CN103328414A - α-烯烃低聚物的制造方法 - Google Patents
α-烯烃低聚物的制造方法 Download PDFInfo
- Publication number
- CN103328414A CN103328414A CN201280005258XA CN201280005258A CN103328414A CN 103328414 A CN103328414 A CN 103328414A CN 201280005258X A CN201280005258X A CN 201280005258XA CN 201280005258 A CN201280005258 A CN 201280005258A CN 103328414 A CN103328414 A CN 103328414A
- Authority
- CN
- China
- Prior art keywords
- alpha
- low polymers
- olefin low
- manufacture method
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004711 α-olefin Substances 0.000 title claims abstract description 69
- 238000000034 method Methods 0.000 title claims description 55
- 230000008569 process Effects 0.000 title description 6
- 238000004519 manufacturing process Methods 0.000 claims abstract description 48
- 239000001301 oxygen Substances 0.000 claims abstract description 31
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 31
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 30
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 20
- 239000003054 catalyst Substances 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims description 69
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 58
- 229910052757 nitrogen Inorganic materials 0.000 claims description 29
- 238000001914 filtration Methods 0.000 claims description 23
- -1 polypropylene Polymers 0.000 claims description 12
- 230000002779 inactivation Effects 0.000 claims description 11
- 230000009849 deactivation Effects 0.000 claims description 9
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 239000012298 atmosphere Substances 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 abstract description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 54
- 239000003921 oil Substances 0.000 description 47
- 239000012071 phase Substances 0.000 description 41
- 238000001556 precipitation Methods 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 238000006116 polymerization reaction Methods 0.000 description 23
- 239000007864 aqueous solution Substances 0.000 description 20
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- 239000004615 ingredient Substances 0.000 description 15
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 238000011156 evaluation Methods 0.000 description 13
- 239000012530 fluid Substances 0.000 description 12
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 239000010959 steel Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 7
- 239000012968 metallocene catalyst Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 6
- CSPRGONDJQVAEM-UHFFFAOYSA-L CC(C)(C)C1(C=CC=C1)[Zr](Cl)Cl Chemical class CC(C)(C)C1(C=CC=C1)[Zr](Cl)Cl CSPRGONDJQVAEM-UHFFFAOYSA-L 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- 229940123973 Oxygen scavenger Drugs 0.000 description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XJONFIGVOQMBIP-UHFFFAOYSA-L Cl[Zr](Cl)C1C=CC=C1 Chemical compound Cl[Zr](Cl)C1C=CC=C1 XJONFIGVOQMBIP-UHFFFAOYSA-L 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- 238000004380 ashing Methods 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- 150000002899 organoaluminium compounds Chemical class 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000006392 deoxygenation reaction Methods 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 150000002927 oxygen compounds Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 2
