CN103372906A - Method for producing decorative floors by using ardealite - Google Patents

Method for producing decorative floors by using ardealite Download PDF

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Publication number
CN103372906A
CN103372906A CN 201210125339 CN201210125339A CN103372906A CN 103372906 A CN103372906 A CN 103372906A CN 201210125339 CN201210125339 CN 201210125339 CN 201210125339 A CN201210125339 A CN 201210125339A CN 103372906 A CN103372906 A CN 103372906A
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CN
China
Prior art keywords
content
ardealite
sheet
floors
carried
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Pending
Application number
CN 201210125339
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Chinese (zh)
Inventor
张小坤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YUNNAN PROSPEROUS HIGH-TECH MATERIALS Co Ltd
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YUNNAN PROSPEROUS HIGH-TECH MATERIALS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by YUNNAN PROSPEROUS HIGH-TECH MATERIALS Co Ltd filed Critical YUNNAN PROSPEROUS HIGH-TECH MATERIALS Co Ltd
Priority to CN 201210125339 priority Critical patent/CN103372906A/en
Publication of CN103372906A publication Critical patent/CN103372906A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to the technical field of waste reuse and provides a method for producing decorative floors by using ardealite. The ardealite piled up like a mountain serves as a novel raw material of finished building materials, the problem of ardealite pollution is solved thoroughly, launch of energy saving and emission reduction and environmental protection work by the country and local governments is facilitated, sustainable development of surrounding compound fertilizer enterprises is promoted, and the method plays an active role in increasing social benefits. The decorative floors produced through the method are superior in performance, non-toxic, odorless, free of formaldehyde, high in strength, good in abrasion resistance, free of deformation, waterproof, antiskid, comfortable in foot feel, resistant to acid and base, worm-proof, superior to solid wood floors, laminate floors and wood-plastic floors in quality and capable of replacing high-end ceramic tiles for usage, environmentally friendly, antibacterial, free of formaldehyde and other harmful gases, capable of being recycled for manufacturing completely and widely applicable to indoor and outdoor decoration, have high promotion and application values and serve as geothermal floors required by building energy efficiency preferably.

