CN103244586B - For the metal-based powder metallurgy brake pad and preparation method thereof of bullet train - Google Patents

For the metal-based powder metallurgy brake pad and preparation method thereof of bullet train Download PDF

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Publication number
CN103244586B
CN103244586B CN201310186888.8A CN201310186888A CN103244586B CN 103244586 B CN103244586 B CN 103244586B CN 201310186888 A CN201310186888 A CN 201310186888A CN 103244586 B CN103244586 B CN 103244586B
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weight percentage
powder
brake pad
metal
bullet train
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CN103244586A (en
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蒋建纯
刘华佾
张弛
张宗岭
陈勇军
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Hunan Intercity Technology Co ltd
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Hunan Ding Mao Science And Technology Ltd
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Abstract

For the metal-based powder metallurgy brake pad and preparation method thereof of bullet train, this brake pad is made up of following raw material: matrix constituent element: copper powder, weight percentage 30 ~ 60%, iron powder, weight percentage 20 ~ 40%; Lubricant component: plumbago, weight percentage 8-20%, molybdenum disulfide, weight percentage 1-5%; Friction component: tungsten, weight percentage 1 ~ 3%, corundum, weight percentage 1 ~ 3%, silica sand, weight percentage 1 ~ 3%, boron carbide, weight percentage 1 ~ 3%; Constituent element is stablized in friction: 80 ~ 400 object Carbon fibe powder, and weight percentage is 1 ~ 4%; Binding material: resin, consumption is 1 ~ 5% of each constituent element weight sum.The present invention also comprises the described preparation method for the metal-based powder metallurgy brake pad of bullet train.The friction system friction factor that brake pad of the present invention and wheel are formed is high and stable, and friction factor fluctuation during braking is little, and reliability is high.

