CN103342845A - Novel fire-proof material and preparing method thereof, light fire-proof aluminium-plastic panel - Google Patents

Novel fire-proof material and preparing method thereof, light fire-proof aluminium-plastic panel Download PDF

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CN103342845A
CN103342845A CN2013102565153A CN201310256515A CN103342845A CN 103342845 A CN103342845 A CN 103342845A CN 2013102565153 A CN2013102565153 A CN 2013102565153A CN 201310256515 A CN201310256515 A CN 201310256515A CN 103342845 A CN103342845 A CN 103342845A
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retardant
fire
novel
novel fire
whipping agent
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CN103342845B (en
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陈梅
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JIANGSU KEYUE NEW MATERIAL CO., LTD.
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SHANGHAI KEYUE MACROMOLECULE MATERIALS CO Ltd
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Abstract

The invention discloses a novel fire-proof material. The novel fire-proof material is characterized by comprising matrix resin, a foaming agent and a flame retardant, wherein the novel fire-proof material comprises the following constituents by weight percent: 15% to 60% of polyolefin, 0.5% to 30% of foaming agent and 20% to 80% of flame retardant. The novel fire-proof material provided by the utility model has the characteristics of stronger processing fluidity, easiness in processing, lightness, fire resistance, heat preservation, thermal insulation, cheapness and so on.

Description

Novel fire-retardant material and preparation method thereof, the light fire-proof aluminium-plastic panel
Technical field
The present invention relates to a kind of novel fire-retardant material and preparation method thereof, the light fire-proof aluminium-plastic panel.
Background technology
Owing to the loss of life and personal injury that causes of fire of building and property damage have in recent years unprecedented soaring, the fire-retardant and fire protection requirement that country has also strengthened structure material.Finishing material for exterior wall must reach certain fire-protection rating.Aluminium-plastic panel has obtained development rapidly owing to have light weight, advantage such as corrosion-resistant, heat insulation as a kind of building and ornament materials.For fire-retardant requirement, the flame-retardant aluminum plastic plate of low cigarette, Halogen also develops, and for example patent CN02113998.9 has disclosed the core material by the polyolefine aluminium-plastic panel of inorganic combustion inhibitor magnesium hydroxide, the low cigarette of aluminium hydroxide filled polyolefin manufacturing, halogen-free flameproof.This class material is the main products of flame-retardant aluminum plastic plate in the market.For halogen-free flameproof aluminium-plastic panel core, reach high flame retardant resistance, must strengthen the loading level of inorganic combustion inhibitor.High loading level can reduce stopping composition and extrude the flowability that adds man-hour, reduces extrusion efficiency, increases energy consumption, the quality of infringement aluminium-plastic panel, high loading level makes density increase simultaneously, the quality of corresponding aluminium-plastic panel increases, have influence on the use of aluminium-plastic panel, reduced range of application.In the traditional technology, aluminium hydroxide is applied in the fire-retardant material as fire retardant usually, lose flame retardant efficiency in order to prevent the aluminium hydroxide decomposes, strict control processing temperature must not be higher than the decomposition temperature of aluminium hydroxide in preparation process, and this kind machining at low temperature temperature has reduced the fire resistance of production efficiency and fire-retardant material to a certain extent.
For reducing the quality of aluminium-plastic panel, patent CN1014757 has disclosed foaming aluminium-plastic panel inflaming retarding core material, is to adopt chemical foaming agent-141b or methylene dichloride, by the decomposition of whipping agent, produces gas and foams in extrusion.Though this method can prepare the core of foaming, the foam of foaming is bigger and inhomogeneous, the intensity of influence foaming back core.Because this whipping agent temperature control is comparatively strict, can not foam under higher temperature simultaneously, otherwise can cause the failure of foaming, so extrusion temperature will need strict control, this will cause the efficient of extruding to reduce, and influences the speed of extrusion board.
Therefore, develop a kind of feasible foaming system, reduce the size of foaming foam, improve the homogeneity of foaming foam, reduce because the reduction of the mechanical property of materials that the foam size causes more greatly; Simultaneously, the foaming temperature influence is less, can foam in the wider processing temperature scope, enhances productivity; Has very significant meaning.
Summary of the invention
The objective of the invention is in order to overcome deficiency of the prior art, provide a kind of can the high novel fire-retardant material of mechanical property.
