CN103408860A - Antistatic plastic floor - Google Patents
Antistatic plastic floor Download PDFInfo
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- CN103408860A CN103408860A CN2013103023778A CN201310302377A CN103408860A CN 103408860 A CN103408860 A CN 103408860A CN 2013103023778 A CN2013103023778 A CN 2013103023778A CN 201310302377 A CN201310302377 A CN 201310302377A CN 103408860 A CN103408860 A CN 103408860A
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Abstract
The invention discloses an antistatic plastic floor. The antistatic plastic floor comprises, by weight, 120-150 parts of PVC, 20-30 parts of dicapryl phthalate, 10-15 parts of tricresyl phosphite, 1-5 parts of a stabilizer, 1-3 parts of calcium stearate, 40-55 parts of lithium carbonate, 10-20 parts of calcium carbonate, 5-10 parts of titanium dioxide, 2-6 parts of polyethylene glycol 2000, 10-15 parts of castor oil, 1-6 parts of an antistatic agent, and 3-8 parts of an antioxidant. Performance test results of the floor made through a calendering technology show that the wear resistance reaches the GROUP level of performance indexes, the antistatic property reaches CLASS (first level), the antiskid performance index during dryness reaches above 0.48, the antiskid performance index during wetness reaches R9, and the soiling resistance reaches a best effect.
Description
Technical field
The invention belongs to building material field, special standby a kind of antistatic plastic floor that relates to.
Background technology
At present, along with improving constantly of people's living standard, everybody to the requirement of healthy living environment more and more higher, plastic floor, because it has very high environment-friendly type, more and more is subject to people's favor.Compare wood floors, plastic floor has following characteristics: environmental protection, and nontoxic, human body and environment are free from side effects, do not contain radioelement; Wear-resistant type is good, protection against the tide, and Anti-moth-eating, corrosion-resistant; Lightweight; Price is low; Water-proof skid-proof, chance water is more puckery, sliding, can well prevent old man or child's the hidden danger slided into; The heat conduction heat retention is good, and evenly, heat-resisting, winter, the light pin was also very comfortable above stepping down in, and there is no the ice-cold sensation of ceramic tile in heat radiation; Easy maintenance, clean and to get final product with clear water at ordinary times, and the words that spot arranged are by eraser wiped clean well just.But the poorly conductive due to plastic floor, life-time service can produce static on surface, make the fragmental productss such as hair in life be easy to be not easy cleaning totally because electrostatic interaction is adsorbed on floor surface, increased clean difficulty, therefore need to carry out modification to the material of plastic floor, make it have anlistatig effect.
Summary of the invention
In order to overcome above the deficiencies in the prior art, the invention provides a kind of antistatic plastic floor.
The present invention is realized by following technique means:
A kind of antistatic plastic floor, comprise PVC120-150 part in components by weight percent, dioctyl phthalate (DOP) 20-30 part, tricresyl phosphite cresols ester 10-15 part, stablizer 1-5 part, calcium stearate 1-3 part, Quilonum Retard 40-55 part, calcium carbonate 10-20 part, titanium dioxide 5-10 part, Macrogol 2000 2-6 part, Viscotrol C 10-15 part, static inhibitor 1-6 part, oxidation inhibitor 3-8 part.
Described antistatic plastic floor, stablizer can be organotin stabilizers.
Described antistatic plastic floor, static inhibitor can be polyethylene oxide or static inhibitor SWJU-1.
Described antistatic plastic floor, oxidation inhibitor can be pentaerythritol ester or antioxidant 1010.
The preparation method of more than one described antistatic plastic floors, undertaken by following steps:
(1) according to weight part, each component is uniformly mixed in mixing machine, mixing temperature is 100-120 ℃, and mixing speed is 60-80 rev/min, and the time is 5-10 minute;
(2) above-mentioned material is sent into to two-roll calendar and carry out calendering formation, wherein front roll temperature is 150-160 ℃, and rear roll temperature is 160-165 ℃;
(3) sheet material after moulding is carried out cooling, cooling employing spraying cooling, temperature is 30-40 ℃.
The antistatic plastic floor that the present invention makes, through performance test, show good level, wherein wear resistance has reached GROUP T level according to the EN660 standard detection, static resistance detects according to NF P62-001 CLASS (one-level) level that reached, resistance to soiling has reached optimum level according to the EN423 standard detection, wear resistance has reached the GROUP T level of performance index, and the non-skid property index has reached more than 0.48 when dry, when wet, has reached R9.
