CN103031728B - Skin-touch matte washing and brightening treatment agent for synthetic leather and preparation method thereof - Google Patents

Skin-touch matte washing and brightening treatment agent for synthetic leather and preparation method thereof Download PDF

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Publication number
CN103031728B
CN103031728B CN201210300433.XA CN201210300433A CN103031728B CN 103031728 B CN103031728 B CN 103031728B CN 201210300433 A CN201210300433 A CN 201210300433A CN 103031728 B CN103031728 B CN 103031728B
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weight portion
synthetic leather
skinfeel
finishing agent
polyurethane resin
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CN201210300433.XA
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CN103031728A (en
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齐春红
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Jiangsu Baoze Polymer Materials Co Ltd
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Jiangsu Baoze Polymer Materials Co Ltd
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Priority to CN201210300433.XA priority Critical patent/CN103031728B/en
Priority to PCT/CN2012/001651 priority patent/WO2014029054A1/en
Publication of CN103031728A publication Critical patent/CN103031728A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12Aldehydes; Ketones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/08Processes in which the treating agent is applied in powder or granular form
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

Abstract

The invention relates to a skin-touch matte washing and brightening treatment agent for synthetic leather. The skin-touch matte washing and brightening treatment agent comprises the following components: modified polyurethane resin, cyclohexanone, dimethyl benzene, butyl acetate, nano-elastic powder, silicon dioxide matting powder, aminosilicone and castor oil. The invention further relates to a preparation method of the skin-touch matte washing and brightening treatment agent for synthetic leather. Compared with the existing treatment agent for ordinary synthetic leather, the skin-touch matte washing and brightening treatment agent for synthetic leather, which is disclosed by the invention, has excellent fog degree and degree of blackness and further has unique skin-touch hand feeling after water washing and graining treatment, the bottom of a surface channel is foggy, the top layer is bright, the bright-fog contrast effect of the leather surface is unique, and the leather treated by using the treatment agent has the advantages of natural luster, clear color and luster, smooth hand feeling, strong true leather effect and excellent comprehensive effects.

Description

A kind of use for synthetic leather skinfeel cloudy surface washes bright finishing agent and preparation method thereof
Technical field
The present invention relates to a kind of use for synthetic leather skinfeel cloudy surface and wash bright finishing agent and preparation method thereof, particularly a kind of use for synthetic leather skinfeel cloudy surface being applied to synthetic leather rear section technique washes bright finishing agent and preparation method thereof.
Background technology
At present, synthetic leather has been widely used in producing the product such as case and bag, clothes, footwear, and synthetic leather has good, the resistance to complications of physical property, pliability is good, tensile strength is large feature, and has gas permeability.Therefore synthetic leather is widely used in the position that the fabric of footwear or case and bag bear weight.The surface of synthetic leather often needs the leather obtaining having different performance feature with some surface conditioning agents.In the last few years, along with consumer requires more and more higher to the color and luster of leather surface and feel, such as require that leather surface has unique skin quality feel, the bright mist contrast effect of leather surface was good, color clarification nature.
Therefore, the common synthetic leather surface conditioning agent of original maturation can not meet the requirement that consumer increases day by day to aesthetic feeling and feel, and use for synthetic leather skinfeel cloudy surface is washed bright finishing agent and had not yet to see report.
Summary of the invention
The object of the invention is to propose a kind of use for synthetic leather skinfeel cloudy surface and wash bright finishing agent and preparation method thereof.
Use for synthetic leather skinfeel cloudy surface of the present invention is washed bright finishing agent and is achieved through the following technical solutions:
Use for synthetic leather skinfeel cloudy surface disclosed in this invention washes bright finishing agent, composed of the following components: modified polyurethane resin, cyclohexanone, dimethylbenzene, butyl acetate, nano-elastic powder, silica flatting silica, amido silicon oil, castor oil.