Be real the above object, the present invention is achieved through the following technical solutions:
A kind of novel fire-retardant material is characterized in that, comprises matrix resin, whipping agent and fire retardant; The weight percent of described novel each component of fire-retardant material is: polyolefine 15%~60%, whipping agent 0.5%~30%, fire retardant 10%~80%.
Preferably, described matrix resin weight percent is 25%~60%.
Preferably, described matrix resin comprises a kind of or any several mixture in Low Density Polyethylene (LDPE), linear low density polyethylene (LLDPE), high density polyethylene(HDPE) (HDPE), ethylene-vinyl acetate copolymer (EVA), ethylene-octene copolymer (POE), ethylene-propylene rubber(EPR) (EPDM), butadiene-styrene copolymer (SBS), hydrogenated butadiene-styrene copolymer (SEBS), the ethene-copolymer-maleic anhydride.
Preferably, described fire retardant weight percent is 20%~60%; More preferably be that the weight percent of described fire retardant is 35%~50%.
Preferably, described fire retardant is magnesium hydroxide.
Preferably, described whipping agent is for to be higher than 180 ℃, to be lower than the material that is subjected to thermogenesis gas or water vapor under 320 ℃.
Preferably, described whipping agent is for being higher than 180 ℃, being lower than 320 ℃ of materials that produce water down, and described water is subjected to the thermogenesis water vapor.
Preferably, described whipping agent weight percent is 1%~20%, more preferably 2%~10%.。
Preferably, described whipping agent is aluminium hydroxide.
Preferably, the particle diameter of described whipping agent is 20 nanometers~10 micron; 20 nanometers~0.5 micron more preferably.
Preferably, also comprise fire retarding synergist; Described fire retarding synergist comprises a kind of or any several mixture in zinc borate, antimonous oxide, sodium antimonate, the zinc oxide, and weight percent is 0%~10%, is used for coordinating the physicals of described fire retardant, improves flame retardant effect.
Preferably, also comprise stabilization aid; Described stabilization aid comprises a kind of or any several mixing in surface treatment agent, lubricant, interface modifier, oxidation inhibitor, the steady agent of light, and weight percent is 0%~10%.
Preferably, described surface treatment agent comprises a kind of or any several mixture in silane coupling agent, titanate coupling agent, aluminate coupling agent, oxidic polyethylene, ethene-copolymer-maleic anhydride wax, the stearic acid, for reducing described whipping agent or described fire retardant surface polarity, improve processing fluidity.
Preferably, described lubricant comprises a kind of or any several mixture in polyethylene wax, stearic acid, stearate, ethylene bis stearamide (EBS), fluorine high molecular polymer (PPA), silicone, erucicamide, the amine hydroxybenzene, is used for improving the processing characteristics of described novel fire-retardant material.
Preferably, described interface modifier comprises a kind of or any several mixture in maleic anhydride graft polyolefine, glycidyl methacrylate graft polymkeric substance or the multipolymer, for increasing the interface adhesion of described novel fire-retardant material.
Preferably, described oxidation inhibitor comprises a kind of in hindered phenolic oxidation inhibitor, the phosphite ester kind antioxidant or both mixing, is used for improving the resistance of oxidation of described novel fire-retardant material, strengthens its stability.Wherein hindered phenolic oxidation inhibitor comprises but is not limited to anti-oxidant Irganox 1010 or anti-oxidant Irganox 1098; Phosphite ester kind antioxidant includes but not limited to oxidation inhibitor Irgafos168.
Preferably, the steady agent of described light comprises a kind of or any several mixing in salol, Octabenzone, the dihydroxyphenyl propane sasapyrin, is used for improving the light stabilizing power of described novel fire-retardant material.
Another object of the present invention provides the preparation method of the high novel fire-retardant material of a kind of mechanical property.
For achieving the above object, the present invention is achieved through the following technical solutions:
The preparation method of novel fire-retardant material is characterized in that, concrete steps are as follows:
A, will each component add in Banbury mixer and mediate, mediate the temperature that is subjected to thermogenesis gas that temperature is lower than described whipping agent, banburying obtains whipping agent and the finely dispersed mixture of fire retardant;
B, the mixture after the above-mentioned kneading is used extruding pelletization in the forcing machine, extrusion temperature is lower than the temperature that described whipping agent is subjected to thermogenesis gas;
C, the said mixture particle is extruded at production line; Extrusion temperature is higher than the temperature that described whipping agent is subjected to thermogenesis gas, the decomposition temperature that is lower than described fire retardant, makes whipping agent be subjected to thermogenesis gas in extrusion, the inner cavity that forms of mixture that described whipping agent is made by thermogenetic gas to extrude.