Description

A kind of method of utilizing ardealite to make decorative floor
Technical field
The invention belongs to the refuse reclamation technical field, relate in particular to a kind of method of utilizing ardealite to make decorative floor.
Background technology
Ardealite is a kind of industrial waste in the phosphorus fertilizer ammonium phosphate production process, and year after year, a large amount of discarded ardealites are piled into the mountain, have have not only occupied land resource, more atmosphere, water system and soil are caused severe contamination.Because it contains acid ingredient, be difficult to process with traditional handicraft, be a great problem of national composite fertilizer enterprise.
Summary of the invention
The invention provides a kind of method of utilizing ardealite to make decorative floor, be intended to solve the ardealites of discarding in a large number at present and be piled into the mountain, not only occupied land resource, more atmosphere, water system and soil are caused severe contamination, because it contains acid ingredient, be difficult to process with traditional handicraft, the processing of using waste phosphorus gypsum and recycling have become the problem of a great problem of national composite fertilizer enterprise.
The object of the present invention is to provide a kind of method of utilizing ardealite to make decorative floor, said method comprising the steps of:
Industrial residue phosphogypsum is carried out preliminary treatment;
Needed raw material is carried out proportioning, and stir;
The raw material that stirs is carried out granulation process, form semifinished sheet;
To the semifinished sheet extrusion modling, and cut on request;
The sheet material of well cutting is modified processing, form the finished product decorative floor.
Further, describedly industrial residue phosphogypsum carried out pretreated implementation method be:
Under 50～70 ℃ temperature, industrial residue phosphogypsum is dried;
Industrial residue phosphogypsum after the oven dry is screened, make granularity greater than 200 orders, and without other impurity.
Further, needed raw material and weight ratio thereof are respectively in the described method:
Ardealite content 42%-45%, calcite in powder 35%-45%, polyvinyl chloride content 20%-25%, diaminobenzil dihydrochloride content 0.3%-0.5%, tribasic lead sulfate content 0.5%-1%, barium sulfate content 0.5%-0.8%, stone sodium content 0.5%-1.5%, hard barium content 0.3%-0.5%, haloflex content 0.5%-0.8%, acrylate content 0.4%-0.6%.
The granularity of the calcite in powder that further, adopts in the described method is greater than more than 400 orders.
Further, described needed raw material is carried out proportioning, and the implementation method that stirs is:
Needed raw material is measured in proportion and mix;
Stir under 120-150 ℃ temperature, mixing time is controlled at about 20min.
Further, describedly the raw material that stirs is carried out granulation process, the implementation method that forms semifinished sheet is:
Be controlled in temperature under 180 ℃ ± 2 ℃ the condition, the raw material that stirs put into comminutor carry out granulation;
The output semifinished sheet is cut off and naturally cooling processing.
Further, described to the semifinished sheet extrusion modling, and the implementation method of cutting on request is:
Be that 120 ℃-175 ℃, rotating speed are controlled under the condition that 300-800 turns semifinished sheet extrusion modling, and the processing of lowering the temperature in temperature;
The sheet material of extrusion modling reaches after the specific length, cuts on request.
Further, described sheet material with well cutting is modified processing, and the implementation method that forms the finished product decorative floor is:
Sheet material to well cutting polishes flat, the baking of plated film, japanning is processed, and forms the finished product decorative floor.
The method of utilizing ardealite to make decorative floor provided by the invention, the ardealite that pile up like a mountain for a long time becomes the novel raw materials for production of finished product construction material, solved up hill and dale the pollution problem of ardealite, be conducive to country and local government's energy-saving and emission-reduction, carrying out of environmental protection work, promoted the sustainable development of peripheral composite fertilizer enterprise, played positive role to improving social benefit, it is remarkable that the method manufactures the performance of decorative floor, nonpoisonous and tasteless formaldehydeless, intensity is high, wearability is good, indeformable, anti-skidding, comfortable foot feeling, acid and alkali-resistance, Anti-moth-eating, quality is better than solid wooden floor board, composite floor board, Wood-plastic floor, simultaneously to use be first choice of the required heating floor of building energy conservation to alternative high-grade ceramic tile; Environmental protection, antibiotic, formaldehydeless and other pernicious gas distributes, and reflectivity meets A level house decorative material standard, can 100% recovery circulation make; Can be widely used in indoor and outdoor, the ground decoration such as family, office, commerce, hotel, school, garden landscape, bath center, swimming place and public place has wide range of applications, and has stronger popularization and using value.
Description of drawings
Fig. 1 is that the ardealite that utilizes that the embodiment of the invention provides is made the flow chart of the method for decorative floor.
The specific embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the present invention is further described in detail.Should be appreciated that specific embodiment described herein only in order to explaining the present invention, and be not used in and limit invention.
The ardealite that utilizes that Fig. 1 shows the embodiment of the invention to be provided is made the flow process of the method for decorative floor.
The method may further comprise the steps:
In step S101, industrial residue phosphogypsum is carried out preliminary treatment;
In step S102, needed raw material is carried out proportioning, and stir;
In step S103, the raw material that stirs is carried out granulation process, form semifinished sheet;
In step S104, to the semifinished sheet extrusion modling, and cut on request;
In step S105, the sheet material of well cutting is modified processing, form the finished product decorative floor.
In embodiments of the present invention, industrial residue phosphogypsum being carried out pretreated implementation method is:
Under 50～70 ℃ temperature, industrial residue phosphogypsum is dried;
Industrial residue phosphogypsum after the oven dry is screened, make granularity greater than 200 orders, and without other impurity.
In embodiments of the present invention, needed raw material and weight ratio thereof are respectively in the method:
Ardealite content 65%-70%, calcite in powder, polyvinyl chloride content 20%-25%, diaminobenzil dihydrochloride content 0.2%-0.5%, tribasic lead sulfate content 0.5%-1%, barium sulfate content 0.2%-0.6%, stone sodium content 0.5%-1.5%, hard barium content 0.1%-0.5%, haloflex content 0.5%-0.8%, acrylate content 0.2%-0.6%.
