CN102942904B - Paraffin-felt phase-changing composite heat storage material and heat storage device thereof - Google Patents
Paraffin-felt phase-changing composite heat storage material and heat storage device thereof Download PDFInfo
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- CN102942904B CN102942904B CN201210467994.9A CN201210467994A CN102942904B CN 102942904 B CN102942904 B CN 102942904B CN 201210467994 A CN201210467994 A CN 201210467994A CN 102942904 B CN102942904 B CN 102942904B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
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Abstract
The invention discloses a paraffin-felt phase-changing composite heat storage material, which mainly comprises paraffin and a felt. The felt is placed in melted paraffin for immersion, and after the felt is fully saturated, the felt is taken out and congealed to prepare the material. According to the paraffin-felt phase-changing composite heat storage material, paraffin is adopted as a phase-changing material, the felt is used as an absorption and support structure to prepare the material, thus the defects of flowing paraffin in a liquid phase and rapid radiation are overcome, and the prepared paraffin-felt phase-changing composite heat storage material has the advantages of a light proportion, fundamental non-flowing, a stable shape, zero corrosion and better and unexpected effects on heat storage and heat preservation.
Description
Technical field
The heat-storing device that the present invention relates to paraffin-felt phase transformation thermal energy storage material and utilize paraffin-felt phase transformation thermal energy storage material to be prepared from.
Background technology
In the winter time when cold weather, people's custom electric hot-water bag is warmed oneself, and electric hot-water bag becomes the indispensable article for keeping out cold of people.But electric hot-water bag adopts water as heat-storage medium, the mobility of water is strong, can scald people when electric hot-water bag leakage, and easily causes water bag expansion blast, can cause very large potential safety hazard to people.
The advantages such as paraffin has that physicochemical property long-term stability, heat accumulation rate are high, wide material sources, cheap, pollution-free, non-corrosiveness, be a kind of ideal phase-change heat-storage material, people attempt using it to replace water as heat accumulating.But single paraffin has liquid phase flow, the shortcomings such as slow and rapid heat dissipation of conducting heat.Although also there is the research of wax phase change matrix material at present, as phase change composite materials etc. such as paraffin-graphite, paraffin-perlite, paraffin-vermiculites, the heat insulation effect, soaking time etc. of these phase change composite materials are all undesirable.
Felt has that adsorptive power is strong, stable molding, the feature such as heat insulation, but it there is no heat storage function, and thermal conductivity is little, felt can be burnt during heating, and after stopping heating, heat disappears very soon.
Summary of the invention
The object of the invention is to overcome above-mentioned shortcoming, a kind of paraffin-felt phase transformation thermal energy storage material is provided, and the heat-storing device utilizing paraffin-felt phase transformation thermal energy storage material to be prepared from, utilize paraffin for phase change material, be that absorption and supporting structure are prepared from felt, have than single paraffin and the beyond thought better heat-storage heat-preserving effect of water.
For solving the problem, the present invention is achieved through the following technical solutions:
Paraffin of the present invention-felt phase transformation thermal energy storage material, it, primarily of paraffin and felt composition, is flooded by paraffin felt being placed in fusing, after felt absorption is full, takes out cooled and solidified and is prepared from.
The PE wax of 10% is added by weight in described paraffin.
Described paraffin is refined wax or the SEMI-REFINED PARAFFIN WAX of fusing point 58-60 DEG C.
The invention still further relates to a kind of heat-storing device utilizing described paraffin-felt phase transformation thermal energy storage material to be prepared from, its outside paraffin-felt phase transformation thermal energy storage material with aluminium-foil paper or conventional high-temperature resistant membrane (as nylon film etc.) coated encapsulation.
At least two-layer paraffin-felt phase transformation thermal energy storage material is comprised in described heat-storing device.
Position between described paraffin-felt phase transformation thermal energy storage material is two-layer arranges fever tablet and temperature control electronic package.
