CN103195528A - Method and device for generating power through low-temperature waste gas waste in industrial furnace production technology - Google Patents
Method and device for generating power through low-temperature waste gas waste in industrial furnace production technology Download PDFInfo
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- 239000002912 waste gas Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 238000005516 engineering process Methods 0.000 title description 3
- 239000002699 waste material Substances 0.000 title description 2
- 238000010248 power generation Methods 0.000 claims abstract description 40
- 239000002918 waste heat Substances 0.000 claims abstract description 36
- 238000000605 extraction Methods 0.000 claims abstract description 23
- 239000007789 gas Substances 0.000 claims abstract description 21
- 238000001816 cooling Methods 0.000 claims abstract description 14
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 13
- 239000003546 flue gas Substances 0.000 claims description 13
- 239000000498 cooling water Substances 0.000 claims description 11
- 238000011084 recovery Methods 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 9
- 238000000746 purification Methods 0.000 claims description 9
- 239000012530 fluid Substances 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 230000005611 electricity Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
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- 238000005272 metallurgy Methods 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明公开了一种工业窑炉生产工艺低温废气余热发电方法与装置,是以发电机组的取热设备代替现有工艺中的冷却装置,或者直接将取热设备放置在工业窑炉废气出口,通过膨胀机、放热设备、高压工质泵与取热设备之间构成的循环回路驱动膨胀机带动低温热双循环发电机做功发电,提取工业窑炉排空废气中的低品位余热,对废气降温的同时,将吸收的热量送到发电机组中转化成电能,发电后的废气再回到原工艺系统或者排放到大气中。以有效提高低品位工业窑炉排空余热的利用率,降低企业运行成本,减轻对环境的热污染。
The invention discloses a method and device for power generation of low-temperature waste gas waste heat in the production process of an industrial kiln. The cooling device in the existing process is replaced by the heat extraction equipment of the generator set, or the heat extraction equipment is directly placed at the exhaust gas outlet of the industrial kiln. The expansion machine is driven by the circulation loop formed by the expander, heat release equipment, high-pressure working fluid pump and heat extraction equipment to drive the low-temperature thermal double-cycle generator to generate power and extract the low-grade waste heat from the exhaust gas of industrial kilns, which is beneficial to the exhaust gas. While cooling down, the absorbed heat is sent to the generator set to be converted into electrical energy, and the waste gas after power generation is returned to the original process system or discharged into the atmosphere. In order to effectively improve the utilization rate of low-grade industrial kiln exhaust waste heat, reduce enterprise operating costs, and reduce thermal pollution to the environment.
Description
技术领域 technical field
本发明涉及一种废气余热的回收发电方法及其装置,特别是涉及一种对工业窑炉生产工艺中排放的废热气体实施降温冷却,利用冷却过程中排放的余热实施发电,达到废热回收利用的方法和装置。 The present invention relates to a waste gas waste heat recovery power generation method and its device, in particular to a method for cooling the waste heat gas discharged in the production process of an industrial kiln, and using the waste heat discharged in the cooling process to generate electricity to achieve waste heat recovery and utilization Methods and Apparatus.
背景技术 Background technique
能源是国民经济的物质基础,经济发展的原动力,能源的高效利用是经济可持续发展的重要保证。工业余热的回收利用在节能减排中成为愈来愈重要的角色,目前,高温和中温废气余热回收发电技术已经得到了广泛推广,但是对于低温余热,目前是以换热利用为主,大量的低品位余热以废热的形式直接排放。 Energy is the material basis of the national economy and the driving force behind economic development, and the efficient use of energy is an important guarantee for sustainable economic development. The recovery and utilization of industrial waste heat has become an increasingly important role in energy conservation and emission reduction. At present, high-temperature and medium-temperature exhaust gas waste heat recovery and power generation technologies have been widely promoted, but for low-temperature waste heat, heat exchange is currently the main method, and a large number of Low-grade waste heat is directly discharged in the form of waste heat.
工业窑炉是陶瓷、冶金、建材、石化等行业中对物料或工件进行冶炼、焙烧、烧结、熔化、加热等的至关重要的热工装备,也是能源消耗和环境热污染的重要源头。工业窑炉排空的废气热值占窑炉总能耗的20%以上,但废气的余热利用率仅为4-5%,节能潜力巨大,解决工业窑炉设备的节能问题,对于上述工业乃至我国国民经济的可持续发展都具有重大的促进作用。 Industrial kiln is a vital thermal equipment for smelting, roasting, sintering, melting, heating, etc. of materials or workpieces in ceramics, metallurgy, building materials, petrochemical and other industries, and it is also an important source of energy consumption and environmental thermal pollution. The calorific value of the waste gas exhausted by industrial kilns accounts for more than 20% of the total energy consumption of the kiln, but the waste heat utilization rate of the waste gas is only 4-5%, and the energy saving potential is huge. Solving the energy saving problem of industrial kiln equipment is very important for the above industries and The sustainable development of our country's national economy has a significant role in promoting.
