CN103206020B - Laminated layer structures - Google Patents
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- CN103206020B CN103206020B CN201210092474.4A CN201210092474A CN103206020B CN 103206020 B CN103206020 B CN 103206020B CN 201210092474 A CN201210092474 A CN 201210092474A CN 103206020 B CN103206020 B CN 103206020B
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Abstract
The invention provides a kind of laminated layer structures, base material is provided with the insulation material layer be made up of organic foaming body, the face side of this insulation material layer is provided with layer of cover material, this layer of cover material forms by one or more cladding material is stacked, more than at least one of this cladding material comprises resinous principle and heat absorption material.This laminated layer structures while guarantee building thermal insulation, can improve its heat resistance.
Description
Technical field
The present invention relates to a kind of laminated layer structures of novelty.
Background technology
In recent years, expense of being saved cold air and heating installation by height heat insulationization and height airtightization prevailing in the buildings such as commercial facility, apartment, only house, realizes the saving of the energy and resource.Usually, do not implementing in the building of Design on thermal insulation, time winter supplies heating installation, indoor hot gas can push up from room, floor, window, the position such as wall shed, time summer opens cold air, outdoor hot gas can invade indoor from these positions.
In order to suppress this heat waste, realize the saving of the resource of building, high heat insulationization is carried out to the above-mentioned various position for isolating indoor and outdoors and is absolutely necessary.Address that need, have already been proposed the multiple scheme being provided with the structure of thermal insulation material.Such as, on the exterior wall surface of building, the heat-barrier material such as polystyrene foam or phenol formaldehyde foam is set, and then the structure that layer arranges layer of cover material is widely known by the people (such as patent document 1 etc.) thereon.
Patent document 1: JP 2005-155216 publication
But, the heat-barrier material that this lamination structure adopts, once under being placed in high temperature, easily deform, burning etc., thus heat resistance is not enough.If use the heat-barrier material with self fire extinguishing property etc., although be expected to improve heat resistance, be sometimes difficult to according to the difference of condition reach the effect fully improving heat resistance.
Summary of the invention
The present invention in view of the above problems, its object is to provide a kind of laminated layer structures, while guarantee building thermal insulation, can improve its heat resistance.
In order to reach above-mentioned purpose, present inventor has performed conscientious research, result is expected folding the insulation material layer be made up of organic foaming body and the layer of cover material formed by specific cladding material at the layers on substrates of separating building thing indoor and outdoor, finally completes the present invention.
That is, the present invention has following characteristics:
1, a laminated layer structures, it is the laminated layer structures on building, it is characterized in that:
Base material is provided with the insulation material layer be made up of organic foaming body, layer of cover material is set in the face side of this insulation material layer;
This layer of cover material forms by one or more cladding material is stacked;
More than at least one of this cladding material comprise resinous principle and heat absorption material.
2, the laminated layer structures according to scheme 1, described layer of cover material has multicolor patterns and/or relief pattern.
3, the laminated layer structures according to scheme 1, more than at least one of described cladding material comprises organic resin and silicon matter as resinous principle.
4, the laminated layer structures according to scheme 1, layer of cover material forms by least two or more cladding materials is stacked, and at least two or more of this cladding material comprise resinous principle and heat absorption material.
Invention effect
Laminated layer structures of the present invention can improve heat resistance, and can also obtain the decorative appearance with excellent aesthetic property.
Detailed description of the invention
Below, embodiments of the present invention are described.
Laminated layer structures of the present invention can be applicable to the indoor of separating building thing with on outdoor position.Especially, laminated layer structures of the present invention is specially adapted on the external surface of building.When being applicable on skin wall, towards outdoor side, insulation material layer, layer of cover material are stacked gradually to the base material forming external surface.
Wherein, base material can adopt such as: concrete, mortar, cement board, extruded sheet, slate flat board, PC plate, ALC plate, fiber reinforced cement board, metal species wallboard, ceramic-like wallboard, ceramic wafer, calcium silicate board, plastic plate, hard wood cement board, brick and tile, ceramic tile etc.This base material also can comprise existing film layer etc.
Insulation material layer makes building have thermal insulation.Insulation material layer can use the heat-barrier material be made up of organic foaming bodies such as polystyrene foam, poly-mephenesin Carbamate foam, poly-phenol formaldehyde foams.The insulation material layer be made up of this organic foaming body has low-thermal conductivity and excellent heat-proof quality.The organic foaming body of tabular can use bonding adhesive or metal parts etc. to be fixed on base material.The thickness of insulation material layer is not particularly limited, is generally about 5 ~ 150mm.
