CN103236280A - Flexible conductive film - Google Patents

Flexible conductive film Download PDF

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Publication number
CN103236280A
CN103236280A CN2013101473385A CN201310147338A CN103236280A CN 103236280 A CN103236280 A CN 103236280A CN 2013101473385 A CN2013101473385 A CN 2013101473385A CN 201310147338 A CN201310147338 A CN 201310147338A CN 103236280 A CN103236280 A CN 103236280A
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China
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graphene
flexible
conductive film
transparent
layer
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CN2013101473385A
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CN103236280B (en
Inventor
邵丽
史浩飞
张为国
李占成
刘海燕
杜春雷
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Chongqing Institute of Green and Intelligent Technology of CAS
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Chongqing Institute of Green and Intelligent Technology of CAS
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Abstract

A flexible conductive film, which relates to a conductive film, comprises two layers of flexible transparent films, two graphene conductive layers are arranged between the two layers of flexible transparent films, transparent insulating points are arranged between the two graphene conductive layers, and the flexible conductive film can be used in the production of resistive touch screens. Since the invention adopts graphene to replace ITO (indium tin oxide) as the material of the conductive film and the transparent insulating points are arranged between the two graphene conductive layers, when no pressure is applied, the two graphene conductive layers are separated from each other under the support of the transparent insulating points; after pressure is applied, the two graphene conductive layers are in contact with each other to conduct at the position where pressure is applied, so that an electric signal is generated; and the touched position is detected by a control circuit, so that touch operation is conducted. The touch screen made of graphene has the advantages of sensitive touch response, high light transmittance, high conductivity, low cost and environment-friendliness.

