CN103189283B

CN103189283B - Aerosol container for multiple fluid discharge, multiple fluid discharge aerosol product, and internal container used therefor

Info

Publication number: CN103189283B
Application number: CN201180052402.0A
Authority: CN
Inventors: 寺元圭一郎
Original assignee: Daizo Corp
Current assignee: Daizo Corp
Priority date: 2010-10-29
Filing date: 2011-10-28
Publication date: 2015-01-07
Anticipated expiration: 2031-10-28
Also published as: JPWO2012057342A1; EP2634111A1; JP5952739B2; WO2012057342A1; CN103189283A; EP2634111A4; US20130284759A1

Abstract

To provide an internal container that is composed of a laminated sheet containing a metal foil layer that is resistant to degradation such as corrosion even if immersed in the content to be put in the container, an aerosol container for multiple fluid discharge provided therewith, and a multiple fluid discharge aerosol product. [Solution] A multiple fluid discharge type aerosol product (10) comprises: an outer container (11); an intermediate container (12) flexible enough to be inserted into the outer container; an internal container (13) flexible enough to be inserted into the intermediate container; and an aerosol valve (14) (hereinafter, valve) for closing the openings of these containers. The aerosol product independently stores and discharges two kinds of contents. The internal container is obtained by bonding one or more laminated sheets having the flexibility and provided with a metal foil layer and a synthetic resin layer, and is provided with a protection means on the end surface of the laminated sheet.

Description

Multiple liquid output automiser spray, multiple liquid export the internal container of spray product and use thereof

Technical field

The present invention relates to multiple liquid output automiser spray, internal container that multiple liquid exports spray product and use thereof.

Background technology

Automiser spray is for filling content and propellant in Pressure Container, by the pressure of propellant, content is outputted to outside container.As such automiser spray, receive multiple different content independently, and the automiser spray they side by side exported independently is well known.But, even if multiple content is accommodated in respective internal container respectively, if the internal container that synthetic resin is made, then also exist because of content through and situation about mixing.Particularly, when as hair dye be two contents react each other material, there is the problem losing the effect as product because content is mixed with each other.

Therefore, enumerated the automiser spray possessing inner bag, this inner bag uses at least has possessed the laminates of metal foil layer.

In patent documentation 1, disclose a kind of double-deck automiser spray, it is made up of external container and two inner bags be accommodated in wherein, in each inner bag, receive different contents.In addition, also disclose: as inner bag, be by overlapped by the sheet of lamination system, by the bonding structure of the right and left edge and upper and lower end parts of heat seal.

In Fig. 4 of patent documentation 2, disclose a kind of local cross-sectional shape, it possesses: the first pouch of filling first content thing; Filling second content, is contained in the second pouch in the first pouch; Be communicated with the first pouch and outside first flow path; The second stream being communicated with the second pouch and outside and the valve body linked with first flow path and the second stream.

At first technical literature

Patent documentation

Patent documentation 1: Japanese Unexamined Patent Publication 63-28684 publication

Patent documentation 2: Japanese Unexamined Patent Application Publication 2009-537403 publication

Summary of the invention

Invent problem to be solved

But as patent documentation 1, multiple inner bag be accommodated in external container and between external container and inner bag when filling spray agent, the round shape opening of two inner bags from external container must be being inserted, its operation easily becomes complicated.

On the other hand, in patent documentation 2, because the second pouch (the first space) is contained in the first pouch (second space), so in fact only inserted by the opening of the first pouch from external container, therefore, its operation becomes easy.But know, after being filled with content to each pouch, the second pouch becomes the state in the content that impregnated in the first pouch, the second pouch is easily deterioration because of the content in this first pouch.

The object of the invention is to, even if provide by having the internal container, the automiser spray possessing this internal container and the spray product that form at the laminates that impregnated in the metal foil layer being also difficult to the deteriorations such as generation corrosion under the state in content like this.

In order to solve the means of problem

Multiple liquid output automiser spray of the present invention, it possesses the internal container of the inside of external container and this external container of insertion, have by the first space formed in described internal container and surround the first space and independent of the second space in the first space, different contents is filled in the first space and second space respectively, wherein, described internal container is that one or more the laminates with flexibility possessing metal foil layer and synthetic resin layer is overlapping or folding overlapping in synthetic resin layer mode outwardly, then internal container outer peripheral edges have been bonded to each other, formed in the mode that the end face of described metal foil layer does not expose in second space.

In so multiple liquid output automiser sprays, also middle container can also be possessed, described middle container is inserted in external container, internal container is inserted in described middle container, described second space is made up of middle container, has the 3rd space independent of the first space and second space between described middle container and external container.

In multiple liquid output automiser spray of the present invention, preferably on the end face of described laminates, be provided with protection assembly.This protection assembly can be arranged after making described laminates bond, and also can arrange before bonding.

The internal container of multiple liquid output automiser spray of the present invention, the laminates preferably by end face bending is to the inside overlapping or folding overlapping, then by internal container that its outer edge has bonded mutually.

The internal container of multiple liquid output automiser spray of the present invention, preferably use the metal foil layer less than synthetic resin layer, the end of metal foil layer is positioned at the bonding part of synthetic resin layer.

Preferably form container in the end face ratio of the metal foil layer of the laminates of internal container of the present invention to give prominence to laterally.

In described arbitrary multiple liquid output automiser spray, also can make following structure: described first space is communicated with outside, being communicated with of disconnection and second space and outside, disconnection, operated by the opening and closing of a valve simultaneously.

In addition, carry out that the first space is communicated with outside, the valve of disconnection, from carry out being communicated with of second space and outside, disconnection valve different.

The feature that multiple liquid of the present invention exports spray product is, its by multiple liquid output automiser spray of the present invention, the first content thing be filled in described first space, be filled in the second content in described second space and the propellant be filled in described first space and/or second space is formed.

The feature that multiple liquid of the present invention exports the second form of spray product is, its by possess middle container of the present invention multiple liquid output automiser sprays, the first content thing be filled in described first space, be filled in the second content in described second space and the propellant be filled in described 3rd space is formed.

The feature that multiple liquid of the present invention exports the 3rd form of spray product is, its by possess middle container of the present invention multiple liquid output automiser sprays, the first content thing be filled in described first space, be filled in the second content in described second space and the propellant be filled in described 3rd space is formed.

Internal container of the present invention; it is for receiving in the automiser spray of multiple content independently; at least two contents are directly separated; it is characterized in that; the internal container of described automiser spray; be that one or more the flexible laminates that has possessing metal foil layer and synthetic resin layer is become the mode overlap of outside or folding overlap with synthetic resin layer, then by the internal container that its outer peripheral edges have been bonded to each other, the end face of described laminates be provided with protection assembly.