In the present invention, the surface surface of outdoor side (be preferably) of insulation material layer is provided with layer of cover material.Layer of cover material of the present invention by stacked one or more cladding material and formed.Each cladding material of formation layer of cover material comprises the resinous principle as bond material.
In the present invention, form more than at least one of the cladding material of layer of cover material and comprise resinous principle and heat absorption material.The present invention, by using this cladding material, can improve heat resistance with this.
Heat absorption material is the metallic compound of releasing water by heating.This heat absorption material produces steam when heating, and improves heat resistance by its heat-absorbing action.
This heat absorption material can be enumerated such as: the metal hydroxides such as aluminium hydroxide, magnesium hydroxide, calcium hydroxide, barium hydroxide, strontium hydroxide, scandium hydroxide; The metal borates such as borax (sodium tetraborate), eight boric acid disodiums, Firebrake ZB; Zeolite, galapectite, allophane, entringite etc.; Also can use wherein one or more.As heat absorption material, particularly preferably metal hydroxides.
Relative to the solid constituent of the resinous principle of 100 weight portions, the ratio of heat absorption material is preferably 10 ~ 800 weight portions, is more preferably 20 ~ 600 weight portions, more preferably 40 ~ 500 weight portions, best preferably 60 ~ 400 weight portions.If heat absorption material adopts above-mentioned ratio, then can obtain the effect fully improving heat resistance.
Can use such as the resinous principle in cladding material: vinyl acetate resin, mylar, alkyd resins, vinyl chloride resin, epoxy resin, acrylic resin, mephenesin Carbamate resin, acrylic acid silicones, fluororesin etc.Also can use wherein one or more.In addition, above-mentioned resinous principle also can be the material with cross-linking reaction.
In the present invention, form more than at least one of the cladding material of layer of cover material, expect to comprise organic resin and silicon matter as resinous principle.If use the cladding material comprising the resinous principle (hereinafter simply referred to as " compound resin ") of organic resin and silicon matter, then can improve effect of the present invention further.The generation type of this compound resin can be enumerated as: the mode mixed with silicon matter by organic resin, the mode etc. that organic resin and silicon matter are reacted.The weight ratio of organic resin and silicon matter, is converted by solid constituent and is preferably 100: 10 ~ 100: 90, be more preferably 100: 15 ~ 100: 70.When meeting this scope, the layer of cover material with excellent heat resistance can be formed.Although its mechanism of action it be unclear that, but inventor infers, may be also there is aeration owing to using the layer of cover material of above-mentioned compound resin not only to have heat resistance, therefore when laminated layer structures of the present invention is exposed to high temperature, on the inside that the imflammable gas produced by isolation layer is difficult to be trapped in laminated layer structures or top layer, thus effectively can suppress burning.
In described compound resin, can list above-mentioned various resin as organic resin, wherein acrylic resin most preferably.Acrylic resin can by making various acrylic acid monomer polymerization reaction take place or by making various acrylic acid monomer and other monomer generation copolyreaction and obtaining.Wherein, acrylic acid monomer can be enumerated such as: () alkyl acrylate such as methyl () acrylate, ethyl () acrylate, isopropyl () acrylate, positive butyl ester () acrylate, isobutyl group () acrylate, n-hexyl () acrylate, 2-ethylhexyl () acrylate, cyclohexyl () acrylate, phenyl () acrylate, benzyl () acrylate; The acrylic acid monomer containing carboxyl such as () acrylic acid; N-methylamino ethyl ester () acrylate etc. are containing amino acrylic acid monomer; The acrylic acid monomer containing amide groups such as () acrylamide; The acrylic acid monomer containing carbonyl such as acetone () acrylamide; The acrylic acid monomer containing hydroxyl such as 2-hydroxy ethyl ester () acrylate; The acrylic acid monomer of () third rare nitrile etc. containing itrile group; The acrylic acid monomer etc. containing hydrolyzable silyl group such as γ-methoxy silane acrylic acid third fat.
In above-mentioned compound resin, silicon matter can be enumerated as silica, silicone etc., is especially applicable to using silica.
