CN103148602A - Solid particle accumulation bed-type air heat absorber for solar thermal power station - Google Patents
Solid particle accumulation bed-type air heat absorber for solar thermal power station Download PDFInfo
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- 238000009825 accumulation Methods 0.000 title 1
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- 230000005611 electricity Effects 0.000 claims description 6
- 238000005338 heat storage Methods 0.000 abstract description 4
- 230000005855 radiation Effects 0.000 description 16
- 238000010521 absorption reaction Methods 0.000 description 8
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- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
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- 238000004519 manufacturing process Methods 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
- Y02E10/44—Heat exchange systems
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
- Y02E10/46—Conversion of thermal power into mechanical power, e.g. Rankine, Stirling or solar thermal engines
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Abstract
一种太阳能热发电站用固体颗粒堆积床式空气吸热器,由石英玻璃管束(1)、固体颗粒(2)、冷空气集箱(3)、热空气集箱(4)、冷空气入口(5)和热空气出口(6)组成。石英玻璃管束(1)由多根石英玻璃管组成。固体颗粒(2)堆积于石英玻璃管束(1)中的石英玻璃管内部,固体颗粒(2)在工作过程中保持静止状态。冷空气集箱(3)位于石英玻璃管束(1)的下部与石英玻璃管束(1)的下部密封连接,热空气集箱(4)位于石英玻璃管束(1)的上部与石英玻璃管束(1)的上部密封连接。冷空气入口(5)位于冷空气集箱(3)上,热空气出口(6)位于热空气集箱(4)上。本发明可获得700℃-1300℃、常压或者1MPa压力以上的高温空气,同时利用自身的显热储热。
A solid particle stacked bed air heat absorber for a solar thermal power station, consisting of quartz glass tube bundles (1), solid particles (2), cold air headers (3), hot air headers (4), and cold air inlets (5) and hot air outlet (6). The quartz glass tube bundle (1) is composed of multiple quartz glass tubes. Solid particles (2) are accumulated inside the quartz glass tubes in the quartz glass tube bundle (1), and the solid particles (2) remain static during the working process. The cold air header (3) is located at the lower part of the quartz glass tube bundle (1) and is sealed and connected with the lower part of the quartz glass tube bundle (1), and the hot air header (4) is located at the upper part of the quartz glass tube bundle (1) and is connected with the quartz glass tube bundle (1) ) of the upper seal connection. The cold air inlet (5) is located on the cold air header (3), and the hot air outlet (6) is located on the hot air header (4). The present invention can obtain high-temperature air of 700°C-1300°C, normal pressure or pressure above 1MPa, and utilize its own sensible heat storage at the same time.
Description
技术领域technical field
本发明涉及一种太阳能热发电站用空气吸热器。The invention relates to an air heat absorber for a solar thermal power station.
背景技术Background technique
太阳能是取之不尽用之不竭的可再生能源,在化石燃料逐年减少、国际能源形势日趋严峻的今天,开发利用太阳能是实现能源供应多元化、保证能源安全的重要途径之一。塔式热发电装置基本原理是利用众多的定日镜,将太阳辐射反射到置于塔上的太阳能接收器上,借助加热工质产生过热蒸汽或高温空气,驱动发电机组,产生电能。高温太阳能吸热器是塔式热发电系统的核心部件。国外围绕此项技术进行了诸多研究,主要集中在美国、西班牙、德国、以色列、澳大利亚、韩国等。其中应用较多的是容积式吸热器,就是一种由三维基体所构成的接收太阳辐射的吸热体,流过的工作流体与其进行直接的热交换而被加热。容积式太阳能吸热器通常有一个空心壳体,用于容纳容积式太阳能吸收装置,壳体由玻璃透光窗覆盖,形成封闭的吸热装置腔体,腔体可以容纳与吸收装置直接接触的工作流体,工作流体流过吸热装置腔体,从吸收装置上吸收热量。美国专利4394859公开了一种以空气为传热流体的柱状金属管式吸热器,该吸热器对金属要求较高,系统复杂,成本高,而且许用能流密度较低,难以获得高温度的空气。美国专利4777934公布了采用带有粒子的压缩空气为传热流体的太阳能吸热器,其温度可被加热至700℃,该吸热器无法应用到更高的温度。美国专利US6668555B1公布了基于吸热器的太阳能发电系统,采用热管式太阳能吸热器,其传热工质为空气,虽然传热效率较高,但应用于高温需要采用金属钠等物质作为热管内的相变材料,对安全性要求苛刻。中国专利CN2758657提出了腔式太阳能吸收器,分为内外两个腔,内腔体临近石英玻璃窗表面涂覆太阳能选择性吸收涂层,并且采用不同的物质用于传热和蓄热,用于高温场合,但其结构较为复杂。中国专利CN2872208提出了一种空腔式太阳能空气吸热器,采用了针管冷却玻璃窗、管状吸热体,管状吸热体的换热表面积小,传热效率不高,冷却玻璃窗也难于制作为较大尺寸。