Embodiment:
Embodiment 1
A kind of antistatic plastic floor, comprise PVC120 part in components by weight percent, 20 parts of dioctyl phthalate (DOP)s, 10 parts of tricresyl phosphite cresols esters, 1 part of organotin stabilizer, 1 part of calcium stearate, 40 parts of Quilonum Retards, 10 parts, calcium carbonate, 5 parts of titanium dioxides, 2 parts of Macrogol 2000s, 10 parts of Viscotrol C, 1 part of polyethylene oxide, 3 parts of pentaerythritol esters.
Above-described antistatic plastic floor is prepared by following steps:
(1) according to weight part, each component is uniformly mixed in mixing machine, mixing temperature is 100 ℃, and mixing speed is 60 rev/mins, and the time is 5 minutes.
(2) above-mentioned material is sent into to two-roll calendar and carry out calendering formation, wherein front roll temperature is 150 ℃, and rear roll temperature is 160 ℃.
(3) sheet material after moulding is carried out cooling, cooling employing spraying cooling, temperature is 30 ℃.
Embodiment 2
A kind of antistatic plastic floor, comprise PVC130 part in components by weight percent, 23 parts of dioctyl phthalate (DOP)s, 12 parts of tricresyl phosphite cresols esters, 2 parts of organotin stabilizers, 1 part of calcium stearate, 43 parts of Quilonum Retards, 12 parts, calcium carbonate, 6 parts of titanium dioxides, 3 parts of Macrogol 2000s, 11 parts of Viscotrol C, 2 parts of polyethylene oxides, 4 parts of antioxidant 1010s.
Above-described antistatic plastic floor is prepared by following steps:
(1) according to weight part, each component is uniformly mixed in mixing machine, mixing temperature is 105 ℃, and mixing speed is 65 rev/mins, and the time is 6 minutes.
(2) above-mentioned material is sent into to two-roll calendar and carry out calendering formation, wherein front roll temperature is 152 ℃, and rear roll temperature is 160 ℃.
(3) sheet material after moulding is carried out cooling, cooling employing spraying cooling, temperature is 32 ℃.
Embodiment 3
A kind of antistatic plastic floor, comprise PVC130 part in components by weight percent, 25 parts of dioctyl phthalate (DOP)s, 13 parts of tricresyl phosphite cresols esters, 3 parts of organotin stabilizers, 2 parts of calcium stearates, 48 parts of Quilonum Retards, 15 parts, calcium carbonate, 7 parts of titanium dioxides, 4 parts of Macrogol 2000s, 13 parts of Viscotrol C, static inhibitor SWJU-14 part, 5 parts of antioxidant 1010s.
Above-described antistatic plastic floor is prepared by following steps:
(1) according to weight part, each component is uniformly mixed in mixing machine, mixing temperature is 110 ℃, and mixing speed is 70 rev/mins, and the time is 8 minutes.
(2) above-mentioned material is sent into to two-roll calendar and carry out calendering formation, wherein front roll temperature is 155 ℃, and rear roll temperature is 162 ℃.
(3) sheet material after moulding is carried out cooling, cooling employing spraying cooling, temperature is 36 ℃.
Embodiment 4
A kind of antistatic plastic floor, comprise PVC142 part in components by weight percent, 28 parts of dioctyl phthalate (DOP)s, 14 parts of tricresyl phosphite cresols esters, 4 parts of organotin stabilizers, 3 parts of calcium stearates, 53 parts of Quilonum Retards, 19 parts, calcium carbonate, 8 parts of titanium dioxides, 5 parts of Macrogol 2000s, 14 parts of Viscotrol C, 5 parts of polyethylene oxides, 6 parts of pentaerythritol esters.
Above-described antistatic plastic floor is prepared by following steps:
(1) according to weight part, each component is uniformly mixed in mixing machine, mixing temperature is 115 ℃, and mixing speed is 76 rev/mins, and the time is 8 minutes.
(2) above-mentioned material is sent into to two-roll calendar and carry out calendering formation, wherein front roll temperature is 160 ℃, and rear roll temperature is 163 ℃.
(3) sheet material after moulding is carried out cooling, cooling employing spraying cooling, temperature is 36 ℃.
Embodiment 5
A kind of antistatic plastic floor, comprise PVC150 part in components by weight percent, 30 parts of dioctyl phthalate (DOP)s, 15 parts of tricresyl phosphite cresols esters, 5 parts of organotin stabilizers, 3 parts of calcium stearates, 55 parts of Quilonum Retards, 20 parts, calcium carbonate, 10 parts of titanium dioxides, 6 parts of Macrogol 2000s, 15 parts of Viscotrol C, static inhibitor SWJU-16 part, 8 parts of pentaerythritol esters.
Above-described antistatic plastic floor is prepared by following steps:
(1) according to weight part, each component is uniformly mixed in mixing machine, mixing temperature is 120 ℃, and mixing speed is 80 rev/mins, and the time is 10 minutes.