This silica, such as, can manufacture for raw material with silicate of soda, lithium metasilicate, potassium silicate, silicate compound.Wherein, can enumerate such as silicate compound: tetramethoxy-silicane, tetraethoxysilane, four positive propoxy silane, tetraisopropoxysilan, four n-butoxy silane, tetraisobutoxy-silicane alkane, four sec-butoxy silane, four tert-butoxy silane, four phenolic silanes etc., or the polymer etc. of these silicate compounds.Also catalyzer etc. can be used during fabrication.In addition, the contained metals such as catalyzer, until after manufacturing, can be removed by ion-exchange treatment etc. by manufacture process.The particle diameter of silica is preferably 1 ~ 200nm, is more preferably 3 ~ 100nm.
This compound resin, particularly preferably comprises the compound resin of emulsion acrylic resin and silica.Wherein, the emulsion acrylic resin emulsion acrylic resin that preferably can react with silica.Specifically, that preferably can react with the silanol group that exists in silica, that there is hydroxyl, hydrolyzable silyl group etc. (selective hydrolysis silicyl) functional group emulsion.By using this resinous principle, effect of the present invention can be improved further.
When forming layer of cover material of the present invention, the cladding material that can use can be exemplified below:
(A1) cladding material of resinous principle and heat absorption material is comprised;
(A2) cladding material (not comprising heat absorption material) of resinous principle is comprised.
Deng (following, (A1) and (A2) is collectively referred to as " A type ").
Further, comprise the cladding material of preferred resin composition, can be enumerated as:
(B1) comprise the cladding material of compound resin and heat absorption material, compound resin wherein comprises organic resin and silicon matter;
(B2) comprise the cladding material (not comprising heat absorption material) of compound resin, compound resin wherein comprises organic resin and silicon matter.
Deng (following, (B1) and (B2) is collectively referred to as " Type B ").
In the present invention, adopt one or more formation individual layers of above-mentioned cladding material or two-layer above layer of cover material, more than at least one of cladding material comprise resinous principle and heat absorption material (above-mentioned (A1) or above-mentioned (B1)).That is, form layer of cover material each layer among, more than one deck be at least comprise resinous principle and heat absorption material layer (layer formed by above-mentioned (A1) or above-mentioned (B1)).
The form of layer of cover material of the present invention, can list form as follows:
(1) when layer of cover material is made up of individual layer
Now, the cladding material of (A1) or (B1) is used to form the layer of cover material of individual layer.
(2) when layer of cover material is made up of bilayer
Now, in the first layer of cover material and the second layer of cover material, at least one deck is formed by (A1) or (B1).Such as, by the lamination of following cladding material, the first layer of cover material/the second layer of cover material can be formed successively in the face side of insulation material layer.
(A1)/{ (A1), (A2), (B1) or (B2) }
(A2)/{ (A1) or (B1) }
(B1)/{ (A1), (A2), (B1) or (B2) }
(B2)/{ (A1) or (B1) }
In this form, any or all preferred Type B of the first layer of cover material and the second layer of cover material, or at least the second layer of cover material (layer of cover material most top layer) preferably Type B.
(3) when layer of cover material is formed by more than three layers
Now, among each layer of formation layer of cover material, at least one deck is formed by (A1) or (B1).And then, in the present invention, at least preferred Type B in most top layer of layer of cover material.
As described in above-mentioned (2) (3), when cladding material is by when forming more than two-layer, preferably at least two-layerly to be formed by (A1) or (B1) above.Thus, multilayer comprises heat absorptivity material, effect of the present invention can be played further thus.
Form the cladding material of this layer of cover material, as long as meet above-mentioned condition, various form can be adopted.Specifically, the form as the cladding material that can use can be enumerated such as: synthetic resin emulsion coating, have the flat painting coating such as light type synthetic resin emulsion coating, non-aqueous dispersion type resin enamel; Architectural decorative coating (such as, the scumbling type decorative paint such as lysine coating, single layer elastomeric coating of JISA6909 defined; Ash paste paint uniform thickness painting type decorative paint; Multilayer decorative coating etc.); Other coating of multi-colour pattern, imitative stone decoration coating, sandstone style decorative paint etc.In addition, the various subbings, bottom adjustment coating etc. (polymer cement etc.) that comprise resinous principle also can be used as cladding material of the present invention.In addition, the various clean coating comprising resinous principle also can be used as cladding material of the present invention.It is the water-based cladding material of medium that these cladding materials preferably comprise with water.Also the tabular sheet material be shaped by these wet type cladding materials in advance can be used as cladding material of the present invention.