Second form of internal container of the present invention, it is for receiving in the automiser spray of multiple content independently, at least two contents are directly separated, it is characterized in that, the internal container of described automiser spray, with the mode bending towards inner side by one or more the end face with flexible laminates possessing metal foil layer and synthetic resin layer, the mode that laminates by this bending becomes outside with synthetic resin layer is overlapping or folding overlapping, then by internal container that its outer peripheral edges have been bonded to each other.

The effect of invention

Multiple liquid output automiser spray of the present invention, because the internal container being positioned at second space is by overlapping or folding overlapping in synthetic resin layer mode outwardly for the laminates possessing metal foil layer and synthetic resin layer, then internal container outer peripheral edges have been bonded to each other, formed in the mode that the end face of described metal foil layer does not expose in second space, so metal foil layer is difficult to the second content because being accommodated in second space and corrodes, durability is high.In addition, because internal container is made up of the laminates with metal foil layer, even if so in automiser spray filling two kinds of contents, also can prevent in the first space and second space content through, stably can take care of content.

In multiple liquid output automiser spray of the present invention, also possesses middle container, in this, container inserts in external container, internal container is inserted in container in this, described second space is made up of middle container, there is the 3rd space not only independent of the first space but also independent of second space between described middle container and external container, can with the kind of content, propellant correspondingly, they are accommodated in arbitrarily three in Pressure Container independently in space.

The end face of laminates is provided with protection assembly, the metal foil layer of the end face of laminates reliably can be covered.

The laminates that internal container has passed through end face bending is to the inside overlapping or folding overlapping, and then its outer edge is bonded to each other shaping, in the case, the end face of the metal foil layer of laminates is not exposed to the outside of internal container.

Internal container uses the metal foil layer less than synthetic resin layer, and the end of metal foil layer is positioned at the bonding part of synthetic resin layer, and in the case, the end face of the metal foil layer of laminates does not expose in second space.

In the end face ratio of laminates, container is given prominence to laterally, because the end face of laminates exposes in the outside of middle container, so the corrosion of the end face of the metal foil layer that can prevent the content because being accommodated in middle container (second space) from causing.

In described arbitrary multiple liquid output automiser spray, first space is communicated with outside, being communicated with of disconnection and second space and outside, disconnecting and being operated by the opening and closing of a valve simultaneously, in the case, output, the stopping of two liquid can be switched by single job.In addition, internal container externally the insertion of container and the installation of valve easy.In addition, the path in injecting-unit can be shortened, the residue in path can be reduced in output afterwards.

On the other hand, when carrying out that described first space is communicated with outside, the valve of disconnection with carry out being communicated with of second space and outside, disconnection valve different, as long as the easy structure of each valve one liquid output.From each valve filling content, can manufacture and become easy.In addition, if possess the injecting-unit two valves being carried out to opening and closing operations simultaneously, then can be switched output, the stopping of two liquid by single job, if possess the injecting-unit of independent operation two valves, then can export respectively.

Multiple liquid of the present invention exports spray product, because being made up of, so at least two liquid in many liquid stably can be taken care of multiple liquid output automiser spray of the present invention, the first content thing be filled in the first space, the propellant that is filled in the second content in described second space and is filled in described first space and/or second space.In addition, because first content thing and/or the second content and propellant can be exported, so the output state of the content such as foam and lotion, foam and gel can be changed simultaneously.

Multiple liquid of the present invention exports the second form of spray product, by possessing multiple liquid output automiser sprays of middle container of the present invention, the first content thing be filled in described first space, the propellant that is filled in the second content in described second space and is filled in described 3rd space form, so stably can take care of many liquid.

By possessing multiple liquid output automiser sprays of described middle container, the first content thing be filled in described first space, being filled in the second content in described second space and propellant and being present in the spray product that the gas in the 3rd space forms; owing to there is gas between middle container and external container; so when external container is metal can, external container can be protected further.

Internal container of the present invention; insert in the automiser spray of the multiple content of filling independently; at least two contents are directly separated; by the internal container that the laminates bonding possessing metal foil layer and synthetic resin layer is formed; owing to being provided with protection assembly on the end face of laminates, so do not have the metal foil layer in end face to expose.Therefore, be difficult to corrosion, durability is high.

Second form of internal container of the present invention, insert in the automiser spray of the multiple content of filling independently, at least two contents are directly separated, the internal container formed by will the laminates bonding of metal foil layer and synthetic resin layer be possessed, because pass through the end face of laminates with the mode bending towards inner side, the mode that laminates by this bending becomes outside with synthetic resin layer is overlapping or folding overlapping, then its outer peripheral edges are bonded to each other shaping, so there is no exposing of the metal foil layer in end face.Therefore, be difficult to corrosion, durability is high.

Accompanying drawing explanation

Fig. 1 represents that multiple liquid of the present invention exports the side cut away view of an embodiment of spray product.

Fig. 2 a, b, c are front elevation, lateral plan, the side cut away view of the internal container representing Fig. 1.

Fig. 3 is the side cut away view of the valve representing Fig. 1.

Fig. 4 a ~ Fig. 4 d is the process chart of the production process of the spray product representing Fig. 1.

Fig. 5 represents that multiple liquid of the present invention exports the side part sectional view of other embodiment of spray product.

Fig. 6 is the side cut away view of the valve representing Fig. 5.

Fig. 7 a ~ Fig. 7 d is the side cut away view of other form of the bonding part of the internal container representing Fig. 2, and Fig. 7 e is the front elevation cut away the local of the bonding part of Fig. 7 d.

Fig. 8 a, Fig. 8 b are block diagram, the section-drawing of the another form representing internal container of the present invention, and Fig. 8 c is the block diagram representing its bag.

Fig. 9 is the side cut away view of the valve linked with the internal container of Fig. 8 a.

Figure 10 is the front elevation of the another form representing internal container of the present invention.

Figure 11 is the block diagram of the embodiment representing screening glass of the present invention.

Figure 12 a is the front elevation of the state opened of the screening glass representing Figure 11, and Figure 12 b is the front elevation representing the state of having installed this screening glass in internal container, and Figure 12 c is the main portion section-drawing of the internal container representing the screening glass having installed Figure 12 b.

Figure 13 represents that multiple liquid of the present invention exports the side cut away view of the another embodiment of spray product.

Figure 14 represents that multiple liquid of the present invention exports the front cross-sectional view of the another embodiment of spray product.

Figure 15 is the birds-eye view of the injecting-unit of the spray product having pulled down Figure 14.

Figure 16 represents that multiple liquid of the present invention exports the side cut away view of the another embodiment of spray product.

Figure 17 is the birds-eye view of the spray product of Figure 16.

Figure 18 represents that multiple liquid of the present invention exports the side cut away view of the another embodiment of spray product.