通常烟气余热利用的途径主要有:1、装设预热器,利用烟气预热助燃空气和燃料;2、装设余热锅炉,产生热水或蒸汽,以供生产或生活用;3、利用烟气作为低温炉的热源或用来预热冷的工件或炉料。回收烟气余热的最有效和应用最广的是换热器,其余热初步利用后的废气排放温度在200℃以下。 Usually, the ways to utilize flue gas waste heat mainly include: 1. Install a preheater to preheat combustion-supporting air and fuel with flue gas; 2. Install a waste heat boiler to generate hot water or steam for production or domestic use; 3. Use the flue gas as a heat source for a low temperature furnace or to preheat a cold workpiece or charge. The most effective and widely used method for recovering flue gas waste heat is the heat exchanger, and the exhaust gas discharge temperature after the initial utilization of the waste heat is below 200°C.
随着我国经济的高速发展,我国工业对电力资源的需求越来越大。若将窑炉排空废气中的余热转化成电能供企业自身使用,则会实现企业经济效益和环境效益的双赢。 With the rapid development of my country's economy, my country's industrial demand for power resources is increasing. If the waste heat in the exhaust gas of the kiln is converted into electric energy for the enterprise's own use, it will achieve a win-win situation for the economic and environmental benefits of the enterprise.
发明内容 Contents of the invention
本发明的目的是提供一种工业窑炉生产工艺低温废气余热发电的方法与装置,将低温热双循环发电技术应用于工业提取窑炉初步利用之后的排空废气余热,以减少余热排放和提高能源利用率。 The purpose of the present invention is to provide a method and device for power generation with low-temperature waste gas waste heat in the production process of industrial kilns. The low-temperature thermal double-cycle power generation technology is applied to the waste heat of exhausted waste gas after the initial utilization of industrial kilns, so as to reduce waste heat discharge and improve energy efficiency.
现有的工业窑炉生产工艺中,经初步利用后的废气或者直接排空,或者经过物料回收、废气净化后再排空,这样热量最终被排放到大气中,形成浪费和热污染。 In the existing industrial kiln production process, the exhaust gas after preliminary utilization is either directly emptied, or emptied after material recovery and exhaust gas purification, so that the heat is finally discharged into the atmosphere, resulting in waste and heat pollution.
本发明的工业窑炉生产工艺低温废气余热发电方法是以低温热双循环发电机组的取热设备代替现有工艺中的冷却装置,或者直接将取热设备放置在工业窑炉废气出口,提取工业窑炉排空废气中的低品位余热,在对废气降温的同时,将吸收的热量送到发电机组中转化成电能,发电后的废气再回到原工艺系统或者排放到大气中。这样,有效提高了低品位工业窑炉排空余热的利用率,降低了企业的运行成本,减轻了对环境的热污染。 The low-temperature waste gas waste heat power generation method of the industrial kiln production process of the present invention is to replace the cooling device in the existing process with the heat extraction equipment of the low-temperature thermal double-cycle generator set, or directly place the heat extraction equipment at the exhaust gas outlet of the industrial kiln to extract industrial The kiln evacuates the low-grade waste heat in the waste gas. While cooling the waste gas, it sends the absorbed heat to the generator set to convert it into electrical energy. After power generation, the waste gas is returned to the original process system or discharged into the atmosphere. In this way, the utilization rate of low-grade industrial kiln exhaust waste heat is effectively improved, the operating cost of the enterprise is reduced, and the heat pollution to the environment is reduced.
本发明的工业窑炉生产工艺低温废气余热发电装置包括通过废气管路依次连接的工业窑炉废气初步利用装置、取热设备和物料回收或烟气净化装置,并在取热设备上连接有发电机组。其中,所述的发电机组由低温热双循环发电机、膨胀机、放热设备和高压工质泵组成,膨胀机、放热设备与取热设备之间构成供发电介质流动的循环回路,并在所述循环回路上设置驱动发电介质流动的高压工质泵,低温热双循环发电机连接在膨胀机上,由膨胀机带动做功发电。在放热设备上还设置有冷却水回路。 The low-temperature waste gas and waste heat power generation device of the industrial kiln production process of the present invention includes a preliminary utilization device for industrial kiln waste gas, a heat extraction device, and a material recovery or flue gas purification device connected in sequence through an exhaust gas pipeline, and a power generation device is connected to the heat extraction device. unit. Wherein, the generator set is composed of a low-temperature thermal double-cycle generator, an expander, heat release equipment and a high-pressure working medium pump, and a circulation loop for the flow of power generation medium is formed between the expander, heat release equipment and heat extraction equipment, and A high-pressure working medium pump that drives the flow of the power generation medium is arranged on the circulation loop, and a low-temperature thermal double-cycle generator is connected to the expander, which is driven by the expander to generate power. A cooling water circuit is also provided on the exothermic equipment.