Layer of cover material of the present invention, in its last decorative appearance, preferably has multicolor patterns and/or relief pattern.This layer of cover material can improve aesthetic property by these patterns.In addition, said multicolor patterns refers to the pattern that the color of more than at least dichromatism mixes with cognizable state herein.In addition, relief pattern refers to the picture on surface with about about 0.2 ~ 5mm difference of height.
Multicolor patterns, such as, can be formed by using coating of multi-colour pattern, imitative stone decoration coating etc.In addition, also multicolor patterns can be formed by using the different multiple cladding materials of color to carry out part application etc.
Relief pattern, such as can by using above-mentioned architectural decorative coating, imitating stone decoration coating, sandstone style decorative paint etc. and formed.
In the application of cladding material, known coating tool can be used.Coating tool can use such as: drencher, roller, hairbrush, trowel etc.
The coating amount of cladding material, suitably can set according to the material used and the kind of coating tool, the surface configuration etc. of layer of cover material.When application, can dilute cladding material as required.
When layer of cover material is formed relief pattern, suitably can select the kind of coating tool and its using method.Thereby, it is possible to formed various relief pattern (such as: sand wall shape, pomelo peel shape, fiber wall shape, wavy, grey pulpous state, concavo-convex, the moon planar, comb draws shape, worm-eaten shape etc.).After cladding material application, before its cover layer (layer of cover material) drying, by dandyprat, trowel, hairbrush, comb, scraper etc., painting face is processed, thus various relief pattern can be formed.
In addition, layer of cover material also can be made in the present invention to form joint pattern.When joint pattern is formed, such as, can adopt and joint filler is closely attached on coated surface, after application cladding material, remove the method etc. of this joint filler.
The present invention between insulation material layer and layer of cover material or the inside of layer of cover material can be provided with the enhancement Layer be made up of reticulate body etc.The intensity of laminate, durability, breakage-proof, heat resistance etc. can be improved by arranging above-mentioned enhancement Layer.This enhancement Layer is embedded to the mode of the inside of layer of cover material by the most applicable employing.Especially preferred mode is when layer of cover material is by when forming more than two-layer, enhancement Layer is imbedded the inside of the layer (first layer of cover material) adjacent with insulation material layer.
Embodiment
In embodiment shown below, feature of the present invention definitely is described.
(cladding material)
As cladding material, prepare following various cladding material.
Cladding material 1
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing heat absorption material (aluminium hydroxide) 25 weight portion, calcium carbonate 255 weight portion, titanium oxide 80 weight portion, coalescents 8 weight portion, viscosity adjusting agent 3 weight portion, dispersing agent 2 weight portion, defoamer 3 weight portion and water 60 weight portion, thus manufacture cladding material 1.This cladding material 1 is equivalent to synthetic resin emulsion coating.
Cladding material 2
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing heat absorption material (aluminium hydroxide) 55 weight portion, calcium carbonate 225 weight portion, titanium oxide 80 weight portion, coalescents 8 weight portion, viscosity adjusting agent 3 weight portion, dispersing agent 2 weight portion, defoamer 3 weight portion and water 60 weight portion, thus manufacture cladding material 2.This cladding material 2 is equivalent to synthetic resin emulsion coating.
Cladding material 3
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing heat absorption material (aluminium hydroxide) 90 weight portion, calcium carbonate 190 weight portion, titanium oxide 80 weight portion, coalescents 8 weight portion, viscosity adjusting agent 3 weight portion, dispersing agent 2 weight portion, defoamer 3 weight portion and water 60 weight portion, thus manufacture cladding material 3.This cladding material 3 is equivalent to synthetic resin emulsion coating.
Cladding material 4
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing heat absorption material (aluminium hydroxide) 140 weight portion, calcium carbonate 140 weight portion, titanium oxide 80 weight portion, coalescents 8 weight portion, viscosity adjusting agent 3 weight portion, dispersing agent 2 weight portion, defoamer 3 weight portion and water 60 weight portion, thus manufacture cladding material 4.This cladding material 4 is equivalent to synthetic resin emulsion coating.
