95 ℃, insulation reaction 90min, reaction checks after finishing, if also contain formaldehyde, add appropriate urea or melamine to continue reaction, until detect the content<5mg/L of formaldehyde, the pH value that adds the alkali conditioned reaction to finish liquid is 7.2~7.5.
Manually select Eucalyptus veneer of the same size, coat above-mentioned adhesive, resin added is 300g/ ㎡, and 5 layers of assemblies, cold pressing for the first time, and temperature is normal temperature, and pressure is 0.5MPa, hot pressing for the first time, and temperature is 115~120 ℃, pressure is 0.8MPa; 60~80 ℃ of standing healths of thermostatic chamber 5~8 hours, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the second time, temperature is normal temperature, and pressure is 0.5MPa, hot pressing for the second time, and temperature is 110~115 ℃, pressure is 0.8MPa; The standing health of thermostatic chamber for the second time, the thermostatic chamber temperature is 60~80 ℃, time 90~120min, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the third time, temperature is normal temperature, and pressure is 0.5MPa, hot pressing for the third time, temperature is 120~125 ℃, pressure is 0.8MPa, fixed thick with coarse sand and fine sandpaper polishing, paste low face side, the polishing face side, face side sticks the melamine gum dipped paper, hot pressing, and temperature is 120 ℃, pressure is 1.5MPa, heat radiation arranges, and beats limit, obtains heat-resisting full Eucalyptus lamination decoration panel.
Embodiment 2
Manually select Eucalyptus veneer of the same size, coat the adhesive of embodiment 1, resin added is 250g/ ㎡, and assembly (7 layers), cold pressing for the first time, and temperature is normal temperature, and pressure is 0.65MPa, hot pressing for the first time, and temperature is 115~120 ℃, pressure is 0.9MPa; 60~80 ℃ of standing healths of thermostatic chamber 5~8 hours, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the second time, temperature is normal temperature, and pressure is 0.65MPa, hot pressing for the second time, and temperature is 110~115 ℃, pressure is 0.9MPa; The standing health of thermostatic chamber for the second time, the thermostatic chamber temperature is 60~80 ℃, time 90~120min, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the third time, temperature is normal temperature, and pressure is 0.65MPa, hot pressing for the third time, temperature is 120~125 ℃, pressure is 0.9MPa, fixed thick with coarse sand and fine sandpaper polishing, paste low face side, the polishing face side, face side sticks the melamine gum dipped paper, hot pressing, and temperature is 120 ℃, pressure is 1.5MPa, heat radiation arranges, and beats limit, obtains heat-resisting full Eucalyptus lamination decoration panel.
Embodiment 3
Manually select Eucalyptus veneer of the same size, coat the adhesive of embodiment 1, resin added is 200g/ ㎡, and assembly (9 layers), cold pressing for the first time, and temperature is normal temperature, and pressure is 0.8MPa, hot pressing for the first time, and temperature is 115~120 ℃, pressure is 1.0MPa; 60~80 ℃ of standing healths of thermostatic chamber 5~8 hours, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the second time, temperature is normal temperature, and pressure is 0.8MPa, hot pressing for the second time, and temperature is 110~115 ℃, pressure is 1.0MPa; The standing health of thermostatic chamber for the second time, the thermostatic chamber temperature is 60~80 ℃, time 90~120min, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the third time, temperature is normal temperature, and pressure is 0.8MPa, hot pressing for the third time, temperature is 120~125 ℃, pressure is 1.0MPa, fixed thick with coarse sand and fine sandpaper polishing, paste low face side, the polishing face side, face side sticks the melamine gum dipped paper, hot pressing, and temperature is 120 ℃, pressure is 1.5MPa, heat radiation arranges, and beats limit, obtains heat-resisting full Eucalyptus lamination decoration panel.
the comparative example 1
Manually select Eucalyptus veneer of the same size, coat the adhesive of embodiment 1, resin added is 300g/ ㎡, and assembly (11 layers), cold pressing, and temperature is normal temperature, and pressure is 2MPa, hot pressing, and temperature is 120~125 ℃, pressure is 3MPa; 60~80 ℃ of standing healths of thermostatic chamber 5~8 hours, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Fixed thick with coarse sand and fine sandpaper polishing, paste low face side, the polishing face side, face side sticks the melamine gum dipped paper, hot pressing, temperature is 160 ℃, and pressure is 1.5MPa, and heat radiation arranges, and beats limit, obtains heat-resisting full Eucalyptus lamination decoration panel.
