CN103258745A - Thin film transistor, manufacturing method of thin film transistor, array substrate and display device - Google Patents

Thin film transistor, manufacturing method of thin film transistor, array substrate and display device Download PDF

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CN103258745A
CN103258745A CN201310133306XA CN201310133306A CN103258745A CN 103258745 A CN103258745 A CN 103258745A CN 201310133306X A CN201310133306X A CN 201310133306XA CN 201310133306 A CN201310133306 A CN 201310133306A CN 103258745 A CN103258745 A CN 103258745A
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layer
active layer
etching
etching barrier
film
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任庆荣
郭炜
卜倩倩
赵磊
王路
姜志强
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BOE Technology Group Co Ltd
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BOE Technology Group Co Ltd
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Priority to CN201310133306XA priority Critical patent/CN103258745A/en
Priority to PCT/CN2013/080280 priority patent/WO2014169544A1/en
Priority to US14/342,234 priority patent/US20150295094A1/en
Publication of CN103258745A publication Critical patent/CN103258745A/en
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    • H01L29/76Unipolar devices, e.g. field effect transistors
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    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
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    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66742Thin film unipolar transistors
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    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31105Etching inorganic layers
    • H01L21/31111Etching inorganic layers by chemical means
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    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76802Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
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    • H01L21/76841Barrier, adhesion or liner layers

Abstract

The invention discloses a thin film transistor, a manufacturing method of the thin film transistor and a display device, and relates to the field of display. The problems of uneven etching, incomplete etching, over-etching and the like during interlayer through hole forming are resolved and technology reject ratio is lowered. The manufacturing method of the array substrate comprises the steps of forming an active layer, and after the active layer is formed, forming an etching blocking layer at the position, where an interlayer through hole is formed subsequently, on the active layer to protect the active layer during the process of etching the interlayer through hole. The active layer is connected with a source and a leakage electrode through the interlayer through hole.

Description

Thin-film transistor and preparation method thereof, array base palte, display unit
Technical field
The present invention relates to the demonstration field, relate in particular to a kind of thin-film transistor and preparation method thereof, array base palte, display unit.
Background technology
Existing display is many based on amorphous silicon (a-si), be that (Thin Film Transistor TFT) adopts amorphous silicon materials more, but by contrast for the thin-film transistor of display floater, polysilicon (Poly-Si) has higher electron mobility, is considered to the TFT better than amorphous silicon and makes material.
As shown in Figure 1, existing polysilicon array base palte comprises from bottom to top successively: substrate 10, be arranged on the resilient coating 11 (SiO on the substrate 10 x/ SiN xLaminated construction), polysilicon active layer 12, gate insulation layer 13, grid 14 and interlayer insulating film (ILD) 15, also comprise the source leakage source metal layer drain electrode (not shown) that is arranged on the interlayer insulating film 15, the source is leaked the source metal layer drain electrode and is contacted conducting by interlevel via 100 with polysilicon active layer 12.Wherein, interlayer insulating film 15 also needs high visible light transmissive degree except needs good coverage property and insulation effect, and in order to reach above purpose and to keep out external steam and the mechanicalness scratch, interlayer insulating film more than 15 adopts SiO x, SiN xThe perhaps laminated construction SiO of the two x/ SiN xAs interlayer insulating film.The SiO of employing in concrete the enforcement more x/ SiN xLaminated construction, except having pretty good electrology characteristic, and, the preparation SiN xThe working gas of layer comprises hydrogen, therefore forms SiN xAlso have in the time of layer existing rete is carried out hydrotreated effect.
When forming interlevel via 100, the inventor finds prior art, and there are the following problems at least:
Because interlayer insulating film 15 is generally thicker, and is laminated construction, add when forming interlevel via 100, except etching interlayer insulating film 15, also need etching gate insulation layer 13, rete to be etched is blocked up, and compares SiO with polysilicon xThe etching difficulty is a lot of greatly, be difficult to debug out the two splendid selective etching during physical etchings and compare technology, and the polysilicon of active layer is thinner, the zone that often has there is not etching saturating, the zone that has serious over etching again causes active layer to damage, have a strong impact on the product yield, and the application of low temperature polycrystalline silicon technology on large scale shows.
Summary of the invention
The invention provides a kind of thin-film transistor and preparation method thereof, array base palte, display unit, can solve when forming interlevel via, etching is inhomogeneous, do not have problems such as etching is saturating, overetch, reduces the technology fraction defective.