Description

For the metal-based powder metallurgy brake pad and preparation method thereof of bullet train
Technical field
The present invention relates to a kind of metal-based powder metallurgy brake pad for bullet train and preparation method thereof, specifically, metal-based powder metallurgy brake pad relating to a kind of bullet train for speed 250km/h ~ more than 380km/h and preparation method thereof.
Background technique
At present, the brake pad that railroad train vehicle uses mainly contains two kinds: composite brake lining and powder metallurgy brake pad.The heat load of high-speed train braking is large, and temperature is high, and composite brake lining braking ability is unstable, and braking force is low, can not meet the requirement that bullet train runs.Powder metallurgy brake pad stable performance, there is the advantages such as good wear resistance, resistance to bond, thermal conductivity, porosity and functional reliability, powder metallurgy brake pad is applied to bullet train, high-power locomotive by the country such as Germany, Japan, France, Italy, Sweden, Canada, achieves good effect.The passenger train of China, the bullet train such as motor-car, CRH2, CRH3 all uses powder metallurgy brake pad.
Powder metallurgy brake pad divides iron-based and the large class of copper base two.
Present military service in speed per hour lower than a kind of iron-based brake shoe formula of 250km/h is, iron powder 45 ~ 60%, copper powder 7 ~ 8%, and graphite 10 ~ 15%, also containing some bronze powders and ceramic powder etc.; According to the observation, usually there is hot crack and darker polishing scratch in the antithesis surface of iron-based brake lining and wheel surface or brake disc surface, its reason may this iron-based friction material hardness and intensity higher, thermal conductivity is bad, simultaneously due to this iron-based brake lining and wheel or brake disc, to contain same metal iron a lot, its intermiscibility is good, so that brake lining and steel wheel or Brake drum produce localized hyperthermia to grinding, and adhesion and adhesive wear occur on surface; Cause friction surface temperature to raise, produce comparatively serious adhesive wear; Contact creep is trapped in friction surface after growing up, and also results in caused by abrasive wear.
CN1995436A discloses a kind of copper base particle reinforced friction material on July 11st, 2007, and this material is made up of the component of following mass percent: Cu:30 ~ 70%, Sn:4 ~ 11%, Al:1 ~ 15%, Fe:5 ~ 18%, Al 2o 3: 2 ~ 15%, SiO 2: 2 ~ 15%, ferrochrome: 0 ~ 15%, graphite: 5 ~ 20%, it is suitable for manufacturing speed per hour≤200km bullet train brake lining and wind-driven generator brake sheet.
CN101623759B discloses a kind of powdered metallurgical material for EMU brake pad on July 13rd, 2010, comprises following weight percent composition: Cu:55 ~ 70%, Sn:2 ~ 7%, Zn:2 ~ 6%, Fe:1 ~ 7%, Al 2o 3: 3 ~ 7%, SiO 2: 1 ~ 5%, MoO 3: 4 ~ 8%, carbon: 6 ~ 13%, also can add Ni:5 ~ 9%, W:4 ~ 7%, Pb:1 ~ 6%, and this material is suitable for the motor-car brake lining of manufacturing speed≤250km/h.
CN101602105B discloses a kind of copper-base powder metallurgy brake pad material on July 11st, 2007, adopts mechanical alloy powder Cu-Sn:10 ~ 80%, mechanical activation powder Ti-C:1.25 ~ 15%, Ni:0 ~ 10%, Cr:0 ~ 12%, Al 2o 3: 2 ~ 8%, graphite: 7.75 ~ 23%, the powder of previously prepared mechanical alloying and mechanical activation powder, form TiC through presintering, manufacturing process is very complicated.
This formula, based on copper, not containing iron powder, not too may mix with steel surface, but the moment of braking surface friction high temperature, be enough to that low melting point is melted mutually, soften, equally can produce adhesion and adhesive wear phenomenon.Along with the passing of active time, frictional behaviour decays, and friction material compares at the friction factor of state of wear with brand-new state, may reduce significantly.
Summary of the invention
Technical problem to be solved by this invention is, provides a kind of and improves metal-based powder metallurgy brake pad for bullet train of the friction and wear behavior of stable friction factor and friction system and preparation method thereof.This brake pad is high temperature resistant, heat fade is little, friction factor is high and stable, through stand test simulation train braking condition Verification, self wear rate of this brake lining is low, simultaneously low to the line wear rate of mating plate, fire damage and the wearing and tearing on mating plate surface are little, can ensure the applicability of braking system, reliability and Economy.
The technical solution adopted for the present invention to solve the technical problems is:
The metal-based powder metallurgy brake pad for bullet train of the present invention, be made up of following raw material:
Matrix constituent element: copper powder, weight percentage 30 ~ 60%, iron powder, weight percentage 20 ~ 40%; Lubricant component: plumbago, weight percentage 8-20%, molybdenum disulfide, weight percentage 1-5%; Friction component: tungsten, weight percentage 1 ~ 3%, corundum, weight percentage 1 ~ 3%, silica sand, weight percentage 1 ~ 3%, boron carbide, weight percentage 1 ~ 3%; Constituent element is stablized in friction: 80 ~ 400 object Carbon fibe powder, and weight percentage is 1 ~ 4%; Described each constituent element weight percentage sum is 100%;
Binding material: resin, consumption is 1 ~ 5% of described each constituent element weight sum.
Further, described copper powder can be electrolytic copper powder or copper reduction.
Further, described iron powder is the mixture of reducing iron powder and iron alloy powder, and described iron alloy powder can be the one in Cr iron powder, Ni iron powder, B iron powder or ferromanganese powder, and consumption accounts for 5 ~ 15% of iron powder weight.
Further, in described matrix constituent element, the weight percentage of copper powder is 40 ~ 50%, and the weight percentage of iron powder is 25 ~ 35%.
Further, in described lubricant component, the weight percentage of plumbago is 10-15%; The weight percentage of molybdenum disulfide is 2-4%.
Further, in described friction component, the weight percentage of tungsten is 1.5 ~ 2.5%, and the weight percentage of corundum is 1.5 ~ 2.5%, and the weight percentage of silica sand is 1.5 ~ 2.5%, and the weight percentage of boron carbide is 1.5 ~ 2.5%.
Further, described resin can be phenolic resin.
Described carbon fiber powder, preferably there is certain thickness chemical vapor deposition charcoal on its surface, and the thickness of deposit carbon is advisable with 5 ~ 20 microns; For ensureing density and the intensity of friction material, carbon fiber was preferably >=300 object carbon fibers.
The preparation method of the metal-based powder metallurgy brake pad for bullet train of the present invention, comprises the following steps;
(1) prepare burden: take each component raw material by predetermined weight per distribution ratio, for subsequent use;
(2) batch mixing: each component raw material that step (1) takes is placed in pebble mill mixing 4-10 hour, obtains mixture;
