CN102869334A - combination - Google Patents

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CN102869334A
CN102869334A CN2011800217268A CN201180021726A CN102869334A CN 102869334 A CN102869334 A CN 102869334A CN 2011800217268 A CN2011800217268 A CN 2011800217268A CN 201180021726 A CN201180021726 A CN 201180021726A CN 102869334 A CN102869334 A CN 102869334A
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preferably
composition
gel network
oil
fatty
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CN2011800217268A
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Chinese (zh)
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A·M·默里
T-A·法姆
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荷兰联合利华有限公司
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Priority to EP10161636 priority
Application filed by 荷兰联合利华有限公司 filed Critical 荷兰联合利华有限公司
Priority to PCT/EP2011/056162 priority patent/WO2011134832A2/en
Publication of CN102869334A publication Critical patent/CN102869334A/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/72Cosmetics or similar toilet preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/737Galactomannans, e.g. guar; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/02Cosmetics or similar toilet preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/042Gels
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/342Alcohols having more than seven atoms in an unbroken chain
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42Amides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

Abstract

Conditioning shampoo composition comprising: i) a cleansing phase, ii) a conditioning gel network comprising a fatty material; an anionic surfactant and a cationic surfactant; wherein the conditioning gel network has no overall charge or is anionic; iii) an oil; and iv) a hydrophobically modified cationic deposition polymer; in which cationic deposition polymer and the anionic surfactant of the gel network contain alkyl groups with within 4 carbons of each other.

Description

组合物技术领域[0001] 本发明涉及包含油的组合物。 Composition Technical Field [0001] The present invention relates to compositions comprising oil. 发明内容[0002] 在头发护理领域,需要改进的包含油的调理洗发剂组合物。 SUMMARY OF THE INVENTION [0002] In the hair care art, a need for improved conditioning shampoo composition comprising an oil composition. 特别是寻找尤其是在温度升高时的产品稳定性方面的改进。 In particular, looking especially to improve the stability of the product at elevated temperatures. [0003] 此外,本发明还具有不需要聚合悬浮剂、因此降低制剂成本的优点。 [0003] Further, the present invention further comprises a suspending agent does not require a polymerization, thus reducing the cost advantage of the formulation. [0004] 共同未决专利申请号EP09163568描述了包含1-26% wt.的清洁相、其中分散有油的调理凝胶网络、聚合悬浮剂和阳离子沉积聚合物的调理洗发剂组合物。 [0004] The copending patent application No. EP09163568 describes compositions comprising 1-26% wt. Of the cleansing phase, wherein the dispersed oil conditioning gel network, suspension polymerization, and cationic deposition polymer conditioning shampoo composition. [0005] 因此,本发明提供一种调理洗发剂组合物,其包含:[0006] i)清洁相,[0007] ii)调理凝胶网络,其包含脂肪物质、阴离子表面活性剂和阳离子表面活性剂;其中所述调理凝胶网络总体不带电荷或者是阴离子型;[0008] iii)油;和[0009] iv)疏水改性的阳离子沉积聚合物; [0005] Accordingly, the present invention provides a conditioning shampoo composition, comprising: [0006] i) a cleansing phase, [0007] ii) conditioning gel network, comprising fatty substances, anionic surfactants and cationic surfactants an active agent; wherein the conditioning gel network overall charge or is anionic; [0008] iii) an oil; and [0009] iv) a hydrophobically modified cationic deposition polymer;