Cladding material 5
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing heat absorption material (aluminium hydroxide) 350 weight portion, titanium oxide 80 weight portion, coalescents 8 weight portion, viscosity adjusting agent 3 weight portion, dispersing agent 2 weight portion, defoamer 3 weight portion and water 80 weight portion, thus manufacture cladding material 5.This cladding material 5 is equivalent to synthetic resin emulsion coating.
Cladding material 6
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing calcium carbonate 280 weight portion, titanium oxide 80 weight portion, coalescents 8 weight portion, viscosity adjusting agent 3 weight portion, dispersing agent 2 weight portion, defoamer 3 weight portion and water 60 weight portion, thus manufacture cladding material 6.This cladding material 6 is equivalent to synthetic resin emulsion coating.
Cladding material 7
Vinyl acetate resin 100 weight portion, portland cement 1250 weight portion, heat absorption material (aluminium hydroxide) 380 weight portion, silica sand 2000 weight portion, water 750 weight portion and additive 5 weight portion are carried out Homogeneous phase mixing by common method, thus manufactures cladding material 7.This cladding material 7 is equivalent to bottom adjustment coating.
Cladding material 8
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing heat absorption material (aluminium hydroxide) 210 weight portion, aggregate (mixture of yellow aggregate, black aggregate, brown aggregate, gypsum rubrum) 550 weight portions, coalescents 10 weight portion, viscosity adjusting agent 4 weight portion, defoamer 2 weight portion and water 110 weight portion, thus manufacture cladding material 8.This cladding material 8 is equivalent to imitative stone decoration coating.
Cladding material 9
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing calcium carbonate 210 weight portion, aggregate (mixture of yellow aggregate, black aggregate, brown aggregate, gypsum rubrum) 550 weight portions, coalescents 10 weight portion, viscosity adjusting agent 4 weight portion, defoamer 2 weight portion and water 110 weight portion, thus manufacture cladding material 9.This cladding material 9 is equivalent to imitative stone decoration coating.
Cladding material 10
Relative to the silica composite acrylic resin emulsion (weight 50% of solid constituent of 250 weight portions, acrylic resin containing hydrolyzable silyl group: silica=100: 25 (solid constituent ratios), the average grain diameter 15nm of silica), by common method Homogeneous phase mixing heat absorption material (aluminium hydroxide) 210 weight portion, aggregate (yellow aggregate, black aggregate, brown aggregate, the mixture of gypsum rubrum) 550 weight portions, coalescents 10 weight portion, viscosity adjusting agent 4 weight portion, defoamer 2 weight portion and water 110 weight portion, thus manufacture cladding material 10.This cladding material 10 is equivalent to imitative stone decoration coating.
Cladding material 11
Relative to the silica composite acrylic resin emulsion (weight 50% of solid constituent, the acrylic resin containing hydrolyzable silyl group: silica=100: the average grain diameter 15nm of 25 (solid constituent ratios), silica) of 250 weight portions, by common method Homogeneous phase mixing calcium carbonate 210 weight portion, aggregate (mixture of yellow aggregate, black aggregate, brown aggregate, gypsum rubrum) 550 weight portions, coalescents 10 weight portion, viscosity adjusting agent 4 weight portion, defoamer 2 weight portion and water 110 weight portion, thus manufacture cladding material 11.This cladding material 11 is equivalent to imitative stone decoration coating.
Cladding material 12
Relative to the silica composite acrylic resin emulsion (weight 50% of solid constituent, the acrylic resin containing hydrolyzable silyl group: silica=100: the average grain diameter 5nm of 25 (solid constituent ratios), silica) of 250 weight portions, by common method Homogeneous phase mixing calcium carbonate 210 weight portion, aggregate (mixture of yellow aggregate, black aggregate, brown aggregate, gypsum rubrum) 550 weight portions, coalescents 10 weight portion, viscosity adjusting agent 4 weight portion, defoamer 2 weight portion and water 110 weight portion, thus manufacture cladding material 12.This cladding material 12 is equivalent to imitative stone decoration coating.
Cladding material 13
Relative to the silica composite acrylic resin emulsion (weight 50% of solid constituent, the acrylic resin containing hydrolyzable silyl group: silica=100: the average grain diameter 5nm of 17 (solid constituent ratios), silica) of 234 weight portions, by common method Homogeneous phase mixing calcium carbonate 210 weight portion, aggregate (mixture of yellow aggregate, black aggregate, brown aggregate, gypsum rubrum) 550 weight portions, coalescents 10 weight portion, viscosity adjusting agent 4 weight portion, defoamer 2 weight portion and water 110 weight portion, thus manufacture cladding material 13.This cladding material 13 is equivalent to imitative stone decoration coating.