Solar energy is an inexhaustible renewable energy source. Today, as fossil fuels are decreasing year by year and the international energy situation is becoming increasingly severe, the development and utilization of solar energy is one of the important ways to realize the diversification of energy supply and ensure energy security. The basic principle of the tower thermal power generation device is to use many heliostats to reflect solar radiation to the solar receiver placed on the tower, and generate superheated steam or high-temperature air with the help of heating medium to drive the generator set to generate electricity. The high temperature solar heat absorber is the core component of the tower thermal power generation system. Many studies on this technology have been carried out abroad, mainly in the United States, Spain, Germany, Israel, Australia, South Korea and so on. Among them, the most widely used is the volumetric heat absorber, which is a heat absorber composed of a three-dimensional matrix to receive solar radiation, and the working fluid flowing through it is heated by direct heat exchange with it. The volumetric solar heat absorber usually has a hollow shell for containing the volumetric solar absorbing device, and the shell is covered by a glass light-transmitting window to form a closed heat absorbing device cavity, which can accommodate the direct contact with the absorbing device. Working fluid, the working fluid flows through the cavity of the heat absorbing device and absorbs heat from the absorbing device. U.S. Patent 4394859 discloses a cylindrical metal tube heat absorber with air as the heat transfer fluid. temperature of the air. US Patent No. 4,777,934 discloses a solar heat absorber that uses compressed air with particles as a heat transfer fluid, and its temperature can be heated to 700° C., but the heat absorber cannot be applied to higher temperatures. U.S. Patent US6668555B1 discloses a solar power generation system based on a heat absorber. A heat pipe solar heat absorber is used. The heat transfer medium is air. Although the heat transfer efficiency is high, it is necessary to use metal sodium and other substances as the heat pipe for high temperature applications. phase change materials, which have strict requirements on safety. Chinese patent CN2758657 proposes a cavity-type solar absorber, which is divided into two cavities inside and outside. The inner cavity is coated with a solar selective absorption coating near the surface of the quartz glass window, and different materials are used for heat transfer and heat storage. High temperature occasions, but its structure is more complex. Chinese patent CN2872208 proposes a cavity-type solar air heat absorber, which uses a needle tube to cool the glass window and a tubular heat absorber. The heat transfer surface area of the tubular heat absorber is small, the heat transfer efficiency is not high, and the cooling glass window is also difficult to manufacture. for larger sizes.
综上所述,为了获得高温高压空气,目前的空气吸热器多采用石英玻璃窗实现透光和密封功能,在由于受到石英玻璃生产工艺的限制,单片石英玻璃难以被加工成较大面积,限制了承压式空气吸热器的功率。在通常的容积式空气吸热器中,陶瓷或金属吸热体均会出现局部的“热斑”而造成吸热体损坏,而且在大功率应用中,大尺寸陶瓷体的制备和连接均存在技术难题。To sum up, in order to obtain high-temperature and high-pressure air, the current air heat sinks mostly use quartz glass windows to achieve light transmission and sealing functions. Due to the limitation of the production process of quartz glass, it is difficult to process a single piece of quartz glass into a larger area. , limiting the power of the pressurized air heater. In the usual volumetric air heat absorber, there will be local "hot spots" on the ceramic or metal heat absorber, which will cause damage to the heat absorber, and in high-power applications, there are problems in the preparation and connection of large-scale ceramic bodies. technical challenge.
发明内容Contents of the invention
本发明的目的是克服现有承压式空气吸热器难以用于较大功率的不足,提供一种新的空气吸热器。The purpose of the present invention is to overcome the disadvantage that the existing pressurized air heat absorber is difficult to be used for larger power, and provide a new air heat absorber.