Preferably, the kneading temperature described in the step a is lower than 180 ℃.
Preferably, the extrusion temperature described in the step b is lower than 180 ℃.
Preferably, the extrusion temperature described in the step c is higher than 180 ℃ and be lower than 320 ℃.
Another object of the present invention provides a kind of light fire-proof aluminium-plastic panel that uses the high novel fire-retardant material of mechanical property.
For achieving the above object, the present invention is achieved through the following technical solutions:
The light fire-proof aluminium-plastic panel is characterized in that, comprises aluminium sheet and fireproofing; Described fireproofing uses aforesaid novel fire-retardant material to make.
Preferably, also comprise adhesive foil; Described novel fire-retardant material rolls through tri-roll press machine, carries out compoundly with described adhesive foil and described aluminium sheet, obtains described light fire-proof aluminium-plastic panel.
Novel fire-retardant material provided by the invention, processing fluidity is stronger, is easier to processing, has lightweight, fire-retardant, insulation, characteristics such as heat insulation, inexpensive.By adding whipping agent aluminium hydroxide, utilize aluminium hydroxide decomposes at a certain temperature, produce water vapour, realize the foaming to novel fireproof material layer.More traditional whipping agent, the aluminium hydroxide decomposes, no toxic gas produces, and plays the resolvent water vapour nontoxic pollution-free of foaming effect, is a kind of environment-friendly foaming mode, is conducive to the protection of environment.
Preferred 20 nanometers of whipping agent aluminium hydroxide particle diameter~0.5 micrometer range, ultra-fine particle diameter is conducive to produce littler foam, it is also more even to foam, excessive or the inhomogeneous novel fireproof material layer intensity that causes reduces or problem such as fireproof aluminum-plastic board distortion because of foam to have avoided traditional whipping agent, has improved the quality of light fire-proof aluminium-plastic panel.Select for use aluminium hydroxide to be that as another advantage of whipping agent more traditional whipping agent has wideer blowing temperature, can under higher temperature, foam, it is easy to control namely to foam, and has further improved the production efficiency of light fire-proof aluminium-plastic panel, has increased the quality of light fire-proof aluminium-plastic panel.
The interpolation of fire retarding synergist, the physicals for coordinating described fire retardant helps to improve flame retardant effect.The interpolation of surface treatment agent, reduced the surface polarity of aluminium hydroxide and magnesium hydroxide, promote its in the matrix resin polyolefine of fusion dispersion and improve matrix resin and the interface interaction of aluminium hydroxide, magnesium hydroxide, can promote the processing fluidity of the novel fire-retardant material of foamed light simultaneously.The interpolation of oxidation inhibitor has improved the resistance of oxidation of novel fire-retardant material, has strengthened its stability in use.For guaranteeing that novel fire-retardant material has the good processing characteristics of extruding, and adds a certain amount of lubricant.In order to guarantee to have the good interface associativity between fire retardant and the matrix resin, add a certain amount of interface modifier.The interpolation of the steady agent of light is for the light stability that improves the novel fire-retardant material of foamed light.
Novel fire-retardant material during the present invention is genuine, whipping agent produces gas or water in the high temperature extrusion, and water forms water vapor through heat, and gas or water vapor expansion make that the inner formation of fire-retardant material is empty.After the cooling, water recovery is water, and its volume is very little, and therefore, foaming process of the present invention can not produce the gas of contaminative, production process environmental protection.Whipping agent is uniformly dispersed, and therefore the cavity of novel fire-retardant material inside is evenly distributed, and the aluminium-plastic panel mechanical property of making is even.
The preparation method of novel fire-retardant material provided by the invention, technology is simple, and does not produce any chemical gas in novel fireproof material layer foaming process, and environmentally safe is the preparation method of a kind of cleaning, environmental protection.
The light fire-proof aluminium-plastic panel that comprises novel fire-retardant material provided by the invention, complete processing is simple.Because adopt above-mentioned novel fire-retardant material as fireproofing, fire resistance strengthens, also further prolong work-ing life, improved the physical strength of aluminium-plastic panel simultaneously, reduced the quality of aluminium-plastic panel, enlarged range of application.