Cladding material 14
Relative to the silica composite acrylic resin emulsion (weight 50% of solid constituent, the acrylic resin containing hydrolyzable silyl group: silica=100: the average grain diameter 5nm of 33 (solid constituent ratios), silica) of 267 weight portions, by common method Homogeneous phase mixing calcium carbonate 210 weight portion, aggregate (mixture of yellow aggregate, black aggregate, brown aggregate, gypsum rubrum) 550 weight portions, coalescents 10 weight portion, viscosity adjusting agent 4 weight portion, defoamer 2 weight portion and water 110 weight portion, thus manufacture cladding material 14.This cladding material 14 is equivalent to imitative stone decoration coating.
Cladding material 15
By grey resin particle (with emulsion acrylic resin, black iron oxide, yellow iron oxide, titanium oxide and water are the particle of the coloured material of main component, particle diameter is about 3mm), Dark grey resin particle is (with emulsion acrylic resin, black iron oxide, yellow iron oxide, titanium oxide and water are the particle of the coloured material of main component, particle diameter is about 4mm), and black resin particle is (with emulsion acrylic resin, black iron oxide and water are the particle of the coloured material of main component, particle diameter is about 2mm) be distributed in aqueous medium (comprising emulsion acrylic resin), thus manufacture cladding material 15.In addition, the weight ratio of grey resin particle, Dark grey resin particle and black resin particle is 35: 35: 30.This cladding material 15 is equivalent to coating of multi-colour pattern.
Cladding material 16
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing calcium carbonate 140 weight portion, titanium oxide 20 weight portion, aggregate (gypsum rubrum) 200 weight portion, coalescents 10 weight portion, viscosity adjusting agent 3 weight portion, defoamer 2 weight portion and water 80 weight portion, thus manufacture cladding material 16.This cladding material 16 is equivalent to sandstone style decorative paint.
Cladding material 17
Relative to the emulsion acrylic resin (weight of solid constituent accounts for 50%) of 200 weight portions, by common method Homogeneous phase mixing calcium carbonate 1200 weight portion, titanium oxide 30 weight portion, coalescents 15 weight portion, viscosity adjusting agent 1 weight portion, defoamer 3 weight portion and water 250 weight portion, thus manufacture cladding material 17.This cladding material 17 is equivalent to Multilayer decorative coating.
Cladding material 18
At basic unit (glass non-woven fabric: thickness 0.4mm, level ground amount (weight of every square metre) 50g/m
2) above, with coating amount 4.0kg/m
2shower coat cladding material 9, and make its at 80 DEG C dry 1 hour, thus obtain cladding material 18.This cladding material 18 is equivalent to imitative stone slice building materials.
< test example I>
(embodiment 1)
Slate flat board is pasted the base material of tabular polystyrene foam (thickness 50mm) in this, as coating object.To on whole of this base material, with coating amount 0.15kg/m
2shower coat as the cladding material 1 of the first cladding material, after carrying out the sclerosis of 2 hours, with coating amount 4.0kg/m
2shower coat is as the cladding material 9 of the second cladding material.Thereafter, the sclerosis of 7 days is carried out, in this, as test body.In addition, above step is all carried out under standard state (temperature 23 DEG C, relative humidity 50%).
(evaluating 1: heat-resistance test)
This test utilizes gas burner to heat 30 seconds to test body surface (cladding material side), after stopping heating, observes its attack time and state.Its result is as shown in table 1.In addition, stop the state after heating, extremely small the representing with A of distortion, representing with D of significantly distortion occurs, evaluates with A > B > C > D tetra-grades.
In embodiment 1, heating stops within latter 20 seconds, stopping with combustion and being out of shape small (evaluate B).
(embodiment 2) ~ (embodiment 16), (comparative example 1) ~ (comparative example 2)
As shown in table 1, except using the first cladding material, the second cladding material, adopt the method identical with embodiment 1 to test.Its result is as shown in table 1.
(embodiment 17)
Similarly to Example 1 to whole of base material, with coating amount 0.15kg/m
2shower coat as the cladding material 4 of the first cladding material, and pastes cladding material 18, carries out the sclerosis of 7 days.Test body is made by above method.In addition, above step is all carried out under standard state (temperature 23 DEG C, relative humidity 50%).Test by the test body that method obtains identical with embodiment 1.Its result is as shown in table 1.