Detailed description of the invention

In order to the mode carried out an invention

Multiple liquid output type spray products 10 shown in Fig. 1, possess external container 11, insert there is flexible middle container 12, insert there is flexible internal container 13 and close their spray valve (hereinafter referred to as valve) 14 of peristome in this in container in this external container, be that two kinds of contents is separate and receive and the spray product of the biliquid output type exported (multiple liquid output type) independent of propellant.In the present embodiment, (the first space S 1) storage first content thing A in internal container, in middle container, (second space S2) receives the second content B, (the 3rd space S 3) filling spray agent P in external container.That is, internal container 13 is present in the second content B.

External container 11 is the containers having bottom tube-like of resistance to pressure with bottom, body, shoulder, defines flanging part 11a in shoulder upper end.The neck of tubular also can be set between shoulder and flanging part.This external container 11 is the integrally formed product be shaped through overbump processing, stretch process etc. by the metal sheet such as aluminium or tin-plate.But, also can be the external container being linked multiple parts by double seam.In addition, also can be by other material forming such as synthetic resin or withstand voltage glass, but preferably there is the duromer of resistance to pressure.

Middle container 12 is the containers having bottom tube-like with flexibility with bottom, body, shoulder, defines flange part 12a in shoulder upper end.The neck of tubular also can be set between the shoulder of container and flange part hereinto.In addition, also more than neck, shoulder or body, wrinkle protective case can be set the lower mode bent.Middle container is like this lamination of individual layer or PE/EvOH/PE, PE/NY/PE etc. by having the forming synthetic resins such as polyolefin, ethylene-vinyl alcohol copolymer (EvOH), nylon (NY) such as flexible polyethylene (PE) and polypropylene (PP), can be exported by the second content B by being flattened by the thrust pressure of propellant P.Middle container 12, when not having metal foil layer, such as, can make parison bloat relative to forming die and be shaped.

Internal container 13, as shown in Fig. 2 a, b, c, the bag 16 be made up of, to be formed by the connecting member 17 that these two laminates clip bonding two laminates.Laminates is in the three-decker being provided with synthetic resin layer on the two sides of metal foil layer.But as long as possess the structure with flexibility of metal foil layer and synthetic resin layer, the outermost layer of a side is synthetic resin layer.Such as, can enumerate: also can be two layers that are made up of metal foil layer and synthetic resin layer, also it can be provided with different synthetic resin layers continuously in the one side side of metal foil layer three layers, also can be the three-decker being provided with identical or different synthetic resin layer on the two sides of metal foil layer, and the outermost layer of a side be the structure of more than four layers of synthetic resin layer.As metallic paper, aluminium foil (Al) etc. can be enumerated.As synthetic resin layer, polyethylene terephthalate (PET), polyethylene (PE), polypropylene (PP), ethylene-vinyl alcohol copolymer (EvOH), nylon (NY) etc. can be enumerated, such as, PET/Al/PET, PE/Al/PE, PET/Al/PE, PET/Al/NY, PE/EvOH/Al/PE, PE/EvOH/Al/PET, PE/EvOH/Al/NY etc.In addition, also can to surperficial steam coating silicon dioxide (Si), the aluminium oxide (Al of synthetic resin layer ₂o ₃), carbon (C) etc.Particularly when content is biliquid formula hair dye, preferably use PET/Al/PE, PE/Al/PE, PET/Al/NY, so that the face contacted with the second medicament of the acidity containing oxidizers such as hydrogen peroxide becomes PET or PE, become PE or NY with the face contacted with alkalescence first medicament of the alkalization medicament of ammonia etc. containing acid dye.

Bag 16 is shapes laminates being cut into regulation, take outer peripheral face as overlapping two laminates of mode of synthetic resin layer, is shaped by its outer peripheral edges of bonding such as thermally welded or ultrasonic wave coatings.In fig. 2 a, bonding part 18 is represented by dashed line.In addition, at the edge of this bonding part 18, throughout the all-round protective coat 18a be provided with as protection assembly.That is, bonding part 18 is positions of two laminates overlaps, but the Rotating fields comprising the metal foil layer of two laminates at its edge exposes.Therefore, by arranging the protection assemblies such as protective coat 18a at the edge of bonding part 18, the end face of the metal foil layer that the end face that can cover laminates exposes.Thus, end and the content of metallic paper can be solved, particularly as biliquid formula hair dye acidity the second medicament, alkaline first medicament reaction and produce soaking into from bonding portion of gas and peel off and then react and the problem of deterioration etc. with the first content thing in internal container.As such protective coat 18a, such as, following resinous coat, rubber coating etc. can be enumerated: this resinous coat is at the resinous coat fluorocarbon resin such as synthetic resin, polytetrafluoroethylene of the liquid such as epoxy novolac, epoxy urea, polyamidoimide being sprayed at bonding part, whole internal container forms resin involucra, or internal container be impregnated in the resinous coat forming resin involucra in the liquid resins such as epoxy novolac, epoxy urea, polyamidoimide on whole internal container; Or the hardness resins such as polyethylene, polyethylene terephthalate, nylon are carried out to bonding part, whole internal container the resinous coat etc. that electrostatic spraying forms resin involucra; This rubber coating internal container be impregnated in the rubber coating forming rubbery membrana dermalis in silaatic, neoprene etc. on whole internal container.In addition, also can whole outside face, bonding part steam coating silicon dioxide (Si), the aluminium oxide (Al of internally container ₂o ₃), carbon (C) etc. and vapor-deposited film is set.

Connecting member 17 is the cylindrical body possessing centre hole 17a through up and down, is made up of, forms the peristome of internal container 12 the bottom 19b of cross sectional shape to be roughly elliptoid top 19a and cross sectional shape be roughly round shape.Upper end and the valve described later 14 of top 19a link.Top 19a has flat cross sectional shape extending transversely, therefore large with the bond area of laminates.The end face being fixed on the laminates on this connecting member 17 is also provided with protective coat 18a.This connecting member 17 is made up of the structure covered by the adhesive resins such as polyester, polyurethane, polyolefin on stainless steel or the synthetic resin such as polyformaldehyde, nylon.

Because form like this, although so internal container 13 is that the laminates with metal foil layer is bonded shape, metal foil layer (end face of laminates) also can not be exposed to outside.Therefore, even if be filled with the content of biliquid response type in this automiser spray after, the corrosion to metal foil layer that the second content B, air, moisture etc. because being accommodated in second space S2 produce also can be prevented.Particularly actv. in the material situation that the second content B is reactive high.Like this, internal container 13 is preferably for the automiser spray of the content in order to output-response type.In addition, protective coat 18a also can be arranged at the end of laminates before overlapping layer lamination.

Valve 14, as shown in Figure 3, the mounting cup 21 (with reference to Fig. 1) curling by the flanging part 11a of externally container; Be held in the central authorities of this mounting cup, make two contents independently by housing 22; Move up and down and be freely contained in this housing, possess the valve rod 23 of the first valve rod hole 23a of downside and the second valve rod hole 23b of upside; The first valve rod rubber 24a of downside that two of opening and closing valve rod hole are separately cylindric and the second valve rod rubber 24b of upside; Be arranged between these valve rod rubber, the fixed parts 25 of the cylindrical shape near the outer circumference end of fixing each valve rod rubber; Upwards the spring 26 that this valve rod loads is formed at ordinary times.