本发明工业窑炉生产工艺低温废气余热发电装置的工作过程是:工业窑炉产生的废气经过废气初步利用装置后,进入取热设备,在其中与发电介质进行热交换,发电介质变成高压气态进入膨胀机,膨胀机膨胀做功带动发电机运转产生电能。发电之后的低压气液两相发电介质进入放热设备,与冷却水进行热交换,变成液态,之后经高压工质泵送入取热设备中,继续吸收废气热量,同时冷却水将带走的热量释放后循环使用。与发电介质热交换降温后的废气进入物料回收或烟气净化装置,经处理后排空。 The working process of the low-temperature waste gas waste heat power generation device of the industrial kiln production process of the present invention is: the waste gas produced by the industrial kiln passes through the waste gas preliminary utilization device, enters the heat extraction equipment, and exchanges heat with the power generation medium in it, and the power generation medium becomes a high-pressure gaseous state Entering the expander, the expander expands and does work to drive the generator to run to generate electricity. After power generation, the low-pressure gas-liquid two-phase power generation medium enters the heat release equipment, exchanges heat with cooling water, and becomes liquid, and then pumps it into the heat extraction equipment through high-pressure working fluid to continue to absorb the heat of the exhaust gas, and at the same time the cooling water will take it away After the heat is released, it can be recycled. After heat exchange with the power generation medium, the exhaust gas enters the material recovery or flue gas purification device, and is emptied after treatment.
本发明将低温热双循环发电机组与工业窑炉废气的余热系统相结合,将初步利用后废气中的余热回收进行发电,其发电后的最低温度可达到50℃,节能效果显著。同时本发明的余热发电工艺不影响原有工艺的正常运转,具有双重功能,达到了节能减排的目的。 The invention combines the low-temperature thermal double-cycle generator set with the waste heat system of industrial kiln waste gas, and recovers the waste heat in the waste gas after preliminary utilization to generate electricity. The lowest temperature after power generation can reach 50°C, and the energy saving effect is remarkable. At the same time, the waste heat power generation process of the present invention does not affect the normal operation of the original process, has dual functions, and achieves the purpose of energy saving and emission reduction.
附图说明 Description of drawings
图1是本发明工业窑炉生产工艺低温废气余热发电装置的结构示意图。 Fig. 1 is a schematic structural diagram of a low-temperature waste gas waste heat power generation device for an industrial kiln production process of the present invention.
图中:1-废气,2-工业窑炉废气初步利用装置,4-冷却水进口,5-冷却水出口,6-物料回收或烟气净化装置,7-废气排空通道,8-取热设备,9-发电机组,10-低温热双循环发电机,11-膨胀机,12-高压工质泵,13-放热设备。 In the figure: 1-exhaust gas, 2-industrial kiln exhaust gas preliminary utilization device, 4-cooling water inlet, 5-cooling water outlet, 6-material recovery or flue gas purification device, 7-exhaust gas evacuation channel, 8-heat extraction Equipment, 9-generator set, 10-low temperature thermal double cycle generator, 11-expander, 12-high pressure working medium pump, 13-exothermic equipment.
具体实施方式 Detailed ways
以下结合附图对本发明的装置和方法做进一步说明。 The device and method of the present invention will be further described below in conjunction with the accompanying drawings.