The proportioning that use for synthetic leather skinfeel cloudy surface provided by the invention washes each component of bright finishing agent is as follows: modified polyurethane resin 35 ~ 38 weight portion, cyclohexanone 22 ~ 28 weight portion, dimethylbenzene 10 ~ 12 weight portion, butyl acetate 15 ~ 18 weight portion, nano-elastic powder 3 ~ 5 weight portion, silica flatting silica 3 ~ 4 weight portion, amido silicon oil 1.5 ~ 2 weight portion, castor oil 0.5 ~ 1 weight portion.
In one embodiment of the invention, the proportioning that use for synthetic leather skinfeel cloudy surface washes each component of bright finishing agent is as follows: modified polyurethane resin 38 weight portion, cyclohexanone 23 weight portion, dimethylbenzene 12 weight portion, butyl acetate 17 weight portion, nano-elastic powder 3 weight portion, silica flatting silica 4 weight portion, amido silicon oil 2 weight portion, castor oil 1 weight portion.
In another embodiment of the invention, the proportioning that use for synthetic leather skinfeel cloudy surface washes each component of bright finishing agent is as follows: modified polyurethane resin 33 weight portion, cyclohexanone 28 weight portion, dimethylbenzene 10 weight portion, butyl acetate 18 weight portion, nano-elastic powder 5 weight portion, silica flatting silica 4 weight portion, amido silicon oil 1.5 weight portion, castor oil 0.5 weight portion.
In another embodiment of the invention, the proportioning that use for synthetic leather skinfeel cloudy surface washes each component of bright finishing agent is as follows: modified polyurethane resin 38 weight portion, cyclohexanone 26 weight portion, dimethylbenzene 11 weight portion, butyl acetate 15 weight portion, nano-elastic powder 4 weight portion, silica flatting silica 3 weight portion, amido silicon oil 2 weight portion, castor oil 1 weight portion.
In another embodiment of the invention, the proportioning that use for synthetic leather skinfeel cloudy surface washes each component of bright finishing agent is as follows: modified polyurethane resin 35 weight portion, cyclohexanone 28 weight portion, dimethylbenzene 10 weight portion, butyl acetate 18 weight portion, nano-elastic powder 3 weight portion, silica flatting silica 3.6 weight portion, amido silicon oil 1.7 weight portion, castor oil 0.7 weight portion.
In another embodiment of the invention, the proportioning that use for synthetic leather skinfeel cloudy surface washes each component of bright finishing agent is as follows: modified polyurethane resin 38 weight portion, cyclohexanone 22 weight portion, dimethylbenzene 12 weight portion, butyl acetate 16 weight portion, nano-elastic powder 5 weight portion, silica flatting silica 4 weight portion, amido silicon oil 2 weight portion, castor oil 1 weight portion.
The preparation method that use for synthetic leather skinfeel cloudy surface of the present invention washes bright finishing agent is:
1) grind filtration after cyclohexanone, dimethylbenzene, butyl acetate, nano-elastic powder, silica flatting silica and partially modified polyurethane resin being stirred, discard filter residue;
2) amido silicon oil, castor oil are added in the mixture of step 1) gained, stir;
3) in step 2) add remaining modified polyurethane resin in the mixture of gained, stir.
Use for synthetic leather skinfeel cloudy surface provided by the present invention is washed in the preparation method of bright finishing agent, the proportioning of each component can be as follows: modified polyurethane resin 35 ~ 38 weight portion, cyclohexanone 22 ~ 28 weight portion, dimethylbenzene 10 ~ 12 weight portion, butyl acetate 15 ~ 18 weight portion, nano-elastic powder 3 ~ 5 weight portion, silica flatting silica 3 ~ 4 weight portion, amido silicon oil 1.5 ~ 2 weight portion, castor oil 0.5 ~ 1 weight portion.
In any of the embodiments of the present invention, use for synthetic leather skinfeel cloudy surface wash the preparation method of bright finishing agent institute carry out all at normal temperatures and pressures in steps.
