CN103131516A - Cement plant fire coal combustion supporting and sulfur fixation composition method - Google Patents
Cement plant fire coal combustion supporting and sulfur fixation composition method Download PDFInfo
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- CN103131516A CN103131516A CN2013100610510A CN201310061051A CN103131516A CN 103131516 A CN103131516 A CN 103131516A CN 2013100610510 A CN2013100610510 A CN 2013100610510A CN 201310061051 A CN201310061051 A CN 201310061051A CN 103131516 A CN103131516 A CN 103131516A
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Abstract
The invention discloses a cement plant fire coal combustion supporting and sulfur fixation composition method. The composition comprises 30-50wt% of limestone, 3-20wt% of calcium hydroxide, 10-20wt% of calcium carbonate, 3-15wt% of sodium carbonate, 10-20wt% of ammonium nitrate and 10-30wt% of a clinker sintering aid, the sum of the weight proportions of the above components is 100%, the water content is less than 2%, and the content of calcium oxide in limestone is not lower than 40%. The method has the advantages of easy buying of the above raw materials in the market, saving of above 13% coal, and reduction of the sulfide dioxide discharge amount by above 90%.
Description
Technical field
The invention belongs to the combustion-supporting solid sulfide technical field, especially a kind of cement mill fire coal combustion-supporting solid sulfide compound formulation.
Background technology
Fast development along with national economy, the subsurface storage amount of coal in China also is tending towards the impetus of minimizing rapidly, fat coal is because of excess exploitation and a large amount of outlet, the impetus of its minimizing is particularly serious, and the high sulphur coal inferior of the first sample of image-stone is stayed domestic, bring exceptional hardship because its calorific value hangs down with seriously polluted to industrial production and people's lives, caused serious harm to atmospheric environment simultaneously.From development and strategic perspective, environmental pollution and energy shortage problem have consisted of serious threat to its people's the survival and development, have arrived the stage of solution.
Produce the coal combustion supporting and sulphur fixing agent kind on market a lot of, but really can solve the very little of the problems such as environmental protection in the coal burning process, energy-conservation, sulphur removal, for example coal-fired insufficient, dust, coking deleterious acidic gaseous emission are not thorough, not sulphur removal etc. causes and can not effectively improve thermo-efficiency and sulfurous gas enters atmosphere.In coal, sulphur is the most harmful chemical composition.During coal combustion, wherein sulphur generates sulfurous gas, corroding metal equipment, contaminate environment.
Coal combustion supporting and sulphur fixing agent composition on market is manganese ore, calcium carbonate and chemical admixture.Manganese ore and chemical admixture acting in conjunction can reduce the burning-point of coal dust, improve the fusing point of coal powder fraction, and at high temperature regulate combustion atmosphere, reach the purpose of the concentrated combustion that promotes low grade coal; Calcium carbonate and chemical admixture acting in conjunction are met the sulfurous gas that produces after coal combustion and are reacted, and sulfur material is deposited in cinder, thereby has reduced the sulfurous gas that enters atmosphere; But the chemical admixture that adopts relatively is difficult to obtain at nature, and the effect requirements to coal combustion and sulfur fixation is very high in the cement mill, therefore, need a kind of more preferably combustion-supporting solid sulfide compound formulation, can further reduce the burning-point of coal dust, improve the utilising efficiency of coal dust, more be sparing in the use of coal, element sulphur in the sulfurous gas that produces during further with coal combustion is deposited in cinder, reduces the discharging of obnoxious flavour.
In view of the foregoing, existing fire coal combustion-supporting solid sulphur formula needs to improve.
Summary of the invention
The objective of the invention is in order to overcome deficiency of the prior art, a kind of cement mill fire coal combustion-supporting solid sulfide compound formulation is provided, raw material is easily bought on market, can reach and economize on coal more than 13%, reduces the effect of sulphur dioxide emission more than 90%.
The present invention to achieve these goals, adopt following technical scheme: a kind of cement mill fire coal combustion-supporting solid sulfide compound formulation, the assembly weight percent is: Wingdale 30-50%, calcium hydroxide 3-20%, calcium carbonate 10-20%, sodium carbonate 3-15%, ammonium nitrate 10-20%, grog sintering agent 10-30%, above each component sum by weight ratio are 100%.