Because whipping agent of the present invention is the aluminium hydroxide of low particle diameter, consequent foam size is also lower, generally between 50 nanometers to 5 micron, far below the size of the foam that has chemical foaming agent to produce.Simultaneously owing to as the even dispersion of particle in matrix of the aluminium hydroxide of whipping agent, make that foam of the present invention is more even, like this, make the light fire-proof material have higher intensity and better thermal insulation.
Embodiment
Embodiment 1
Novel fire-retardant material, its each component and corresponding weight percent be as shown in Table 1:
Table one
Preparation method's concrete steps are as follows:
A, be that 5 microns aluminium hydroxide and 40% magnesium hydroxide and 45% low density polyethylene (LDPE) were mediated 30 minutes in 155 ℃ Banbury mixer with 15% median size, obtain the finely dispersed mixture of aluminium hydroxide and magnesium hydroxide.
B, with single screw extrusion machine with said mixture extruding pelletization 155 ℃ the time, obtain compound particles.
C, the said mixture particle extruded to foam earlier on the composite production line at aluminium-plastic panel extrude.The temperature of extrusion die is set at 300 ℃, is higher than 180 ℃ of the decomposition temperatures of aluminium hydroxide, is lower than 320 ℃ of the decomposition temperatures of magnesium hydroxide.Obtain novel fire-retardant material after extruding.
According to prior art that novel fire-retardant material and aluminium sheet is compound, produce fireproof aluminum-plastic board.
Embodiment 2
Novel fire-retardant material, its each component and corresponding weight percent be as shown in Table 2:
Table two
Preparation method's concrete steps are as follows:
A, each component was mediated 30 minutes in 160 ℃ Banbury mixer, obtain the finely dispersed mixture of each component.
B, with single screw extrusion machine with said mixture at 160 ℃ of following extruding pelletizations, obtain compound particles.
C, the said mixture particle extruded to foam earlier on the composite production line at aluminium-plastic panel extrude.The temperature of extrusion die is set at 260 ℃, is higher than 180 ℃ of the decomposition temperatures of aluminium hydroxide, is lower than 320 ℃ of the decomposition temperatures of magnesium hydroxide.Obtain novel fire-retardant material after extruding.
According to prior art that novel fire-retardant material and aluminium sheet is compound, produce fireproof aluminum-plastic board.
Embodiment 3
Novel fire-retardant material, its each component and corresponding weight percent be as shown in Table 3:
Table three
Preparation method's concrete steps are as follows:
A, each component was mediated 30 minutes in 120 ℃ Banbury mixer, obtain the finely dispersed mixture of each component.
B, with single screw extrusion machine with said mixture at 175 ℃ of following extruding pelletizations, obtain compound particles.
C, the said mixture particle extruded to foam earlier on the composite production line at aluminium-plastic panel extrude.The temperature of extrusion die is set at 200 ℃, is higher than 180 ℃ of the decomposition temperatures of aluminium hydroxide, is lower than 320 ℃ of the decomposition temperatures of magnesium hydroxide.Obtain novel fire-retardant material after extruding.
According to prior art that novel fire-retardant material and aluminium sheet is compound, produce fireproof aluminum-plastic board.
Embodiment 4
Novel fire-retardant material, its each component and corresponding weight percent be as shown in Table 4:
Table four
Preparation method's concrete steps are as follows:
A, each component was mediated 30 minutes in 130 ℃ Banbury mixer, obtain the finely dispersed mixture of each component.
B, with single screw extrusion machine with said mixture at 155 ℃ of following extruding pelletizations, obtain compound particles.
C, the said mixture particle extruded to foam earlier on the composite production line at aluminium-plastic panel extrude.The temperature of extrusion die is set at 220 ℃, is higher than 180 ℃ of the decomposition temperatures of aluminium hydroxide, is lower than 320 ℃ of the decomposition temperatures of magnesium hydroxide.Obtain novel fire-retardant material after extruding.
According to prior art that novel fire-retardant material and aluminium sheet is compound, produce fireproof aluminum-plastic board.
Embodiment 5
Novel fire-retardant material, its each component and corresponding weight percent be as shown in Table 5:
Table five
Preparation method's concrete steps are as follows:
A, each component was mediated 30 minutes in 140 ℃ Banbury mixer, obtain the finely dispersed mixture of each component.
B, with single screw extrusion machine with said mixture at 150 ℃ of following extruding pelletizations, obtain compound particles.