(3) die mould: carry out mould die mould to step (2) gained mixture, the pressure of die mould is 250-350MPa, ensures that the density of briquetting reaches 4.3-4.7g/cm 3, the pressed compact after compacting, lamination is put, ensure each layer base substrate number of packages or compression area identical;
(4) pressure sintering: step (3) gained base substrate is placed in sintering furnace, adopt hydraulic station and frock to pressurize to pressing blank, sintering pressure maintains 1 ~ 3MPa, leads to hydrogen shield during intensification, and sintering temperature controls at 950 ~ 1200 DEG C, is incubated 2 ~ 5 hours; Then hung out by the heating mantle of sintering furnace, buckle water cooling cover, bath cooling 3 ~ 6 hours, hang out water-cooling cover, product is come out of the stove.
The powder metallurgy brake pad for bullet train of the present invention passes through formulation optimization, after adding suitable friction stabilising agent short carbon fiber, the friction system that brake pad and steel disk form, the change of its friction coefficient retro-speed and surperficial braking energy density is little, with the wearing depth of brake lining or the impact of service time less, stable friction factor, the life-cycle braking ability high conformity of brake lining.
The stable friction performance of the powder metallurgy brake pad for bullet train of the present invention is mainly reflected in: the environmental sensitivity reducing friction system frictional behaviour, control the heat fade performance of friction material, take into account high friction factor and low wearing character, effectively control the inefficacy mechanism in advance of heavy wear and part.
The friction system friction factor that the brake pad utilizing material of the present invention to make and wheel are formed high (0.4) and stablizing; Little (the μ of friction factor fluctuation during braking min/ μ max>=0.5); Condition with environment and friction system changes the amplitude of variation of friction factor within 30%; Heat fade is little, to the life-span, needs the friction factor of the brake pad newer part changed reduction amplitude to be less than 26%; Brake pad part line wear rate is little, to the damage of mating plate and wearing and tearing very little, reliability is high, long service life, good combination property.Through taking the technological measure adding transition layer bed material, brake pad friction material is combined firmly with steel backing.
Accompanying drawing explanation
Fig. 1 is surface power density is 3213.35J/cm 3combined test curve;
Mm1000-III type testing machine carries out stopping brake test, test speed 6500r/min, test pressure 0.31MPa, test area 21.6cm 2, average moment 7.93Nm, maximum moment 9.61Nm, maximum power density 79.84W/cm 2, period of braking 25.73s, average friction coefficient 0.35, maximum friction coefficient 0.42;
Fig. 2 is surface power density is 5284.98J/cm 3combined test curve;
Test speed 8000r/min, test pressure 0.60MPa, test area 21.6cm 2, average moment 12.21Nm, maximum moment 14.14Nm, maximum power density 506.48W/cm 2, period of braking 22.33s, average friction coefficient 0.28, maximum friction coefficient 0.33;
In Fig. 1 and Fig. 2, abscissa is period of braking/s, and y coordinate is moment of torsion/× 100Nm respectively, pressure/× 2MPa, temperature/× 1000 DEG C, rotating speed/× 1000rpm, friction factor/× 0.8 and power/× 10000W;
The curve that the curve label 1,2,3,5,6 marked in figure is respectively moment of torsion, pressure, friction factor, rotating speed, power change with period of braking, this twice test does not take out temperature signal.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment
The metal-based powder metallurgy brake pad for bullet train of the present embodiment, be made up of following raw material:
Matrix constituent element: electrolytic copper powder, weight percentage 45%; Iron powder, weight percentage 30%(iron powder comprises reducing iron powder and iron alloy powder, and iron alloy powder used is ferromanganese powder, accounts for the 10wt% of iron powder);
Lubricant component: plumbago, weight percentage 12%; Molybdenum disulfide, weight percentage 3%;
Friction component: tungsten, weight percentage 2%; Corundum, weight percentage 2%; Silica sand, weight percentage 2%; Boron carbide, weight percentage 2%;
Constituent element is stablized in friction: Carbon fibe powder (cross 400 orders, there is the CVD coating of 6 microns on surface), and weight percentage is 2%;
Binding material: phenolic resin, consumption is 5% of described each constituent element weight sum.
Preparation method, comprises the following steps:
(1) prepare burden: take each component raw material by predetermined weight per distribution ratio, for subsequent use;
(2) batch mixing: each component raw material that step (1) takes is placed in pebble mill mixing 6 hours, obtains mixture;
(3) die mould: carry out mould die mould to step (2) gained mixture, the pressure of die mould is 300MPa, and the density of briquetting reaches 4.4g/cm 3, the pressed compact after compacting, lamination is put, ensure each layer base substrate number of packages or compression area identical;
(4) pressure sintering: step (3) gained base substrate is placed in sintering furnace, adopt hydraulic station and frock to pressurize to pressing blank, sintering pressure is 2MPa, leads to hydrogen shield during intensification, and sintering temperature is 1000 DEG C, is incubated 4 hours; Then hung out by the heating mantle of sintering furnace, buckle water cooling cover, bath cooling 4 hours, hang out water-cooling cover, product is come out of the stove.
The present embodiment gained brake lining is made friction test ring, MM-1000 III type friction wear testing machine carries out simulating brake test.
According to high-speed train braking condition, the design parameter of setting simulation test carries out testing same sample: on mm1000-III type testing machine, carry out stopping brake test, test speed 6500r/min, test pressure 0.31MPa, test area 21.6cm 3, average moment 7.93Nm, maximum moment 9.61Nm, maximum power density 79.84W/cm 2, period of braking 25.73s, energy density 3213.35J/cm 3, average friction coefficient 0.35, maximum friction coefficient 0.42; Test result curve as shown in Figure 1.
Test speed 8000r/min, test pressure 0.60MPa, test area 21.6cm 3, average moment 12.21Nm, maximum moment 14.14Nm, maximum power density 506.48W/cm 2, period of braking 22.33s, energy density 5284.98J/cm 3, average friction coefficient 0.28, maximum friction coefficient 0.33; Test result curve as shown in Figure 2.
Powder metallurgy brake pad of the present invention has the advantage of existing iron-based, copper base brake shoe concurrently, after adding carbon fiber friction stabilizer, except ensureing good thermal conductivity and intensity, stability and the moisture-resistant attenuation performance of friction factor can also be improved, thus improve friction catch brake lining to the applicability of high speed braking condition and the stability of mechanical braking sytem and reliability.