The granularity of the calcite in powder that adopts in the method in embodiments of the present invention, is greater than more than 200 orders.
In embodiments of the present invention, needed raw material is carried out proportioning, and the implementation method that stirs is:
Needed raw material is measured in proportion and mix;
Stir under 120-150 ℃ temperature, mixing time is controlled at about 20min.
In embodiments of the present invention, the raw material that stirs is carried out granulation process, the implementation method that forms semifinished sheet is:
Be controlled in temperature under 180 ℃ ± 2 ℃ the condition, the raw material that stirs put into comminutor carry out granulation;
The output semifinished sheet is cut off and naturally cooling processing.
In embodiments of the present invention, to the semifinished sheet extrusion modling, and the implementation method of cutting on request is:
Be that 120 ℃-175 ℃, rotating speed are controlled under the condition that 300-800 turns semifinished sheet extrusion modling, and the processing of lowering the temperature in temperature;
The sheet material of extrusion modling reaches after the specific length, cuts on request.
In embodiments of the present invention, the sheet material of well cutting is modified processing, the implementation method that forms the finished product decorative floor is:
Sheet material to well cutting polishes flat, the baking of plated film, japanning is processed, and forms the finished product decorative floor.
Below in conjunction with drawings and the specific embodiments application principle of the present invention is further described.
When utilizing ardealite to make decorative floor to the requirement of material: industrial residue phosphogypsum needs dry under 50～70 ℃ temperature, and granularity is greater than 200 orders, and without other impurity; The calcite in powder granularity is greater than more than 200 orders; Polyvinyl chloride; Additive comprises: diaminobenzil dihydrochloride, tribasic lead sulfate, barium sulfate, stone sodium, hard barium, haloflex, acrylate.
The processing compound of each raw material is: ardealite content 65%-70%, polyvinyl chloride content 20%-25%, diaminobenzil dihydrochloride content 0.2%-0.5%, tribasic lead sulfate content 0.5%-1%, barium sulfate content 0.2%-0.6%, stone sodium content 0.5%-1.5%, hard barium content 0.1%-0.5%, haloflex content 0.5%-0.8%, acrylate content 0.2%-0.6%.
The method of utilizing ardealite to make decorative floor is: above-mentioned raw materials is measured in proportion, and through stirring at 120-150 ℃, mixing time is controlled at about 20min; The material that stirs is put into comminutor carry out granulation, temperature must be controlled at 180 ℃ ± 2 ℃, and the semi-finished product of institute's output cut off, and cooling is processed naturally; With the semi-finished product of making grain, 120 ℃-175 ℃ of temperature controls, rotating speed is controlled at 300-800 and turns extrusion modling, and all water for cooling immediately after forming out prevent distortion, reaches after certain specific length on request cutting; With the sheet material of well cutting polish flat, japanning, UV baking, form the finished product of decorative floor.
Three, properties of product:
The decorative floor physicochemical property that utilizes ardealite to produce
MOR: 15.0-18MPa
Elastic modelling quantity 2500---the 3000MPa of this decorative floor, thickness swelling rate is qualified; Surface cold-hot circulation is without be full of cracks, without bubbling; The anti-cigarette calcination in surface is without blackspot, crackle and bubbling; Surface abrasion resistance 0.05-0.07g/100r; Shock resistance: 2-7mm is less than standard-required; Do not detect burst size of methanal.Reflectivity meets house decorative material category-A standard-required.
The ardealite that utilizes that the embodiment of the invention provides is made the method for decorative floor, the ardealite that pile up like a mountain for a long time becomes the novel raw materials for production of finished product construction material, solved up hill and dale the pollution problem of ardealite, be conducive to country and local government's energy-saving and emission-reduction, carrying out of environmental protection work, promoted the sustainable development of peripheral composite fertilizer enterprise, played positive role to improving social benefit, it is remarkable that the method manufactures the performance of decorative floor, nonpoisonous and tasteless formaldehydeless, intensity is high, wearability is good, indeformable, anti-skidding, comfortable foot feeling, acid and alkali-resistance, Anti-moth-eating, quality is better than solid wooden floor board, composite floor board, Wood-plastic floor, simultaneously to use be first choice of the required heating floor of building energy conservation to alternative high-grade ceramic tile; Environmental protection, antibiotic, formaldehydeless and other pernicious gas distributes, and can 100% recovery circulation make; Can be widely used in indoor and outdoor, the ground decoration such as family, office, commerce, hotel, school, garden landscape, bath center, swimming place and public place has wide range of applications, and has stronger popularization and using value.
The ardealite that utilizes that the embodiment of the invention provides is made the method for decorative floor, the ardealite that pile up like a mountain for a long time becomes the novel raw materials for production of finished product construction material, solved up hill and dale the pollution problem of ardealite, be conducive to country and local government's energy-saving and emission-reduction, carrying out of environmental protection work, promoted the sustainable development of peripheral composite fertilizer enterprise, played positive role to improving social benefit, it is remarkable that the method manufactures the performance of decorative floor, nonpoisonous and tasteless formaldehydeless, intensity is high, wearability is good, indeformable, waterproof, anti-skidding, comfortable foot feeling, acid and alkali-resistance, Anti-moth-eating, quality is better than solid wooden floor board, composite floor board, Wood-plastic floor, simultaneously to use be first choice of the required heating floor of building energy conservation to alternative high-grade ceramic tile; Environmental protection, antibiotic, formaldehydeless and other pernicious gas distributes, and can 100% recovery circulation make; Can be widely used in indoor and outdoor, the ground decoration such as family, office, commerce, hotel, school, garden landscape, bath center, swimming place and public place has wide range of applications, and has stronger popularization and using value.
The above only is preferred embodiment of the present invention, not in order to limiting the present invention, all any modifications of doing within the spirit and principles in the present invention, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.