本发明以石英玻璃管束的石英玻璃管为空气流道,利用石英玻璃的高透光率和耐高温特性,采用堆积石英玻璃管内的固体颗粒为吸热体,利用固体颗粒的吸收率高、耐高温、导热系数高、比表面积大的特点进行高效吸热与换热。In the present invention, the quartz glass tube of the quartz glass tube bundle is used as the air flow channel, the high light transmittance and high temperature resistance characteristics of the quartz glass are used, and the solid particles in the stacked quartz glass tube are used as the heat absorber, and the high absorption rate of the solid particles and the high temperature resistance are used. High temperature, high thermal conductivity, and large specific surface area for efficient heat absorption and heat transfer.
所述的固体颗粒在接收太阳辐射时还具有储热功能,可以在一定时间内避免空气温度的较大波动。本发明可根据使用要求建造较大容量的空气吸热器,可用于常压和高压系统。The solid particles also have a heat storage function when receiving solar radiation, which can avoid large fluctuations in air temperature within a certain period of time. The present invention can build larger-capacity air heat absorbers according to usage requirements, and can be used in normal pressure and high pressure systems.
选择碳化硅、氮化硅、石墨等耐温高材料作为固体颗粒可在1200℃及更高温度范围内使用,确保了本发明的空气吸热器可用于较高的温度。碳化硅、石墨等固体颗粒的导热系数高温时可大于10W/(mK),而且具有很高的辐射吸收率,通过设计颗粒的形状和大小,可以最大限度吸收投入的太阳辐射能。堆积于石英玻璃管中固体颗粒群具有较大的比表面积,确保了换热过程中空气与吸热体间可获得较高的传热效率。Selecting silicon carbide, silicon nitride, graphite and other high temperature-resistant materials as solid particles can be used in the temperature range of 1200 ° C and higher, which ensures that the air heat absorber of the present invention can be used at higher temperatures. The thermal conductivity of silicon carbide, graphite and other solid particles can be greater than 10W/(mK) at high temperature, and has a high radiation absorption rate. By designing the shape and size of the particles, the input solar radiation energy can be absorbed to the maximum. The solid particle group accumulated in the quartz glass tube has a large specific surface area, which ensures a high heat transfer efficiency between the air and the heat absorber during the heat exchange process.
本发明的固体颗粒堆积床式空气吸热器,以堆积于石英玻璃管中的固体颗粒为吸热介质,空气为传热流体。所述的吸热器包括位于上部的热空气集箱、位于下部的冷空气集箱和与热空气集箱、冷空气集箱密封连接的石英玻璃管束组成。石英玻璃管束为多根管径相同或者不同的石英玻璃管排列而成。石英玻璃管内充满固体颗粒。热空气集箱的侧面或底部开有一个或多个热空气出口,冷空气集箱的侧面或底部开有一个或多个冷空气入口。固体颗粒为球形、椭球形或者其他形状,颗粒大小可以相同也可以不同,固体颗粒的形状、颗粒直径和颗粒密度等参数由流入石英玻璃管束中空气速度分布决定,其原则是实现固体颗粒与空气充分换热,吸热器工作在高温环境,吸热器未用于接收太阳光的部分包覆有耐高温保温层,以控制热量的散失。The solid particle stacked bed type air heat absorber of the present invention uses the solid particles accumulated in the quartz glass tube as the heat absorbing medium, and the air as the heat transfer fluid. The heat absorber comprises an upper hot air header, a lower cold air header, and a quartz glass tube bundle sealingly connected with the hot air header and the cold air header. The quartz glass tube bundle is formed by arranging a plurality of quartz glass tubes with the same or different diameters. The quartz glass tube is filled with solid particles. One or more hot air outlets are opened on the side or bottom of the hot air header, and one or more cold air inlets are opened on the side or bottom of the cold air header. The solid particles are spherical, ellipsoid or other shapes, and the particle size can be the same or different. The parameters such as the shape, particle diameter and particle density of the solid particles are determined by the velocity distribution of the air flowing into the quartz glass tube bundle. The principle is to realize the solid particles and air Fully heat exchange, the heat absorber works in a high temperature environment, and the part of the heat absorber that is not used to receive sunlight is covered with a high-temperature heat-resistant insulation layer to control heat loss.
