CN103161028A - Non-woven fabrics containing carboxymethyl cellulose fibers and purpose thereof in beauty mask substrate - Google Patents
Non-woven fabrics containing carboxymethyl cellulose fibers and purpose thereof in beauty mask substrate Download PDFInfo
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- CN103161028A CN103161028A CN201110416571XA CN201110416571A CN103161028A CN 103161028 A CN103161028 A CN 103161028A CN 201110416571X A CN201110416571X A CN 201110416571XA CN 201110416571 A CN201110416571 A CN 201110416571A CN 103161028 A CN103161028 A CN 103161028A
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Abstract
The invention relates to non-woven fabrics containing carboxymethyl cellulose fibers and a purpose of the non-woven fabrics containing the carboxymethyl cellulose fibers in a beauty mask substrate. The non-woven fabrics are composed of the carboxymethyl cellulose fibers or composed of the carboxymethyl cellulose fibers and any one kind of calcium alginate fibers, chitin fibers, chitosan fibers and modified chitosan fibers, wherein the content of the carboxymethyl cellulose fibers is 1%-95% of the weight of the non-woven fabrics. The invention further provides non-woven fabrics which are composed of the carboxymethyl cellulose fibers and any two kinds of the calcium alginate fibers, the chitin fibers, the chitosan fibers and the modified chitosan fibers, wherein the content of the carboxymethyl cellulose fibers is 1%-95% of the weight of the non-woven fabrics, and the weight ratio of the any two kinds of fibers is 1:8-8:1. The non-woven fabrics are strong in hygroscopicity, strong in moisture retention, strong in oxygen permeability, and have good biological compatibility, and are convenient to use, and safe and non-toxic.
Description
Technical field
The present invention relates to a kind of nonwoven fabric, more particularly, the present invention relates to a kind of purposes that contains the nonwoven fabric of carboxymethyl cellulose (CMC) fiber and be used for the beauty mask base material.
Background technology
Comparatively general a kind of facial cosmetic maintenance mode is that deployed high concentration maintenance Essence is adsorbed on facial mask cloth (paper) at present, stay in the time of skin to extend Essence, improve skin care ingredient to infiltration capacity and the length of penetration of skin, and change rapidly moisture content of skin.
From in essence, the aesthetic nursing process of skin is exactly the suction moisturizing process of skin, and its key is that face-mask material is skin moisturizing and moisturizing.For this reason, in the market facial mask cloth is the high-hygroscopicity macromolecular material.On market, popular facial mask cloth mostly is the blending nonwoven fabric of 30g-70g thickness, and the facial mask cloth that this kind method is made is recovery for want of, and product surface is stiffening, can not fit tightly with face.Due to polyster fibre, the facial mask cloth that viscose is made is soft, and is yielding, wet water, and facial mask is yielding after beautifying liquid soaks.
Popular tencel fiber nonwoven fabric, improved the right inadequate shortcoming of mounted mask sheet greatly in recent years.Tencel (day silk) fiber is the brand name of the Lyocell fiber of Britain Acordis company production, the registration Chinese " day silk " by name in China, the fiber that a kind of intensity high, blending good, boiling water shrinkage low of this fiber for producing through the solvent spinning process take wood pulp as raw material.It silk has concurrently outside the advantages such as the good hygroscopicity of common viscose fiber, soft and smooth elegant property and comfortableness, has overcome the common viscose fiber brute force low, especially wet strong low defective, and its brute force is almost close with terylene.The preparation method that US Patent No. 2002148050A1 discloses Lyocell fiber preparation method and has been made into nonwoven fabric by the Lyocell fiber.The Lyocell nonwoven fabric has good hygroscopicity, after tested, and the be absorbed as 9.4g/g of common cotton to deionized water, and day silk facial mask is to the 12.1g/g that is absorbed as of deionized water.Although the Lyocell nonwoven fabric possesses good hygroscopicity, because it is excessively thin, spread on 15min on the face, the Essence on cloth is absorbed by the skin soon and seems dry, causes moisture of skin partly to run off.Carboxymethyl cellulose (CMC) is the fibrid element ether that viscose is made after carboxy methylation, industrial multiplex its sodium salt (CMC-Na).They belong to polymeric anion type electrolyte, and good biocompatibility and high-hygroscopicity are arranged.Generally describe the carboxy methylation degree of cellulose fibre with substitution value (DS), by controlling technological parameter, carboxymethylated DS can be controlled in a narrow scope, when the DS of CMC＞0.3, the CMC fiber absorbs water into clear gel, and when DS＞0.4, CMC is water-soluble.Therefore the DS that is used for the CMC fiber of beauty mask should be lower than 0.3.