Description

A kind of compliant conductive film
Technical field
The present invention relates to a kind of conductive film, particularly a kind of for the conductive film of making resistive touch screen.
Background technology
Touch-screen is simple, convenient, the most natural present a kind of man-machine interaction mode, given multimedia with brand-new looks, be extremely attractive brand-new multimedia interactive equipment, be mainly used in inquiry, office automatic, Industry Control, military commanding, electronic game, choosing song or selecting dish, multimedia teaching, real estate presell of public information etc.Transparency electrode is the part of touch-screen core, and therefore the transparency electrode technology also becomes one of current important research field.
In the market the used conductive film of Zhu Dao resistive touch screen products adopt material be tin indium oxide (Indium Tin Oxide, ITO).Along with development of science and technology, also more and more to the demand of transparency electrode, the performance requirement to transparency electrode also uprises thereupon simultaneously, faces the test of bottleneck day by day as the technology of transparency electrode with ITO.Trace it to its cause, mainly be: the ITO color is yellow partially, conductivity is lower, easily crisp, unstable chemcial property, poisonous, rise day by day because of the very rare price of indium.
In addition, ITO resistive touch screen working pressure is in the market responded to control principle, and the ITO screen is owing to have frangible shortcoming, and its surface-treated is very hard, so regular meeting kicks the beam because of the pressure use and makes people's sensory reaction insensitive when the user uses often.
Summary of the invention
Purpose of the present invention just provides a kind of compliant conductive film, and it has replaced the material of ITO as conductive film with Graphene, have touch be quick on the draw, the advantage of high transmission rate, high conductivity, low cost and environmental protection.
The objective of the invention is to realize by such technical scheme, it includes the two sheets of flexible transparent membrane, between the two sheets of flexible transparent membrane, be provided with two-layer graphene conductive layer, between two-layer graphene conductive layer, be provided with a plurality of for the transparent insulation point of isolating two-layer graphene conductive layer.
Further, described transparent insulation point is ultra-violet curing glue particle.
Further, described graphene conductive layer is made up of the Graphene of one deck to ten layer.
Further, described Graphene is pure Graphene, adopts chemical vapour deposition technique, at gaseous carbon sources and protective condition growth Graphene, the Graphene of growth is transferred on the flexible and transparent film again.
Further, described Graphene is doped graphene, adopts chemical vapour deposition technique, and the Graphene of growing under the condition of gaseous carbon sources and protection gas is transferred to the Graphene of growth on the flexible and transparent film, and it is soaked doping in containing the chemical doping reagent solution.
Further, described Graphene is doped graphene, adopts chemical vapour deposition technique, and the Graphene of growing under the condition of gaseous carbon sources and protection gas is transferred to the Graphene of growth on the flexible and transparent film, carries out metal nanoparticle again and mixes.
Further; described Graphene is the Graphene with metal grill; adopt photoetching or lithographic technique to make the metal grill structure at the flexible and transparent film; adopt chemical vapour deposition technique; the Graphene of under gaseous carbon sources and protective condition, growing, and the Graphene of growth is transferred on the flexible and transparent film with metal grill.
Owing to adopted technique scheme, the present invention to have following advantage:
The present invention has replaced the material of ITO as conductive film with Graphene, is provided with the transparent insulation point of a plurality of orderly arrangements between two graphene conductive layers, can be used for making resistive touch screen.Do not having pressure to do the time spent, two graphene conductive layers are separated under the support of transparent insulation point mutually; When on-load pressure, two layer graphenes at on-load pressure place produce the signal of telecommunication because being in contact with one another conducting, can detect touch location by control circuit, realize touch control operation.The touch-screen that utilizes Graphene to make have touch be quick on the draw, the advantage of high transmission rate, high conductivity, low cost and environmental protection.
Other advantages of the present invention, target and feature will be set forth to a certain extent in the following description, and to a certain extent, based on being apparent to those skilled in the art to investigating hereinafter, perhaps can obtain instruction from the practice of the present invention.Target of the present invention and other advantages can realize and obtain by following specification and claims.
Description of drawings
Description of drawings of the present invention is as follows.
Fig. 1 is structural representation of the present invention.
Embodiment
The invention will be further described below in conjunction with drawings and Examples.
A kind of compliant conductive film includes the two sheets of flexible transparent membrane, is provided with two-layer graphene conductive layer between the two sheets of flexible transparent membrane, is provided with a plurality of for the transparent insulation point of isolating two-layer graphene conductive layer between two-layer graphene conductive layer.
Described transparent insulation point is ultra-violet curing glue particle.
Described graphene conductive layer is made up of the Graphene of one deck to ten layer.
Described Graphene is pure Graphene, adopts chemical vapour deposition technique, at gaseous carbon sources and protective condition growth Graphene, the Graphene of growth is transferred on the flexible and transparent film again.
Described Graphene is doped graphene, adopts chemical vapour deposition technique, and the Graphene of growing under the condition of gaseous carbon sources and protection gas is transferred to the Graphene of growth on the flexible and transparent film, and it is soaked doping in containing the chemical doping reagent solution.
Described Graphene is doped graphene, adopts chemical vapour deposition technique, and the Graphene of growing under the condition of gaseous carbon sources and protection gas is transferred to the Graphene of growth on the flexible and transparent film, carries out metal nanoparticle again and mixes.
Described Graphene is the Graphene with metal grill; adopt photoetching or lithographic technique to make the metal grill structure at the flexible and transparent film; adopt chemical vapour deposition technique; the Graphene of under gaseous carbon sources and protective condition, growing, and the Graphene of growth is transferred on the flexible and transparent film with metal grill.
Graphene is extensively admitted as a kind of novel conductive film material.Graphene is made of the monoatomic layer flat film of hexangle type lattice with the sp2 hybridized orbit carbon atom, the advantages such as novel electrode that have high transmission rate, high conductivity, low cost, high stability, environmental protection and can prepare at various substrates can overcome the shortcoming of present ito transparent electrode.
The present invention has replaced the material of ITO as conductive film with Graphene, is provided with the transparent insulation point of a plurality of orderly arrangements between two graphene conductive layers, can be used for making resistive touch screen.Do not having pressure to do the time spent, two graphene conductive layers are separated under the support of transparent insulation point mutually; When on-load pressure, two layer graphenes at on-load pressure place produce the signal of telecommunication because being in contact with one another conducting, can detect touch location by control circuit, realize touch control operation.The touch-screen that utilizes Graphene to make have touch be quick on the draw, the advantage of high transmission rate, high conductivity, low cost and environmental protection.
As shown in Figure 1, ground floor is the flexible and transparent film, and the second layer is the graphene conductive layer, and the 3rd layer is the separator that transparent insulation point is formed, and the 4th layer is the graphene conductive layer, and layer 5 is the flexible and transparent film.(X, physical location Y) are converted to the voltage that represents X coordinate and Y coordinate with touch point in the rectangular area.When touch operation, the Graphene coating of the second layer can touch the 4th layer Graphene coating, spreads out of the corresponding signal of telecommunication via inductor, delivers to processor through change-over circuit, is converted into X, Y value on the screen by computing, thereby detects the touch point position.
Explanation is at last, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, although with reference to preferred embodiment the present invention is had been described in detail, those of ordinary skill in the art is to be understood that, can make amendment or be equal to replacement technical scheme of the present invention, and not breaking away from aim and the scope of the technical program, it all should be encompassed in the middle of the claim scope of the present invention.

