CN103408380A - Nanometer carbon active water-containing amino acid water soluble fertilizer and preparation method thereof - Google Patents

Abstract

The present invention discloses a nanometer carbon active water-containing amino acid water soluble fertilizer and a preparation method thereof. The nanometer carbon active water-containing amino acid water soluble fertilizer comprises, by weight, 600-800 parts of 0.5% nanometer carbon active water, 100-150 parts of urea, 80-120 parts of ammonium nitrate, 40-50 parts of ammonium dihydrogen phosphate, 50-80 parts of pig nail, 40-50 parts of potassium chloride, 1-2 parts of magnesium sulfate, 2-3 parts of ferrous sulfate, 2-3 parts of sodium molybdate, 1-2 parts of manganese sulfate, 1-2 parts of cobalt chloride, and 20-30 parts of insecticide. The nanometer carbon active water-containing amino acid water soluble fertilizer has the following characteristics that: the formula is reasonable, nutrients are diversified, amino acids and trace fertilizer are effectively chelated so as to supplement trace elements required by crops and promote crop growth and development, water solubility is good, fertilizer efficiency is significant and rapid, and the nanometer carbon active water-containing amino acid water soluble fertilizer has advantages of crop trace element absorption rate increase, soil improvement, yield increase, quality improvement, harvesttime advancing, and the like compared with the conventional humic acid fertilizer.

Description

A kind of nano-sized carbon active water amino acid water-soluble fertilizer and preparation method thereof that contains

Technical field

The present invention relates to a kind of nano-sized carbon active water amino acid water-soluble fertilizer and preparation method thereof that contains, belong to technical field of fertilizers.

Background technology

The amino acid water-soluble fertilizer is a kind of new-type fertilizer grown up in recent years, plays an important role for raising crop yield, reduction fertilizer application amount.It not only can provide plant necessary amino acid, can promote plant to micro-absorption by sequestering action again, prevents the fixing and leaching loss of trace element.But the problems such as quality is unstable, poorly water-soluble, biological activity is low, fertilizer efficiency is low that the amino acid water-soluble fertilizer on existing market is also being deposited.

Summary of the invention

Purpose of the present invention is to provide a kind of good stability, water-soluble height, biological activity is high, fertilizer efficiency is high contains nano-sized carbon active water amino acid water-soluble fertilizer and preparation method thereof.

For achieving the above object, the technical solution used in the present invention is as follows:

A kind of nano-sized carbon active water amino acid water-soluble fertilizer that contains is comprised of the raw material of following weight part:

Described sterilant is made by the raw material of following weight part: pyrethre 10-15, amorpha fruticosa leaf 14-18, trypterygine 12-16, folium eucalypti 5-10, tuber of stemona 10-15, Root of Black Nightshade 8-12, Cortex Meliae 10-15, Artemisia scoparia 4-8, Folium Zanthoxyli Bungeani 13-17, PERICARPIUM ARECAE 9-14, root of langdu 15-20, peel of Citrus reticulata Blanco 12-16, Leaf of Luffa 5-10, Semen Pharbitidis 8-12, Cucumber stem 10-15.

Get above-mentioned raw materials and add the 10-15 times of micro-decoction 40-50 minute that boils of water, filter, filter residue adds 8-12 times of micro-the boiling of water again and decocts 25-35 minute, filter, merging filtrate, add the Rhizoma Zingiberis Recens of 1-2%, the rice vinegar of 3-5% and the alum of 2-3% to stir, concentrated, be spray dried to powder and get final product.

Preferably, a kind of nano-sized carbon active water amino acid water-soluble fertilizer that contains is comprised of the raw material of following weight part:

Described sterilant is made by the raw material of following weight part: pyrethre 15, amorpha fruticosa leaf 16, trypterygine 13, folium eucalypti 6, the tuber of stemona 10, Root of Black Nightshade 8, Cortex Meliae 12, Artemisia scoparia 6, Folium Zanthoxyli Bungeani 15, PERICARPIUM ARECAE 12, the root of langdu 18, peel of Citrus reticulata Blanco 14, Leaf of Luffa 8, Semen Pharbitidis 10, Cucumber stem 12.

Get above-mentioned raw materials and add micro-the boiling of 12 times of water and decocted 40 minutes, filter, filter residue adds 10 times of micro-boiling of water again and decocted 30 minutes, filters, and merging filtrate, add 1.5% Rhizoma Zingiberis Recens, 4% rice vinegar and 2.5% alum to stir, concentrated, is spray dried to powder and gets final product.