CMC is of many uses, and Powdered CMC is used for the industry such as food, medicine, and wherein CMC can be used as stabilizing agent, emulsifying agent in toothpaste, cold cream, shampoo, plays adjusting viscosity, stable foam, enhancing dirt-removing power, and makes quality fine and smooth.For example, patent US20040243042A1 with the CMC powder water-soluble for facial mask solubility base material to increase viscosity.Fibrous CMC can be used for wound dressing, and for example, WO93/12275 has described a kind of CMC wound dressing, it is characterized in that substitution value is 0.2-0.5, absorb water 15 times, this wound dressing is the CMC fiber that is obtained by Lyocell fiber process carboxy methylation, then makes nonwoven fabric.
The nonwoven fabric that contains the CMC fiber that is not reported so far is used for beauty mask cloth.Ideal situation is, can reach required Essence absorptivity based on the facial mask cloth of CMC, and reach the required wet strength of facial mask cloth.
Summary of the invention
The object of the present invention is to provide a kind of beauty mask base material with good biological activity, biocompatibility, sucting wet air permeability take carboxymethyl cellulose fiber as main raw material.
The invention provides a kind of nonwoven fabric, it is comprised of carboxymethyl cellulose fiber, perhaps formed with the second component that is selected from calcium alginate fibre, chitin fiber, chitin fiber or modified chitosan fiber by the carboxymethyl cellulose fiber as the first component, wherein, the content of the first component carboxymethyl cellulose fiber is counted the 1-95 % by weight with nonwoven fabric weight.
The present invention also provides a kind of nonwoven fabric, it is comprised of with the second component that is selected from any two kinds of fibers in calcium alginate fibre, chitin fiber, chitin fiber, modified chitosan fiber the carboxymethyl cellulose fiber as the first component, wherein, the content of the first component carboxymethyl cellulose fiber is counted the 1-95 % by weight with nonwoven fabric weight, and the weight ratio of any two kinds of fibers in second component is 1: 8-8: 1.
In one embodiment, take the deionized water water absorbing capacity as standard, the hygroscopicity of described nonwoven fabric is 6～40g/g.
In one embodiment, the dry strength of described nonwoven fabric is 0.1～4N/cm, and wet strength is 0.3～10N/cm.
In one embodiment, the net weight of described nonwoven fabric is 40-140g/m
2, expansion and contraction is lower than 30%.
In one embodiment, described carboxymethyl cellulose fiber is obtained through carboxy methylation by viscose or Lyocell fiber.
In one embodiment, described modified chitosan fiber comprises the acylation chitosan fiber.Preferably, described acylation chitosan fiber is cm-chitosan fiber or N-succinyl-chitosan fiber.
In one embodiment, the length of all fibres in described nonwoven fabric is 3～125cm, and line density is 1～5dtex.
In addition, the present invention also provides nonwoven fabric of the present invention to be used for the purposes of beauty mask base material.
Nonwoven fabric of the present invention has high-hygroscopicity, humectant, oxygen flow gas and good biocompatibility, and easy to use, safety non-toxic.When nonwoven fabric of the present invention was used for the beauty mask base material, its hygroscopicity still kept the facial mask cloth characteristics that fit tightly with skin as thin as cicada's wings simultaneously greater than sky silk facial mask cloth.