- IHCCLXNEEPMSIO-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 IHCCLXNEEPMSIO-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- KTAXQEDBVWJLAO-UHFFFAOYSA-N C1(C=CC=C1)[Zr](OC)OC Chemical compound C1(C=CC=C1)[Zr](OC)OC KTAXQEDBVWJLAO-UHFFFAOYSA-N 0.000 description 1
- QEVFXLZVXJQPKH-UHFFFAOYSA-N CC(C)(C)C[Zr](CC(C)(C)C)C1C=CC=C1 Chemical compound CC(C)(C)C[Zr](CC(C)(C)C)C1C=CC=C1 QEVFXLZVXJQPKH-UHFFFAOYSA-N 0.000 description 1
- PRQXONWMWVCAEW-UHFFFAOYSA-L CCC1(C=CC=C1)[Zr](Cl)Cl Chemical compound CCC1(C=CC=C1)[Zr](Cl)Cl PRQXONWMWVCAEW-UHFFFAOYSA-L 0.000 description 1
- FAPMWDLBEPHSIP-UHFFFAOYSA-L CCCC1=CC(C=C1)[Zr](Cl)Cl Chemical compound CCCC1=CC(C=C1)[Zr](Cl)Cl FAPMWDLBEPHSIP-UHFFFAOYSA-L 0.000 description 1
- QCQVAFWRDIJQRR-UHFFFAOYSA-L C[Zr](Cl)(Cl)C1C=CC=C1 Chemical compound C[Zr](Cl)(Cl)C1C=CC=C1 QCQVAFWRDIJQRR-UHFFFAOYSA-L 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- NZDLIIBVQQCHBI-UHFFFAOYSA-L Cl[Zr]Cl.CC1=C[CH]C=C1 Chemical compound Cl[Zr]Cl.CC1=C[CH]C=C1 NZDLIIBVQQCHBI-UHFFFAOYSA-L 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 206010018612 Gonorrhoea Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- CMEWLCATCRTSGF-UHFFFAOYSA-N N,N-dimethyl-4-nitrosoaniline Chemical compound CN(C)C1=CC=C(N=O)C=C1 CMEWLCATCRTSGF-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910007926 ZrCl Inorganic materials 0.000 description 1
- IOFYWQPZAISAIR-UHFFFAOYSA-L [Cl-].[Cl-].C(C)[Zr+2]C1C=CC=C1 Chemical compound [Cl-].[Cl-].C(C)[Zr+2]C1C=CC=C1 IOFYWQPZAISAIR-UHFFFAOYSA-L 0.000 description 1
- NKKALSOFYFMKGW-UHFFFAOYSA-L [Cl-].[Cl-].C(CCC)C1=CC=CC1[Zr+2] Chemical compound [Cl-].[Cl-].C(CCC)C1=CC=CC1[Zr+2] NKKALSOFYFMKGW-UHFFFAOYSA-L 0.000 description 1
- XGMPLHDENBQOTK-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)[Zr+2]C1C=CC=C1 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)[Zr+2]C1C=CC=C1 XGMPLHDENBQOTK-UHFFFAOYSA-L 0.000 description 1
- SMOCBYKMWCDGHB-UHFFFAOYSA-L [Cl-].[Cl-].C[Si](C1=CC(C=C1)[Zr+2])(C)C Chemical compound [Cl-].[Cl-].C[Si](C1=CC(C=C1)[Zr+2])(C)C SMOCBYKMWCDGHB-UHFFFAOYSA-L 0.000 description 1
- RLRDLFOYTPDVOF-UHFFFAOYSA-L [Cl-].[Cl-].[Si](C)(C)(C)CC1(C=CC=C1)[Zr+2] Chemical compound [Cl-].[Cl-].[Si](C)(C)(C)CC1(C=CC=C1)[Zr+2] RLRDLFOYTPDVOF-UHFFFAOYSA-L 0.000 description 1
- LREUFPOQFXNWRE-UHFFFAOYSA-N [Zr].C1(C=CC=C1)C1=C(C=CC=C1)C1=CC=CC=C1 Chemical compound [Zr].C1(C=CC=C1)C1=C(C=CC=C1)C1=CC=CC=C1 LREUFPOQFXNWRE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 239000010722 industrial gear oil Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002902 organometallic compounds Chemical group 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012465 retentate Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