Mounting cup 21 is known parts, has: bent flanges 21a (with reference to Fig. 1) curling on crimping 11a and the housing maintaining part 21b having bottom tube-like of maintenance housing 22.Mounting cup is such as made up of the metal sheet such as aluminium, tin-plate.

Housing 22 possesses bottom 31, possesses the connecting part 32 of the cylindrical shape extended from bottom surface downwards, possesses the flange part 33 given prominence to laterally on top.Connecting part 32 is embedded in the position in the centre hole 17a of connecting member 17.The intercommunicating pore 31a that centre hole 22a is communicated with connecting part 32 is defined at the center of bottom 31.The top inner face of housing defines the lower rubber maintaining part 22b of the valve rod rubber 24a keeping downside, upper end inner face defines the upper rubber maintaining part 22c of the valve rod rubber 24b keeping upside.In addition, define the slit 33a extended up and down at the flange part 33 of housing 22, from then on the upper end (between upper and lower rubber maintaining part 22b, 22c) of slit 33a defines through hole 33b to centre hole 21a.

Valve rod 23 possesses: the first recess 36a being annularly formed at side lower, annularly be formed at the second recess 36b in the middle part of side, the second centre hole 36c of the position of the second recess 36b is extended to from upper-center, with the first centre hole 36d extending to the ring-type of the position of the first recess 36a from upper end that the mode of surrounding this second centre hole 36c is formed, second valve rod hole 23b of the first valve rod hole 23a extending to the lower end of the first centre hole 36d from the first recess 36a and the lower end extending to the second centre hole 36c from the second recess 36b.In addition, form the upper end of the first cylindrical portion 36g of the first centre hole 36d, be configured at the position lower than the upper end of the second cylindrical portion 36f of formation second centre hole 36c.Thus, when from valve rod 23 to the first space S 1 and second space S2 filling respective content, can simply the side in the second centre hole 36c or the first centre hole 36d be stayed and seal.Therefore, it is possible to reliably filling content separately.

First valve rod rubber 24a and the second valve rod rubber 24b is that respective centre hole is with the first recess 36a and the second recess 36b keeps leak tightness while the parts of the ring-type engaged.

Fixed parts 25 is with go its internal diameter to become upward along with inner face parts that large mode has made the cylindrical shape of taper, clamp the first valve rod rubber 24a by lower end 25a and lower rubber maintaining part 22b, clamp the second valve rod rubber 24b by the inner face of upper end 25b and upper rubber maintaining part 22c and mounting cup.In addition, define inside and outside member passes hole 25c, to be communicated with the through hole 33c of housing.Fixed parts 25 is arranged between two valve rod rubber 24a, 24b, near the periphery fixing two valve rod rubber.In addition, prevent valve rod 23 come off beat and pushed valve rod 23 time, bend, so pushing of valve rod 23 can not be hindered owing to making the inner peripheral portion of valve rod rubber 24a, 24b.

Because form like this, so in valve housing 22, define the storage A room 30a of the storage first content thing divided by the first valve rod rubber 24a of the centre hole 22a of housing 22, valve rod 23 and downside, and the storage B room 30b of storage second content divided by upper and lower valve rod rubber 24a, 24b and fixed parts 25.

And, flow through the first content thing A come from connecting member 17, arrive through intercommunicating pore 31a and store A room 30a.On the other hand, be filled in the second content B in middle container to arrive store B room 30b through slit 33a, the through hole 33b of housing, the member passes hole 25c of fixed parts.

In addition, if push valve rod 23 downwards, then store first content thing A in the 30a of A room through the first valve rod hole 23a from the first centre hole 36d externally or injecting-unit (not shown) release, store the second content B in the 30b of B room through the second valve rod hole 23b from the second centre hole 36c externally or injecting-unit release.

Then, utilize Fig. 4 that the manufacture method of this automiser spray 10 is described.First, middle container 12 is inserted in external container 11, the second content B is filled to middle container 12 interior (with reference to Fig. 4 a).Now, the flange part 12a of middle container 12 is positioned at top than the flanging part 11a of external container 11.That is, the state that the upper end becoming middle container is given prominence to from external container.Then, conservation treatment is carried out to the end face of laminates, the internal container 13 being filled with first content thing A is linked with valve 14.Under the state of this link, in being inserted by internal container 13, container 12 is interior (with reference to Fig. 4 b, c).Now, internal container 13 is because being made up of laminates, so can fold simply or bend simply, its insertion be also simple.Time in internal container 13 is inserted in container 12, the bottom of internal container 13 arrive in container 12 bottom before, the flange part 12a of middle container 12 abuts with the inner face of the bent flanges 21a of mounting cup 21.That is, internal container 13 is supported by the flange part 12a of middle container 12, becomes state floating in middle container 12.

In the present embodiment, between bent flanges 21a and flange part 12a, be provided with the sealing element 37 of ring-type.Therefore, bent flanges 21a, sealing element 37 and flange part 12a pile up overlapping.But, sealing element 37 ground also can not be used to guarantee leak tightness in the mode of being flattened by the flange part 12a of middle container 12.In this case, the therefrom space filling propellant P of the downside of the flange part 12a of container 12 externally between container 11 and middle container 12 (direction of arrow, lower cup filling).And, by while filling spray agent P, the mounting cup 21 of valve 13 is riveted relative to external container 11, valve 14 is fixed on external container 11 to manufacture spray product (with reference to Fig. 4 d).In addition, first content thing also, can be filled in internal container 13 after valve 13 is fixed on external container 11 in filling spray agent while closedown second centre hole 36c.In the case, because internal container 13 can be made to shrink in an empty state, so become easy to the insertion of container 12, air does not enter in middle container.In addition, first three space S 3 of propellant externally between container 11 and middle container 12 can also be carried out lower cup filling, valve 13 is fixed on external container 11, then, after pushing valve rod and the air in the first space S 1 and second space S2 is discharged, from valve rod filling first content thing A and the second content B respectively simultaneously.

As the content be filled in this automiser spray 10, can enumerate, carry out the material reacted preferably by two kinds of contents mixed such as making biliquid formula hair dye, biliquid formula agent for permanent hair waving, biliquid formula lining cement.Particularly when filling biliquid formula hair dye, the aspect of disconnection effect of two kinds of liquid of being easy to get calmly is seen, the first medicament that preferably storage is alkaline in internal container (the first space S 1), the second medicament that storage is acid in middle container (second space S2).But, also can play effect of the present invention even if exchange.

In addition, as propellant, the blue gas etc. such as the pressure gas of nitrogen, carbon dioxide, nitrous oxide gas, pressurized air and their miscellaneous gas etc., autogas, dimethyl ether, HF hydrocarbon, hydrogen fluorohydrocarbon and their miscellaneous gas can be enumerated.