Use for synthetic leather skinfeel cloudy surface provided by the present invention washes bright finishing agent after on probation, finds to compare with original leather surface treatment agent, has the following advantages:
1, use for synthetic leather skinfeel cloudy surface washes bright finishing agent is ep-type material, meets the environmental protection standard of European Union;
2, form that each component that skinfeel cloudy surface washes bright finishing agent is coordinated mutually, acting in conjunction, mist degree, blackness are splendid, after line process is rubbed in washing, have unique skinfeel feel, surface bottom of trench mist, top layer is bright, and the bright mist contrast effect of leather surface is unique, the leather gloss nature made with this kind of finishing agent, color clarification, feel is smooth, and leather effect is strong, and resultant effect is good;
3, skinfeel cloudy surface of the present invention is washed bright finishing agent to apply on existing synthetic leather production line, technique is simple, is a kind of new material of back segment printing washing, increases cost without the need to changing production equipment.
Wherein, " nano-elastic powder " in the present invention is " elastic polyurethane powder ", specifically refers to the powder of Nano grade.
Detailed description of the invention
Below by embodiment, technical solution of the present invention is described in detail, but protection scope of the present invention is not limited to described embodiment.
embodiment 1
At normal temperatures and pressures, modified polyurethane resin 20 weight portion is dropped in the reactor of 1L, cyclohexanone 23 weight portion, dimethylbenzene 12 weight portion, butyl acetate 17 weight portion, nano-elastic powder 3 weight portion, silica flatting silica 4 weight portion, filter after being at room temperature stirred well to grinding in few 30 minutes, discard filter residue; Amido silicon oil 2 weight portion, castor oil 1 weight portion is added, at room temperature uniform stirring in the mixture of gained; Add remaining modified polyurethane resin 18 weight portion again, at room temperature uniform stirring is after at least 30 minutes to viscosity stabilization, and the use for synthetic leather skinfeel cloudy surface namely obtained without precipitation, micro-yellow transparency liquid washes bright finishing agent finished product.
The use for synthetic leather skinfeel cloudy surface obtained washes the performance indications of bright finishing agent in table 1.
Table 1
Project Index Testing result
PH value 6.5-8 7.6
Outward appearance Micro-yellow transparency liquid Micro-yellow transparency liquid
Stability Without precipitation, nondiscolouring Without precipitation, nondiscolouring
Viscosity (cps/ DEG C) 500-800 728
Solid content (%) 22±1 22.4
The methods such as the stirring adopted in above-mentioned preparation process, filtration are customary way in this area.
embodiment 2
At normal temperatures and pressures, modified polyurethane resin 15 weight portion is dropped in the reactor of 1L, cyclohexanone 28 weight portion, dimethylbenzene 10 weight portion, butyl acetate 18 weight portion, nano-elastic powder 5 weight portion, silica flatting silica 4 weight portion, filter after being at room temperature stirred well to grinding in few 30 minutes, discard filter residue; Amido silicon oil 1.5 weight portion, castor oil 0.5 weight portion is added, at room temperature uniform stirring in the mixture of gained; Add remaining modified polyurethane resin 18 weight portion again, at room temperature uniform stirring is after at least 30 minutes to viscosity stabilization, and the use for synthetic leather skinfeel cloudy surface namely obtained without precipitation, micro-yellow transparency liquid washes bright finishing agent finished product.
The use for synthetic leather skinfeel cloudy surface obtained washes the performance indications of bright finishing agent in table 2.
Table 2
Project Index Testing result
PH value 6.5-8 6.7
Outward appearance Micro-yellow transparency liquid Micro-yellow transparency liquid
Stability Without precipitation, nondiscolouring Without precipitation, nondiscolouring
Viscosity (cps/ DEG C) 500-800 634
Solid content (%) 22±1 22.4
The methods such as the stirring adopted in above-mentioned preparation process, filtration are customary way in this area.