Claims (7)

1. compliant conductive film, it is characterized in that: described conductive film includes the two sheets of flexible transparent membrane, between the two sheets of flexible transparent membrane, be provided with two-layer graphene conductive layer, between two-layer graphene conductive layer, be provided with a plurality of for the transparent insulation point of isolating two-layer graphene conductive layer.
2. a kind of compliant conductive film as claimed in claim 1, it is characterized in that: described transparent insulation point is ultra-violet curing glue particle.
3. a kind of compliant conductive film as claimed in claim 1 is characterized in that: described graphene conductive layer is made up of the Graphene of one deck to ten layer.
4. a kind of compliant conductive film as claimed in claim 3; it is characterized in that: described Graphene is pure Graphene; adopt chemical vapour deposition technique, at gaseous carbon sources and protective condition growth Graphene, again the Graphene of growth is transferred on the flexible and transparent film.
5. a kind of compliant conductive film as claimed in claim 3; it is characterized in that: described Graphene is doped graphene; adopt chemical vapour deposition technique; the Graphene of growing under the condition of gaseous carbon sources and protection gas; the Graphene of growth is transferred on the flexible and transparent film, it is soaked doping in containing the chemical doping reagent solution.
6. a kind of compliant conductive film as claimed in claim 3; it is characterized in that: described Graphene is doped graphene; adopt chemical vapour deposition technique; the Graphene of growing under the condition of gaseous carbon sources and protection gas; the Graphene of growth is transferred on the flexible and transparent film, carried out metal nanoparticle again and mix.
7. a kind of compliant conductive film as claimed in claim 3; it is characterized in that: described Graphene is the Graphene with metal grill; adopt photoetching or lithographic technique to make the metal grill structure at the flexible and transparent film; adopt chemical vapour deposition technique; the Graphene of under gaseous carbon sources and protective condition, growing, and the Graphene of growth is transferred on the flexible and transparent film with metal grill.
CN201310147338.5A 2013-04-25 2013-04-25 A kind of flexible conductive film Active CN103236280B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104333975A (en) * 2014-11-13 2015-02-04 中国科学院重庆绿色智能技术研究院 Flexible circuit based on graphene
CN104952717A (en) * 2014-03-26 2015-09-30 苏州汉纳材料科技有限公司 Carbon-material-based transparent conducting film, industrialized preparation method and application thereof
CN105734525A (en) * 2014-12-10 2016-07-06 黑龙江鑫达企业集团有限公司 Method for preparing graphene thin film through chemical vapor deposition
CN108108063A (en) * 2018-01-26 2018-06-01 江西合力泰科技有限公司 The four line pure-surface electric resistance touch screens and its recognition methods that a kind of low-cost and easy-to makes
WO2021051634A1 (en) * 2019-09-17 2021-03-25 武汉华星光电半导体显示技术有限公司 Resistive touch screen and flexible display apparatus

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CN101852935A (en) * 2010-06-02 2010-10-06 北京富纳特创新科技有限公司 Touch liquid crystal display
CN102191476A (en) * 2011-04-11 2011-09-21 兰州大学 Method for preparing sulfur-doped graphene films
CN102392225A (en) * 2011-07-22 2012-03-28 中国科学院上海微系统与信息技术研究所 Method for preparing graphene nanoribbon on insulating substrate
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CN101676832A (en) * 2008-09-19 2010-03-24 清华大学 Desktop computer
CN101852935A (en) * 2010-06-02 2010-10-06 北京富纳特创新科技有限公司 Touch liquid crystal display
CN102191476A (en) * 2011-04-11 2011-09-21 兰州大学 Method for preparing sulfur-doped graphene films
US20120280946A1 (en) * 2011-05-02 2012-11-08 Shih Hua Technology Ltd. Touch input device
CN102392225A (en) * 2011-07-22 2012-03-28 中国科学院上海微系统与信息技术研究所 Method for preparing graphene nanoribbon on insulating substrate

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104952717A (en) * 2014-03-26 2015-09-30 苏州汉纳材料科技有限公司 Carbon-material-based transparent conducting film, industrialized preparation method and application thereof
CN104952717B (en) * 2014-03-26 2018-04-06 苏州汉纳材料科技有限公司 Transparent conductive film based on carbon material, its industrialization preparation method and application
CN104333975A (en) * 2014-11-13 2015-02-04 中国科学院重庆绿色智能技术研究院 Flexible circuit based on graphene
CN104333975B (en) * 2014-11-13 2017-07-28 重庆石墨烯研究院有限公司 A kind of flexible circuit based on graphene
CN105734525A (en) * 2014-12-10 2016-07-06 黑龙江鑫达企业集团有限公司 Method for preparing graphene thin film through chemical vapor deposition
CN108108063A (en) * 2018-01-26 2018-06-01 江西合力泰科技有限公司 The four line pure-surface electric resistance touch screens and its recognition methods that a kind of low-cost and easy-to makes
WO2021051634A1 (en) * 2019-09-17 2021-03-25 武汉华星光电半导体显示技术有限公司 Resistive touch screen and flexible display apparatus

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