In addition, as the output form of content, except liquid, lotion, gel, can also be add the foaming agent such as normal butane or isopentane and at lotion, the gel of post-foaming exporting post-foaming.

Spray product 50 shown in Fig. 5, possesses external container 51, inserts the internal container 52 in this external container and closes their valve 53 of peristome, is the spray product making it stand upside down to carry out to operate.In addition, between external container 11 and internal container 52, be filled with the second content B and propellant P, in internal container 52, be filled with first content thing A.External container 51 is identical in fact with the external container 11 of Fig. 1.

Internal container 52 is made up of bag 56 and the connecting member 57 being fixed on this bag.In addition, protective coat 18a is provided with at the edge of bonding part 58.This internal container 52 except connecting member 57 be except cylindrical shape, identical in fact with the internal container 12 of Fig. 1.

Valve 53, as shown in Figure 6, is made up of the first valve rod rubber 64a of mounting cup 61, housing 62, valve rod 63, downside and the second valve rod rubber 64b of upside, cylindric fixed parts 65 and spring 66.Mounting cup 61 is identical in fact with valve rod rubber 24a, 24b with the mounting cup 21 of valve rod rubber 64a, 64b and Fig. 3.

Housing 62 is made up of the inner housing 71 of cylindrical shape and the body skin 72 that inserted by this inner housing.

Inner housing 71 by allowing the dynamic up and down centre hole 71a of valve rod, connecting member 57 to be inserted and the tubular connecting part 73 linked, the intercommunicating pore 74 being communicated with centre hole 71a and connecting part 73 and the locking rubber card bonding part 75 being formed at the first valve rod rubber 64a on inner face top are formed.In addition, inner housing 71 possesses the flange part 76 outstanding in the form of a ring to radial outside on top, defines the through hole 76a of this flange part 76 through up and down at this flange part 76.

Body skin 72 is parts of the cylindrical shape of the bottom 72b possessing the top 72a that abuts with the flange part 76 of inner housing 71 and cover with empty standard width of a room in an old-style house unoccupied place, the outside of inner housing 71.

The the second centre hole 63b extending to the ring-type of the position of the second recess 36b from upper end, the first valve rod hole 23a and the second valve rod hole 23b that valve rod 63 possesses the second recess 36b, the first centre hole 63a extending to the position of the first recess 36a from upper-center in the middle part of the first recess 36a of side lower, side, formed in the mode of surrounding this first centre hole 63a.In addition, the upper end forming the first cylindrical portion 63c of the first centre hole 63a is configured at the position higher than the upper end of the second cylindrical portion 63d of formation second centre hole 63b.Except the first centre hole 63a extend to the position of the first recess 36a of downside, the second centre hole 63b extends to except the position of the second recess 36b of upside, identical in fact with the valve rod 23 of Fig. 2, employs identical symbol respectively.

Fixed parts 65 is cylindric parts, defines stage portion 65a outstanding to radial outside upward.In addition, define at stage portion 65a and to be communicated with the through hole 76a of inner housing and to run through the through hole 65b of this stage portion 65a.

Because form like this, so there is the storage A room 70a of the storage first content thing divided by the first valve rod rubber 64a of the centre hole 71a of inner housing 71, valve rod 63 and downside, and storage B room 70b of storage second content divided by upper and lower valve rod rubber 64a, 64b and fixed parts 65.

And the first content thing A in internal container 12 arrives storage A room 70a through the intercommunicating pore 74 of inner housing.On the other hand, handstand state is become by making spray product 50, the second content B between external container 51 and internal container 52 is by the gap 77 between inner housing 71 and body skin 72, and pass through the through hole 76a of flange part 76 and the through hole 65a of fixed parts of inner housing, arrive and store B room 70b.

In addition, if push valve rod 63 downwards under the state that this stands upside down, then store first content thing A in the 70a of A room through the first valve rod hole 23a from the first centre hole 63a externally or injecting-unit (not shown) release, store the second content B in the 70b of B room through the second valve rod hole 23b from the second centre hole 63b externally or injecting-unit release.

The content of from then on spray product output, because the second content can be mixed together with blue gas, so can change output state as foam and lotion, foam and gel etc.In addition, the heat of gasification of blue gas can also be utilized to cool output and obtain cooling performance.

Bonding part 80a, b, c of Fig. 7 a, b, c, represent other form of the bonding part 18 of the internal container 13 of Fig. 2 or the internal container of Fig. 5, is by overlapping for the laminates of end warpage to the inside, by the bonding part that its outer edge is bonded to each other.

The bonding part 80a of Fig. 7 a, by the end 81a bending to the inside laminates once end 81a mode respect to one another with bending, that is, the mode that the end 81a with bending is configured at the inner side of internal container is overlapping, the bonding part that the position by this bending has been bonded to each other.Because form like this, so the end face of laminates is configured at the inner side of internal container, the metallic paper of constituting layer lamination can not contact with the second content B be accommodated in external container in the second content B or Fig. 5 being accommodated in middle container (second space S2) in Fig. 1.But, in the case, because the first content thing A in internal container contacts with the end 81a of laminates, so as first content thing A, preferably use reactive low material.

The bonding part 80b of Fig. 7 b is by end 81a bending to the inside once and by overlapping for the laminates of this bending part 81b bending to the inside further position mode respect to one another with bending, then by bonding part that its outer edge is bonded to each other.In the case, because end 81a is surrounded by laminates, so end 81a does not all expose at the inner face of internal container and outside.Therefore, the metallic paper of constituting layer lamination is not also exposed.

The bonding part 80c of Fig. 7 c is by overlapping for mode facing opposite to each other for the laminates of 81a bending to the inside in end once and then by this bending part 81b bending to the inside position with bending and the bonding part of bonding.In the case, also same with Fig. 7 b, end 81a does not all expose at inner face and outside.

Like this, bonding part 80a, b, c of Fig. 7 a, b, c, the end face of laminates does not expose in second space, can prevent the corrosion of the metallic paper produced because of the second content B in second space.

The bonding part 82 of Fig. 7 d is the bonding part bonded two at circumference with the laminates being layered in the three-decker that the synthetic resin sheet 83,84 on its two sides is formed by the metallic papers such as aluminium foil 85 respectively.As shown in figure 7e, metallic paper 85, than synthetic resin sheet 83,84 little, thus, when having bonded, can have been wrapped into the end of metallic paper 85, having prevented from exposing by inside and outside synthetic resin sheet 83,84.In addition, in the laminates of the such three-decker shown in Fig. 7 d, because synthetic resin sheet 83,83 abuts, so by being manufactured by thermoplastic base resin by the synthetic resin sheet 83 of inner face, can carry out heat seal in inner face side each other.When omitting synthetic resin sheet 83 of inner face side, by the synthetic resin sheet 84 of exterior side is carried out heat seal each other, and metallic paper 85 is bonded by lining cement joint etc. each other.