embodiment 3
At normal temperatures and pressures, modified polyurethane resin 20 weight portion is dropped in the reactor of 1L, cyclohexanone 26 weight portion, dimethylbenzene 11 weight portion, butyl acetate 15 weight portion, nano-elastic powder 4 weight portion, silica flatting silica 3 weight portion, filter after being at room temperature stirred well to grinding in few 30 minutes, discard filter residue; Amido silicon oil 2 weight portion, castor oil 1 weight portion is added, at room temperature uniform stirring in the mixture of gained; Add remaining modified polyurethane resin 18 weight portion again, at room temperature uniform stirring is after at least 30 minutes to viscosity stabilization, and the use for synthetic leather skinfeel cloudy surface namely obtained without precipitation, micro-yellow transparency liquid washes bright finishing agent finished product.
The use for synthetic leather skinfeel cloudy surface obtained washes the performance indications of bright finishing agent in table 3.
Table 3
Project Index Testing result
PH value 6.5-8 6.9
Outward appearance Micro-yellow transparency liquid Micro-yellow transparency liquid
Stability Without precipitation, nondiscolouring Without precipitation, nondiscolouring
Viscosity (cps/ DEG C) 500-800 718
Solid content (%) 22±1 21.8
The methods such as the stirring adopted in above-mentioned preparation process, filtration are customary way in this area.
embodiment 4
At normal temperatures and pressures, modified polyurethane resin 20 weight portion is dropped in the reactor of 1L, cyclohexanone 28 weight portion, dimethylbenzene 10 weight portion, butyl acetate 18 weight portion, nano-elastic powder 3 weight portion, silica flatting silica 3.6 weight portion, filter after being at room temperature stirred well to grinding in few 30 minutes, discard filter residue; Amido silicon oil 1.7 weight portion, castor oil 0.7 weight portion is added, at room temperature uniform stirring in the mixture of gained; Add remaining modified polyurethane resin 15 weight portion again, at room temperature uniform stirring is after at least 30 minutes to viscosity stabilization, and the use for synthetic leather skinfeel cloudy surface namely obtained without precipitation, micro-yellow transparency liquid washes bright finishing agent finished product.
The use for synthetic leather skinfeel cloudy surface obtained washes the performance indications of bright finishing agent in table 4.
Table 4
Project Index Testing result
PH value 6.5-8 7.1
Outward appearance Micro-yellow transparency liquid Micro-yellow transparency liquid
Stability Without precipitation, nondiscolouring Without precipitation, nondiscolouring
Viscosity (cps/ DEG C) 500-800 592
Solid content (%) 22±1 21.3
The methods such as the stirring adopted in above-mentioned preparation process, filtration are customary way in this area.
embodiment 5
At normal temperatures and pressures, modified polyurethane resin 20 weight portion in the reactor of 1L, cyclohexanone 22 weight portion, dimethylbenzene 12 weight portion, butyl acetate 16 weight portion, nano-elastic powder 5 weight portion, silica flatting silica 4 weight portion, filter after being at room temperature stirred well to grinding in few 30 minutes, discard filter residue; Amido silicon oil 2 weight portion, castor oil 1 weight portion is added, at room temperature uniform stirring in the mixture of gained; Add remaining modified polyurethane resin 18 weight portion again, at room temperature uniform stirring is after at least 30 minutes to viscosity stabilization, and the use for synthetic leather skinfeel cloudy surface namely obtained without precipitation, micro-yellow transparency liquid washes bright finishing agent finished product.
The use for synthetic leather skinfeel cloudy surface obtained washes the performance indications of bright finishing agent in table 5.
Table 5
Project Index Testing result
PH value 6.5-8 7.8
Outward appearance Micro-yellow transparency liquid Micro-yellow transparency liquid
Stability Without precipitation, nondiscolouring Without precipitation, nondiscolouring
Viscosity (cps/ DEG C) 500-800 671
Solid content (%) 22±1 21.9
The methods such as the stirring adopted in above-mentioned preparation process, filtration are customary way in this area.