本发明工作过程如下:The working process of the present invention is as follows:
经聚光设备收集的聚光辐射能流投射至组成石英玻璃管束的石英玻璃管表面,部分辐射能被石英玻璃管面向辐射能量投入侧的表面反射,部分辐射能流被石英玻璃管吸收,部分辐射能流被石英玻璃管内充满的固体颗粒反射和吸收,固体颗粒间有空隙,辐射能流在空隙间传播,辐射能被固体颗粒吸收转换为热能,使得固体颗粒温度升高,温度较低的冷空气与温度较高的固体颗粒表面间进行对流传热,由于固体颗粒间为空隙,使得空气与固体颗粒间的传热面积较大,传热效率较高。选择固体颗粒直径在0.1-10mm之间,选在合适的颗粒直径可以实现聚光辐射能流的高效吸收和空气与固体颗粒间的高效传热。The concentrated radiant energy flow collected by the concentrating equipment is projected onto the surface of the quartz glass tubes that form the quartz glass tube bundle, part of the radiant energy is reflected by the surface of the quartz glass tube facing the radiation energy input side, part of the radiant energy flow is absorbed by the quartz glass tube, and part of the radiant energy is absorbed by the quartz glass tube. The radiant energy flow is reflected and absorbed by the solid particles filled in the quartz glass tube. There are gaps between the solid particles, and the radiant energy flow propagates in the gaps. The convective heat transfer between the cold air and the surface of the solid particles with higher temperature, because there are gaps between the solid particles, the heat transfer area between the air and the solid particles is larger, and the heat transfer efficiency is higher. The solid particle diameter is selected between 0.1-10mm, and a suitable particle diameter can realize efficient absorption of concentrated radiation energy flow and efficient heat transfer between air and solid particles.
本发明结构简单,可按需求设计固体颗粒的粒径大小,加之调整空气的流动速度,可实现太阳辐射能高效吸收、热量高效传递给空气的目的。本发明可以获得温度范围为700℃-1600℃、常压或1MPa压力以上的高温空气。同时固体颗粒具有储热功能,可以在一定时间间隔内控制空气温度输出参数的波动。The invention has a simple structure, and the size of the solid particles can be designed according to requirements, and the flow velocity of the air can be adjusted to realize the purposes of efficiently absorbing solar radiation energy and efficiently transferring heat to the air. The invention can obtain high-temperature air with a temperature range of 700°C-1600°C and normal pressure or pressure above 1MPa. At the same time, solid particles have the function of heat storage, which can control the fluctuation of air temperature output parameters within a certain time interval.
附图说明Description of drawings
图1固体颗粒堆积床式空气吸热器工作原理图;Fig. 1 Working principle diagram of solid particle packed bed air heat absorber;
图2以非压缩空气为传热流体的太阳能热发电站运行原理图;Figure 2 is a schematic diagram of the operation of a solar thermal power station using non-compressed air as a heat transfer fluid;
图3压缩空气为传热流体的太阳能热发电站运行原理图;Figure 3 is a schematic diagram of the operation of a solar thermal power station in which compressed air is the heat transfer fluid;
图中:1石英玻璃管束、2固体颗粒、3冷空气集箱、4热空气集箱、5冷空气入口、6热空气出口、7聚光辐射能流、8定日镜场、9支撑塔、10固体颗粒堆积床式空气吸热器、11冷空气、12风机、13热空气、14蒸汽发生器、15水泵、16汽轮机、17发电机、18水换热器、19空气压缩机、20冷压缩空气、21热压缩空气、22空气透平。In the figure: 1 quartz glass tube bundle, 2 solid particles, 3 cold air header, 4 hot air header, 5 cold air inlet, 6 hot air outlet, 7 concentrated radiation energy flow, 8 heliostat field, 9 support tower , 10 solid particle stacked bed air heat absorber, 11 cold air, 12 fan, 13 hot air, 14 steam generator, 15 water pump, 16 steam turbine, 17 generator, 18 water heat exchanger, 19 air compressor, 20 Cold compressed air, 21 hot compressed air, 22 air turbine.
具体实施方式Detailed ways
下面结合附图和具体实施方式进一步说明本发明。The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.