the comparative example 2
Manually select Eucalyptus veneer of the same size, coat the adhesive of embodiment 1, resin added is 300g/ ㎡, and assembly (11 layers), cold pressing for the first time, and temperature is normal temperature, and pressure is 1.5MPa, hot pressing for the first time, and temperature is 115~120 ℃, pressure is 2.0MPa; 60~80 ℃ of standing healths of thermostatic chamber 5~8 hours, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the second time, temperature is normal temperature, and pressure is 1.5MPa, hot pressing for the second time, and temperature is 110~115 ℃, pressure is 2.0MPa; The standing health of thermostatic chamber for the second time, the thermostatic chamber temperature is 60~80 ℃, time 90~120min, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Fixed thick with coarse sand and fine sandpaper polishing, paste low face side, the polishing face side, face side sticks the melamine gum dipped paper, hot pressing, temperature is 160 ℃, and pressure is 1.5MPa, and heat radiation arranges, and beats limit, obtains heat-resisting full Eucalyptus lamination decoration panel.
the comparative example 3
Manually select Eucalyptus veneer of the same size, coat the urea-formaldehyde resin adhesive of buying on market or common process is produced, resin added is 200g/ ㎡, assembly (9 layers), cold pressing for the first time, temperature is normal temperature, and pressure is 0.8MPa, hot pressing for the first time, temperature is 115~120 ℃, pressure is 1.0MPa; 60~80 ℃ of standing healths of thermostatic chamber 5~8 hours, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the second time, temperature is normal temperature, and pressure is 0.8MPa, hot pressing for the second time, and temperature is 110~115 ℃, pressure is 1.0MPa; The standing health of thermostatic chamber for the second time, the thermostatic chamber temperature is 60~80 ℃, time 90~120min, the naturally ventilated cooling of thermostatic chamber, heat radiation health 3~4h; Cold pressing for the third time, temperature is normal temperature, and pressure is 0.8MPa, hot pressing for the third time, temperature is 120~125 ℃, pressure is 1.0MPa, fixed thick with coarse sand and fine sandpaper polishing, paste low face side, the polishing face side, face side sticks the melamine gum dipped paper, hot pressing, and temperature is 120 ℃, pressure is 1.5MPa, heat radiation arranges, and beats limit, obtains heat-resisting full Eucalyptus lamination decoration panel.
According to GB18580-2001 " in indoor decorating and refurnishing materials wood-based plate and goods thereof, burst size of methanal is limited the quantity of ", the burst size of methanal of products obtained therefrom in embodiment is measured; According to GB/T9846---the method detected in 2004 " glued boards " is measured the bonding strength of embodiment products obtained therefrom; The mensuration that plays the drum phenomenon of wood-based plate adopts water-boiling method, wood-based plate is cut out to the length for 80cm() * 30cm(is wide) specification, the thermostatted water of putting into 80 ℃ soaks, record wood-based plate and play the drum time used, the time is longer, illustrates that the quality of wood-based plate is better, under normal condition is used, more difficult drum.Each embodiment products obtained therefrom detects three times, and data are averaged, and every testing result is as shown in the table:
It can be seen from the table, heat-resisting full Eucalyptus lamination decoration panel employing of the present invention is colded pressing for three times, three hot pressing, the production technology of twice standing health of thermostatic chamber and twice heat radiation health can improve the bonding strength of wood-based plate, reduce burst size of methanal, because reduced the inner stress produced of full Eucalyptus lamination decoration panel, even wood-based plate expands with heat and contract with cold and also can easily not be out of shape because being heated, improved the heat resistance of wood-based plate; The reduction of burst size of methanal is except outside the Pass having with production technology; also relevant with the production technology of urea-formaldehyde resin adhesive; therefore only have the production technology of improving urea-formaldehyde resin adhesive and adopt Wood-based Panel Production technique of the present invention; could reduce to greatest extent the burst size of methanal of wood-based plate, the protection living environment.Heat-resisting full Eucalyptus lamination decoration panel good heat resistance of the present invention can be used for a long time under high humility, hot environment, is adapted at southern area and uses.