Fig. 8 is the figure that internal container 90 is integrated with middle 91 one-tenth, container, and in edge (end of the laminates) ratio of the bonding part of internal container 90, container is given prominence to.

Internal container 90 is made up of two laminates are overlapping and the bag 92 bonded its outer edge and the connecting member 93 be fixed on this bag, identical in fact with the internal container 52 of Fig. 5.

Middle container 91 is made up of middle bag 95 and two connecting members 96a, 96b, middle bag 95 is by being overlapped by laminates on the two sides of this internal container 90, two ingathering chambers 95a, 95b the bonding of its outer edge being formed are formed, two connecting members 96a, 96b and respective ingathering chamber 95a, 95b and ft connection, be fixed on middle bag 95.

That is, internal container 90 and middle container 91 refer to overlapping four laminates and define the parts in three independently spaces.Because form like this, so the edge of the bonding part 97 of internal container 90 (the end 97a of laminates) exposes in the outside of middle container 91.Therefore, can not contact with the content in ingathering chamber 95a, 95b of being accommodated in middle container 91.

The valve 100 of Fig. 9 is installed on internal container 90 and middle container 91, is made up of main body 101 and the installing component 102 being installed on its lower end.Main body 101 is valves 53 of Fig. 6, extends downwards with the lower end of body skin 72, and the mode that the lower end in the lower end of intercommunicating pore 74 and the gap 77 between inner housing 71 and body skin 72 becomes same position is formed.In addition, in the lower, outer perimeter of main body 101, define the engaging protrusion 101a for engaging with this installing component 102.Other structure, namely the second valve rod rubber 64b of the first valve rod rubber 64a of mounting cup 61, housing 62, valve rod 63, downside and upside, fixed parts 65 and spring 66, identical in fact with the valve 53 of Fig. 5.

Installing component 102 possesses three through holes 102a, b, c extending up and down.Its position relationship is as follows: through hole 102a is formed at center, and through hole 102b, c are formed at around through hole 102a, with the position consistency of connecting member 93,96a, b.

By being installed in main body 101 by installing component 102, the through hole 102a being formed at central authorities is communicated with the intercommunicating pore 74 of main body 101.Through hole 102b, c, be communicated with the gap 77 between inner housing 71 and body skin 72.

When internal container 90 is linked on valve 100, connecting member 93 and the through hole 102a of internal container 90 is linked, connecting member 96a, 96b of middle container 91 are linked with through hole 102b, c respectively.Thus, the first content thing A in internal container 90 is guided to and stores A room 70a, the second content B in middle container 91 is guided to and stores B room 70b.

The internal container 105 of Figure 10 is by a bag 106 laminates doubling its outer peripheral edges bonded, and the connecting member 107 be fixed on this bag 106 is formed.In addition, protective coat 18a is provided with at bonding part 18.But, also can be by the bending to the inside of the end of laminates, and then doubling, bonding outer peripheral edges.This internal container 105 is also same with other internal container, because the end of laminates is not exposed in second space, so be difficult to corrosion, durability is high.

Have employed protective coat 18a in the above-described embodiment, but also can such as the screening glass 108 of doubling covers in the outside of bonding part 18 by the carrying out shown in Figure 11, carry out joint by heat bonding etc. and make protection assembly.This screening glass 108 is that the mode that can expand with the bag 106 of the internal container 105 of Figure 10 arranges large window portion 109, and the frame 110 two having been made picture frame shape is interconnected at lateral margin, and has carried out the screening glass of doubling.The semicircular cylinder portion 111 that the connecting part 107 of Figure 10 is passed through is provided with in the central authorities of upper end.Screening glass 108 as figure 12 a shows, can be processed peristome 109 and the semicircular cylinder portion 111 at two positions, left and right, fold overlap to manufacture in central authorities on a sheet.

This screening glass 108, as shown in Figure 12 b and Figure 12 c, larger than the bonding part 18 of internal container 105, window portion 109 is less than the bonding part of internal container.Thereby, it is possible to sandwich the bonding part 18 of internal container 105 between two frames 110.And, if carry out thermally welded after sandwiching, then can cover the ora terminalis of bonding part 18.Thus, the metallic paper exposed from ora terminalis is not exposed.In addition, as the internal container 105 of Figure 10, when the lateral margin of a side does not have bonding part 18, the frame corresponding with this part can be omitted, such as, in the screening glass 108 of Figure 12 a, the frame of the longitudinal direction of central authorities can be omitted.In addition, as shown in Figure 11, Figure 12 a, except being formed except screening glass 108 by a sheet, also can be made up of two sheets.The screening glass in the outside of such covering bonding part 18, also can in middle employings such as the internal containers of Fig. 2 a, b, c.

Spray product 120 shown in Figure 13, has the external container 11 identical with the spray product 10 of Fig. 1, middle container 12, internal container 13 and valve 14, and then has installed injecting-unit 121 on the valve rod 23 of valve 14.In the first space S 1 in internal container 13, although be not particularly limited, such as, accommodate the first content thing A be made up of the liquid that the viscosity such as low liquid, lotion or the gel of viscosity are high.As first content thing A, when exporting, the aspect dripped from preventing liquid, the liquid that preferably viscosity such as lotion or gel is high.In second space S2 between middle container 12 and internal container 13, accommodate the second content B and the propellant P of show bubble output.As the second content B, can enumerate, when exporting under the state mixed with propellant, propellant slowly gasifies, the lotion of the post-foaming gradually foamed or gel, the lotion just exporting post-foaming, gel or low-viscosity liquid etc.By foaming, can prevent liquid from dripping.In addition, as propellant, can enumerate, the pressure gas, the blue gas that use in the spray product 10 of Fig. 1.In the 3rd space S 3 between external container 11 and middle container 12, not filling spray agent, the remaining air entered when middle container 12 is inserted outer receptacle 11.Other side is same with the spray product 10 of Fig. 1.

At injecting-unit 121, be provided with the first path 122 be communicated with the first centre hole 36d of valve rod 23 and the alternate path 123 be communicated with the second centre hole 36c.First path 122 is to surround the mode of the surrounding of alternate path 123 in concentrically extending.First path 122 is not communicated with alternate path 123.Therefore, first content thing A and the second content B is externally exported from injecting-unit 121, such as, when being coated on after mixing in palm or brush, pallet etc. on hair etc.When output is lotion, gel and foam, easily mixing, coating, and be difficult to drippage when applying.

In this spray product 120; internal container 13 also impregnated in the second content B; but; same with the situation of the spray product 10 of Fig. 1; do not expose, even if prevent the burn into of metal foil layer deteriorated so the second content B is reactive fluid because the end face of metal foil layer is covered by protection assemblies such as protective coats yet.In addition, in the 3rd space S 3 between external container 11 and middle container 12, because be filled with air, even if so external container 11 is metal by aluminium etc., also prevent corrosion.In addition, as the gas be present in the 3rd space S 3, except leaving the air of the existence when being accommodated in external container by middle container, also the gasifying gas of this air by nitrogen, blue gas can be replaced.In addition, also middle container can be made the single layer structure of PE etc., keep permeability to air, be filled to propellant in second space S2 therefrom container to the 3rd space S 3 through.