如图1所示的工业窑炉生产工艺低温废气余热发电装置,包括通过废气管路依次连接的工业窑炉废气初步利用装置2、取热设备和物料回收或烟气净化装置6,并在取热设备8上连接有发电机组9。发电机组8由低温热双循环发电机10、膨胀机11、放热设备13和高压工质泵12组成,其中膨胀机11、放热设备13和高压工质泵12与取热设备8共同构成供发电介质流动的循环回路,取热设备8的输出端连接膨胀机11的输入端,膨胀机11的输出端连接放热设备13的输入端,放热设备13的输出端连接高压工质泵12后,接入取热设备8的输入端。低温热双循环发电机10连接在膨胀机11上,由膨胀机11带动做功发电。在放热设备13上连接有冷却水进口4和冷却水出口5构成冷却水回路,对发电介质进行冷却。
As shown in Figure 1, the low-temperature waste gas waste heat power generation device for industrial kiln production process includes a
工业窑炉产生的废气1经过工业窑炉废气初步利用装置2后,进入取热设备8,在其中与发电介质进行热交换,发电介质变成高压气态进入膨胀机11,使膨胀机11膨胀做功带动低温热双循环发电机10运转,产生电能。发电之后的低压气液两相发电介质进入放热设备13,与冷却水进行热交换,变成液态,之后经高压工质泵12,将液态发电介质送入取热设备8中,继续吸收废气热量,同时冷却水将带走的热量释放出后循环使用。与发电介质热交换降温后的废气1进入物料回收或烟气净化装置6,经处理后通过废气排空通道7排空。
The
以某建材工厂为例,在其生产工艺中,窑炉内温度1300℃,从窑内出来的废气经过余热锅炉后降温至180℃,排放量9万m3/h。原工艺采用冷却降温,经冷却降温和烟气净化后排入空气中,余热资源未被利用。 Taking a building material factory as an example, in its production process, the temperature inside the kiln is 1300°C, the exhaust gas from the kiln is cooled to 180°C after passing through the waste heat boiler, and the emission volume is 90,000 m3/h. The original process uses cooling and cooling, and after cooling and flue gas purification, it is discharged into the air, and the waste heat resources are not used.
采用本发明工艺方法后,用取热设备代替原来的冷却装置,在保证烟气净化的前提下进行余热发电,发电后烟气温度降至50℃。 After adopting the technological method of the present invention, the heat extraction equipment is used to replace the original cooling device, and waste heat power generation is carried out on the premise of ensuring the purification of the flue gas, and the temperature of the flue gas drops to 50° C. after power generation.
180℃和50℃空气的焓值分别为455.39kJ/kg和323.63kJ/kg,取热设备吸收的热量Q为2531kW,其发电功率P为127kW。 The enthalpy values of air at 180°C and 50°C are 455.39kJ/kg and 323.63kJ/kg respectively, the heat Q absorbed by the heat extraction equipment is 2531kW, and its power generation P is 127kW.
若日运行时间按24小时、年运行时间按330天计算,年发电量可达1002280kWh,节省标准煤350吨/年,减少二氧化碳排放764吨/年。若电价按照0.8元/度计算,则可为企业节约电费80万元/年,具有明显的环境效益和经济效益。 If the daily operation time is 24 hours and the annual operation time is 330 days, the annual power generation can reach 1002280kWh, saving 350 tons of standard coal per year and reducing carbon dioxide emissions by 764 tons per year. If the electricity price is calculated according to 0.8 yuan/kWh, it can save electricity costs of 800,000 yuan/year for enterprises, which has obvious environmental and economic benefits.
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CN103388990A (en) * | 2013-08-18 | 2013-11-13 | 佛山市广旭节能自动化科技有限公司 | Ceramic kiln waste heat utilization system |
CN104832235A (en) * | 2014-02-08 | 2015-08-12 | 山西易通环能科技集团有限公司 | Low temperature waste heat generating set using dead steam of paper mill |
CN105457440A (en) * | 2016-01-16 | 2016-04-06 | 杨德俊 | Device for achieving flue gas power generation and removing harmful substance in flue gas simultaneously |
CN106513426A (en) * | 2016-12-28 | 2017-03-22 | 山西易通环能科技集团有限公司 | Comprehensive resource utilization method for rural waste |
CN110159451A (en) * | 2019-03-08 | 2019-08-23 | 东方宏海新能源科技发展有限公司 | A kind of industrial furnace residual heat utilizes Stirling electricity generation system |
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CN103388990B (en) * | 2013-08-18 | 2015-07-22 | 广东工业大学 | Waste heat utilization system of ceramic kiln |
CN104832235A (en) * | 2014-02-08 | 2015-08-12 | 山西易通环能科技集团有限公司 | Low temperature waste heat generating set using dead steam of paper mill |
CN105457440A (en) * | 2016-01-16 | 2016-04-06 | 杨德俊 | Device for achieving flue gas power generation and removing harmful substance in flue gas simultaneously |
CN105457440B (en) * | 2016-01-16 | 2018-06-29 | 湘南学院 | The device of flue gas harmful substance is removed in a kind of flue gas power generation simultaneously |
CN106513426A (en) * | 2016-12-28 | 2017-03-22 | 山西易通环能科技集团有限公司 | Comprehensive resource utilization method for rural waste |
CN110159451A (en) * | 2019-03-08 | 2019-08-23 | 东方宏海新能源科技发展有限公司 | A kind of industrial furnace residual heat utilizes Stirling electricity generation system |
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