Wingdale 30-40%, calcium hydroxide 10-20%, calcium carbonate 10-20%, sodium carbonate 3-10%, ammonium nitrate 10-15%, grog sintering agent 10-20%, above each component sum by weight ratio are 100%.
In Wingdale, the content of calcium oxide is not less than 40%.
The combustion-supporting solid sulfide material is to contain a kind of or combination wherein of cobalt, cadmium, lanthanide rare natural mineral.
Grog sintering agent assembly weight percent is: cobalt oxide 55-70%, and Cadmium oxide 20-40%, lanthanide rare titanium dioxide lanthanum 5-10%, above each component sum by weight ratio are 100%.
The characteristics of catalyticcombustion are to reduce the required activation energy of reaction, and reaction can be carried out at lower temperature.Coal dust is in the stage of catching fire, and main manifestations is release and the burning of volatile matter.Along with most of volatile discharges complete, oxygen on every side is diffused into gradually the coke surface after the coal dust cracking and is penetrated in pore texture, under certain temperature action, oxygen and coke surface carbon and hydrogen effect form carbonic acid gas and water is main product and past external diffusion.In this stage, what promote oxygen and coke fully contacts the after-flame that can improve coal dust.Particularly at the later stage of coal dust firing, due to the consumption of organic carbon, the coal dust volume shrinks gradually, and the ash content in coal dust covers skin gradually, has hindered the further diffusion of oxygen toward coal tar inside, inevitably causes difficult after-flame.
In said components, a series of physicochemical change at high temperature occurs in ammonium nitrate and grog sintering agent, and ammonium nitrate and grog sintering agent form titanium dioxide ammonium, metal ion (as ammonium, cobalt, lanthanum) etc.Calcium oxide can play the oxygenation effect, the situation of local anoxic when changing coal combustion, and heat is concentrated, helps the further burning of coal, then improves the burning of coal rate, subtracts buckwheat coal and effluxes, and reduces atmospheric pollution and energy dissipation; And the humate that contains in metal ion and coal will carry out the alkali exchange and generate the lower humic acid salt of point of ignition, when the hydrocarbon polymer massfraction of these gaseous molecular amounts on coal dust surface reaches certain value, be far longer than heat radiation with the heat release of oxygen combination reaction, make the quickening that is swift in response, formation is caught fire, and has changed the flammability of coal.Simultaneously, the fracture that some metal-salt decomposes is decomposed, and the gaseous state volatile matter is comparatively fast discharged, and has increased inflammable volatile content, thereby has accelerated ignition of coal speed.
In combustion processes, oxygen is constantly from metal to the carbon atom transmission, accelerated the velocity of diffusion of oxygen, be conducive to accelerate the burning of carbon, increase the burnout rate of coal, but metal ion can be combined by the oxy functional groups in coal also, simultaneously in burning also can with the effect of coal mineral, therefore should note content to the impact of catalytic effect when using cement mill fire coal combustion-supporting solid sulfide compound formulation, be not that volume is The more the better.
The titanium dioxide ammonium that produces in burning, the thermal capacitance of the metal oxides such as sodium oxide own is little, and can catalysis the fracture of long-chain fat family alkane bond in coal, become the molecule of less, increase the motion of molecule, reduce the thermal capacitance of coal, the heat transmission that has improved coal.The transfer transport theory is started with from the electronic catalytic theory, think that inside that metal ion embeds the carbon lattice changes the microtexture of carbon and as electron donor, by transfer transport accelerating part reactions steps, in addition, metal ion in catalyzer can be activated in heat-processed, thereby occuring to shift, the electronics of himself becomes electron donor, metal ion will form the hole, and the electronic configuration of carbon surface also will change, the migration of this electric charge will speed up some reaction, thereby improved the speed of whole reaction, made and burn more fully.Simultaneously, a kind of inorganic salt in the grog sintering agent are heated microexplosion occur when reaching certain temperature, and the combustiblematerials around making is bulk, increases the oxygen supply area, make fire coal can access burning more fully, and coal fuel heating efficient is significantly improved.
Coal produces high temperature when burning, sulphur and oxygen reaction generate sulfurous gas, calcium oxide in Wingdale and sulfurous gas reaction generate calcium sulfite, calcium sulfite generates calcium sulfate with oxygen reaction again, just be fixed by the most sulphur of this process, can be with the form of the sulfurous gas formation acid rain of discharging into the atmosphere.