The specific embodiment
The CMC fiber has good blending, and it can be in conjunction with the advantage of various high polymers with large molecule blending and modifying, thereby improves the various performances of fiber.Therefore, nonwoven fabric of the present invention also can comprise other fibers of calcium alginate fibre, chitin fiber, chitin fiber, modified chitosan fiber, cross-linked carboxymethyl cellulose fiber or its combination.EP 0783605 provides the method that obtains the water imbibition wound dressing by sodium alginate fiber and carboxymethyl cellulose (CMC) co-blended spinning.Calcium alginate fibre has that high-hygroscopicity, oxygen flow gas are good, good biocompatibility, but harder crisp, brute force is lower, has affected the application of fiber.CMC fiber and calcium alginate fibre are as the linear polymeric polysaccharide that contains polyhydroxy and carboxyl, and the similitude of its structure makes both has good compatibility, and the carboxyl of CMC fiber and Ca
2+Also can generate ionomer.Because the three-dimensional effect of carboxymethyl makes the reaction force attenuation between the large molecule of blended fiber, thereby increase the pliability of calcium alginate fibre, improved the hygroscopicity of calcium alginate fibre.Therefore, of the present invention by CMC fiber and calcium alginate fibre blending and the wet strength of the nonwoven fabric that makes is larger, pliability is stronger.The present invention's calcium alginate fibre used is this area calcium alginate fibre commonly used, can make by methods known in the art: sodium alginate is dissolved in water, be mixed with certain density spinning solution, after utilizing pressure that spinning solution is sprayed from spinnerets, inject in the coagulating bath that contains calcium alginate and be frozen into tow.Form calcium alginate fibre through the operation such as a series of stretching, washing, oven dry again.
Chitin is a kind of natural macromolecule polysaccharide; chemical name is β-(1; 4)-2-acetamido-2-deoxy-D-glucose; with β-(1 by 2-Acetamido-2-deoxy-D-glucose; 4) the glycosidic bond condensation forms; molecular weight is 1,000,000-2,000,000; approximately there is 12.5% amino not to be acetylation in the natural chitin molecule; nitrogen content is about 6.3%-6.7%; it is the rare positively charged fibre structure compound of occurring in nature; can adsorb harmful heavy metal, and have antibiotic, anticorrosion and preservation.Patent CN1298972A has described nonwoven cloth made of chitin fibre and production method thereof.Patent CN2728488Y has described chitin pack, and this non-woven fabrics of chitin has the effect of anti-inflammation, is difficult for syneresis, and shortcoming is that intensity is too low, and facial mask cloth is easily torn in shreds.The chitin hygroscopicity is lower, can form shitosan after acetyl is taken off in the concentrated base processing, and shitosan and modification of chitosan can improve its moisture pick-up properties greatly.Preferably, described modified chitosan fiber comprises the acylation chitosan fiber, as cm-chitosan fiber or N-succinyl-chitosan fiber.Therefore, in order to increase the antibacterial and anti-inflammation functions of nonwoven fabric, the present invention is with CMC fiber and chitin fiber, chitin fiber, modified chitosan fiber or their combination blending, thereby obtain to have antibacterial and anti-inflammation functions, and have the nonwoven fabric of acceptable hygroscopicity and intensity, and need not to add any preservative agent.The present invention's chitin fiber, chitin fiber and modified chitosan fiber used is well known to a person skilled in the art, for example, above-mentioned fiber can namely be sent out new material Co., Ltd available from Qingdao.
Those skilled in the art can change the content of calcium alginate fibre, chitin fiber, chitin fiber or modified chitosan fiber according to actual needs, to obtain the character of required nonwoven fabric, as character such as hygroscopicity, intensity, antibacterial and anti-inflammation functions.