[0010] 其中阳离子沉积聚合物和凝胶网络的阴离子表面活性剂包含彼此相差4个碳以内的烧基。 [0010] wherein the cationic deposition polymer and a gel network anionic surfactant comprising differ from one another within groups 4 carbon burning. [0011] 本说明书提到的所有粘度是在30°C下在带有转子(spindle)RV5的布氏粘度计上以20rpm测定的粘度。 [0011] In the present specification, all viscosities mentioned in at 30 ° C on a Brookfield viscometer with a rotor (spindle) RV5 20rpm to viscosity measurement. [0012] 优选地,所述组合物在30°C下测定的粘度为2000-7000cPs。 [0012] Preferably, the viscosity of the composition measured at 30 ° C to 2000-7000cPs. [0013] 调理凝胶网络[0014] 所述调理凝胶网络包含:[0015] (a)脂肪物质;[0016] (b)凝胶网络阴离子表面活性剂,其包含具有16-30个碳的烷基;[0017] (c)阳离子表面活性剂;[0018] 其中所述调理凝胶网络总体不带电荷或者是阴离子型。 [0013] conditioning gel network [0014] The conditioning gel network comprising: [0015] (a) fatty material; [0016] (b) a gel network anionic surfactant comprising 16-30 carbons having alkyl; [0017] (c) cationic surfactant; [0018] wherein the conditioning gel network overall charge or is anionic. [0019] 所述阳离子表面活性剂提供脂肪物质/阴离子表面活性剂凝胶网络的改善的稳定性,导致还包含非阳离子清洁相的组合物的改善的调理益处。 [0019] The cationic surfactant provides improved fatty substance anionic surfactant gel network stability /, resulting in further improved conditioning benefits comprising non-cationic cleansing phase composition. 清洁相中的阴离子表面活性剂和调理凝胶中的阴离子表面活性剂之间的碳链长度的差异明显改善调理凝胶网络的稳定性,并维持其在洗发剂组合物中的完整性。 Carbon chain length difference between the anionic surfactant and a conditioning gel phase anionic cleaning surfactants significantly improve the stability of the conditioning gel network, and maintains its integrity in the shampoo composition. [0020] 优选地,所述凝胶网络中的阴离子和阳离子表面活性剂包含相差4个、优选相差2 个以内的碳,并最优选相同数目的碳。 [0020] Preferably, the gel network anionic and cationic surfactant comprises a difference of 4, preferably by less than two carbons, and most preferably the same number of carbons. 更优选地,它们包含相差4个以内、更优选相差2个以内并最优选相同长度的单个烷基。 More preferably, they comprise less than 4, more preferably by less than 2 and most preferably individual alkyl groups of the same length. 这有助于维持凝胶网络的稳定性。 This helps to maintain the stability of the gel network. [0021] 优选地,凝胶网状阳离子表面活性剂中的碳以单一烷基存在。 [0021] Preferably, the gel network cationic surfactant is present as a single carbon alkyl group. 更优选凝胶网状阳离子表面活性剂具有16-30个碳。 More preferably gel network cationic surfactant has from 16-30 carbons. [0022] 优选地,所述阳离子表面活性剂具有式N+(R1) (R2) (R3) (R4),其中R1、R2、R3和R4独立地是(C16-C3tl)烷基或苄基。 [0022] Preferably, the cationic surfactants have the formula N + (R1) (R2) (R3) (R4), wherein R1, R2, R3 and R4 are independently (C16-C3tl) alkyl or benzyl. [0023] 优选地,R1、R2、R3和R4中的一个、两个或三个独立地为(C16至Cj烷基,R1、R2、R3和R4中的其它一个或多个基团是(C1-C6)烷基或苄基。[0024] 任选地,烷基在烷基链内可包含一个或多个酯(-0C0-或-C00-)和/或醚(-0-) 键。烷基可任选被一个或多个羟基取代。烷基可以是直链或支链,对于具有3个或更多个碳原子的烷基,可以是环状的。烷基可以是饱和的或可包含一个或多个C = C双键(例如, 油基)。烷基在烷基链上可以任选地被一个或多个乙烯氧基乙氧基化。[0025] 用于本发明的调理剂组合物中的适合的阳离子表面活性剂包括十六烷基三甲基氯化铵、二十二烷基三甲基氯化铵、十六烷基氯化吡啶鎗、四甲基氯化铵、四乙基氯化铵、 十八烷基二甲基苄基氯化铵、椰油基三甲基氯化铵、PEG-2-油基甲基氯化铵和它们相应的氢氧化物。其他适合的阳离子表面活性 [0023] Preferably, R1, R2, R3 and R4 are one, two or three independently (C16 to Cj alkyl, R1, R2, R3 and R4 one or more other groups are ( C1-C6) alkyl or benzyl. [0024] optionally, the alkyl groups in the alkyl chain may comprise one or more ester (-0C0- or -C00-) and / or ether (-0-) key the alkyl group may be optionally substituted with one or more hydroxyl groups. the alkyl group may be linear or branched, for the alkyl group having 3 or more carbon atoms, may be cyclic. alkyl groups may be saturated or may comprise one or more C = C double bonds (e.g., oleyl). alkyl may be