A kind of preparation method who contains nano-sized carbon active water amino acid water-soluble fertilizer comprises the following steps:

(1) get Unguis Sus domestica and pulverized the 200-300 mesh sieve, then by the 1-4:5 solid-liquid ratio, adding concentration is the sulphuric acid soln of 20-30%, at microwave power, be 600-800W, temperature is to carry out the microwave constent temperature hydrolysis reaction under 110-120 ℃ of condition, hydrolysis 6-8 hour, then in hydrating solution, add sal epsom, ferrous sulfate, Sodium orthomolybdate, manganous sulfate, cobalt chloride, be heated to 80-90 ℃, stir and with the sodium hydroxide solution that concentration is 10-15%, be neutralized to neutrality after 20-30 minute, filter to obtain the micro-fertilizer of chelating amino acids;

(2) get urea, ammonium nitrate, monoammonium phosphate, Repone K, sterilant, plus nano carbon active water mixes, and is heated to 60-70 ℃, stirs 1-2 hour, is cooled to room temperature, then with the micro-fertilizer of chelating amino acids that step (1) makes, mixes, and obtains.

Beneficial effect of the present invention:

(1) the nano-sized carbon active water adopted in the present invention is compared to common water, it has that movement velocity is fast, perviousness and solvency power is strong, the biological activity high, can effectively promote plant respiration and photosynthesis, improves soil quality, eliminates soil-borne disease, improves utilization rate of fertilizer and quality of agricultural product, the increase crop yield;

(2) the present invention has added plant insecticide on traditional amino acids fertilizer basis, and safety non-pollution, for farm crop provide a good growing environment, reduces the generation of disease and pest, promotes that increasing crop yield increases income;

(3) the present invention fills a prescription rationally, nutrient is polynary, amino acid and micro-fertilizer are carried out to effective chelating, can supplement the required trace element of farm crop, can promote growing of farm crop again, its good water solubility, fertilizer efficiency significantly and fast, than traditional humic acid fertilizer, have more improve the crop trace element specific absorption, improve soil, increase output, improve quality, in advance harvesting time etc. advantage and characteristics.

Embodiment

A kind of nano-sized carbon active water amino acid water-soluble fertilizer that contains is comprised of the raw material of following weight (kg):

Described sterilant is made by the raw material of following weight (g):

Pyrethre 15, amorpha fruticosa leaf 16, trypterygine 13, folium eucalypti 6, the tuber of stemona 10, Root of Black Nightshade 8, Cortex Meliae 12, Artemisia scoparia 6, Folium Zanthoxyli Bungeani 15, PERICARPIUM ARECAE 12, the root of langdu 18, peel of Citrus reticulata Blanco 14, Leaf of Luffa 8, Semen Pharbitidis 10, Cucumber stem 12.

Get above-mentioned raw materials and add 12 times of micro-decoctions 40 minutes of boiling of water, filter, filter residue adds 10 times of micro-boiling of water again and decocted 30 minutes, filter, merging filtrate, add the alum of (being equivalent to sterilant raw material gross weight) 1.5% Rhizoma Zingiberis Recens, 4% rice vinegar and 2.5% to stir, concentrated, be spray dried to powder and get final product.

The nano-sized carbon active water is to be added in deionized water and to be disperseed to obtain by nano-sized carbon, wherein contains nano-sized carbon 5 ‰ in the present invention's 5 ‰ nano-sized carbon active waters used.

A kind of preparation method who contains nano-sized carbon active water amino acid water-soluble fertilizer comprises the following steps:

(1) get Unguis Sus domestica and pulverized 300 mesh sieves, then by the 1-4 solid-liquid ratio, adding concentration is 25% sulphuric acid soln, at microwave power, be 600W, temperature is to carry out the microwave constent temperature hydrolysis reaction under 120 ℃ of conditions, be hydrolyzed 6 hours, then in hydrating solution, add sal epsom, ferrous sulfate, Sodium orthomolybdate, manganous sulfate, cobalt chloride, be heated to 85 ℃, stir and with the sodium hydroxide solution that concentration is 15%, be neutralized to neutrality after 30 minutes, filter to obtain the micro-fertilizer of chelating amino acids;

(2) get urea, ammonium nitrate, monoammonium phosphate, Repone K, sterilant, plus nano carbon active water mixes, and is heated to 70 ℃, stirs 1 hour, is cooled to room temperature, then with the micro-fertilizer of chelating amino acids that step (1) makes, mixes, and obtains.

Field test:

1) for the examination material:

For studying thing, be paddy rice, kind is Tianyou998.For examination fertilizer be above-described embodiment make contain nano-sized carbon active water amino acid water-soluble fertilizer.

2, experimental field select:

Tested on July 05th, 2010 to October 12 and carry out in Ningguo's Rice Cropping base, experimental field soil type is two to close soil, soil physico-chemical property: alkali-hydrolyzable nitrogen 88 mg/kg, rapid available phosphorus 16.4 mg/kg.Available potassium 105mg/kg, organic content is 1.37%, pH value is 8.5, belongs to the medium fertility level.

3, test design:

2 processing, test group are established in test altogether: local habits fertilization+spray the present embodiment contains nano active amino acid water-soluble fertilizer, sprays 4 times; Control group: the clear water of local habits fertilization+spray and test group equivalent.Repeat 3 times, random district group is arranged, community area 30m ².