In sum, it is micro-yellow transparency liquid that use for synthetic leather skinfeel cloudy surface of the present invention washes bright finishing agent, and mist degree, blackness are splendid, after line process is rubbed in washing, have unique skinfeel feel, surperficial bottom of trench mist, top layer is bright, the bright mist contrast effect of leather surface is unique, the leather gloss nature made with this kind of finishing agent, color clarification, feel is smooth, leather effect is strong, and resultant effect is good.
Invention discloses as above with preferred embodiment; so itself and be not used to limit the present invention, any person of ordinary skill in the field, without departing from the spirit and scope of the invention; when doing a little change and improvement, the protection domain of therefore the present invention is when being as the criterion depending on the claim person of defining.

Claims (7)

1. a use for synthetic leather skinfeel cloudy surface washes bright finishing agent, it is characterized in that, the following component following by proportioning forms: modified polyurethane resin 38 weight portion, cyclohexanone 23 weight portion, dimethylbenzene 12 weight portion, butyl acetate 17 weight portion, nano-elastic powder 3 weight portion, silica flatting silica 4 weight portion, amido silicon oil 2 weight portion, castor oil 1 weight portion.
2. a use for synthetic leather skinfeel cloudy surface washes bright finishing agent, it is characterized in that, the each component following by proportioning forms: modified polyurethane resin 33 weight portion, cyclohexanone 28 weight portion, dimethylbenzene 10 weight portion, butyl acetate 18 weight portion, nano-elastic powder 5 weight portion, silica flatting silica 4 weight portion, amido silicon oil 1.5 weight portion, castor oil 0.5 weight portion.
3. a use for synthetic leather skinfeel cloudy surface washes bright finishing agent, it is characterized in that, the each component following by proportioning forms: modified polyurethane resin 38 weight portion, cyclohexanone 26 weight portion, dimethylbenzene 11 weight portion, butyl acetate 15 weight portion, nano-elastic powder 4 weight portion, silica flatting silica 3 weight portion, amido silicon oil 2 weight portion, castor oil 1 weight portion.
4. a use for synthetic leather skinfeel cloudy surface washes bright finishing agent, it is characterized in that, the each component following by proportioning forms: modified polyurethane resin 35 weight portion, cyclohexanone 28 weight portion, dimethylbenzene 10 weight portion, butyl acetate 18 weight portion, nano-elastic powder 3 weight portion, silica flatting silica 3.6 weight portion, amido silicon oil 1.7 weight portion, castor oil 0.7 weight portion.
5. a use for synthetic leather skinfeel cloudy surface washes bright finishing agent, it is characterized in that, the each component following by proportioning forms: modified polyurethane resin 38 weight portion, cyclohexanone 22 weight portion, dimethylbenzene 12 weight portion, butyl acetate 16 weight portion, nano-elastic powder 5 weight portion, silica flatting silica 4 weight portion, amido silicon oil 2 weight portion, castor oil 1 weight portion.
6. the use for synthetic leather skinfeel cloudy surface in claim 1-5 described in any one washes a preparation method for bright finishing agent, it is characterized in that, comprises following steps:
1) grind filtration after cyclohexanone, dimethylbenzene, butyl acetate, nano-elastic powder, silica flatting silica and partially modified polyurethane resin being stirred, discard filter residue;
2) amido silicon oil, castor oil are added step 1) in the mixture of gained, stir;
3) in step 2) add remaining modified polyurethane resin in the mixture of gained, stir.
7. use for synthetic leather skinfeel cloudy surface according to claim 6 washes the preparation method of bright finishing agent, it is characterized in that, institute carries out in steps all at normal temperatures and pressures.
