CN102925048B - A kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof - Google Patents

A kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof Download PDF

Info

Publication number
CN102925048B
CN102925048B CN201210480381.9A CN201210480381A CN102925048B CN 102925048 B CN102925048 B CN 102925048B CN 201210480381 A CN201210480381 A CN 201210480381A CN 102925048 B CN102925048 B CN 102925048B
Authority
CN
China
Prior art keywords
water
component
defoamer
flow agent
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201210480381.9A
Other languages
Chinese (zh)
Other versions
CN102925048A (en
Inventor
朱忠敏
尤先锋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dong Lai coating technology (Shanghai) Limited by Share Ltd
Original Assignee
Eastern Paint Technology (shanghai) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastern Paint Technology (shanghai) Co Ltd filed Critical Eastern Paint Technology (shanghai) Co Ltd
Priority to CN201210480381.9A priority Critical patent/CN102925048B/en
Publication of CN102925048A publication Critical patent/CN102925048A/en
Application granted granted Critical
Publication of CN102925048B publication Critical patent/CN102925048B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof, this varnish comprises following component and weight percentage: component A: water-base resin 50 ~ 70%, water-based defoamer 0.1 ~ 2.0%, water-based thickener 0.5 ~ 4.0%, water-based flow agent 1 ~ 3%, solubility promoter 1 ~ 8%, aqueous wetting agent 0.1 ~ 2% and deionized water 2 ~ 10%; B component: water-based polyisocyanate ester dispersion 15% ~ 25%, solvent 2% ~ 7%.Compared with prior art, the present invention has the advantages such as harmless, environmental protection.