optionally substituted with one or more ethyleneoxy groups on the alkyl chain ethoxylated. [0025] used in the present invention suitable cationic surfactants in conditioning compositions comprising cetyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, cetyl pyridinium chloride gun, tetramethylammonium chloride ammonium, tetraethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, coco trimethyl ammonium chloride, PEG-2- oleyl ammonium chloride, and their corresponding hydroxide thereof. other suitable cationic surfactants 剂包括以CTFA命名的季铵-5、季铵-31和季铵-18 的那些材料。上述任何材料的混合物也可以是适合的。用于本发明的调理剂的特别有用的阳离子表面活性剂是十六烧基三甲基氯化铵,可商购,例如来自Hoechst Celanese公司的GENAMIN CTAC0用于本发明的调理剂的另一种特别有用的阳离子表面活性剂是二十二烷基三甲基氯化铵,可商购,例如来自Clariant的GENAMIN KDMP。[0026] 用于本发明的适合的阳离子表面活性剂种类的另一个例子,单独使用或与一种或多种其它阳离子调节表面活性剂混合使用,是下述(i)和(ii)的组合:[0027] (i)对应于通式(I)的酰氨基胺:[0028] CTFA designations agents include quaternary ammonium -5, quaternary ammonium and quaternary ammonium -31 -18 those materials. Mixtures of any of the above materials may also be suitable. A particularly useful cationic surfactant for use in conditioners according to the present invention sixteen burning trimethylammonium chloride, available commercially, e.g. another particularly useful cationic surfactant conditioning agents GENAMIN CTAC0 from Hoechst Celanese Corporation of the present invention is trimethyl behenyl ammonium chloride, are commercially available, for example GENAMIN KDMP from Clariant. [0026] another example of a type of cationic surfactants suitable for the present invention, used alone or in combination with one or more other cationic conditioning surfactants agent mixture, is the following (i) and composition (ii) is: [0027] (i) an amidoamine corresponding to the general formula (I) are: [0028]

Figure CN102869334AD00041

[0029] 其中R1是具有10个或更多个碳原子的烃基链,R2和R3独立地选自I至10个碳原子的烃基链,和[0030] m是从I至10的整数;以及[0031] (ii)酸。 [0029] wherein R1 is a hydrocarbyl chain having 10 or more carbon atoms, R2 and R3 are independently selected from hydrocarbyl chains of I to 10 carbon atoms, and [0030] m is an integer from I to 10; and [0031] (ii) an acid. [0032] 如本文所用的,术语烃基链是指烷基链或烯基链。 [0032] As used herein, the term hydrocarbyl chain means an alkyl or alkenyl chain. [0033] 优选的酰氨基胺化合物是那些对应于式(I )的化合物,其中,R1是具有约11至约24个碳原子的烃基,R2和R3各自独立地为烃基残基,优选烷基,具有约I至4个碳原子, m是I至约4的整数。 [0033] Preferred amidoamine compounds are those corresponding to formula (I), wherein, Rl is a hydrocarbyl group having from about 11 to about 24 carbon atoms, R2 and R3 are each independently hydrocarbyl residues, preferably alkyl groups having from about I to 4 carbon atoms, m is an integer from I to about 4. [0034] 优选地,R2和R3是甲基或乙基。 [0034] Preferably, R2 and R3 are methyl or ethyl. [0035] 优选地,m是2或3,即亚乙基或亚丙基。 [0035] Preferably, m is 2 or 3, i.e. an ethylene or propylene group. [0036] 在此所用的优选的酰氨基胺包括硬脂酰胺丙基二甲胺、硬脂酰胺丙基二乙胺、硬脂酰胺乙基二乙胺、硬脂酰胺乙基二甲胺、棕榈酰胺丙基二甲胺、棕榈酰胺丙基二乙胺、棕榈酰胺乙基二乙胺、棕榈酰胺乙基二甲胺、山嵛酰胺丙基二甲胺、山嵛酰胺丙基二乙胺、山嵛酰胺乙基二乙胺、山嵛酰胺乙基二甲胺、花生酰胺丙基二甲胺、花生酰胺丙基二乙胺、花生酰胺乙基二乙胺、花生酰胺乙基二甲胺以及它们的混合物。 [0036] As used herein preferred amines include stearyl amido dimethylamine, diethylamine propyl stearamide, stearamide ethyl diethylamine, dimethylamine ethyl stearamide, palmityl dimethylamine, diethylamine palmitic amide propyl, palmitamide ethyl diethylamine, ethyl dimethylamine palmitic amide, behenic dimethylamine, diethylamine behenic amide propyl, mountain diethylamine ethyl behenate amide, behenic acid amide ethyldimethylamine, peanut dimethylamine, diethylamine amidopropyl peanuts, peanut ethyl diethylamine amide, arachidic acid amide, and their ethyldimethylamine mixture. [0037] 在此有用的特别优选的酰氨基胺是硬脂酰胺丙基二甲胺、硬脂酰胺乙基二乙胺以及它们的混合物。 [0037] In particularly useful herein are preferred amidoamine stearyl dimethylamine, diethylamine-ethyl-stearamide and mixtures thereof. [0038] 在此有用的可商购的酰氨基胺包括:可商购自Inolex(费城,宾夕法尼亚州,美国)的商品名LEXAMINE S-13和可商购自Nikko (东京,日本)的AMIDOAMINE MSP的硬脂酰胺丙基二甲胺,可商购自Nikko的商品名为AMIDOAMINE S的硬脂酰胺乙基二乙胺,可商购自Croda(北亨伯赛德郡,英国)的商品名为INCROMINE BB的山嵛酰胺丙基二甲胺以及可商购自Scher (克利夫顿,新泽西州,美国)的商品名为SCHERCODINE的各种酰氨基胺。 [0038] In this useful commercially available amidoamines include: commercially available from Inolex (Philadelphia, PA, USA) under the trade name LEXAMINE S-13 and commercially available from Nikko (Tokyo, Japan) is AMIDOAMINE MSP stearyl dimethylamine, commercially available from Nikko under the tradename AMIDOAMINE S stearamide ethyl diethylamine, commercially available from Croda (North Humberside, England) under the trade name INCROMINE BB behenic dimethylamine and various amidoamines are commercially available from Scher (Clifton, NJ, USA) under the trade name of SCHERCODINE. [0039] 酸(ii)可以是任何能够使头发处理组合物中的酰氨基胺质子化的有机酸或无机酸。 [0039] Acid (ii) may be any hair treatment composition capable of protonating the amidoamine of organic or inorganic acids. 本文中可用的合适的酸包括盐酸、乙酸、酒石酸、富马酸、乳酸、苹果酸、琥珀酸以及它们的混合物。 Suitable acids useful herein include hydrochloric acid, acetic acid, tartaric acid, fumaric acid, lactic acid, malic acid, succinic acid, and mixtures thereof. 优选地,所述酸选自乙酸、酒石酸、盐酸、富马酸以及它们的混合物。 Preferably, the acid is selected from acetic acid, tartaric acid, hydrochloric acid, fumaric acid, and mixtures thereof. [0040] 酸的首要作用是质子化头发处理组合物中的酰氨基胺,从而在头发处理组合物中原位形成叔胺盐(TAS)。 [0040] The primary role of the acid is to protonate the hair treatment composition of the amidoamine, thereby forming a tertiary amine salt in situ (TAS) in the hair treatment composition. 有效的TAS是非永久性的季铵或伪季铵阳离子表面活性剂。 TAS is an effective non-permanent quaternary ammonium or pseudo-quaternary ammonium cationic surfactant. [0041] 适宜的是,包含足量的酸以使存在的所有酰胺基胺质子化,即至少是与组合物中存在的酰胺基胺的量至少等摩尔的水平。 [0041] Suitably, the acid comprises a sufficient amount so that all the amidoamine present in the protonated, i.e. at least the amount of amidoamine present in the composition like at least a horizontal mole. [0042] 阳离子表面活性剂的水平基于组合物的总重量,以阳离子表面活性剂的总重量计,一般是O. 01到10%,更优选为O. 02至7. 5%,最优选的是O. 05至5%的范围。 [0042] The level of cationic surfactant based on the total weight of the composition, based on the total weight of the cationic surfactant, typically O. 01 to 10%, more preferably 7. The O. 02 to 5%, most preferably It is O. range of 05 to 5%. [0043] 凝胶网络的阴离子表面活性剂包含具有16-30个碳,优选16-22个碳的烷基链。 [0043] The gel network anionic surfactant comprising a 16-30 carbons, preferably 16-22 carbons in the alkyl chain. [0044] 优选地,所述阴离子表面活性剂是硫酸盐或磺酸盐,更优选硫酸盐,最优选鲸蜡基硬脂基硫酸纳。 [0044] Preferably, the anionic surfactant is a sulfate or sulfonate, and more preferably sulfate, most preferably sodium cetyl stearyl sulfate. [0045] 优选地,凝胶网络阴离子表面活性剂中的碳是以单一烷基存在。 [0045] Preferably, the gel network anionic surfactant is a single alkyl group in the presence of carbon. [0046] 凝胶网络包含阴离子表面活性剂,用于使凝胶网络获得整体阴离子电荷,或者使凝胶网络整体不带电荷。 [0046] The gel network comprises an anionic surfactant, used to obtain an overall anionic charge to the gel network, the gel network as a whole or uncharged. [0047] 优选地,凝胶网络中的阴离子表面活性剂(b)和凝胶网络中的阳离子表面活性剂(c)之比为6 : I至20 : 1, 最优选9 : I至13 : I。 [0047] Preferably, the ratio of the gel network anionic surfactant (b) and the gel network cationic surfactant (c) is of 6: I to 20: 1, most preferably 9: I to 13: I. [0048] 凝胶网络包含阴离子表面活性剂,用于使凝胶网络获得整体阴离子电荷,或者使凝胶网络整体不带电荷。 [0048] The gel network comprises an anionic surfactant, used to obtain an overall anionic charge to the gel network, the gel network as a whole or uncharged. [0049] 凝胶网状阴离子表面活性剂以O. I至5重量%,更优选O. 5至2. O重量%存在于组合物中。 [0049] The gel network anionic surfactant is O. I to 5 wt%, more preferably from 5 to 2. O O. wt% in the composition. [0050] 优选地,所述脂肪材料选自脂肪酸、脂肪酰胺、脂肪醇、脂肪酯和它们的混合物。 [0050] Preferably, the fatty material selected from fatty acids, fatty amides, fatty alcohols, fatty esters and mixtures thereof. 月旨肪醇是非常优选的。 Month aims fatty alcohols are highly preferred. [0051 ] 优选地,所述脂肪材料包含具有14至30个碳原子,更优选为16至22个的脂肪基。 [0051] Preferably, the fatty material comprises a 14 to 30 carbon atoms, more preferably from 16 to 22 aliphatic groups. 合适的脂肪醇的例子包括鲸蜡醇、硬脂醇以及它们的混合物。 Examples of suitable fatty alcohols include cetyl alcohol, stearyl alcohol, and mixtures thereof. 合适的脂肪酯的例子为单硬脂酸甘油酯。 Examples of suitable fatty ester is glyceryl monostearate. [0052] 本发明的组合物中脂肪材料的含量通常为组合物重量的O. 01至10%,优选O. I至5%。 [0052] The content of the composition of the present invention is typically fatty material weight of the composition O. 01 to 10%, preferably 5% to O. I. [0053] 优选地,凝胶网络中脂肪醇(a)和凝胶网络中阴离子表面活性剂(b)之比为O. I : I到100 : 1,优选1.2 : I到50 : 1,更优选I. 5 : I到10 : 1,最优选约2 : I。 [0053] Preferably, the fatty alcohol gel network (a) and the gel network anionic surfactant ratio (b) of the O. I: I to 100: 1, preferably 1.2: I to 50: 1, more preferably I. 5: I to 10: 1, most preferably from about 2: I. [0054] 优选地,凝胶网络的阴离子和脂肪材料包含相差4个以内,优选相差2个以内的碳的烷基,最优选具有相同的碳数。 [0054] Preferably, the gel network comprising the anionic and fatty materials within 4, preferably by less than two carbons, and most preferably have the same number of carbons. 更优选地,它们包含相差4个以内,更优选相差2个以内碳的单一烷基,最优选具有相同的长度的单一烷基。 More preferably, they comprise less than 4, more preferably by a single group within two carbon atoms, most preferably alkyl groups having the same single length. 这有助于保持凝胶网络的稳定性。 This helps to maintain the stability of the gel network. [0055] 疏水阳离子沉积聚合物[0056] 本发明的组合物包含疏水改性的阳离子沉积聚合物。 [0055] The hydrophobic cationic deposition polymer [0056] The compositions of the present invention comprises a hydrophobically modified cationic deposition polymer. [0057] 优选地,所述疏水改性的阳离子沉积聚合物具有包含14-30个碳的碳链。 [0057] Preferably, the hydrophobically modified cationic deposition polymer having a carbon chain containing 14 to 30 carbons. 优选地, 所述碳链是单烷基链,更优选无支链的。 Preferably, the carbon chain is a single chain alkyl, more preferably unbranched. [0058] 合适的阳离子沉积聚合物可以是均聚物,其可被阳离子取代或可由两种或更多种单体形成。 [0058] Suitable cationic deposition polymers may be homopolymers which are cationically substituted or may be formed from two or more monomers. 聚合物的重均分子量(Mw)通常是在1000至6百万道尔顿,更优选100,000至2 百万道尔顿。 Weight average molecular weight (Mw) is usually 1000 to 6 million daltons, more preferably from 100,000 to 2 million daltons. 该聚合物将具有阳离子含氮基团,如季铵或质子化氨基或它们的混合物。 The polymers will have cationic nitrogen containing groups such as quaternary ammonium or protonated amino groups, or mixtures thereof. 如果聚合物的分子量过低,则调理效果差。 If the molecular weight of the polymer is too low, then the conditioning effect is poor. 如果过高,则可能会出现拉伸粘度高的问题,导致倾倒时组合物的拉丝。 If too high, it may occur problems of high extensional viscosity leading to the drawing of the composition when it is poured. [0059] 阳离子含氮基团一般作为阳离子聚合物的一部分单体单元上的取代基存在。 [0059] The cationic nitrogen-containing group is typically present as a substituent on a portion of the monomer units of the cationic polymer. 因此,当聚合物不是均聚物时,它可以包含间隔的非阳离子单体单元。 