For solving the problems of the technologies described above, on the one hand, the invention provides a kind of film crystal tube preparation method, comprising: form active layer, after the described formation active layer, also comprise:
The position of follow-up formation interlevel via forms etching barrier layer on described active layer, in order to protect described active layer when the described interlevel via of etching;
Described active layer is connected by described interlevel via with source, drain electrode.
Further, the position of follow-up formation interlevel via forms etching barrier layer on described active layer, after protecting described active layer when the described interlevel via of etching, also comprises:
Form gate insulation layer at the active layer that is provided with etching barrier layer;
Form grid at described gate insulation layer;
On described grid, form interlayer insulating film;
The described gate insulation layer of the described interlayer insulating film of etching and below forms described interlevel via.
Alternatively, described etching barrier layer is the semiconductor film of metallic diaphragm or doping.
Preferably, described etching barrier layer adopts identical material with described source-drain electrode.
Alternatively, described etching barrier layer is a kind of in molybdenum film, aluminum metal film, the copper metal film, perhaps,
A kind of in stepped construction titanium/aluminium/titanium and the stepped construction molybdenum/aluminium neodymium/molybdenum.
Preferably, described active layer is polysilicon active layer.
Particularly, described formation active layer specifically comprises:
Form resilient coating at substrate;
Form amorphous silicon layer at described resilient coating;
Described amorphous silicon layer is converted into polysilicon layer;
The described polysilicon layer of etching, the active layer of formation TFT;
Mixing in subregion to described active layer, forms the semiconductor doping zone; Perhaps,
Form resilient coating at substrate;
Form amorphous silicon layer at described resilient coating;
Described amorphous silicon layer is converted into polysilicon layer;
Mixing in subregion to described polysilicon layer, forms the semiconductor doping zone;
Polysilicon layer after mixing is carried out etching, form the polysilicon active layer of TFT.
Alternatively, the thickness of described etching barrier layer is
Figure BDA00003061862800031
On the other hand, the present invention also provides a kind of thin-film transistor, comprising: active layer also comprises:
In order to the etching barrier layer of protection active layer when forming interlevel via, be arranged on the position of follow-up formation interlevel via on the described active layer;
Described interlevel via is in order to connect described active layer and source-drain electrode.
Further, described thin-film transistor also comprises:
Gate insulation layer is arranged on described active layer and the described etching barrier layer;
Grid is arranged on the described gate insulation layer;
Interlayer insulating film is arranged on the described grid;
The described gate insulation layer of described interlayer insulating film and below is provided with interlevel via.
Alternatively, described etching barrier layer is the semiconductor film of metallic diaphragm or doping.
Alternatively, described etching barrier layer adopts the material identical with described source-drain electrode.
Alternatively, described etching barrier layer is a kind of in molybdenum film, aluminum metal film, the copper metal film, perhaps,
A kind of in stepped construction titanium/aluminium/titanium and the stepped construction molybdenum/aluminium neodymium/molybdenum.
Alternatively, described active layer is polysilicon active layer.
Alternatively, the thickness of described etching barrier layer is
Figure BDA00003061862800032
The present invention also provides a kind of array base palte, comprises described arbitrary thin-film transistor.
In addition, the present invention also provides a kind of display unit, comprises described arbitrary thin-film transistor.
The invention provides a kind of row substrate and preparation method thereof, array base palte, display unit; the position of follow-up formation interlevel via forms etching barrier layer on active layer; at the etching interlayer insulating film when forming interlevel via; can protect active layer not to be etched; inhomogeneous when having solved the interlayer insulating film etching, do not have problems such as etching is saturating, overetch, reduce the technology fraction defective.
Description of drawings
In order to be illustrated more clearly in the embodiment of the invention or technical scheme of the prior art, to do to introduce simply to the accompanying drawing of required use in embodiment or the description of the Prior Art below, apparently, accompanying drawing in describing below only is some embodiments of the present invention, for those of ordinary skills, under the prerequisite of not paying creative work, can also obtain other accompanying drawing according to these accompanying drawings.
Fig. 1 is the cross section structure schematic diagram of array base palte;
The flow chart of the film crystal tube preparation method that Fig. 2 provides for the embodiment of the invention one;
Fig. 3 is the structural representation of etching barrier layer on the thin-film transistor in the embodiment of the invention one;
The flow chart of the film crystal tube preparation method that Fig. 4 provides for the embodiment of the invention two;
Fig. 5 is the schematic flow sheet that forms polysilicon active layer in the embodiment of the invention two;
Fig. 6 is the schematic flow sheet that forms etching barrier layer in the embodiment of the invention two;
Fig. 7 is the schematic diagram of gate insulation layer, grid and interlayer insulating film in the embodiment of the invention two;
Fig. 8 is the schematic diagram that forms interlevel via in the embodiment of the invention two.