Tested in paddy rice jointing stage, boot stage and filling stage and spray, totally 3 times, the jointing stage is got stoste 50ml/667m ², be watered 30kg and mix the enforcement foliage-spray; Boot stage and filling stage are got respectively stoste 100ml/667m ², be watered 50kg and mix the enforcement foliage-spray; The community consumption is pressed 667m ²The consumption conversion.

4, experimental result:

Table 1

As shown in Table 1, test group and control group relatively, increase production 117.9kg/667m ², the average spike number of amplification 29%. increases by 8.4 ten thousand fringes, and average grain number per spike increases by 4.3, and thousand seed weight increases 1.8g, and the disease and pest incidence reduces 58%.Illustrate that spraying nano active amino acid water-soluble fertilizer of the present invention can promote plant growth, reduce the generation of disease and pest, improve crop yield and improve crop quality, have important economic benefit.

Claims (3)

1. one kind contains nano-sized carbon active water amino acid water-soluble fertilizer, it is characterized in that, is comprised of the raw material of following weight part:

5 ‰ nano-sized carbon active water 600-800

Urea 100-150

Ammonium nitrate 80-120

Monoammonium phosphate 40-50

Unguis Sus domestica 50-80

Repone K 40-50

Sal epsom 1-2

Ferrous sulfate 2-3

Sodium orthomolybdate 2-3

Manganous sulfate 1-2

Cobalt chloride 1-2

Sterilant 20-30;

Described sterilant is made by the raw material of following weight part: pyrethre 10-15, amorpha fruticosa leaf 14-18, trypterygine 12-16, folium eucalypti 5-10, tuber of stemona 10-15, Root of Black Nightshade 8-12, Cortex Meliae 10-15, Artemisia scoparia 4-8, Folium Zanthoxyli Bungeani 13-17, PERICARPIUM ARECAE 9-14, root of langdu 15-20, peel of Citrus reticulata Blanco 12-16, Leaf of Luffa 5-10, Semen Pharbitidis 8-12, Cucumber stem 10-15;

Get above-mentioned raw materials and add the 10-15 times of micro-decoction 40-50 minute that boils of water, filter, filter residue adds 8-12 times of micro-the boiling of water again and decocts 25-35 minute, filter, merging filtrate, add the Rhizoma Zingiberis Recens of 1-2%, the rice vinegar of 3-5% and the alum of 2-3% to stir, concentrated, be spray dried to powder and get final product.

2. a kind of nano-sized carbon active water amino acid water-soluble fertilizer that contains according to claim 1, is characterized in that, is comprised of the raw material of following weight part:

5 ‰ nano-sized carbon active waters 750

Urea 120

Ammonium nitrate 100

Monoammonium phosphate 45

Unguis Sus domestica 60

Repone K 40

Sal epsom 1

Ferrous sulfate 2

Sodium orthomolybdate 2

Manganous sulfate 1

Cobalt chloride 1

Sterilant 25;

Described sterilant is made by the raw material of following weight part: pyrethre 15, amorpha fruticosa leaf 16, trypterygine 13, folium eucalypti 6, the tuber of stemona 10, Root of Black Nightshade 8, Cortex Meliae 12, Artemisia scoparia 6, Folium Zanthoxyli Bungeani 15, PERICARPIUM ARECAE 12, the root of langdu 18, peel of Citrus reticulata Blanco 14, Leaf of Luffa 8, Semen Pharbitidis 10, Cucumber stem 12;

Get above-mentioned raw materials and add micro-the boiling of 12 times of water and decocted 40 minutes, filter, filter residue adds 10 times of micro-boiling of water again and decocted 30 minutes, filters, and merging filtrate, add 1.5% Rhizoma Zingiberis Recens, 4% rice vinegar and 2.5% alum to stir, concentrated, is spray dried to powder and gets final product.

3. preparation method who contains nano-sized carbon active water amino acid water-soluble fertilizer as claimed in claim 1 is characterized in that comprising the following steps:

(1) get Unguis Sus domestica and pulverized the 200-300 mesh sieve, then by the 1-4:5 solid-liquid ratio, adding concentration is the sulphuric acid soln of 20-30%, at microwave power, be 600-800W, temperature is to carry out the microwave constent temperature hydrolysis reaction under 110-120 ℃ of condition, hydrolysis 6-8 hour, then in hydrating solution, add sal epsom, ferrous sulfate, Sodium orthomolybdate, manganous sulfate, cobalt chloride, be heated to 80-90 ℃, stir and with the sodium hydroxide solution that concentration is 10-15%, be neutralized to neutrality after 20-30 minute, filter to obtain the micro-fertilizer of chelating amino acids;

(2) get urea, ammonium nitrate, monoammonium phosphate, Repone K, sterilant, plus nano carbon active water mixes,

Be heated to 60-70 ℃, stir 1-2 hour, be cooled to room temperature, then with the micro-fertilizer of chelating amino acids that step (1) makes, mix, obtain.