- C07C2/34—Metal-hydrocarbon complexes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
- C10M107/10—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
- C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Lubricants (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011-005501 | 2011-01-14 | ||
JP2011005501 | 2011-01-14 | ||
JP2011-005502 | 2011-01-14 | ||
JP2011005502 | 2011-01-14 | ||
PCT/JP2012/000101 WO2012096160A1 (ja) | 2011-01-14 | 2012-01-11 | α-オレフィンオリゴマーの製造方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103328414A true CN103328414A (zh) | 2013-09-25 |
Family
ID=46507069
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201280005258XA Pending CN103328414A (zh) | 2011-01-14 | 2012-01-11 | α-烯烃低聚物的制造方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US8816034B2 (ja) |
EP (1) | EP2664603A1 (ja) |
JP (2) | JP5868875B2 (ja) |
CN (1) | CN103328414A (ja) |
CA (1) | CA2824274A1 (ja) |
SG (1) | SG191072A1 (ja) |
WO (1) | WO2012096160A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111108082A (zh) * | 2017-09-29 | 2020-05-05 | Sk新技术株式会社 | 烯烃低聚的方法 |
CN113522191A (zh) * | 2020-04-20 | 2021-10-22 | 中国石油化工股份有限公司 | 制备聚α-烯烃的装置和方法 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007011462A1 (en) | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Lubricants from mixed alpha-olefin feeds |
JP5735367B2 (ja) | 2011-07-13 | 2015-06-17 | 出光興産株式会社 | オレフィン重合体の製造方法 |
US9382358B2 (en) | 2011-07-13 | 2016-07-05 | Idemitsu Kosan Co., Ltd. | Method for producing olefin polymer |
JP2013209541A (ja) * | 2012-03-30 | 2013-10-10 | Idemitsu Kosan Co Ltd | 有機化合物の製造装置 |
KR101761395B1 (ko) | 2015-04-15 | 2017-07-25 | 주식회사 엘지화학 | 리간드 화합물, 올리고머화 촉매계 및 이를 이용한 올레핀 올리고머화 방법 |
US10059898B2 (en) | 2015-08-21 | 2018-08-28 | Exxonmobil Chemical Patents Inc. | High-viscosity metallocene polyalpha-olefins with high electrohydrodynamic performance |
JP2018523746A (ja) | 2015-08-21 | 2018-08-23 | エクソンモービル・ケミカル・パテンツ・インク | 潤滑油基油ブレンド |
US10611980B2 (en) | 2015-10-15 | 2020-04-07 | Exxonmobil Chemical Patents Inc. | Lubricant containing high-viscosity metallocene polyalpha-olefins |
US10351488B2 (en) | 2016-08-02 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Unsaturated polyalpha-olefin materials |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08301926A (ja) * | 1995-05-01 | 1996-11-19 | Asahi Chem Ind Co Ltd | 反応後α−オレフィン系重合体の後処理方法 |
JP3501330B2 (ja) * | 1996-11-13 | 2004-03-02 | 出光石油化学株式会社 | 触媒残渣を除去する手段を設けたポリマーの製造方法及びそれに用いるモノマー回収装置 |
JPH10158308A (ja) * | 1996-12-02 | 1998-06-16 | Mitsui Chem Inc | 気相重合装置用バグフィルタ |
CZ20023549A3 (cs) * | 2000-04-27 | 2003-04-16 | Bp Corporation North America Inc. | Způsob regulace chemického výrobního procesu |
WO2005024522A1 (ja) * | 2003-09-03 | 2005-03-17 | Zeon Corporation | トナー |
JP4434713B2 (ja) * | 2003-12-05 | 2010-03-17 | 出光興産株式会社 | 触媒の失活方法 |
JP2007021347A (ja) * | 2005-07-14 | 2007-02-01 | Idemitsu Kosan Co Ltd | 難分解性物質含有水の処理方法 |
EP1754694A1 (en) | 2005-08-10 | 2007-02-21 | Linde AG | Method for deactivation and removal of catalytic components in the oligomerisation of ethylene |