Description of reference numerals
The 10-substrate, the 11-resilient coating, the 12-polysilicon active layer, the 13-gate insulation layer,
14-grid 15-interlayer insulating film, 100-interlevel via 100, the 120-active layer,
The 121-amorphous silicon layer, the 122-polysilicon layer, the 160-metallic diaphragm, the 16-etching barrier layer,
The 17-photoresist, the 171-etching window.
Embodiment
The invention provides a kind of row substrate and preparation method thereof, display unit, can solve the interlayer insulating film etching inhomogeneous, do not have problems such as etching is saturating, overetch, reduce the technology fraction defective.
Below in conjunction with the accompanying drawing in the embodiment of the invention, the technical scheme in the embodiment of the invention is clearly and completely described, obviously, described embodiment only is the present invention's part embodiment, rather than whole embodiment.
Embodiment one
The embodiment of the invention provides a kind of film crystal tube preparation method, and shown in Fig. 2 and 3, this method comprises:
101, form active layer 120, after forming active layer 120, also comprise:
102, the position of follow-up formation interlevel via forms etching barrier layer 16 on active layer 120, and in order to protection active layer 120 when the etching interlevel via, described interlevel via (not shown) is in order to connect active layer 120 and source-drain electrode (not shown).
The described interlevel via of present embodiment is the via hole that runs through all retes between active layer 120 and source, the drain electrode, and source electrode, drain electrode are electrically connected by the doped region of interlevel via with active layer 120 respectively.
Preferably, the material of described etching barrier layer 16 should be metal or the doped semiconductor that can conduct electricity, and not being afraid of during etching has residually, could protect active layer 120 not to be damaged when the etching interlevel via like this.Particularly; this step is depositing metal membrane layer (or the semiconductor film of mixing) on active layer 120; form etching barrier layer 16 by photoetching process in the position of follow-up formation interlevel via; etching barrier layer 16 is in order to protection active layer 120 when adopting lithographic method to form interlevel via, so the area of etching barrier layer 16 should be greater than the area of section of interlevel via.
And, etching barrier layer 16 should have enough thickness, can guarantee etching away interlayer insulating film on the active layer 120 fully (for the TFT of top gate structure, then be gate insulation layer and the interlayer insulating film that etches away on the active layer 120) time, do not damage the active layer 120 below the gate insulation layer, but the thickness of etching barrier layer 16 again should not be too thick, in order to avoid the deposition of face mask layer in the too high influence of step that forms, the thickness of etching barrier layer 16 is generally selected described in concrete the enforcement
Figure BDA00003061862800051
The embodiment of the invention provides a kind of row base plate preparation method; the position of follow-up formation interlevel via forms etching barrier layer on active layer; when adopting lithographic method with the formation interlevel via; can protect active layer 120 not to be etched; inhomogeneous when having solved the interlayer insulating film etching, do not have problems such as etching is saturating, overetch, reduce the technology fraction defective.
Embodiment two
Further, the embodiment of the invention also provides a kind of film crystal tube preparation method, and shown in Fig. 4 and Fig. 5~7, this method specifically comprises:
201, form resilient coating 11 at substrate 10;
202, form amorphous silicon layer 121 at described resilient coating 11;
203, described amorphous silicon layer 121 is converted into polysilicon layer 122;
204, the described polysilicon layer of etching, the active layer 12 of formation TFT;
205, mixed in the subregion of active layer 12, form the semiconductor doping zone;
As shown in Figure 5, alternatively, at first adopt chemical vapour deposition technique (PECVD) deposition resilient coating 11 and amorphous silicon layer 121 in step 201~204, carry out dehydrogenation then, adopt excimer laser crystallization method (ELA) that amorphous silicon layer 121 is converted into polysilicon layer (P-Si) 122 again, by photoetching process polysilicon layer 122 is carried out the active layer etching more at last, utilize photoresist to do mask and carry out source leakage doping, form the active layer 12 of TFT, can certainly carry out source leakage doping earlier and carry out active layer etching (order of these two steps can be changed) again, and then the activation of annealing, activate the doping ion.
Preferably, above-mentioned resilient coating 11 is SiN x/ SiO 2Laminated construction.