(embodiment 18)
Similarly to Example 1 to whole of base material, with coating amount 2kg/m
2the cladding material 7 as the first cladding material is smeared, after carrying out sclerosis in 24 hours, with coating amount 0.15kg/m with trowel
2shower coat as the cladding material 4 of the second cladding material, carry out 2 hours sclerosis after, with coating amount 4.0kg/m
2shower coat, as the cladding material 9 of the 3rd cladding material, carries out the sclerosis of 7 days.Test body is made by above method.In addition, above step is all carried out under standard state (temperature 23 DEG C, relative humidity 50%).Test by the test body that method obtains identical with embodiment 1.Its result is as shown in table 1.
(embodiment 19) ~ (embodiment 20)
As shown in table 1, except using the first cladding material, the second cladding material, the 3rd cladding material, adopt the method identical with embodiment 18 to test.Its result is as shown in table 1.
< tests II>
With above-described embodiment 4,8,9,10 for object, implement the heat-resistance test of following evaluation 2.
(evaluating 2: heat-resistance test)
This test utilizes gas burner to heat 45 seconds to test body surface (cladding material side), after stopping heating, observes its attack time and state.Its result is as shown in table 1.In addition, metewand is identical with evaluation 1.
[table 1]
Claims (2)
1. a laminated layer structures, it is the laminated layer structures on building, it is characterized in that:
Base material is provided with the insulation material layer be made up of organic foaming body, the face side of this insulation material layer is provided with layer of cover material;
This layer of cover material forms by one or more cladding material is stacked;
More than at least one of this cladding material comprise resinous principle and heat absorption material,
Relative to the solid constituent of the resinous principle of 100 weight portions, the ratio of heat absorption material is 10 ~ 800 weight portions,
Described resinous principle comprises the emulsion acrylic resin and silica with hydrolyzable silyl group.
2. laminated layer structures according to claim 1, is characterized in that: described layer of cover material has multicolor patterns and/or relief pattern.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012006832 | 2012-01-17 | ||
| JP2012-006832 | 2012-01-17 | ||
| JP2012024599A JP6108424B2 (en) | 2012-01-17 | 2012-02-08 | Laminated structure |
| JP2012-024599 | 2012-02-08 |
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| Publication Number | Publication Date |
|---|---|
| CN103206020A CN103206020A (en) | 2013-07-17 |
| CN103206020B true CN103206020B (en) | 2016-01-06 |
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| CN107795079A (en) * | 2016-08-30 | 2018-03-13 | 菊水化工（上海）有限公司 | Surface decoration material |
| CN108000984A (en) * | 2016-10-31 | 2018-05-08 | 菊水化工（上海）有限公司 | laminate |
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| CN101956429A (en) * | 2010-09-02 | 2011-01-26 | 海聚高分子材料科技（广州）有限公司 | High flame retardant polyurethane rigid foam outer wall thermal insulation system |
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- 2012-03-31 CN CN201210092474.4A patent/CN103206020B/en not_active Expired - Fee Related
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| GB2083088A (en) * | 1980-07-19 | 1982-03-17 | Yoshida Kogyo Kk | Aluminium hydroxide-based building materials and method for manufacturing same |
| WO1993021406A1 (en) * | 1992-04-10 | 1993-10-28 | BAILEY, Michael, Leonard | Building panel and buildings made therefrom |
| CN2249780Y (en) * | 1994-02-28 | 1997-03-19 | 彭奇琨 | Sandwich boards for construction |
| CN1132187A (en) * | 1994-08-02 | 1996-10-02 | 斯太莱工业株式会社 | Refractory quilt complex compsn. and outer wall panel board of building and its outer wall structure |
| CN1530382A (en) * | 2003-02-27 | 2004-09-22 | 爱克工业株式会社 | Monomer containing colloidal silica, solidified resin composition and resin solidified article thereof |
| CN1594178A (en) * | 2004-06-23 | 2005-03-16 | 任知理 | Thermal insulation energy-saving decoration tile and its making method |
| CN101956429A (en) * | 2010-09-02 | 2011-01-26 | 海聚高分子材料科技（广州）有限公司 | High flame retardant polyurethane rigid foam outer wall thermal insulation system |
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| CN103206020A (en) | 2013-07-17 |
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