(2) above-mentioned material is sent into to two-roll calendar and carry out calendering formation, wherein front roll temperature is 160 ℃, and rear roll temperature is 165 ℃.
(3) sheet material after moulding is carried out cooling, cooling employing spraying cooling, temperature is 40 ℃.
The antistatic plastic floor that above embodiment is made carries out antistatic test, the results are shown in Table 1.
The floor performance test that table 1 embodiment makes
As can be seen from the above data, the floor wear resistance that embodiment 1-5 makes has reached the GROUP T level of performance index, and static resistance has reached CLASS (one-level), and the non-skid property index has reached more than 0.48 when dry, when wet, reached R9, resistance to soiling has reached best effect.
Claims (5)
1. an antistatic plastic floor, is characterized in that, comprises PVC120-150 part in components by weight percent, dioctyl phthalate (DOP) 20-30 part, tricresyl phosphite cresols ester 10-15 part, stablizer 1-5 part, calcium stearate 1-3 part, Quilonum Retard 40-55 part, calcium carbonate 10-20 part, titanium dioxide 5-10 part, Macrogol 2000 2-6 part, Viscotrol C 10-15 part, static inhibitor 1-6 part, oxidation inhibitor 3-8 part.
2. antistatic plastic floor according to claim 1, is characterized in that, stablizer is organotin stabilizer.
3. antistatic plastic floor according to claim 1, is characterized in that, static inhibitor is polyethylene oxide or static inhibitor SWJU-1.
4. antistatic plastic floor according to claim 1, is characterized in that, oxidation inhibitor is pentaerythritol ester or antioxidant 1010.
5. the preparation method of an antistatic plastic floor claimed in claim 1, is characterized in that, undertaken by following steps:
(1) according to weight part, each component is uniformly mixed in mixing machine, mixing temperature is 100-120 ℃, and mixing speed is 60-80 rev/min, and the time is 5-10 minute;
(2) above-mentioned material is sent into to two-roll calendar and carry out calendering formation, wherein front roll temperature is 150-160 ℃, and rear roll temperature is 160-165 ℃;
(3) sheet material after moulding is carried out cooling, cooling employing spraying cooling, temperature is 30-40 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103023778A CN103408860A (en) | 2013-07-18 | 2013-07-18 | Antistatic plastic floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103023778A CN103408860A (en) | 2013-07-18 | 2013-07-18 | Antistatic plastic floor |
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| Publication Number | Publication Date |
|---|---|
| CN103408860A true CN103408860A (en) | 2013-11-27 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2013103023778A Pending CN103408860A (en) | 2013-07-18 | 2013-07-18 | Antistatic plastic floor |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530604A (en) * | 2015-01-03 | 2015-04-22 | 天台县品信地板有限公司 | Formula of novel environment-friendly and flame-retarding macromolecule PVC plastic floor |
| CN105111626A (en) * | 2015-09-18 | 2015-12-02 | 苏州新区佳合塑胶有限公司 | Anti-static foam bottom layer |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1129234A (en) * | 1994-12-28 | 1996-08-21 | 尚和化工株式会社 | Chlorine-containing resin composition |
| CN102344619A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Antistatic PVC plastic floor |
| CN103059548A (en) * | 2012-12-30 | 2013-04-24 | 胶州市富田化工有限公司 | Environmentally friendly plasticizer |
-
2013
- 2013-07-18 CN CN2013103023778A patent/CN103408860A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1129234A (en) * | 1994-12-28 | 1996-08-21 | 尚和化工株式会社 | Chlorine-containing resin composition |
| CN102344619A (en) * | 2010-08-03 | 2012-02-08 | 苏州富通电器塑业有限公司 | Antistatic PVC plastic floor |
| CN103059548A (en) * | 2012-12-30 | 2013-04-24 | 胶州市富田化工有限公司 | Environmentally friendly plasticizer |
Non-Patent Citations (3)
| Title |
|---|
| 张玉龙，等: "《塑料配方与制备手册》", 30 June 2010, article "抗静电半硬质聚氯乙烯地板" * |
| 曹庆辉，等: "抗静电半硬质PVC塑料地板的研制", 《上海塑料》, no. 4, 31 December 2000 (2000-12-31), pages 17 - 19 * |
| 邓舜扬: "《新型塑料材料.工艺.配方（下册）》", 31 January 2000, article "燃烧时不放出氯化氢的含氯树脂地板材料" * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530604A (en) * | 2015-01-03 | 2015-04-22 | 天台县品信地板有限公司 | Formula of novel environment-friendly and flame-retarding macromolecule PVC plastic floor |
| CN105111626A (en) * | 2015-09-18 | 2015-12-02 | 苏州新区佳合塑胶有限公司 | Anti-static foam bottom layer |
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Application publication date: 20131127 |