206, as shown in Figure 6, depositing metal membrane layer 160, by composition technology, the position of follow-up formation interlevel via forms etching barrier layer 16 on active layer 12;
The described interlevel via of present embodiment is the via hole that runs through gate insulation layer and interlayer insulating film, and the source electrode in the source-drain electrode, drain electrode are electrically connected by the doped region of interlevel via with active layer 120 respectively.
This step forms one deck etching barrier layer 16 in doped polycrystalline silicon layer (active layer 12), in order to protection active layer when the etching interlevel via.Preferably, this etching barrier layer 16 is general to adopt the material identical with source-drain electrode, as molybdenum Mo, aluminium Al, copper Cu etc., and perhaps stepped construction titanium/aluminium/titanium (Ti/Al/Ti), stepped construction molybdenum/aluminium neodymium/molybdenum (Mo/AlNd/Mo) etc.When the etching interlevel via, residual even if etching barrier layer 16 has, can not influence the ohmic contact between source, drain electrode and the active layer yet.
Etching barrier layer 16 is selected the stepped construction titanium of metal such as molybdenum Mo, aluminium Al, copper Cu or metal, etch rate is lower, and etching barrier layer 16 is not afraid of by a spot of over etching like this, be not afraid of yet have residual, so just avoided because the etching homogeneity is bad, and etching selection ratio is not good, and the technology that causes is bad.
207, form gate insulation layer 13 at the active layer 12 that is provided with etching barrier layer 16;
208, form grid 14 at gate insulation layer 13;
209, on grid 14, form interlayer insulating film 15;
As shown in Figure 7, deposition gate insulation layer 13 and gate metal layer are continued at the active layer 12 that is provided with etching barrier layer 16 in step 207~209, form grid 14 by photoetching process, and then continue deposition interlayer insulating film 15.Wherein, gate insulation layer 13 and interlayer insulating film 15 are SiO x/ SiN xLaminated construction, grid 14 forms for Mo metal film etching.
210, the gate insulation layer 13 of etching interlayer insulating film 15 and below forms interlevel via.
As shown in Figure 8, this step applies photoresist 17 at interlayer insulating film 15, after exposure, developing, predeterminated position in interlevel via forms the etching window 171 that photoresist is peeled off fully, and then the interlayer insulating film that etching window 171 places are exposed carries out dry etching, remove the interlayer insulating film 15 at etching window 171 places and the gate insulation layer 13 of below, form interlevel via 100.At last, proceed subsequent handling, formation source, drain electrode, pixel electrode (perhaps pixel electrode and public electrode) and passivation protection layer are finished the preparation of thin-film transistor.
The embodiment of the invention provides a kind of film crystal tube preparation method; the position of follow-up formation interlevel via forms etching barrier layer on polysilicon active layer; when adopting dry etching with the formation interlevel via; can protect polysilicon active layer not to be etched; inhomogeneous when having solved the interlayer insulating film etching, do not have problems such as etching is saturating, overetch, reduce the technology fraction defective.
Embodiment three
Accordingly, the present invention also provides a kind of thin-film transistor on the other hand, comprising: active layer also comprises:
In order to the etching barrier layer of protection active layer when forming interlevel via, be arranged on the position of follow-up formation interlevel via on the described active layer;
Described interlevel via is in order to connect active layer and source-drain electrode.
Further, described thin-film transistor also comprises:
Gate insulation layer is arranged on described active layer and the described etching barrier layer;
Grid is arranged on the described gate insulation layer;
Interlayer insulating film is arranged on the grid;
Described interlevel via runs through the gate insulation layer of described interlayer insulating film and below.
The embodiment of the invention provides a kind of thin-film transistor; the position of follow-up formation interlevel via is provided with etching barrier layer on the active layer; be not etched in order to protection polysilicon active layer when adopting dry etching to form interlevel via; inhomogeneous in the time of can solving the interlayer insulating film etching, do not have problems such as etching is saturating, overetch, reduce the technology fraction defective.
Alternatively, described etching barrier layer is the semiconductor film of metallic diaphragm or doping.
Alternatively, described etching barrier layer adopts the material identical with described source-drain electrode.
Alternatively, described etching barrier layer is a kind of in molybdenum film, aluminum metal film, the copper metal film, perhaps,
A kind of in stepped construction titanium/aluminium/titanium and the stepped construction molybdenum/aluminium neodymium/molybdenum.
Alternatively, described active layer is polysilicon active layer.