Paraffin of the present invention-felt phase transformation thermal energy storage material, utilize paraffin for phase change material, be that absorption and supporting structure are prepared from felt, overcome the shortcoming of paraffin liquid phase flow and rapid heat dissipation, obtained paraffin-felt phase transformation thermal energy storage material light specific gravity, substantially do not flow, dimensionally stable, non-corrosiveness, and there is better beyond thought heat-storage heat-preserving effect.Add PE wax (stablizer), make paraffin melting after more not easily trickle.Use refined wax or the SEMI-REFINED PARAFFIN WAX of fusing point 58-60 DEG C, the heat-storage heat-preserving better effects if of paraffin of the present invention-felt phase transformation thermal energy storage material can be made.
Based on the paraffin prepared-felt phase transformation thermal energy storage material, with aluminium-foil paper or conventional high-temperature resistant membrane (as nylon film etc.) coated encapsulation outside paraffin-felt phase transformation thermal energy storage material, the mobility of paraffin can be made to reduce.At least two-layer paraffin-felt phase transformation thermal energy storage material is comprised in heat-storing device, and the position between paraffin-felt phase transformation thermal energy storage material is two-layer arranges fever tablet and temperature control electronic package, this mode adds the contact area of paraffin and heating element, better solve paraffin to conduct heat slow shortcoming, paraffin is heated relatively uniform, increase the quantity of heat storage of paraffin, power and energy saving more.Temperature control electronic package is formed primarily of thermostat and overtemperature prote safety fuse, the temperature of heat-storing device can be made to control safer.
A kind of paraffin of the present invention-felt phase transformation thermal energy storage material, and utilize the heat-storing device that paraffin-felt phase transformation thermal energy storage material is prepared to may be used for the fields such as electric heating bag, warming shoe, incubation canteen, heat accumulation floor.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1:
Melted paraffin wax is become liquid (i.e. solid-liquid phase change) by heating, the paraffin being become by stamping-out the felt block of desired shape and size to be placed in fusing floods, after the absorption of felt block is full, takes out cooling solidification, namely make paraffin of the present invention-felt phase transformation thermal energy storage material.During scale operation, can by the felt of whole by stamping-out on request again after the condensation of e Foerderanlage Adsorption Paraffin.
Embodiment 2:
Melted paraffin wax is become liquid (i.e. solid-liquid phase change) by heating, add the PE wax (polyethylene wax (PE-WAX)) of 10% by weight, the paraffin being become by stamping-out the felt block of desired shape and size to be placed in fusing floods, after the absorption of felt block is full, take out cooling solidification, namely make paraffin of the present invention-felt phase transformation thermal energy storage material.During scale operation, can by the felt of whole by stamping-out on request again after the condensation of e Foerderanlage Adsorption Paraffin.
Embodiment 3:
The refined wax of fusing point 58-60 DEG C or SEMI-REFINED PARAFFIN WAX are fused into liquid (i.e. solid-liquid phase change) by heating, the paraffin being become by stamping-out the felt block of desired shape and size to be placed in fusing floods, after the absorption of felt block is full, take out cooling solidification, namely make paraffin of the present invention-felt phase transformation thermal energy storage material.During scale operation, can by the felt of whole by stamping-out on request again after the condensation of e Foerderanlage Adsorption Paraffin.
Embodiment 4:
The refined wax of fusing point 58-60 DEG C or SEMI-REFINED PARAFFIN WAX are fused into liquid (i.e. solid-liquid phase change) by heating, add the PE wax (polyethylene wax (PE-WAX)) of 10% by weight, the paraffin being become by stamping-out the felt block of desired shape and size to be placed in fusing floods, after the absorption of felt block is full, take out cooling solidification, namely make paraffin of the present invention-felt phase transformation thermal energy storage material.During scale operation, can by the felt of whole by stamping-out on request again after the condensation of e Foerderanlage Adsorption Paraffin.
The paraffin prepared by the present invention-felt phase transformation thermal energy storage material (representing with this material in form) and traditional heat-storage medium-water and single paraffin phase ratio, had the following advantages:
Project | This material | Water | Paraffin |
Light specific gravity | 0.69 | 1 | 0.9 |
Soaking time is long | 4 hours | 2.5 hour | 1.3 hour |
Mobility | Substantially do not flow | Mobility is strong | More liquid |
Felt has that adsorptive power is strong, stable molding, the feature such as heat insulation, but it there is no heat storage function, thermal conductivity is little, heating time felt can be burnt, after stopping heating, heat disappears very soon.