图1所示为本发明固体颗粒堆积床式空气吸热器。该吸热器由石英玻璃管束1、固体颗粒2、冷空气集箱3、热空气集箱4、冷空气入口5和热空气出口6组成。石英玻璃管束1由多根石英玻璃管排列组成。所述的石英玻璃管的直径可以相同也可以不同,石英玻璃管的排列形式可以是顺序排列或交叉排列。石英玻璃管束1的排列形式与管束数量受投入的聚光辐射能流7的特性决定,其原则是确保投入至吸热器上的所有聚光辐射能流7均被固体颗粒2和组成石英玻璃管束1的多根石英玻璃管吸收。固体颗粒2充满于每根石英玻璃管内,固体颗粒2具有高的辐射吸收率,可在1600℃以上温度长期使用,固体颗粒2的直径可以相同也可以不同,固体颗粒的形状、颗粒直径和颗粒密度等参数由流入石英玻璃管束1中空气速度分布决定,其原则是实现固体颗粒2与空气充分换热,固体颗粒2的材料可以是碳化硅陶瓷、石墨、氮化硅陶瓷等。冷空气集箱3位于石英玻璃管束1的下部,与石英玻璃管束1的下部密封连接。冷空气集箱3可实现冷空气汇集和空气压力与流量分配,冷空气集箱3的侧面或底部设有一个或多个冷空气入口5,冷空气入口5的位置、尺寸和数量依据冷空气的流场特征决定。热空气集箱4位于石英玻璃管束1的上部,与石英玻璃管束1的上部密封连接,可实现热空气汇集和空气压力分配,热空气集箱4的侧面或顶部设有一个或多个热空气出口6,热空气出口6的位置、尺寸和数量依据热空气和固体颗粒2的流场特征决定。Fig. 1 shows the solid particle packed bed air heat absorber of the present invention. The heat absorber is composed of quartz glass tube bundle 1,
工作时,经太阳能聚光场提供的聚光辐射能流7投射至石英玻璃管束1的石英玻璃管表面,聚光辐射能流7的绝大部分辐射能透过石英玻璃管壁至石英玻璃管束1内堆积的固体颗粒2上,固体颗粒2在工作过程中始终维持静止状态。由于固体颗粒2具有较高辐射吸收率,聚光辐射能流7被固体颗粒2吸收转化为固体颗粒2的热能,少部分辐射能被石英玻璃管壁吸收,转化为石英玻璃管的热能,被加热的固体颗粒2和石英玻璃管壁温度升高与来自冷空气集箱3内的冷空气进行对流换热,将冷空气加热为热空气流入热空气集箱4内从热空气出口6流出,冷空气入口5不断向石英玻璃管束1内输送冷空气,聚光辐射能流7通过固体颗粒2和石英玻璃管束1管壁的吸收和与冷空气的对流换热,实现了辐射能到空气热能的转换。When working, the concentrated
图2为以非压缩空气为传热流体的太阳能热发电站运行原理,工作时,定日镜场8上将太阳光会聚至位于支撑塔9上的固体颗粒堆积床式空气吸热器10上,环境中的冷空气11经风机12被吹入固体颗粒堆积床式空气吸热器10内,固体颗粒2在工作过程中始终维持静止状态,固体颗粒2吸收太阳能辐射能后温度升高,冷空气11经与固体颗粒2对流换热后被加热为热空气13,热空气13流入蒸汽发生器14内与经水泵15泵入的高压水换热产生过热蒸汽输入至汽轮机16中做功带动发电机17发电,经汽轮机16做功后的过热蒸汽经水换热器18换热后在水泵15的作用下流回蒸汽发生器14,完成水工质的循环。Figure 2 shows the operating principle of a solar thermal power station using non-compressed air as the heat transfer fluid. During operation, the
图3为以压缩空气为传热流体的太阳能热发电站运行原理,工作时,定日镜场8上将太阳光会聚至位于支撑塔9上的固体颗粒堆积床式空气吸热器10上,环境中的冷空气11经空气压缩机19压缩后成为冷压缩空气20,冷压缩空气20进入固体颗粒堆积床式空气吸热器10内,固体颗粒2在工作过程中保持不动,固体颗粒2吸收太阳能辐射能后温度升高,冷压缩空气20经与固体颗粒2对流换热后被加热为热压缩空气21,热压缩空气21流入空气透平22内做功带动发电机17发电和推动空气压缩机19旋转做功。热压缩空气21在空气透平22内做功后流入蒸汽发生器14内与经水泵15泵入的高压水换热产生过热蒸汽输入至汽轮机16中做功带动发电机17发电,经汽轮机16做功后的过热蒸汽经水换热器18换热后在水泵15的作用下流回蒸汽发生器14,完成水工质的循环。Fig. 3 is the operating principle of a solar thermal power station using compressed air as the heat transfer fluid. During operation, the
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