Claims (8)

1. a method of utilizing ardealite to make decorative floor is characterized in that, said method comprising the steps of:
Industrial residue phosphogypsum is carried out preliminary treatment;
Needed raw material is carried out proportioning, and stir;
The raw material that stirs is carried out granulation process, form semifinished sheet;
To the semifinished sheet extrusion modling, and cut on request;
The sheet material of well cutting is modified processing, form the finished product decorative floor.
2. the method for claim 1 is characterized in that, describedly industrial residue phosphogypsum is carried out pretreated implementation method is:
Under 50～70 ℃ temperature, industrial residue phosphogypsum is dried;
Industrial residue phosphogypsum after the oven dry is screened, make granularity greater than 200 orders, and without other impurity.
3. the method for claim 1 is characterized in that, needed raw material and weight ratio thereof are respectively in the described method:
Ardealite content 42%-45%, calcite in powder 35%-45%, polyvinyl chloride content 20%-25%, diaminobenzil dihydrochloride content 0.3%-0.5%, tribasic lead sulfate content 0.5%-1%, barium sulfate content 0.5%-0.8%, stone sodium content 0.5%-1.5%, hard barium content 0.3%-0.5%, haloflex content 0.5%-0.8%, acrylate content 0.4%-0.6%.
4. the method for claim 1 is characterized in that, the granularity of the calcite in powder that adopts in the described method is greater than more than 400 orders.
5. the method for claim 1 is characterized in that, described needed raw material is carried out proportioning, and the implementation method that stirs is:
Needed raw material is measured in proportion and mix;
Stir under 120-150 ℃ temperature, mixing time is controlled at about 20min.
6. the method for claim 1 is characterized in that, describedly the raw material that stirs is carried out granulation processes, and the implementation method that forms semifinished sheet is:
Be controlled in temperature under 180 ℃ ± 2 ℃ the condition, the raw material that stirs put into comminutor carry out granulation;
The output semifinished sheet is cut off and naturally cooling processing.
7. the method for claim 1 is characterized in that, and is described to the semifinished sheet extrusion modling, and the implementation method of cutting on request is:
Be that 120 ℃-175 ℃, rotating speed are controlled under the condition that 300-800 turns semifinished sheet extrusion modling, and the processing of lowering the temperature in temperature;
The sheet material of extrusion modling reaches after the specific length, cuts on request.
8. the method for claim 1 is characterized in that, described sheet material with well cutting is modified processing, and the implementation method that forms the finished product decorative floor is:
Sheet material to well cutting polishes flat, japanning, UV toast processing, forms the finished product decorative floor.
CN 201210125339 2012-04-26 2012-04-26 Method for producing decorative floors by using ardealite Pending CN103372906A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201210125339 CN103372906A (en) 2012-04-26 2012-04-26 Method for producing decorative floors by using ardealite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201210125339 CN103372906A (en) 2012-04-26 2012-04-26 Method for producing decorative floors by using ardealite

Publications (1)

Publication Number Publication Date
CN103372906A true CN103372906A (en) 2013-10-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 201210125339 Pending CN103372906A (en) 2012-04-26 2012-04-26 Method for producing decorative floors by using ardealite

Country Status (1)

Country Link
CN (1) CN103372906A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104909686A (en) * 2015-02-04 2015-09-16 贵州开磷集团股份有限公司 Phosphogypsum-based aluminium alloy-like decoration material and preparation method thereof
CN105348686A (en) * 2015-11-29 2016-02-24 贵州开磷集团股份有限公司 Process for producing PVC (polyvinyl chloride) section bar by taking phosphogypsum as filler
CN109866307A (en) * 2019-03-12 2019-06-11 上海纷雅新型材料有限公司 A kind of novel process production procedure of green environmental protection plate

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104909686A (en) * 2015-02-04 2015-09-16 贵州开磷集团股份有限公司 Phosphogypsum-based aluminium alloy-like decoration material and preparation method thereof
CN105348686A (en) * 2015-11-29 2016-02-24 贵州开磷集团股份有限公司 Process for producing PVC (polyvinyl chloride) section bar by taking phosphogypsum as filler
CN109866307A (en) * 2019-03-12 2019-06-11 上海纷雅新型材料有限公司 A kind of novel process production procedure of green environmental protection plate

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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20131030

C02 Deemed withdrawal of patent application after publication (patent law 2001)