Description

A kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof
Technical field
The present invention relates to a kind of automobile retouching paint, especially relate to a kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof.
Background technology
Widely used on current automotive refinishing market is solvent-based varnishes, the solvent of traditional solvent-borne type retouching paint is everlasting more than 40%, these volatile organic compounds (VOC) enter air, can cause the pollution of environment, work the mischief to the healthy of application workman simultaneously.Along with the raising of people to the attention degree of health, car refinishing paint also towards health environment-friendly development, just progressively rise to aqueous automobile retouching paint varnish demand in market.
Summary of the invention
Object of the present invention be exactly in order to overcome above-mentioned prior art exist defect and a kind of harmless environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof is provided.
Object of the present invention can be achieved through the following technical solutions: a kind of environment-friendly water-based bicomponent automobile retouching paint varnish, and it is characterized in that, this varnish comprises following component and weight percentage:
Component A: water-base resin 50 ~ 70%, water-based defoamer 0.1 ~ 2.0%, water-based thickener 0.5 ~ 4.0%, water-based flow agent 1 ~ 3%, solubility promoter 1 ~ 8%, aqueous wetting agent 0.1 ~ 2% and deionized water 2 ~ 10%;
B component: water-based polyisocyanate ester dispersion 15% ~ 25%, solvent 2% ~ 7%.
Described water-base resin is selected from water-based hydroxyl acrylated polyurethane resin; Described water-based defoamer is polyether type defoamer or organic defoamer; Described water-based thickener is agent for polyacrylic acid thickening, cellulose thickener or polyurethanes thickening material; Described water-based flow agent is modified polyorganosiloxane class water-based flow agent, silicone based water-based flow agent or micronization wax emulsion class water-based flow agent; Described aqueous wetting agent is polyether silicone class wetting agent.
Described water-based hydroxyl acrylated polyurethane resin is Bayhydrol A 2801, Bayhydrol A 2470 or Bayhydrol A 2770; Described polyether type defoamer is TEGO Foamex 825, TEGO Foamex 822 or TEGO Foamex 830, and described organic defoamer is whiteruss or lipid acid; Described agent for polyacrylic acid thickening is Viscalex HV 30, and described cellulose thickener is HEC or HPC, and described polyurethanes thickening material is Rheolate 212 or Rheolate288; Described modified polyorganosiloxane class water-based flow agent is Levelol W-469 or Levaslip W-461, and described silicone based water-based flow agent is BYK-341 or BYK335, and described micronization wax emulsion class water-based flow agent is EFKA-906; Described aqueous wetting agent is Tego wet 245.
Described solubility promoter is selected from propyl carbinol, Virahol, one or more in propylene glycol monomethyl ether, dipropylene glycol monomethyl ether.
Described water-based polyisocyanate ester dispersion is Bayhydrol XP 305 or Bayhydrol XP 304.
Described solvent is PMA.
A kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof, it is characterized in that, the method comprises the following steps:
(1) by water-base resin, water-based defoamer, water-based thickener adds successively and mixes under whipped state;
(2) by water-based flow agent, aqueous wetting agent, solubility promoter and deionized water add in above-mentioned component successively, and stir, and prepare component A;
(3) by water-based polyisocyanate resin, solvent and deionized water add under whipped state, and stir, and prepare component B;
During use, component A and B component are mixed use;
By weight percentage, in aforesaid method, each raw-material add-on used adds up to: component A: water-base resin 50 ~ 70%, water-based defoamer 0.1 ~ 2.0%, water-based thickener 0.5 ~ 4.0%, water-based flow agent 1 ~ 3%, solubility promoter 1 ~ 8%; Aqueous wetting agent 0.1 ~ 2% and deionized water 2 ~ 10%; B component: water-based polyisocyanate ester dispersion 15% ~ 25%, solvent 2% ~ 7%.
Compared with prior art, the invention provides a kind of preparation method of environment-friendly water-based bicomponent automobile retouching paint varnish, thinner can adopt deionized water, and decrease harmful organic solvent and to volatilize the pollution caused, product performance reach the technical indicator of solvent borne car repair varnish.And have the following advantages:
(1) environment-friendly type, to workman's health almost fanout free region;
(2) can directly use deionized water as thinner, reduce the discharge of VOC;
(3) can with the solvent borne priming paint of routine and colored paint coordinative construction.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
In following examples, each component is all by weight percentage:
Embodiment 1
A preparation method for environment-friendly water-based bicomponent automobile retouching paint varnish, the method comprises following processing step:
(1) first by water-base resin (Bayhydrol A 2801) 60%, water-based defoamer (Foamex825) 1%, water-based thickener (Rheolate288) 3.0%, adds successively under whipped state and mixes;
(2) by water-based flow agent (BYK 341) 2%, aqueous wetting agent (Tego Wet 245) 1%, solubility promoter (propylene glycol monomethyl ether) 2%, deionized water 8% adds in above-mentioned component successively, and stir, prepare component A
(3) by water-based polyisocyanate ester dispersion (Bayhydrol XP 305) 18%, solvent (PMA) 5%, adds successively and stirs; Obtain component B.
Component A and B uses after mixing when constructing.
Embodiment 2
A preparation method for environment-friendly water-based bicomponent automobile retouching paint varnish, the method comprises following processing step:
(1) first by water-base resin (Bayhydrol A 2470) 60%, water-based defoamer (Foamex822) 1.5%, water-based thickener (Rheolate212) 2.5%, adds successively under whipped state and mixes;
(2) by water-based flow agent (BYK 341) 2%, aqueous wetting agent (Tego Wet 245) 1%, solubility promoter (propylene glycol monomethyl ether) 2%, deionized water 8% adds in above-mentioned component successively, and stir, prepare component A
(3) by water-based polyisocyanate ester dispersion (Bayhydrol XP 304) 18%, solvent (PMA) 5%, adds successively and stirs; Obtain component B.
Component A and B uses after mixing when constructing.
Embodiment 3
A preparation method for environment-friendly water-based bicomponent automobile retouching paint varnish, the method comprises following processing step:
(1) first by water-base resin (BayhydrolA 2770) 60%, water-based defoamer (Foamex830) 1%, water-based thickener (Rheolate288) 3.0%, adds successively under whipped state and mixes;
(2) by water-based flow agent (BYK 335) 1.5%, aqueous wetting agent (Tego Wet 245) 1.5%, solubility promoter (propylene glycol monomethyl ether) 2%, deionized water 8% adds in above-mentioned component successively, and stir, prepare component A
(3) by water-based polyisocyanate ester dispersion (Bayhydrol XP 305) 18%, solvent (PMA) 5%, adds successively and stirs; Obtain component B.
Component A and B uses after mixing when constructing.
Embodiment 4
A preparation method for environment-friendly water-based bicomponent automobile retouching paint varnish, the method comprises following processing step:
(1) first by water-base resin (Bayhydrol A 2770) 50%, water-based defoamer (Foamex830) 2%, water-based thickener (Viscalex HV 30) 4%, adds successively under whipped state and mixes;
(2) by water-based flow agent (Levelol W-469) 3%, aqueous wetting agent (Tego Wet 245) 8%, solubility promoter (propylene glycol monomethyl ether) 1%, deionized water 10% adds in above-mentioned component successively, and stir, prepare component A
(3) by water-based polyisocyanate ester dispersion (Bayhydrol XP305) 15%, solvent (PMA) 7%, adds successively and stirs; Obtain component B.
Component A and B uses after mixing when constructing.
Embodiment 5
A preparation method for environment-friendly water-based bicomponent automobile retouching paint varnish, the method comprises following processing step:
(1) first by water-base resin (Bayhydrol A 2470) 70%, water-based defoamer (TEGO Foamex 825) 0.1%, water-based thickener (HEC) 0.5%, adds successively under whipped state and mixes;
(2) by water-based flow agent (EFKA-906) 1%, aqueous wetting agent (Tego Wet 245) 1.3%, solubility promoter (propylene glycol monomethyl ether) 0.1%, deionized water 2% adds in above-mentioned component successively, and stir, prepare component A
(3) by water-based polyisocyanate ester dispersion (Bayhydrol XP 304) 23%, solvent (PMA) 2%, adds successively and stirs; Obtain component B.
Component A and B uses after mixing when constructing.
The technical indicator of above-described embodiment gained car repair varnish is as follows:

Claims (4)

1. an environment-friendly water-based bicomponent automobile retouching paint varnish, it is characterized in that, this varnish comprises following component and weight percentage:
Component A: water-base resin 50 ~ 70%, water-based defoamer 0.1 ~ 2.0%, water-based thickener 0.5 ~ 4.0%, water-based flow agent 1 ~ 3%, solubility promoter 1 ~ 8%, aqueous wetting agent 0.1 ~ 2% and deionized water 2 ~ 10%;
B component: water-based polyisocyanate ester dispersion 15% ~ 25%, solvent 2% ~ 7%;
Described water-base resin is selected from water-based hydroxyl acrylated polyurethane resin; Described water-based defoamer is polyether type defoamer or organic defoamer; Described water-based thickener is agent for polyacrylic acid thickening, cellulose thickener or polyurethanes thickening material; Described water-based flow agent is modified polyorganosiloxane class water-based flow agent, silicone based water-based flow agent or micronization wax emulsion class water-based flow agent; Described aqueous wetting agent is polyether silicone class wetting agent;
Described water-based hydroxyl acrylated polyurethane resin is Bayhydrol A2801, Bayhydrol A2470 or Bayhydrol A2770; Described polyether type defoamer is TEGO Foamex 825, TEGO Foamex 822 or TEGO Foamex 830, and described organic defoamer is whiteruss or lipid acid; Described agent for polyacrylic acid thickening is Viscalex HV 30, and described cellulose thickener is HEC or HPC, and described polyurethanes thickening material is Rheolate 212 or Rheolate288; Described modified polyorganosiloxane class water-based flow agent is Levelol W-469 or Levaslip W-461, and described silicone based water-based flow agent is BYK-341 or BYK335, and described micronization wax emulsion class water-based flow agent is EFKA-906; Described aqueous wetting agent is Tego wet 245.
2. one according to claim 1 environment-friendly water-based bicomponent automobile retouching paint varnish, is characterized in that, described solubility promoter is selected from propyl carbinol, Virahol, one or more in propylene glycol monomethyl ether, dipropylene glycol monomethyl ether.
3. one according to claim 1 environment-friendly water-based bicomponent automobile retouching paint varnish, is characterized in that, described solvent is PMA.
4. a preparation method for environment-friendly water-based bicomponent automobile retouching paint varnish as claimed in claim 1, it is characterized in that, the method comprises the following steps:
(1) by water-base resin, water-based defoamer, water-based thickener adds successively and mixes under whipped state;
(2) by water-based flow agent, aqueous wetting agent, solubility promoter and deionized water add in above-mentioned component successively, and stir, and prepare component A;
(3) by water-based polyisocyanate resin, solvent and deionized water add under whipped state, and stir, and prepare component B;
During use, component A and B component are mixed use;
By weight percentage, in aforesaid method, each raw-material add-on used adds up to: component A: water-base resin 50 ~ 70%, water-based defoamer 0.1 ~ 2.0%, water-based thickener 0.5 ~ 4.0%, water-based flow agent 1 ~ 3%, solubility promoter 1 ~ 8%; Aqueous wetting agent 0.1 ~ 2% and deionized water 2 ~ 10%; B component: water-based polyisocyanate ester dispersion 15% ~ 25%, solvent 2% ~ 7%.
CN201210480381.9A 2012-11-22 2012-11-22 A kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof Active CN102925048B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210480381.9A CN102925048B (en) 2012-11-22 2012-11-22 A kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210480381.9A CN102925048B (en) 2012-11-22 2012-11-22 A kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof

Publications (2)

Publication Number Publication Date
CN102925048A CN102925048A (en) 2013-02-13
CN102925048B true CN102925048B (en) 2015-09-02

Family

ID=47639983

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201210480381.9A Active CN102925048B (en) 2012-11-22 2012-11-22 A kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof

Country Status (1)