The spray product 120 of Figure 13, not filling spray agent between external container 11 and middle container 12, but propellant is filled with in middle container 12.Therefore, middle container 12 also can by the manufacture such as synthetic resin not having flexible hard.In addition, this propellant can not only push internal container, and first content thing is exported, and can also make the second content foaming.In addition, do not possess and the second content B is picked up and the dip-tube supplied to valve 14.Therefore, the spray product as the so-called inverted type making the second content B export under the state of standing upside down uses.

Spray product 125 shown in Figure 14, Figure 15, possesses two valves 126,127 for exporting two liquid and operates an injecting-unit 128 of these valves simultaneously.The above-mentioned spray product such as Fig. 1, Fig. 5, Figure 13 is all switched output simultaneously by a valve, disconnected the spray product of two liquid, make following structure: the path possessing separate dual system in the inside of valve, made its opening and closing by operation injecting-unit simultaneously.Therefore, the complex structure of valve.At this, in the spray product 125 of Figure 14, separate two valves 126,127 are closely installed on the oral area of external container 11 by a valve seat 129 and mounting cover 130.Thereby, it is possible to each valve 126,127 is made easy structure.Valve 126,127, valve seat 129 and mounting cover 130, be preferably assembled into valve module 131 in advance.

The bottom of valve seat 129 is chimeric with the upper end inner face of external container 11, has the hole (seat portion) (with reference to Figure 15) of maintenance two valves 126,127 on above.Each valve 126,127 has the housing 22 of tubular; Move up and down the valve rod 23 of the inside being freely contained in this housing 22; At ordinary times upwards to the spring 26 that this valve rod loads; Be configured at housing 22 above on, the valve rod rubber 24 of the valve rod hole of opening and closing valve rod 23; With the cap 132 this valve rod rubber is fixed on housing 22.

And, the internal container 13 forming the first space S 1 is installed in the lower end of the housing 22 of the first valve 126, in the lower end of the valve housing of the second valve 127, dip-tube 133 has been installed, be communicated with in the external container 11 forming second space S2.Even if being provided with in internal container 13 tails off for surplus also guarantee the protective tube 134 of stream.In this spray product 125, do not use the middle container of Fig. 1.Filling first content thing A in internal container 13, filling second content B and propellant P in external container 11.Internal container 13, same with Fig. 2 a ~ c, Fig. 7 a ~ e, Figure 10, Figure 12 a ~ c etc., all can adopt the internal container of above-mentioned pouch.This spray product 125 owing to having dip-tube 133, so can export under upright state.

In addition, the external container 11 of this spray product 125 is plastic Pressure Containers, and possess cylindric neck 135 in the upper end of body, periphery is provided with the flange 135a of heavy wall at its upper end.Valve module 131, for riveting the lower end of mounting cover 130, is fixed on external container 11 by this flange 135a.On mounting cover 130, the reinforced rib (with reference to Figure 15) for improving resistance to pressure is preferably set.

External container 11 is because be plastic, even if so directly accommodate the second content B, inner face is also difficult to corrosion.External container 11 also can adopt the synthetic resin with light transmission.In this case, can the surplus of visual confirmation second content B.In addition, the surplus of first content thing A can also be inferred by the inflation status of internal container 13.External container 11 such as can be shaped by biaxial stretch blow molding by synthetic resin such as polyethylene terephthalate, nylon, polypropylene.But, also can be shaped by injection molding.External container 11, in order to suppress the infiltration of the second content B, propellant, also can arrange the vapor-deposited film of carbon, aluminium oxide, silicon dioxide etc. on inner face and/or outside.

In this spray product 125, because the metal foil layer of internal container 13 does not also expose in outside, so metal foil layer does not directly contact the second content B.Therefore, the corrosion of metal foil layer is prevented.In addition, due to the path that can be flowed by two valves 126,127 opening and closing first content thing A and the second content B, so the structure of each valve is simple.In addition, the ratio of the output of first content thing A and the second content B can be regulated by the first valve 126 and the second valve 127.The ratio of the output of first content thing A and the second content B, by the size in the hole of selector valve rod aperture, housing bottom, can adjust in the scope of such as 1:1 ~ 1:5.

Spray product 136 shown in Figure 16, Figure 17, possesses container 12 in the synthetic resin system of the external container 11 be made up of metal can, the inside being accommodated in this external container, is accommodated in the valve module 131 of the peristome of container 12 and external container 11 in the internal container 13 of the inside of container 12 in this and blocking.External container 11, same with the external container 11 of Fig. 1 etc., be aluminum, there is in upper end flanging part 11a, in there being bottom tube-like.Middle container 12 also can use the middle container same with Fig. 1, such as, use the blow molded article of the synthetic resin of the three-decker of PE/EvOH/PE.

As for internal container 13, being also the pouch same with Fig. 1, is that bag-shaped container has been made in the lamination body piece bondings such as PE/PET/Al/PE (from inside to outside, or from outside to inside), PE/Al/PE.Be the first space S 1 in internal container 13, be filled with the first content thing A of lotion etc.The second content B of lotion etc. is filled with in second space S2 between internal container 13 and middle container 12.The propellant P for exporting first content thing A and the second content B is filled with in the 3rd space S 3 between middle container 12 and external container 11.As propellant P, such as, can adopt the pressure gas of nitrogen etc.

Valve module 131 is identical in fact with the valve module of Figure 14, is made up of the first valve 126, second valve 127, valve seat 129 and mounting cover 130.The top of mounting cover 130 as shown in figure 17, be aspect is elliptoid tubular or coniform, and bottom is in order to consistent with the oral area of external container 11 and made cylindrical shape.The lower end of mounting cover 130 is riveted on the flanging part 11a of the upper end of external container 11.About this spray product 136, because valve 126,127 is also arrange, so can select the ratio of output at design phase each content A, B.

Spray product 137 shown in Figure 18 the internal container 13 of the spray product 136 of Figure 16 is connected into the Deformational patterns of two.Because the first space S 1 in internal container 13 becomes twice, so when first content thing A is identical, its charging quantity can be increased.In addition, also can the first content thing A of the different kind of filling.Connect into two along with by internal container 13, the valve be arranged on valve module 131 is the first valve 138, second valve 139,140 3, the 3rd valve.Valve seat 129 keeps this three valves.First valve 126 of Figure 16 is equivalent at this said first valve 138 and the second valve 139.Other side is same with the spray product 136 of Figure 16, and internal container 13 is made up of the pouch of the above-mentioned metal foil layer of protection.The situation of three valves is being set as mentioned above, and then when arranging the 4th valve being used for filling gas, ellipticity is not made in the top of mounting cover 130, but makes cylindrical shape.

