CN103254396B - 一种基于二元醇中发色团的荧光型水性聚氨酯及其制备方法 - Google Patents
一种基于二元醇中发色团的荧光型水性聚氨酯及其制备方法 Download PDFInfo
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- CN103254396B CN103254396B CN201310222308.6A CN201310222308A CN103254396B CN 103254396 B CN103254396 B CN 103254396B CN 201310222308 A CN201310222308 A CN 201310222308A CN 103254396 B CN103254396 B CN 103254396B
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- Polyurethanes Or Polyureas (AREA)
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Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103641973B (zh) * | 2013-11-15 | 2015-10-28 | 宏元(江门)化工科技有限公司 | 一种侧链偶氮型水性聚氨酯的制备方法 |
CN104177585B (zh) * | 2014-08-29 | 2016-08-17 | 安徽省思维新型建材有限公司 | 一种荧光性聚氨酯乳液的制备方法 |
CN104311779B (zh) * | 2014-10-11 | 2017-06-16 | 江南大学 | 一种水性聚氨酯高分子染料的合成方法 |
CN104927017B (zh) * | 2015-06-08 | 2017-07-28 | 中国科学技术大学 | 一种可同时发荧光和磷光的双发射型水性聚氨酯的制备方法 |
CN105037651B (zh) * | 2015-06-25 | 2017-07-11 | 中国科学技术大学 | 一种偶氮嵌段阳离子水性聚氨酯的制备方法 |
CN105693985B (zh) * | 2016-03-16 | 2019-01-18 | 江苏科技大学 | 一种水性荧光聚氨酯复合物的制备工艺 |
WO2018021158A1 (ja) * | 2016-07-28 | 2018-02-01 | 富士フイルム株式会社 | インクジェット捺染方法、着色組成物、インクジェットインク、インクカートリッジ、及び染料ポリマー |
CN106349449A (zh) * | 2016-09-14 | 2017-01-25 | 潍坊昊海新材料有限公司 | 环保型荧光水性聚氨酯及其制备方法 |
CN106947381B (zh) * | 2017-04-26 | 2019-04-16 | 中国科学技术大学 | 一种聚丙烯酸酯/聚氨酯荧光涂料及其制备方法 |
CN107400453B (zh) * | 2017-08-15 | 2019-09-20 | 中国科学技术大学 | 一种白色荧光水性聚氨酯涂料的制备方法 |
CN109568176A (zh) * | 2018-11-21 | 2019-04-05 | 安徽清彩科技有限公司 | 一种共聚彩色荧光水性聚氨酯指甲油及其制备方法 |
CN109411810A (zh) * | 2018-11-22 | 2019-03-01 | 安徽大学 | 一种荧光型聚氨酯基固态电解质及其电解质膜和锂电池 |
CN110862507B (zh) * | 2019-10-29 | 2021-12-21 | 温州大学 | 一种可自恢复的力致变色荧光水基聚氨酯的制备方法 |
CN110746569B (zh) * | 2019-11-28 | 2022-08-23 | 淮阴工学院 | 荧光水性聚氨酯的合成方法 |
CN111234601A (zh) * | 2020-03-31 | 2020-06-05 | 浙江材华科技有限公司 | 一种水性大分子荧光防伪油墨及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003006523A1 (en) * | 2001-07-09 | 2003-01-23 | Clariant International Ltd. | Inherently colored polyurea and polyurethane |
CN101284900A (zh) * | 2008-05-24 | 2008-10-15 | 烟台万华聚氨酯股份有限公司 | 一种用于木器漆的阴离子水性聚氨酯分散体及其制备方法 |
-
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003006523A1 (en) * | 2001-07-09 | 2003-01-23 | Clariant International Ltd. | Inherently colored polyurea and polyurethane |
CN101284900A (zh) * | 2008-05-24 | 2008-10-15 | 烟台万华聚氨酯股份有限公司 | 一种用于木器漆的阴离子水性聚氨酯分散体及其制备方法 |
Non-Patent Citations (1)
Title |
---|
"基于BHORA和DIX荧光性水性聚氨酯的合成与荧光性能研究";周静;《基于BHORA和DIX荧光性水性聚氨酯的合成与荧光性能研究-中国科学技术大学硕士学位论文》;20121130;第13-14,25-28页 * |
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