Original applying number 2011101942641, on July 12 2011 applying date, denomination of invention is: a kind of preparation method of cloudy-surface release paper.
Background technology
Mould release membrance is coated on the top layer of environmental-protecting material PET, PE, OPP film substrate by silicone mould release, allows it can show extremely light and stable off-type force for various different organic pressure-sensing glue.
Pressure sensitive adhesive of different organic pressure-sensing glue such as PUR, acryl glue and rubber system etc., required mould release membrance off-type force is different, for needing, the viscosity of isolated product glue is different, the corresponding adjustment of off-type force, makes it to reach extremely light and stable off-type force when peeling off.
Concavo-convex in order to what the glue face of pressure-sensing glue can be made to acquire a certain degree, there are certain mist degree (roughness) and low reflecting effect in glue face, and has a kind of comfortable sensation when naked eyes see glue face, and Misty-faced release film serves vital effect.
At present, the preparation method of Misty-faced release film is: polished coarse by abrasive segments by film substrate; The dust on cleaning film substrate surface; Again at film substrate surface coating one deck mould release after washing, dust removal process.The shortcoming of the method is: the weight of polishing is inconsistent, film surface concavo-convex uneven, causes the peeling force of mould release membrance unstable, there is release bad risk, and the mist degree in pressure-sensing glue glue face is uneven, causes the waste of product.
Summary of the invention
The object of the invention is to provide a kind of manufacturing process of the mould release membrance for organic pressure sensitive adhesive.
For achieving the above object, the technical solution used in the present invention is: a kind of manufacturing process of the mould release membrance for organic pressure sensitive adhesive, forms primarily of the following step:
The first step: be coated with one deck mist-surface release agent on film substrate, the composition of raw materials of this mist-surface release agent is made up of the material of following masses percentage composition:
Hydroxy silicon oil 25 ~ 27%;
Curing agent 0.5 ~ 2%;
Catalyst 5 ~ 6%;
Polyurethane binder 42 ~ 55%;
Aerosil 3%;
Filler 16 ~ 27%;
Described curing agent is Methyl Hydrogen Polysiloxane Fluid; Described catalyst is platinum; Described filler is the talcum powder that particle diameter is less than or equal to 15 microns;
Second step: described mist-surface release agent is dried;
The viscosity of described hydroxy silicon oil is 8000 ~ 13000cps;
The viscosity of described polyurethane binder is 2000 ~ 2500cps.
Related content in technique scheme is explained as follows:
1, in such scheme, the viscosity of described hydroxy silicon oil is 8000 ~ 10000cps.
2, in such scheme, the viscosity of described polyurethane binder is 2000 ~ 2100cps.
3, in such scheme, mould release, also known as interleaving agent, antitack agent, remover.
4, in such scheme, described hydroxy silicon oil, English name is: Hydroxy silicone oil, and be the oligosiloxane telomerized through ring body, its structural formula is as follows:
。
Polysiloxane molecule main chain is Si-O key, and bond energy is 462KJ/mol, and the bond energy of C-O to be the bond energy of 369KJ/mol, Si-O larger than C-O, so the good heat resistance of polysiloxanes.In addition, the bond distance of side chain Si-C is 0.193 nanometer, the bond distance of C-C is 0.154 nanometer, because the bond distance of Si-C is long, the steric hindrance being connected in the methyl on Si atom is little, so methyl rotates quite free, and when connecting methyl on C-C key, the steric hindrance of methyl is large, so methyl can not rotate freely.In addition, large than C-O key of Si-O bond angle, and silicon atom is larger than carbon atom, methyl occupies suitable space when rotating around Si-O key, and intermolecular gravitation is diminished, between polysiloxane molecule, gravitation is little, illustrates that its cohesive energy is little, and resistance to bond and the cohesive energy of polymer are closely related.
6, in such scheme, described Methyl Hydrogen Polysiloxane Fluid, has another name called polymethyl hydrogen siloxane, containing hydrogen silicone oil, high containing hydrogen silicone oil, poly-methyl hydrogen radical siloxane, methyl height containing hydrogen silicone oil, 202 high containing hydrogen silicone oils, trimethylsiloxy group end-blocking gathers methyl.English name Polymethylhydrosiloxane, PMHS.No. CAS: 63148-57-2; Molecular formula: C
3h
9oSi (CH
4oSi) nC
3h
9si.Its structural formula is as follows:
。
7, in such scheme, described hydroxy silicon oil and Methyl Hydrogen Polysiloxane Fluid are under catalyst platinum existent condition, and the mechanism type of the material generated after reaction is as follows:
。
8, in such scheme, described polyurethane binder and polyurethane adhesive, refer to the adhesive containing carbamate groups (-NHCOO-) or NCO (-NCO) in strand.Polyurethane adhesive is divided into polyisocyanates and the large class of polyurethane two.Containing isocyano group (-NCO) and carbamate groups (-NHCOO-) in polyisocyanate molecule chain, therefore polyurethane adhesive shows activity and the polarity of height.With the base material containing active hydrogen, as porous materials such as foam, plastics, timber, leather, fabric, paper, potteries, and the material of any surface finish such as metal, glass, rubber, plastics has excellent chemical adhesive power.