JP2009007386A (ja) * | 2006-02-17 | 2009-01-15 | Kaneka Corp | イソブチレン系重合体の製造方法 |
JP2008231261A (ja) | 2007-03-20 | 2008-10-02 | Sumitomo Chemical Co Ltd | オレフィン系重合体の製造方法およびオレフィン系重合体 |
JP2009101981A (ja) * | 2007-10-02 | 2009-05-14 | Osumo:Kk | 洗車方法及び洗車装置 |
-
2012
- 2012-01-11 CN CN201280005258XA patent/CN103328414A/zh active Pending
- 2012-01-11 WO PCT/JP2012/000101 patent/WO2012096160A1/ja active Application Filing
- 2012-01-11 SG SG2013044300A patent/SG191072A1/en unknown
- 2012-01-11 JP JP2012552677A patent/JP5868875B2/ja active Active
- 2012-01-11 CA CA2824274A patent/CA2824274A1/en not_active Abandoned
- 2012-01-11 US US13/978,971 patent/US8816034B2/en active Active
- 2012-01-11 EP EP12734029.7A patent/EP2664603A1/en not_active Withdrawn
-
2016
- 2016-01-05 JP JP2016000358A patent/JP6326072B2/ja active Active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111108082A (zh) * | 2017-09-29 | 2020-05-05 | Sk新技术株式会社 | 烯烃低聚的方法 |
CN111108082B (zh) * | 2017-09-29 | 2023-11-17 | Sk新技术株式会社 | 烯烃低聚的方法 |
CN113522191A (zh) * | 2020-04-20 | 2021-10-22 | 中国石油化工股份有限公司 | 制备聚α-烯烃的装置和方法 |
Also Published As
Publication number | Publication date |
---|---|
EP2664603A1 (en) | 2013-11-20 |
CA2824274A1 (en) | 2012-07-19 |
SG191072A1 (en) | 2013-07-31 |
JP6326072B2 (ja) | 2018-05-16 |
JP5868875B2 (ja) | 2016-02-24 |
JP2016041829A (ja) | 2016-03-31 |
US20130296518A1 (en) | 2013-11-07 |
WO2012096160A1 (ja) | 2012-07-19 |
JPWO2012096160A1 (ja) | 2014-06-09 |
US8816034B2 (en) | 2014-08-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103328414A (zh) | α-烯烃低聚物的制造方法 | |
CN101490105B (zh) | 采用茂金属催化剂制备聚烯烃的方法 | |
CN102015787B (zh) | 聚α烯烃和形成聚α烯烃的方法 | |
CN101945899B (zh) | 用于制备聚烯烃的溶液聚合方法 | |
EP2242778B1 (en) | Controlling branch level and viscosity of polyalphaolefins with propene addition | |
US8202959B2 (en) | Process for preparing polymers from 3-methylbut-1-ene | |
JP2020514353A (ja) | アルファオレフィンを製造するためのエチレンオリゴマー化の方法 | |
CN102471396A (zh) | 控制聚α烯烃粘度的方法 | |
JP2014534319A (ja) | 非担持不均一系ポリオレフィン重合用触媒組成物およびその製造方法 | |
CN103080146A (zh) | 可官能化的合成的烃流体和用于生产所述烃流体的集成的方法 | |
CN102059144B (zh) | 负载型非茂金属催化剂、其制备方法及其应用 | |
EP2059538B1 (en) | Process for removal of residual catalyst components | |
WO2014142206A1 (ja) | α-オレフィン重合体及び水添α-オレフィン重合体の製造方法 | |
CN102039191B (zh) | 负载型非茂金属催化剂、其制备方法及其应用 | |
PL71758B1 (en) | Process for the preparation of alkene polymers[ca924450a] | |
CN102558405B (zh) | α-烯烃聚合催化剂及制备方法与应用 | |
JPWO2012070240A1 (ja) | α−オレフィン重合体及びその製造方法 | |
EP3504250A1 (en) | Olefin polymerization processes | |
RU2007101713A (ru) | Способ получения компонентов катализатора полимеризации олефинов | |
WO2018038796A1 (en) | Olefin polymerization processes | |
CN114829419B (zh) | 基于茂金属和二有机镁的催化体系 | |
CN1955200B (zh) | 多核半金属茂催化剂和使用该多核半金属茂催化剂制备间同立构聚苯乙烯的方法 | |
CN102964483A (zh) | 负载型非茂金属催化剂、其制备方法及其应用 | |
JP4413848B2 (ja) | 新たなハーフメタロセン触媒及びそれを利用したシンジオタクチックポリスチレンの製造方法 | |
USRE29004E (en) | Deactivating and removing aluminum and titanium contaminant from Ziegler-Natta polymerization mixtures |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130925 |