C, the said mixture particle extruded to foam earlier on the composite production line at aluminium-plastic panel extrude.The temperature of extrusion die is set at 280 ℃, is higher than 180 ℃ of the decomposition temperatures of aluminium hydroxide, is lower than 320 ℃ of the decomposition temperatures of magnesium hydroxide.Obtain novel fire-retardant material after extruding.
According to prior art that novel fire-retardant material and aluminium sheet is compound, produce fireproof aluminum-plastic board.
Provide the novel fire-retardant material component of Comparative Examples fireproof aluminum-plastic board as shown in Table 6:
Table six
According to the material produce aluminium-plastic panel in the prior art use Comparative Examples.
The fireproof aluminum-plastic board of embodiment 1 to embodiment 5 and Comparative Examples carries out performance test, obtains test data as shown in Table 7:
Table seven
According to the test data of table seven as can be known, novel fire-retardant material provided by the invention by adding whipping agent aluminium hydroxide, utilizes the chemical feature of small particle size aluminium hydroxide decomposes generation at a certain temperature water vapour, realization is to the even foaming of novel fireproof material layer, and the foam particle diameter is little.More traditional novel fire-retardant material, density of material reduces significantly, but the tensile property increase, flexural strength also improves greatly, when namely having reduced the quality of novel fire-retardant material, has improved the physical strength of aluminium-plastic panel, has prolonged work-ing life, has enlarged range of application.On the other hand, the novel fire-retardant material that novel fire-retardant material provided by the invention is more traditional, thermal conductivity reduces significantly, has improved the heat-insulating property of fireproof aluminum-plastic board provided by the invention, further very high its fire resistance.
Novel fire-retardant material during the present invention is genuine, whipping agent produces gas or water in the high temperature extrusion, and water forms water vapor through heat, and gas or water vapor expansion make that the inner formation of fire-retardant material is empty.After the cooling, water recovery is water, and its volume is very little, and therefore, foaming process of the present invention can not produce the gas of contaminative, production process environmental protection.Whipping agent is uniformly dispersed, and therefore the cavity of novel fire-retardant material inside is evenly distributed, and the aluminium-plastic panel mechanical property of making is even.
The preparation method of novel fire-retardant material provided by the invention, technology is simple, and does not produce any chemical gas in novel fireproof material layer foaming process, and environmentally safe is the preparation method of a kind of cleaning, environmental protection.
The light fire-proof aluminium-plastic panel that comprises novel fire-retardant material provided by the invention, complete processing is simple.Because adopt above-mentioned novel fire-retardant material as fireproofing, fire resistance strengthens, also further prolong work-ing life, improved the physical strength of aluminium-plastic panel simultaneously, reduced the quality of aluminium-plastic panel, enlarged range of application.
Because whipping agent of the present invention is the aluminium hydroxide of low particle diameter, consequent foam size is also lower, generally between 50 nanometers to 5 micron, far below the size of the foam that has chemical foaming agent to produce.Simultaneously owing to as the even dispersion of particle in matrix of the aluminium hydroxide of whipping agent, make that foam of the present invention is more even, like this, make the light fire-proof material have higher intensity and better thermal insulation.
Embodiment among the present invention only is used for that the present invention will be described, does not constitute the restriction to the claim scope, and other substituting of being equal in fact that those skilled in that art can expect are all in protection scope of the present invention.

Claims (18)

1. a novel fire-retardant material is characterized in that, comprises matrix resin, whipping agent and fire retardant; The weight percent of described novel each component of fire-retardant material is: polyolefine 15%~60%, whipping agent 0.5%~30%, fire retardant 10%~80%.
2. novel fire-retardant material according to claim 1 is characterized in that, described matrix resin weight percent is 25%~60%.
3. novel fire-retardant material according to claim 1, it is characterized in that described matrix resin comprises a kind of or any several mixture in Low Density Polyethylene (LDPE), linear low density polyethylene (LLDPE), high density polyethylene(HDPE) (HDPE), ethylene-vinyl acetate copolymer (EVA), ethylene-octene copolymer (POE), ethylene-propylene rubber(EPR) (EPDM), butadiene-styrene copolymer (SBS), hydrogenated butadiene-styrene copolymer (SEBS), the ethene-copolymer-maleic anhydride.
4. novel fire-retardant material according to claim 1 is characterized in that, described fire retardant weight percent is 20%~50%.
5. novel fire-retardant material according to claim 1 is characterized in that, described fire retardant is magnesium hydroxide.