9, in such scheme, described aerosil (gas phase White Carbon black) is one of ultra tiny New Inorganic Materials of extremely important high-tech, and because its particle diameter is very little, therefore specific area is large, superficial attractive forces strong, and surface energy is large; The aspects such as chemical purity is high, dispersive property good, thermal resistance, resistance have special performance, with its superior stability, reinforcing, thickening property and thixotropy, show unique characteristics in numerous subject and field.
10, in such scheme, described talcous English is called PULVISTALCI, for white or off-white color, fine, without the powder of grittiness, hand touches with greasy feeling.CAS No.:14807-96-6。
11, in such scheme, film substrate can be the film substrates such as environmental-protecting material PET, PE, OPP.
Because technique scheme is used, the present invention compared with prior art has following advantages and effect:
The manufacturing process that the present invention is used for the mould release membrance of organic pressure sensitive adhesive is simple, cost-saving, handled easily, can produce peeling force stable and make the good Misty-faced release film of pressure-sensing glue glue face mist degree effect, make glue face reach low reflecting effect.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment one: a kind of manufacturing process of the mould release membrance for organic pressure sensitive adhesive, its manufacture craft is as follows:
The first step: by film substrate and PET film surface treatment clean.
Second step: prepare mist-surface release agent
First, according to following masses percentage, material weighing is got ready:
Hydroxy silicon oil 27%;
Curing agent 2%;
Catalyst 6%;
Polyurethane binder 42%;
Aerosil 3%;
Filler 20%.
Described curing agent is Methyl Hydrogen Polysiloxane Fluid; Described catalyst is platinum; Described filler is the talcum powder that particle diameter is less than or equal to 15 microns; The viscosity of described hydroxy silicon oil is 8000cps.The viscosity of described polyurethane binder is 2000 cps.
Then, material is placed in container, stirs with the mixing speed of 300 revs/min with agitator.
3rd step: be coated with the obtained mist-surface release agent of one deck at film substrate one side surface.The method of coating is funny cutter coating.Also anilox roll can be adopted to be coated with.
4th step: dry, the temperature of the baking oven of use is set to 90 DEG C, 130 DEG C, 140 DEG C, 130 DEG C, 110 DEG C, 80 DEG C.
5th step: maturation, then rolling.
Namely the surface being coated on PET film base material in use obtains mould release membrance.
Embodiment two: a kind of manufacturing process of the mould release membrance for organic pressure sensitive adhesive, its manufacture craft is as follows:
The first step: by film substrate and PET film surface treatment clean.
Second step: prepare mist-surface release agent
First, according to following masses percentage, material weighing is got ready:
Hydroxy silicon oil 25%;
Curing agent 1%;
Catalyst 5%;
Polyurethane binder 50%;
Aerosil 3%;
Filler 16%.
Note, what the % in table represented is mass percentage.
Described curing agent is Methyl Hydrogen Polysiloxane Fluid; Described catalyst is platinum; Described filler is the talcum powder that particle diameter is less than or equal to 15 microns; The viscosity of described hydroxy silicon oil is 10000cps.The viscosity of described polyurethane binder is 2100 cps.
Then, material is placed in container, stirs with the mixing speed of 300 revs/min with agitator.
3rd step: be coated with the obtained mist-surface release agent of one deck at film substrate one side surface.The method of coating is funny cutter coating.Also anilox roll can be adopted to be coated with.
4th step: dry, the temperature of the baking oven of use is set to 90 DEG C, 130 DEG C, 140 DEG C, 130 DEG C, 110 DEG C, 80 DEG C.
5th step: maturation, then rolling.
Namely the surface being coated on PET film base material in use obtains mould release membrance.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its object is to person skilled in the art can be understood content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences done according to Spirit Essence of the present invention change or modify, and all should be encompassed within protection scope of the present invention.