CN201210300433.XA 2012-08-22 2012-08-22 Skin-touch matte washing and brightening treatment agent for synthetic leather and preparation method thereof Active CN103031728B (en)

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PCT/CN2012/001651 WO2014029054A1 (en) 2012-08-22 2012-12-07 Skin-touch matte washing and brightening treatment agent for synthetic leather and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103255627A (en) * 2013-05-21 2013-08-21 江苏宝泽高分子材料股份有限公司 Skin-touch polishing treatment agent for synthetic leather and preparation method thereof
CN103306138B (en) * 2013-06-26 2015-02-04 江苏宝泽高分子材料股份有限公司 Water-kneading pressure change resin for synthetic leather and preparing method of resin
CN104074056B (en) * 2014-07-03 2016-05-04 江苏宝泽高分子材料股份有限公司 Goth black inorganic agent of the special mist of a kind of use for synthetic leather and preparation method thereof
CN104088142B (en) * 2014-07-30 2016-03-09 江苏宝泽高分子材料股份有限公司 A kind of use for synthetic leather skin light polishing agent and preparation method thereof
CN104499291B (en) * 2014-12-17 2017-07-11 广东菲安妮皮具股份有限公司 A kind of leather matte surface finishing agent
CN105155275A (en) * 2015-07-13 2015-12-16 温州日胜新材料科技有限公司 Waterborne ultra-misty ultra-black velvet-feel treating agent used for synthetic leather
CN105297451A (en) * 2015-11-27 2016-02-03 江苏宝泽高分子材料股份有限公司 Skin-touch treatment agent and preparation method thereof
CN106521957A (en) * 2016-10-27 2017-03-22 江苏宝泽高分子材料股份有限公司 Skin feeling scraper material treating agent for synthetic leather and preparation method of skin feeling scraper material treating agent
CN110863359B (en) * 2019-11-29 2022-05-31 江苏宝泽高分子材料股份有限公司 Water-based transparent polishing treatment agent for clothing leather and preparation method thereof
CN111139661A (en) * 2019-12-24 2020-05-12 南通紫琅生物医药科技有限公司 Polyurethane skin-feel resin for high-temperature-resistant printable coating and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240145A (en) * 2008-03-13 2008-08-13 徐沛枫 Single-component skin similar texture paint
CN101328512A (en) * 2007-06-20 2008-12-24 时云刚 Carzy horse brushed resin for processing leather surface and preparing method thereof
CN101597438A (en) * 2009-02-04 2009-12-09 孔赟荣 A kind of prescription of polyurethane elastic process paint and preparation method
CN101892594A (en) * 2010-07-23 2010-11-24 江苏宝泽高分子材料股份有限公司 Sheep leather wax sense ironing brightness treating agent for synthetic leather and preparation method thereof
CN102182064A (en) * 2010-12-01 2011-09-14 江苏宝泽高分子材料股份有限公司 Super black flock oil wax sense polishing treatment agent for synthetic leather and preparation method thereof
CN102191689A (en) * 2010-12-01 2011-09-21 江苏宝泽高分子材料股份有限公司 Fogging surface silky wax feel finishing agent for synthetic leather and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101928510A (en) * 2010-09-29 2010-12-29 杭州中富彩新材料科技有限公司 Flatting agent for UV cured leathers and preparation method thereof
CN102168376B (en) * 2010-12-01 2013-06-19 江苏宝泽高分子材料股份有限公司 Ultra-black plush polish processing agent used for synthetic leather and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101328512A (en) * 2007-06-20 2008-12-24 时云刚 Carzy horse brushed resin for processing leather surface and preparing method thereof
CN101240145A (en) * 2008-03-13 2008-08-13 徐沛枫 Single-component skin similar texture paint
CN101597438A (en) * 2009-02-04 2009-12-09 孔赟荣 A kind of prescription of polyurethane elastic process paint and preparation method
CN101892594A (en) * 2010-07-23 2010-11-24 江苏宝泽高分子材料股份有限公司 Sheep leather wax sense ironing brightness treating agent for synthetic leather and preparation method thereof
CN102182064A (en) * 2010-12-01 2011-09-14 江苏宝泽高分子材料股份有限公司 Super black flock oil wax sense polishing treatment agent for synthetic leather and preparation method thereof
CN102191689A (en) * 2010-12-01 2011-09-21 江苏宝泽高分子材料股份有限公司 Fogging surface silky wax feel finishing agent for synthetic leather and preparation method thereof

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