6. novel fire-retardant material according to claim 1 is characterized in that, described whipping agent weight percent is 1%~20%.
7. novel fire-retardant material according to claim 1 is characterized in that, described whipping agent is for to be higher than 180 ℃, to be lower than the material that is subjected to thermogenesis gas or water vapor under 320 ℃.
8. novel fire-retardant material according to claim 7 is characterized in that, described whipping agent is for being higher than 180 ℃, being lower than 320 ℃ of materials that produce water down, and described water is subjected to the thermogenesis water vapor.
9. novel fire-retardant material according to claim 1 is characterized in that, described whipping agent is aluminium hydroxide.
10. novel fire-retardant material according to claim 1 is characterized in that, the particle diameter of described whipping agent is 20 nanometers~10 micron.
11. novel fire-retardant material according to claim 1 is characterized in that, also comprises fire retarding synergist; Described fire retarding synergist comprises a kind of or any several mixture in zinc borate, antimonous oxide, sodium antimonate, the zinc oxide, and weight percent is 0%~10%, is used for coordinating the physicals of described fire retardant, improves flame retardant effect.
12. novel fire-retardant material according to claim 1 is characterized in that, also comprises stabilization aid; Described stabilization aid comprises a kind of or any several mixing in surface treatment agent, lubricant, interface modifier, oxidation inhibitor, the steady agent of light, and weight percent is 0%~10%.
13. the preparation method of each described novel fire-retardant material is characterized in that in the claim 1~12, concrete steps are as follows:
A, will each component add in Banbury mixer and mediate, mediate the temperature that is subjected to thermogenesis gas that temperature is lower than described whipping agent, banburying obtains whipping agent and the finely dispersed mixture of fire retardant;
B, the mixture after the above-mentioned kneading is used extruding pelletization in the forcing machine, extrusion temperature is lower than the temperature that described whipping agent is subjected to thermogenesis gas;
C, the said mixture particle is extruded at production line; Extrusion temperature is higher than the temperature that described whipping agent is subjected to thermogenesis gas, the decomposition temperature that is lower than described fire retardant, makes whipping agent be subjected to thermogenesis gas in extrusion, the inner cavity that forms of mixture that described whipping agent is made by thermogenetic gas to extrude.
14. the preparation method of novel fire-retardant material according to claim 13 is characterized in that, the kneading temperature described in the step a is lower than 180 ℃.
15. the preparation method of novel fire-retardant material according to claim 13 is characterized in that, the extrusion temperature described in the step b is lower than 180 ℃.
16. the preparation method of novel fire-retardant material according to claim 13 is characterized in that, the extrusion temperature described in the step c is higher than 180 ℃ and be lower than 320 ℃.
17. the light fire-proof aluminium-plastic panel is characterized in that, comprises aluminium sheet and fireproofing; Described fireproofing comprises that right to use requires the described novel fire-retardant material of the arbitrary claim of 1-12 to make.
18. light fire-proof aluminium-plastic panel according to claim 17 is characterized in that, also comprises adhesive foil; Described novel fire-retardant material rolls through tri-roll press machine, carries out compoundly with described adhesive foil and described aluminium sheet, obtains described light fire-proof aluminium-plastic panel.
CN201310256515.3A 2013-06-25 2013-06-25 Fire proofing material and preparation method thereof, light fire-proof aluminium-plastic panel Active CN103342845B (en)

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CN104018665A (en) * 2013-02-28 2014-09-03 合肥杰事杰新材料股份有限公司 Building template material and preparing method of building template material
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CN103978744B (en) * 2014-05-16 2016-01-06 义乌市晒康塑胶厂 Plastic-aluminum combined stiff sheet material of a kind of halogen-free flameproof and preparation method thereof
CN105058920A (en) * 2015-07-21 2015-11-18 上海婉静纺织科技有限公司 Fireproof aluminum-plastic panel for advertisements
CN107022110A (en) * 2017-05-18 2017-08-08 三斯达(江苏)环保科技有限公司 The preparation and its application in high flame retardant EVA expanded materials of compound antimony oxide
CN108793091A (en) * 2018-07-03 2018-11-13 贵州大学 A kind of technique preparing flame-retardant plastic building materials co-producing sulfuric acid
CN110760137A (en) * 2019-11-14 2020-02-07 航天特种材料及工艺技术研究所 High-performance flame-retardant foaming material and preparation method thereof

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