Below in conjunction with as following embodiment the present invention is described in more detail, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
The CMC nonwoven fabric
Viscose is fed intake make the viscose nonwoven fabric, then through carboxymethylation reaction, obtain the CMC nonwoven fabric.This nonwoven fabric is absorbed as 15.0g/g to deionized water, and dry strength is 3.52N/cm, and wet strength is 3.44N/cm, and the frivolous gas permeability of material is good.
Embodiment 2
CMC, calcium alginate fibre blending nonwoven fabric
With the CMC fiber: calcium alginate fibre feeds intake after mixing at 90: 10 with mass ratio, then makes CMC and calcium alginate blending nonwoven fabric.This nonwoven fabric is absorbed as 20.5g/g to deionized water, and dry strength is 3.46N/cm, and wet strength is 5.02N/cm, and the frivolous gas permeability of material is good.
Embodiment 3
CMC, chitin fiber blended nonwoven fabric
With the CMC fiber: chitin fiber feeds intake after mixing at 95: 5 with mass ratio, then makes CMC and chitin blending nonwoven fabric.This nonwoven fabric is absorbed as 19.4g/g to deionized water, and dry strength is 3.75N/cm, and wet strength is 1.52N/cm, and the frivolous gas permeability of material is good.
Embodiment 4
CMC, chitin fiber blending nonwoven fabric
With the CMC fiber: chitin fiber feeds intake after mixing at 90: 10 with mass ratio, then makes the nonwoven fabric of CMC and shitosan blending.This nonwoven fabric is absorbed as 26.6g/g to deionized water, and dry strength is 1.02N/cm, and wet strength is 1.69N/cm, and the frivolous gas permeability of material is good.
Embodiment 5
CMC, N-succinyl-chitosan fiber blend nonwoven fabric
With the CMC fiber: N-succinyl-chitosan fiber feeds intake after mixing at 95: 5 with mass ratio, then makes the nonwoven fabric of CMC and the blending of N-succinyl-chitosan.This nonwoven fabric is absorbed as 28.3g/g to deionized water, and dry strength is 0.45N/cm, and wet strength is 1.36N/cm, and the frivolous gas permeability of material is good.
Embodiment 6
CMC, calcium alginate fibre, chitin fiber (mass ratio 80: 10: 10) blending nonwoven fabric
With the CMC fiber: calcium alginate fibre: chitin fiber feeds intake after mixing at 80: 10: 10 with mass ratio, then makes the nonwoven fabric of CMC and calcium alginate, shitosan blending.This nonwoven fabric is absorbed as 26.5g/g to deionized water, and dry strength is 1.15N/cm, and wet strength is 2.71N/cm, and the frivolous gas permeability of material is good, and intensity is large.
Embodiment 7
CMC, calcium alginate fibre, chitin fiber (mass ratio 33: 33: 33) blending nonwoven fabric
With the CMC fiber: calcium alginate fibre: chitin fiber feeds intake after mixing at 33: 33: 33 with mass ratio, then makes the nonwoven fabric of CMC and calcium alginate, shitosan blending.This nonwoven fabric is absorbed as 18.0g/g to deionized water, and dry strength is 3.15N/cm, and wet strength is 8.02N/cm, and the frivolous gas permeability of material is good.
Embodiment 8
CMC, calcium alginate fibre, chitin fiber (mass ratio 10: 10: 80) blending nonwoven fabric
With the CMC fiber: calcium alginate fibre: chitin fiber feeds intake after mixing at 10: 10: 80 with mass ratio, then makes the nonwoven fabric of CMC and calcium alginate, shitosan blending.This nonwoven fabric is absorbed as 22.8g/g to deionized water, and dry strength is 2.02N/cm, and wet strength is 3.86N/cm, and the frivolous gas permeability of material is good.
Embodiment 9
CMC, calcium alginate fibre, chitin fiber (mass ratio 10: 80: 10) blending nonwoven fabric
With the CMC fiber: calcium alginate fibre: chitin fiber feeds intake after mixing at 10: 80: 10 with mass ratio, then makes the nonwoven fabric of CMC and calcium alginate, shitosan blending.This nonwoven fabric is absorbed as 23.8g/g to deionized water, and dry strength is 2.35N/cm, and wet strength is 3.98N/cm, and the frivolous gas permeability of material is good.