Country Link
CN (1) CN102925048B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103666227A (en) * 2013-11-28 2014-03-26 河南三元科技化工有限公司 Water-based environment-friendly two-component PU (polyurethane) automobile varnish and preparation method thereof
CN104130709A (en) * 2014-08-01 2014-11-05 苏彬煌 Varnish and preparation method thereof
JP6497700B2 (en) * 2015-03-26 2019-04-10 関西ペイント株式会社 Aqueous coloring base coating composition
JP6455853B2 (en) * 2015-03-30 2019-01-23 関西ペイント株式会社 Water-based metallic base coating composition
CN105295597A (en) * 2015-07-02 2016-02-03 江苏足迹涂料有限公司 Water-borne automobile polyurethane varnish and preparation method thereof
CN105086798B (en) * 2015-08-10 2017-07-14 上海市涂料研究所有限公司 It is a kind of suitable for aqueous protective coating of wide variety of substrates and preparation method thereof
CN107119213B (en) * 2017-07-05 2018-10-23 合肥万之景门窗有限公司 A kind of aluminium alloy extrusions and its preparation process
CN108219646A (en) * 2018-01-05 2018-06-29 东来涂料技术(上海)股份有限公司 One kind can selfreparing aqueous automobile repairing varnish and preparation method thereof
JP6626955B1 (en) * 2018-12-27 2019-12-25 日本ペイント・インダストリアルコ−ティングス株式会社 Aqueous coating composition and coating film forming method
CN113045977A (en) * 2021-03-17 2021-06-29 山东七维新材料有限公司 Water-based acrylic polyurethane coating for assembly type building steel structure and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7638198B2 (en) * 2004-06-09 2009-12-29 Honda Motor Co., Ltd. Clear coating composition, method of forming multilayer coating film and inmold decoration product
JP5139729B2 (en) * 2007-06-22 2013-02-06 大日精化工業株式会社 Waterborne intermediate coating for automobiles
CN102504660A (en) * 2011-11-15 2012-06-20 东莞劲胜精密组件股份有限公司 Water-based finishing paint for plastics and preparation method and application thereof
CN102604530B (en) * 2012-03-19 2014-07-09 上海门普来新材料股份有限公司 Environment-friendly water-based bi-component polyurethane steel-structure anti-corrosion finish paint and preparation method

Also Published As

Publication number Publication date
CN102925048A (en) 2013-02-13

Similar Documents

Publication Publication Date Title
CN102925048B (en) A kind of environment-friendly water-based bicomponent automobile retouching paint varnish and preparation method thereof
CN102190952A (en) Environment-friendly water-based single-component metallic-effect refinish paint for automobiles and preparation method thereof
CN102250536A (en) Environmentally-friendly water-based single-component solid-color automobile refinishing paint and preparation method thereof
CN107459892A (en) A kind of farm machinery baking vanish and preparation method thereof
CN102732131B (en) Thick slurry floating coating of a kind of water-base epoxy and preparation method thereof
CN104419286B (en) Spherical graphite coating and preparation method thereof
CN105155275A (en) Waterborne ultra-misty ultra-black velvet-feel treating agent used for synthetic leather
CN103666227A (en) Water-based environment-friendly two-component PU (polyurethane) automobile varnish and preparation method thereof
CN107629656A (en) A kind of aqueous elastic paint of quick-drying and pot-life length and preparation method thereof
CN105295597A (en) Water-borne automobile polyurethane varnish and preparation method thereof
CN102363705B (en) Water-based single-component full-gloss clear finishing paint and preparation method thereof
CN106010161A (en) Water-based metal anti-corrosion material and preparation method thereof
CN107400454A (en) A kind of salt spray resistance dual-component aqueous polyurethane varnish and preparation method thereof
CN107652729A (en) A kind of municipal environment-friendly type aqueous protective paint of iron guardrail and preparation method thereof
CN108329824A (en) A kind of aqueous light UV solidification aluminium paint, preparation method and its application method
CN105949914A (en) Waterborne glass baking paint and preparation method thereof
CN104559553A (en) Water-based plastic paint
CN103497607B (en) For environment-friendly water-based automobile metal effect coating and the preparation of plastic basis material ABS
CN104059461A (en) High-solid-content water-based clear lacquer
CN104987818A (en) High hardness and high wear resistance waterborne wood paint and preparation method thereof
CN103497664A (en) Environment-friendly water clear automobile original factory paint and preparation method thereof
CN102925047B (en) Prime and preparation method thereof in a kind of environment-friendly water-based bicomponent automobile retouching paint
CN109468045A (en) A kind of preparation method of aqueous high-performance nano antiseptic project machinery coating
CN102977688A (en) Water and oil available color paste and preparation method of same
CN106118399A (en) A kind of high-strength abrasion-proof modified poly ester amino-stoving varnish and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: 201807 new and Road No. 1221, Jiading Industrial Zone, Jiading District, Shanghai

Patentee after: Dong Lai coating technology (Shanghai) Limited by Share Ltd

Address before: 201807 Jiading District, Jiading Industrial Zone, North Road, the new and the No. 1221

Patentee before: Eastern paint technology (Shanghai) Co., Ltd.