The invention has the beneficial effects as follows: raw material is easily bought on market, can reach and economize on coal more than 13%, reduces the effect of sulphur dioxide emission more than 90%.
Add Cadmium oxide can improve the active and stable of raw material, can significantly improve clinker quality after appropriate Cadmium oxide adds, but the excessive grog free calcium oxide that makes of admixture increases, clinker quality descends.
lanthanum at high temperature plays obvious effect to fast reaction speed, lanthanide series rare-earth elements is the gang's element take lanthanum as representative, has similar outer electronic structure, calcining to grog all has promoter action, lanthanide series rare-earth elements burns till the solid state reaction stage at grog can be by forming intermediate product promotion solid state reaction, in the stage of burning till, silicate minerals has been formed katalysis, can make the carbonate decomposition temperature, the solid state reaction temperature, the decline 10-35 degree such as Ismet Atli formation temperature, reach the time shorten 5-10 second of the degree of burning till equally, when adding lanthanide series rare-earth elements in system, but the abstraction reaction molecule forms reaction activation body, and then change the product molecule into, thereby greatly accelerated the formation speed of mineral, corresponding therewith, mineral form speed, and [quickening of rate impels again the quickening of calcium oxide particle diffusive migration speed, the calcium oxide that makes new decomposition and produce can form intermediate product with the acidic oxide reaction rapidly, and cause the rapid attenuation of product layer of the carbonate particle that decomposing, and then accelerate again the speed of carbonate decomposition reaction, the reaction of accelerating sulfurous gas and calcium oxide generates the speed of calcium sulfite, simultaneously the catalysis calcium sulfite when generating rapidly and the oxygen generation calcium sulfate that reacts, and impel calcium sulfate to be solidified into piece.
The fire coal combustion-supporting solid sulphur formula contains a large amount of active metal oxide, except with sulfurous gas generation chemical reaction, also play combustion-supporting and effect catalyticcombustion, changed the inadequate situation of original burning.Also have a considerable amount of elemental metals high energy fuels in the fire coal combustion-supporting solid sulphur formula, during burning and strong oxidizer generation replacement(metathesis)reaction discharge a large amount of heat energy, more than making temperature of combustion raising 50-100 degree, original aphlogistic composition in low grade coal, also can fully burn as coal gangue, make the rear slag content decline 5-10% of burning.After adding solid sulphur formula, make the temperature of combustion in burner hearth improve 50-100, those superfine pulverized coal faces and the abundant burning conversion of suspended particulate are become heat energy.
Therefore, improve burning of coal thermo-efficiency, reduced widely again smoke contamination simultaneously, make the graceful blackness of flue dust lattice reach the standard of national requirements and control.Solve problem of environmental pollution, can not discharge black smoke and dust to sky, reduced the destruction to air quality, greatly reduced the sulfur dioxide in flue gas discharge capacity, improved temperature of combustion, made fuel combustion abundant, eliminated black smoke, purified air, reduced the pollution to environment.
In the fire coal combustion-supporting solid sulphur formula, each component is harmless to calciner, can effectively reduce the sulphur gaseous emission by the solid sulphur of economizing on coal, and therefore, has great economy, society, environmental benefit, can be widely used in the production of cement mill.
Embodiment
The invention will be further described below in conjunction with embodiment:
Embodiment 1
The assembly weight percent is: Wingdale 30-50%, and calcium hydroxide 3-20%, calcium carbonate 10-20%, sodium carbonate 3-15%, ammonium nitrate 10-20%, grog sintering agent 10-30%, above each component sum by weight ratio are 100%; In Wingdale, the content of calcium oxide is not less than 40%.
Embodiment 2
Wingdale 30-40%, calcium hydroxide 10-20%, calcium carbonate 10-20%, sodium carbonate 3-10%, ammonium nitrate 10-15%, grog sintering agent 10-20%, above each component sum by weight ratio are 100%; In Wingdale, the content of calcium oxide is not less than 40%.
Embodiment 3
The combustion-supporting solid sulfide material is to contain a kind of or combination wherein of cobalt, cadmium, lanthanide rare natural mineral.