The beauty mask base material made by nonwoven fabric of the present invention and the comparison of existing beauty mask base material have been shown as following table 1.
Table 1
The method of testing that in table 1, deionized water absorbs is: at 20 ℃, under 65% relative humidity, the face mask substrate material sample of 5 * 5cm is soaked 30min in the 100ml deionized water, take out 30s, weigh.The method of testing of fluid loss characteristics is: the face mask substrate material sample after above-mentioned absorption deionized water is placed in drier, weighs after 1h.The minimizing of sample quality is the water yield that sample reduces before and after 1 hour, by comparative analysis, and moisture retention that can more different samples.
As can be seen from Table 1, the high moisture absorption of beauty mask base material of the present invention, high moisturizing, wet strength are large, good permeability, can improve himself hygroscopicity and wet strength with other fiber blends, also have simultaneously antibiotic effect.U.S.A is facial mask (100%Lyocell fiber) moisture pick-up properties, all lower than facial mask 1 of the present invention, wet strength is low for performance of keeping humidity, without antibiotic effect.The common non-woven fabric facial mask (viscose: terylene=70: 30) hygroscopicity, moisture retention be well below facial mask 1 of the present invention, and without antibiotic effect.
One skilled in the art will appreciate that and to make multiple change to the details of above-described embodiment and embodiment under the prerequisite that does not break away from basic principle of the present invention.Under the premise without departing from the spirit and scope of the present invention, will be apparent to those skilled in the art to various modifications of the present invention and change.Therefore, the application's protection domain should only be determined by claims.
Claims (10)
1. nonwoven fabric, its
Formed by carboxymethyl cellulose fiber, perhaps
Formed with the second component that is selected from calcium alginate fibre, chitin fiber, chitin fiber or modified chitosan fiber by the carboxymethyl cellulose fiber as the first component, wherein, the content of the first component carboxymethyl cellulose fiber is counted the 1-95 % by weight with nonwoven fabric weight.
2. nonwoven fabric, it is comprised of with the second component that is selected from any two kinds of fibers in calcium alginate fibre, chitin fiber, chitin fiber, modified chitosan fiber the carboxymethyl cellulose fiber as the first component, wherein, the content of the first component carboxymethyl cellulose fiber is counted the 1-95 % by weight with nonwoven fabric weight, and the weight ratio of any two kinds of fibers in second component is 1: 8-8: 1.
3. nonwoven fabric according to claim 1 and 2, take the deionized water water absorbing capacity as standard, the hygroscopicity of described nonwoven fabric is 6～40g/g.
4. nonwoven fabric according to claim 1 and 2, the dry strength of described nonwoven fabric is 0.1～4N/cm, wet strength is 0.3～10N/cm.
5. nonwoven fabric according to claim 1 and 2, the net weight of described nonwoven fabric is 40-140g/m
2, expansion and contraction is lower than 30%.
6. nonwoven fabric according to claim 1 and 2, wherein said carboxymethyl cellulose fiber is obtained through carboxy methylation by viscose or Lyocell fiber.
7. nonwoven fabric according to claim 1 and 2, wherein said modified chitosan fiber comprises the acylation chitosan fiber.
8. nonwoven fabric according to claim 7, wherein said acylation chitosan fiber is cm-chitosan fiber or N-succinyl-chitosan fiber.
9. nonwoven fabric according to claim 1 and 2, wherein the length of all fibres is 3～125cm, line density is 1～5dtex.
10. be used for the purposes of beauty mask base material as the described nonwoven fabric of aforementioned claim any one.
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| CN104963086A (en) * | 2015-07-09 | 2015-10-07 | 厦门百美特生物材料科技有限公司 | Alginate fiber anti-bacteria facial mask base cloth |
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Application publication date: 20130619 |