The explanation of symbol:

A: first content thing

B: the second content

P: propellant

S1: the first space

S2: second space

S3: the three space

10: spray product

11: external container

11a: flanging part

12: middle container

12a: flange part

13: internal container

14: spray valve (valve)

16: bag

17: connecting member

17a: centre hole

18: bonding part

18a: protective coat

19a: top

19b: bottom

21: mounting cup

21a: bent flanges

21b: housing maintaining part

22: housing

22a: the centre hole of housing

22b: lower rubber maintaining part

22c: upper rubber maintaining part

23: valve rod

23a: the first valve rod hole

23b: the second valve rod hole

24a: the first valve rod rubber

24b: the second valve rod rubber

25: fixed parts

25a: lower end

25b: upper end

25c: member passes hole

26: spring

30a: store A room

30b: store B room

31: the bottom of housing

31a: intercommunicating pore

32: the connecting part of housing

33: the flange part of housing

33a: slit

33b: through hole

36a: the first recess

36b: the second recess

36c: the second centre hole

36d: the first centre hole

36f: the second cylindrical portion

36g: the first cylindrical portion

37: sealing element

50: spray product

51: external container

52: internal container

53: valve

56: bag

57: connecting member

58: bonding part

61: mounting cup

62: housing

63: valve rod

63a: the first centre hole

63b: the second centre hole

63c: the first cylindrical portion

63d: the second cylindrical portion

64a: the first valve rod rubber

64b: the second valve rod rubber

65: fixed parts

65a: stage portion

65b: through hole

66: spring

70a: store A room

70b: store B room

71: inner housing

71a: centre hole

72: body skin

72a: top

72b: bottom

73: connecting part

74: intercommunicating pore

75: rubber card bonding part

76: flange part

76a: the through hole of flange part

77: gap

80a, b, c: bonding part

81a: the end of laminates

81b: bending part

82: bonding part

83,84: synthetic resin sheet

85: metallic paper

90: internal container

91: middle container

92: bag

93: connecting member

95: middle bag

95a, b: ingathering chamber

96a, b: connecting member

97: bonding part

97a: end

100: valve

101: main body

101a: engaging protrusion

102: installing component

102a, b, c: through hole

105: internal container

106: bag

107: connecting member

108: screening glass

109: window portion

110: frame

111: semicircular cylinder portion

120: spray product

121: injecting-unit

122: the first paths

123: alternate path

125: spray product

126: the first valves

127: the second valves

128: injecting-unit

129: valve seat

130: mounting cover

131: valve module

132: neck

133: dip-tube

134: protective tube

135: neck

135a: flange

136,137: spray product

138: the first valves

139: the second valves

140: the three valves

Claims

1. a multiple liquid output automiser spray, it possesses the internal container of the inside of external container and this external container of insertion,

Have by the first space formed in described internal container and surround the first space and independent of the second space in the first space,

Different contents is filled in the first space and second space respectively,

It is characterized in that, described internal container is that one or more the laminates with flexibility possessing metal foil layer and synthetic resin layer is overlapping or folding overlapping in synthetic resin layer mode outwardly, the internal container then outer peripheral edges be bonded to each other,

Formed in the mode that the end face of described metal foil layer does not expose in second space.

2. multiple liquid output automiser spray as claimed in claim 1, wherein,

Also possess middle container, described middle container is inserted in external container, in described middle container, be inserted into internal container,

Described second space is made up of middle container,

There is the 3rd space independent of the first space and second space between described middle container and external container.

3. multiple liquid output automiser spray as claimed in claim 1, wherein, the end face of described laminates is provided with protection assembly.

4. multiple liquid output automiser spray as claimed in claim 2, wherein, the end face of described laminates is provided with protection assembly.

5. multiple liquid output automiser spray as claimed in claim 1, wherein, described internal container is that the laminates by end face bending is to the inside overlapping or folding overlapping, then by internal container that its outer edge has bonded mutually.

6. multiple liquid output automiser spray as claimed in claim 2, wherein, described internal container is that the laminates by end face bending is to the inside overlapping or folding overlapping, then by internal container that its outer edge has bonded mutually.

7. multiple liquid output automiser spray as claimed in claim 1, wherein, described internal container uses the metal foil layer less than synthetic resin layer, and the end of metal foil layer is positioned at the bonding part of synthetic resin layer.

8. multiple liquid output automiser spray as claimed in claim 2, wherein, described internal container uses the metal foil layer less than synthetic resin layer, and the end of metal foil layer is positioned at the bonding part of synthetic resin layer.

9. multiple liquid output automiser spray as claimed in claim 2, wherein, in the end face ratio of described laminates, container is given prominence to laterally.

10. the multiple liquid output automiser sprays as described in any one in claim 1 ~ 9, wherein, described first space is communicated with outside, being communicated with of disconnection and second space and outside, disconnection, operated by the opening and closing of a valve simultaneously.

11. multiple liquid output automiser sprays as described in any one in claim 1 ~ 9, wherein, carry out that described first space is communicated with outside, the valve of disconnection, from carry out being communicated with of second space and outside, disconnection valve different.

12. 1 kinds of multiple liquid export spray product, it is characterized in that, its by the multiple liquid output automiser sprays described in any one in claim 1 ~ 11, the first content thing be filled in described first space, be filled in the second content in described second space and the propellant be filled in described first space and/or second space is formed.

13. 1 kinds of multiple liquid export spray product, it is characterized in that, its by the multiple liquid output automiser sprays described in any one in claim 2 ~ 9, the first content thing be filled in described first space, be filled in the second content in described second space and the propellant be filled in described 3rd space is formed.

14. 1 kinds of multiple liquid export spray product, it is characterized in that, its by the multiple liquid output automiser sprays described in any one in claim 2 ~ 9, the first content thing be filled in described first space, be filled in the second content in described second space and propellant and the gas be present in described 3rd space and form.

The internal container of 15. 1 kinds of automiser sprays, at least two contents, for receiving independently in the automiser spray of multiple content, directly separate by it, it is characterized in that,

The internal container of described automiser spray, that one or more the flexible laminates that has possessing metal foil layer and synthetic resin layer is become the mode overlap of outside or folding overlap with synthetic resin layer, then by internal container that its outer peripheral edges have been bonded to each other

The end face of described laminates is provided with protection assembly.

The internal container of 16. 1 kinds of automiser sprays, at least two contents, for receiving independently in the automiser spray of multiple content, directly separate by it, it is characterized in that,

The internal container of described automiser spray, with the mode bending towards inner side by one or more the end face with flexible laminates possessing metal foil layer and synthetic resin layer, the mode that laminates by this bending becomes outside with synthetic resin layer is overlapping or folding overlapping, then by internal container that its outer peripheral edges have been bonded to each other.