Alternatively, the thickness of described etching barrier layer is
Figure BDA00003061862800081
In addition, the present invention also provides a kind of array base palte, comprises described arbitrary thin-film transistor.
The present invention also provides a kind of display unit, comprises described arbitrary thin-film transistor.
Array base palte provided by the invention, display unit; the position of follow-up formation interlevel via forms etching barrier layer on active layer; when forming interlevel via; can protect active layer not to be etched; inhomogeneous when having solved the interlayer insulating film etching, do not have problems such as etching is saturating, overetch, reduce the technology fraction defective.
The above; only be the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, anyly is familiar with those skilled in the art in the technical scope that the present invention discloses; can expect easily changing or replacing, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection range of described claim.

Claims (17)

1. the preparation method of a thin-film transistor comprises: form active layer, it is characterized in that, after the described formation active layer, also comprise:
The position of follow-up formation interlevel via forms etching barrier layer on described active layer, in order to protect described active layer when the described interlevel via of etching;
Described active layer is connected by described interlevel via with source, drain electrode.
2. method according to claim 1 is characterized in that, the position of follow-up formation interlevel via forms etching barrier layer on described active layer, after protecting described active layer when the described interlevel via of etching, also comprises:
Form gate insulation layer at the active layer that is provided with etching barrier layer;
Form grid at described gate insulation layer;
On described grid, form interlayer insulating film;
The described gate insulation layer of the described interlayer insulating film of etching and below forms described interlevel via.
3. method according to claim 1 and 2 is characterized in that,
Described etching barrier layer is the semiconductor film of metallic diaphragm or doping.
4. method according to claim 3 is characterized in that,
Described etching barrier layer adopts the material identical with described source-drain electrode.
5. method according to claim 4 is characterized in that, described etching barrier layer is a kind of in molybdenum film, aluminum metal film, the copper metal film, perhaps,
A kind of in stepped construction titanium/aluminium/titanium and the stepped construction molybdenum/aluminium neodymium/molybdenum.
6. method according to claim 1 and 2 is characterized in that,
Described active layer is polysilicon active layer.
7. method according to claim 6 is characterized in that, described formation active layer specifically comprises:
Form resilient coating at substrate;
Form amorphous silicon layer at described resilient coating;
Described amorphous silicon layer is converted into polysilicon layer;
The described polysilicon layer of etching, the active layer of formation TFT;
Mixing in subregion to described active layer, forms the semiconductor doping zone; Perhaps,
Form resilient coating at substrate;
Form amorphous silicon layer at described resilient coating;
Described amorphous silicon layer is converted into polysilicon layer;
Mixing in subregion to described polysilicon layer, forms the semiconductor doping zone;
Polysilicon layer after mixing is carried out etching, form the polysilicon active layer of TFT.
8. method according to claim 1 is characterized in that,
The thickness of described etching barrier layer is
Figure FDA00003061862700021
9. thin-film transistor comprises: active layer, it is characterized in that, and also comprise:
In order to the etching barrier layer at etching interlevel via time protection active layer, be arranged on the position of follow-up formation interlevel via on the described active layer;
Described interlevel via is in order to connect described active layer and source-drain electrode.
10. thin-film transistor according to claim 9 is characterized in that, also comprises:
Gate insulation layer is arranged on described active layer and the described etching barrier layer;
Grid is arranged on the described gate insulation layer;
Interlayer insulating film is arranged on the described grid;
Described interlevel via runs through the gate insulation layer of described interlayer insulating film and below.
11. according to claim 9 or 10 described thin-film transistors, it is characterized in that,
Described etching barrier layer is the semiconductor film of metallic diaphragm or doping.
12. thin-film transistor according to claim 11 is characterized in that,
Described etching barrier layer adopts the material identical with described source-drain electrode.
13. thin-film transistor according to claim 11 is characterized in that, described etching barrier layer is a kind of in molybdenum film, aluminum metal film, the copper metal film, perhaps,
A kind of in stepped construction titanium/aluminium/titanium and the stepped construction molybdenum/aluminium neodymium/molybdenum.
14. according to claim 9 or 10 described thin-film transistors, it is characterized in that,
Described active layer is polysilicon active layer.
15. thin-film transistor according to claim 9 is characterized in that,
The thickness of described etching barrier layer is
Figure FDA00003061862700022
16. an array base palte is characterized in that, comprises each described thin-film transistor of claim 9-15.
17. a display unit is characterized in that, comprises each described thin-film transistor of claim 9-15.
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