Embodiment 5:
First required paraffin-felt phase transformation thermal energy storage material is obtained according to the method for embodiment 1-4, then outside paraffin-felt phase transformation thermal energy storage material with aluminium-foil paper or conventional high-temperature resistant membrane (as nylon film etc.) coated encapsulation, be prepared into heat-storing device; Comprise at least two-layer paraffin-felt phase transformation thermal energy storage material in heat-storing device, and the position between paraffin-felt phase transformation thermal energy storage material is two-layer arranges fever tablet and temperature control electronic package.
The outside of heat-storing device cover is designed to the cloth bag of different shape on request, and on cloth bag back boxing, sponge etc. strengthen feel, just make Waterless electric heating bag.Heat-storing device is arranged at the large end of shoes, just becomes heat-storage warm-keeping shoes.Heat-storing device is arranged in incubation canteen, just greatly can extends soaking time.Heat-storing device is arranged in floor, just can makes the significant heat accumulation floor of power saving.The present invention can also develop the warming product innovation of more heat accumulation, is a kind of very promising heat accumulation novel material.
In sum, be only preferred embodiment of the present invention, not any pro forma restriction done to the present invention; The those of ordinary skill of all industry all can implement the present invention by the above swimmingly; But all those skilled in the art are not departing within the scope of technical solution of the present invention, disclosed above technology contents can utilized and a little change of making, modify and the equivalent variations developed, be Equivalent embodiments of the present invention; Meanwhile, all according to substantial technological of the present invention to the change of any equivalent variations that above embodiment is done, modify and differentiation, within the protection domain all still belonging to technical scheme of the present invention.
Claims (1)
1. the heat-storing device utilizing paraffin-felt phase transformation thermal energy storage material to be prepared from, is characterized in that:
Paraffin-felt phase transformation thermal energy storage material, primarily of paraffin and felt composition, is flooded by paraffin felt being placed in fusing, after felt absorption is full, takes out cooled and solidified and is prepared from;
At least two-layer paraffin-felt phase transformation thermal energy storage material is comprised in heat-storing device; Position between paraffin-felt phase transformation thermal energy storage material is two-layer arranges fever tablet and temperature control electronic package;
With aluminium-foil paper or the coated encapsulation of high-temperature resistant membrane outside paraffin-felt phase transformation thermal energy storage material;
Wherein paraffin is refined wax or the SEMI-REFINED PARAFFIN WAX of fusing point 58-60 DEG C, adds the PE wax of 10% in paraffin by weight.
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CN103409113A (en) * | 2013-07-23 | 2013-11-27 | 苏州天脉导热科技有限公司 | A heat storage material |
CN106820524A (en) * | 2015-12-03 | 2017-06-13 | 哈尔滨市三和佳美科技发展有限公司 | Heat storage type incubation canteen |
CN105694824A (en) * | 2016-04-12 | 2016-06-22 | 段传璞 | Method for preparing phase-change composite materials applied to hot-water bags |
CN113388240B (en) * | 2021-06-15 | 2023-05-09 | 威驰腾(福建)汽车有限公司 | Graphite felt composite material and forming method thereof |
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CN102282302A (en) * | 2008-12-19 | 2011-12-14 | Iq泰克斯专利管理有限责任公司 | Super absorber polymer felt and method for the production thereof |
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CN102282302A (en) * | 2008-12-19 | 2011-12-14 | Iq泰克斯专利管理有限责任公司 | Super absorber polymer felt and method for the production thereof |
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Denomination of invention: Paraffin-felt phase-changing composite heat storage material and heat storage device thereof Effective date of registration: 20160322 Granted publication date: 20150715 Pledgee: Foshan Nanhai Lishui Town Xinlian Economic Association Pledgor: Feng Zhibiao Registration number: 2016990000227 |
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