Claims (7)

1. for a metal-based powder metallurgy brake pad for bullet train, it is characterized in that, be made up of following raw material:
Matrix constituent element: copper powder, weight percentage 30 ~ 60%, iron powder, weight percentage 20 ~ 40%; Lubricant component: plumbago, weight percentage 8-20%, molybdenum disulfide, weight percentage 1-5%; Friction component: tungsten, weight percentage 1 ~ 3%, corundum, weight percentage 1 ~ 3%, silica sand, weight percentage 1 ~ 3%, boron carbide, weight percentage 1 ~ 3%; Constituent element is stablized in friction: 80 ~ 400 object carbon fiber powders, and weight percentage is 1 ~ 4%; Described each constituent element weight percentage sum is 100%;
Binding material: resin, consumption is 1 ~ 5% of described each constituent element weight sum;
There is the chemical vapor deposition charcoal of 5 ~ 20 micron thickness on the surface of described carbon fiber powder;
The preparation method of the described metal-based powder metallurgy brake pad for bullet train, comprises the following steps;
(1) prepare burden: take each component raw material by predetermined weight per distribution ratio, for subsequent use;
(2) batch mixing: each component raw material that step (1) takes is placed in pebble mill mixing 4-10 hour, obtains mixture;
(3) die mould: carry out mould die mould to step (2) gained mixture, the pressure of die mould is 250-350MPa, ensures that the density of briquetting reaches 4.3-4.7g/cm 3, the pressed compact after compacting, lamination is put, ensure each layer base substrate number of packages or compression area identical;
(4) pressure sintering: step (3) gained base substrate is placed in sintering furnace, adopt hydraulic station and frock to pressurize to pressing blank, sintering pressure maintains 1 ~ 3MPa, leads to hydrogen shield during intensification, and sintering temperature controls at 1000 ~ 1200 DEG C, is incubated 2 ~ 5 hours; Then hung out by the heating mantle of sintering furnace, buckle water cooling cover, bath cooling 3 ~ 6 hours, hang boiling water cooling cover, product is come out of the stove.
2. the metal-based powder metallurgy brake pad for bullet train according to claim 1, is characterized in that: described copper powder is electrolytic copper powder or copper reduction.
3. the metal-based powder metallurgy brake pad for bullet train according to claim 1 and 2, it is characterized in that: described iron powder is the mixture of reducing iron powder and iron alloy powder, described iron alloy powder is the one in Cr iron powder, Ni iron powder, B iron powder or ferromanganese powder, and consumption accounts for 5 ~ 15% of iron powder weight.
4. the metal-based powder metallurgy brake pad for bullet train according to claim 1 and 2, it is characterized in that: in described matrix constituent element, the weight percentage of copper powder is 40 ~ 50%, the weight percentage of iron powder is 25 ~ 35%.
5. the metal-based powder metallurgy brake pad for bullet train according to claim 1 and 2, is characterized in that: in described lubricant component, and the weight percentage of plumbago is 10-15%, and the weight percentage of molybdenum disulfide is 2-4%.
6. the metal-based powder metallurgy brake pad for bullet train according to claim 1 and 2, it is characterized in that: in described friction component, the weight percentage of tungsten is 1.5 ~ 2.5%, the weight percentage of corundum is 1.5 ~ 2.5%, the weight percentage of silica sand is 1.5 ~ 2.5%, and the weight percentage of boron carbide is 1.5 ~ 2.5%.
7. the metal-based powder metallurgy brake pad for bullet train according to claim 1 and 2, is characterized in that: described resin is phenolic resin.
CN201310186888.8A 2013-05-20 2013-05-20 For the metal-based powder metallurgy brake pad and preparation method thereof of bullet train Expired - Fee Related CN103244586B (en)

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CN110387212A (en) * 2018-04-20 2019-10-29 西安交通大学 Friction material composition and with its preparation bullet train brake pad and application
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Granted publication date: 20150805