Embodiment 4
Grog sintering agent assembly weight percent is: cobalt oxide 55-70%, and Cadmium oxide 20-40%, lanthanide rare titanium dioxide lanthanum 5-10%, above each component sum by weight ratio are 100%.
Claims (5)
1. cement mill fire coal combustion-supporting solid sulfide compound formulation, it is waited to levy and is: the assembly weight percent is: Wingdale 30-50%, calcium hydroxide 3-20%, calcium carbonate 10-20%, sodium carbonate 3-15%, ammonium nitrate 10-20%, grog sintering agent 10-30%, above each component sum by weight ratio are 100%.
2. a kind of cement mill according to claim 1 fire coal combustion-supporting solid sulfide compound formulation, it is waited to levy and is: Wingdale 30-40%, calcium hydroxide 10-20%, calcium carbonate 10-20%, sodium carbonate 3-10%, ammonium nitrate 10-15%, grog sintering agent 10-20%, above each component sum by weight ratio are 100%.
3. a kind of cement mill according to claim 1 fire coal combustion-supporting solid sulfide compound formulation, it is waited to levy and is: in Wingdale, the content of calcium oxide is not less than 40%.
4. a kind of cement mill according to claim 1 fire coal combustion-supporting solid sulfide compound formulation, it is waited to levy and is: the combustion-supporting solid sulfide material is to contain a kind of or combination wherein of cobalt, cadmium, lanthanide rare natural mineral.
5. a kind of cement mill according to claim 1 fire coal combustion-supporting solid sulfide compound formulation, it is waited to levy and is: grog sintering agent assembly weight percent is: cobalt oxide 55-70%, Cadmium oxide 20-40%, lanthanide rare titanium dioxide lanthanum 5-10%, above each component sum by weight ratio are 100%.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103131513A (en) * | 2013-02-07 | 2013-06-05 | 洛阳大泽节能环保科技有限公司 | Thermal power plant fire coal combustion supporting and sulfur fixation composition method |
| CN103131519A (en) * | 2013-02-07 | 2013-06-05 | 洛阳大泽节能环保科技有限公司 | Boiler fire coal sulfur fixation composition method |
Citations (5)
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| US5246470A (en) * | 1992-12-02 | 1993-09-21 | Lloyd Berg | Removal of sulfur from coal and pitch with dolomite |
| CN1766074A (en) * | 2005-11-01 | 2006-05-03 | 海城正大环保节能材料有限公司 | Formulation and preparation method of desulfurization agent for assisting combustion of fire coal |
| CN101168128A (en) * | 2006-10-25 | 2008-04-30 | 刘芬 | Composite metal oxide catalyst and its preparing process and use |
| CN101691514A (en) * | 2009-10-22 | 2010-04-07 | 洛阳大泽节能环保科技有限公司 | Coal dust combustion improver for cement kiln |
| CN102559331A (en) * | 2011-12-26 | 2012-07-11 | 洛阳大泽节能环保科技有限公司 | Pulverized coal combustion improver for thermal power plant |
-
2013
- 2013-02-07 CN CN2013100610510A patent/CN103131516A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5246470A (en) * | 1992-12-02 | 1993-09-21 | Lloyd Berg | Removal of sulfur from coal and pitch with dolomite |
| CN1766074A (en) * | 2005-11-01 | 2006-05-03 | 海城正大环保节能材料有限公司 | Formulation and preparation method of desulfurization agent for assisting combustion of fire coal |
| CN101168128A (en) * | 2006-10-25 | 2008-04-30 | 刘芬 | Composite metal oxide catalyst and its preparing process and use |
| CN101691514A (en) * | 2009-10-22 | 2010-04-07 | 洛阳大泽节能环保科技有限公司 | Coal dust combustion improver for cement kiln |
| CN102559331A (en) * | 2011-12-26 | 2012-07-11 | 洛阳大泽节能环保科技有限公司 | Pulverized coal combustion improver for thermal power plant |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103131513A (en) * | 2013-02-07 | 2013-06-05 | 洛阳大泽节能环保科技有限公司 | Thermal power plant fire coal combustion supporting and sulfur fixation composition method |
| CN103131519A (en) * | 2013-02-07 | 2013-06-05 | 洛阳大泽节能环保科技有限公司 | Boiler fire coal sulfur fixation composition method |
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Application publication date: 20130605 |