Thus, when the polymer is not a homopolymer it can contain spacer non-cationic monomer units is. 这类聚合物在CTFA化妆品成分指南(Cosmetic Ingredient Directory),第3版中描述。 Such polymers in the CTFA Cosmetic Ingredient Directory (Cosmetic Ingredient Directory), 3rd edition described. 选择阳离子与非阳离子单体单元的比例,以赋予聚合物所需范围的阳离子电荷密度,通常为O. l-5meq/gm,更优选O. 2-3. Omeq/gm。 Select cationic to non-cationic monomer units ratio to impart the desired range of cationic charge density polymer, typically O. l-5meq / gm, more preferably O. 2-3. Omeq / gm. 聚合物的阳离子电荷密度可通过凯氏定氮法适当地确定,如在美国药典(US Pharmacopoeia)中描述的氮的化学测定。 The cationic charge density of the polymer can be suitably determined by the Kjeldahl method, of nitrogen chemistry as described in the USP (US Pharmacopoeia) was measured. [0060] 取决于组合物的特定种类和pH,阳离子胺可以是伯、仲或叔胺。 [0060] Depending upon the particular species and the pH of the composition, cationic amines can be primary, secondary or tertiary amines. 一般优选仲胺和叔胺,特别优选叔胺。 Secondary and tertiary amines are generally preferred, particularly preferably a tertiary amine. [0061] 胺取代的乙烯基单体和胺可以以胺形式进行聚合,然后再通过季铵化转化为铵。 [0061] Amine substituted vinyl monomers and amines can be polymerized in the amine form and then converted to ammonium by a quaternary ammonium. [0062] 疏水改性的阳离子聚合物可以包括源自胺-和/或季铵-取代的单体和/或相容的间隔单体的单体单元的混合物。 [0062] The hydrophobically modified cationic polymers derived from amines may include - a mixture of substituted monomer and / or compatible spacer monomers monomer units of - and / or quaternary ammonium. [0063] 用于本发明的疏水阳离子沉积聚合物可通过来自瓜尔胶、槐豆、他拉(tara)胶、 皂荚、肉桂、胡芦巴和凤凰木的疏水改性沉积聚合物而获得。 [0063] The hydrophobic cationic deposition polymers useful in the present invention can be obtained from guar gum, locust bean, tara (Tara) gum, acacia, cassia, fenugreek, and flame tree hydrophobically modified polymer deposition. 其他有用的聚合物可包括黄原胶、结冷胶(gellan gum)、威兰胶(welan gum)、拉姆珊胶(rhamsan gum)、魔芋、甘露聚糖、 阿拉伯树胶、大豆多糖、木果糖胶(xylofructose gum)、多聚葡萄糖(淀粉)和罗望子胶。 Other useful polymers can include xanthan gum, gellan gum (gellan gum), welan gum (welan gum), rhamsan gum (rhamsan gum), konjac, mannan, gum arabic, soy polysaccharide, fructose wood gum (xylofructose gum), polydextrose (starch) and tamarind gum. [0064] 疏水改性的阳离子沉积聚合物和凝胶网络的阴离子表面活性剂包含相差4个、优选相差2个以内的碳、最优选相同数目的碳的烷基。 [0064] The hydrophobically modified cationic deposition polymer and a gel network anionic surfactant comprising four difference, preferably by less than two carbons, and most preferably the same number of carbons. 更优选地,它们包含相差4个以内、更优选相差2个以内、最优选相同长度的单个烷基。 More preferably, they comprise less than 4, more preferably by less than 2, most preferably individual alkyl groups of the same length. 这有助于维持凝胶网络的稳定性并降低对悬浮剂的需要。 This helps to maintain the stability of the gel network and reduce the need for suspending agent. [0065] 类似地,疏水改性的阳离子沉积聚合物和凝胶网络的脂肪物质包含相差4个、优选相差2个以内的碳、最优选相同数目的碳的烷基。 [0065] Similarly, the hydrophobically modified cationic deposition polymer and a fatty substance in the gel network comprising four difference, preferably by less than two carbons, and most preferably the same number of carbons. 更优选地,它们包含相差4个以内、更优选相差2个以内的碳、最优选相同长度的单个烷基。 More preferably, they comprise less than 4, more preferably by less than two carbons, and most preferably individual alkyl groups of the same length. 这有助于维持凝胶网络的稳定性并降低对悬浮剂的需要。 This helps to maintain the stability of the gel network and reduce the need for suspending agent. [0066] 基于组合物的总重量,本发明洗发剂组合物中存在的阳离子聚合物的含量以阳离子聚合物的总重量计通常为0. 01%至5%、优选0. 05%至2%、更优选0. 07%至I. 2%。 [0066] based on the total weight of the composition, the content of cationic polymer in shampoo compositions of the present invention, the total weight of the cationic polymer to the range of usually 0.01 to 5%, preferably 0.05% to 2 %, more preferably from 0.07% to I. 2%. [0067]油[0068] 所述油可以是任何通常用于个人护理产品的油,例如聚烯烃油、酯油、甘油三酯油、烃油及其混合物。 [0067] Oil [0068] The oil may be any oil commonly used in personal care products, such as polyolefin oils, ester oils, triglyceride oils, hydrocarbon oils and mixtures thereof. 优选地,所述油是轻质油。 Preferably, the oil is light oil. [0069] 优选的油包括选自以下的油:[0070]-在30°C下测得的粘度为0. I到500厘泊的油。 [0069] Preferred oils include oils selected from: [0070] - at 30 ° C measured at 0. I to a viscosity of 500 centipoise oil. [0071]-粘度大于500厘泊(500-500000cp)的油,其含有最高20%的较低粘度部分(小于500cp)ο[0072] 所述油可以分散在凝胶网络中或作为清洁相的一部分。 [0071] - Oil viscosity greater than 500 centipoise (500-500000cp), which contain up to 20% of the portion of lower viscosity (less than 500cp) ο [0072] The oil may be dispersed within the gel network, or as a cleaning phase, portion. 如果油在凝胶网络中,将获得改进的稳定性。 If the oil within the gel network, and obtain improved stability. [0073] 如果油在清洁相中,产品可被容易地加工。 [0073] If the oil phase in the cleaning, the product can be easily processed. [0074] 聚a-烯烃油[0075] 优选地,所述油是聚α-烯烃油。 [0074] The poly-a- olefin oil [0075] Preferably, the oil is a poly-α- olefin oil. 如硅油,这些物质可以增加本发明组合物的调理效益。 Such as silicone oils, these materials may increase the conditioning benefits of the compositions of the present invention. 适合的聚α-烯烃油类包括衍生自具有6至16个碳,优选6至12个碳的I-烯烃单体的那些。 Suitable poly-α- olefins include those derived from oils having 6 to 16 carbons, preferably those olefin monomers I- 6 to 12 carbons. 材料的非限制性实例包括I-己烯、I-辛烯、I-癸烯、I-十二碳烯、I-十四碳烯、 I-十六碳烯、支链异构体,如4-甲基-I-戊烯和它们的混合物。 Non-limiting examples of materials include I- hexene, octene, I-, I- decene, I- dodecene, tetradecene I-, I- hexadecene, branched isomers, such as -I- 4-methyl-pentene, and mixtures thereof. [0076] 优选的聚α -烯烃包括可商购自Mobil的数均分子量为约500的Puresyn 6 (商品名),分子量为约3000的Puresyn 100以及分子量为约6000的Puresyn 300的聚癸烯。 [0076] Preferred poly α - olefins include several commercially available from Mobil-average molecular weight of Puresyn. 6 (trade name) of about 500, a molecular weight of Puresyn about 3000. 100 and a molecular weight polydecene to about 6000 Puresyn 300 of. [0077] 优选地,聚α-烯烃油以组合物重量的O. 05至10%,特别是0.2至5%,尤其是O. 5至3%的量存在。 [0077] Preferably, the poly-olefin oil is O. α- weight of the composition 05 to 10%, in particular 0.2 to 5%, especially in the presence of an amount of 5-3% O.. [0078] 甘油三酯油[0079] 适合的是甘油三酯油类,包括脂肪和油类,包括天然脂肪和油类,如霍霍巴油、大豆油、向日葵籽油、米糠油、鳄梨油、杏仁油、橄榄油、芝麻油、蓖麻油、椰子油、椰子棕榈油、 向日葵油、水貂油,可可脂、牛脂、猪油,通过氢化上述油类得到的硬化油,以及合成的单、二和三甘油酯,如肉豆蘧酸甘油酯和2-乙基己酸甘油酯。 [0078] Triglyceride oil [0079] Suitable triglyceride oils include fats and oils including natural fats and oils such as jojoba, soybean oil, sunflower seed oil, rice bran oil, avocado oil , almond oil, olive oil, sesame oil, castor oil, coconut oil, palm oil, coconut oil, sunflower oil, mink oil, cacao butter, beef tallow, lard, oils obtained by hydrogenating the above-described hardened oils, and synthetic mono, di and triglycerides, such as glyceryl myristoyl Qu and 2-ethylhexanoic acid glyceride. [0080] 优选地,所述甘油三酯油以所述组合物重量的O. 05到10%,特别是O. 2到5%,尤其是O. 5到3%存在。 [0080] Preferably, the triglyceride oil is O. The composition of 05-10% by weight, especially O. 2 to 5%, in particular to. 3. 5% by O.. [0081] 藍浊[0082] 适合的烃油具有至少12个碳原子,并包括石蜡油、聚烯烃油、矿物油、饱和的和不饱和的十二烷、饱和的和不饱和的十三烷、饱和的和不饱和的十四烷、饱和的和不饱和的十五烷、饱和的和不饱和的十六烷、以及它们的混合物。 [0081] Blue turbidity [0082] Suitable hydrocarbon oils have at least 12 carbon atoms, and include paraffin oil, polyolefin oil, mineral oil, saturated and unsaturated dodecane, saturated and unsaturated tridecane , saturated and unsaturated tetradecane, saturated and unsaturated pentadecane, saturated and unsaturated hexadecane, and mixtures thereof. 也可以使用这些化合物的支链化的异构体以及较长链的烃。 Isomers may be used, and longer chain branched hydrocarbons of these compounds. 还适合的是C2_6的烯基单体的聚合烃,如聚异丁烯。 Also suitable are polymeric hydrocarbons of alkenyl monomers C2_6, such as polyisobutylene. [0083] 优选地,所述烃油以所述组合物重量的O. 05到10 %,特别是O. 2到5 %,并尤其从O. 5到3%存在。 [0083] Preferably, the hydrocarbon oil is O. The composition by weight of 05-10%, in particular O. 2 to 5%, and in particular, from O. to. 3. 5% by. [0084] 藍浊[0085] 合适的酯油具有至少10个碳原子,且包括具有衍生自脂肪酸或醇的烃基链的酯。 [0084] Blue turbidity [0085] Suitable ester oils have at least 10 carbon atoms, and include those derived from fatty acids or alcohols having a hydrocarbon chain. 典型的酯油是式V C00R,其中R'和R独立表示烷基或烯基,且R'和R的碳原子总数为至少10,优选至少20。 Typical ester oils are formula V C00R, wherein R 'and R independently denote alkyl or alkenyl group, and R' and R total number of carbon atoms is at least 10, preferably at least 20. 也可使用羧酸的二-和三烷基和烯基酯。 Di- carboxylic acids may also be used - and tri-alkyl and alkenyl esters. [0086] 优选地,所述酯油以所述总组合物重量的O. 05到10 %,特别是O. 2到5 %,且尤其是O. 5到3%存在。 [0086] Preferably, the ester oil is O. weight of the total composition of from 05 to 10%, in particular O. 2 to 5%, and especially to. 3. 5% by O.. [0087] 优选地,所述组合物包含清洁阴离子表面活性剂,其包含具有10到14个碳的烷基。 [0087] Preferably, the composition comprises a cleansing anionic surfactant which comprises an alkyl group having 10 to 14 carbons. [0088] 清洁相[0089] 本发明的组合物优选以总组合物的1-26% wt.的含量包含清洁相。 [0088] Cleansing Phase [0089] The compositions of the invention preferably at 1-26 wt% of the total composition. The cleansing phase comprises a content. [0090] 所述清洁相包含清洁表面活性剂。 The [0090] The cleansing phase comprises a cleansing surfactant. 所述清洁相阴离子表面活性剂具有8-14个碳, 更优选10-12个,最优选12个碳。 The cleansing phase anionic surfactant having 8-14 carbons, more preferably 10-12, most preferably 12 carbons. 更优选地,这些碳以单个烷基存在。 More preferably, the carbon is present in a single alkyl group. [0091] 优选阴离子清洁表面活性剂包括碱金属烷基硫酸盐,更优选烷基醚硫酸盐。 [0091] Preferred anionic cleansing surface active agents include alkali metal alkyl sulfates, more preferably an alkyl ether sulfates. 特别优选的阴离子清洁表面活性剂包括月桂基醚硫酸钠。 Particularly preferred anionic cleansing surfactants include sodium lauryl ether sulfate. [0092] 所述清洁表面活性剂的含量为总组合物的5到26重量%。 [0092] The content of cleansing surfactant is from 5 to 26% by weight of the total composition. [0093] 其他组分[0094] 本发明的水性洗发剂组合物可进一步包含悬浮剂,然而,如果所述组合物包含小于O. lwt%的悬浮剂是优选的,优选不含悬浮剂。 [0093] Other ingredients [0094] Aqueous shampoo compositions of the invention may further comprise a suspending agent, however, if the composition comprises less than O. lwt% suspending agents are preferred, preferably free of suspending agents. [0095] 优选地,本发明的头发护理组合物是水性的,即,它们以水或水溶液或易溶(lyotropic)液晶相作为其主要成分。 [0095] Preferably, the hair care compositions of the present invention are aqueous, i.e. water or an aqueous solution thereof or a soluble (Lyotropic) liquid crystalline phase as its main component. [0096] 适宜地,基于所述组合物的总重量,所述组合物包含10到98%,优选30到95%的水。 [0096] Suitably, based on the total weight of the composition, said composition comprising 10 to 98%, preferably 30 to 95% water. [0097] 本发明的组合物优选包含硅氧烷。 The composition of the invention is preferably [0097] This comprises a siloxane. [0098] 特别优选的聚硅氧烷调理剂是硅氧烷乳液,例如由硅氧烷如聚二有机硅氧烷形成的那些,所述聚二有机硅氧烷特别是聚二甲基硅氧烷(其CTFA命名为dimethicone (聚二甲基娃氧烧))、具有轻基端基的聚_■甲基娃氧烧(其CTFA命名为dimethiconol (聚_■甲基硅氧烷醇))和氨基官能聚二甲基硅氧烷(其CTFA命名为amodimethicond氨基封端聚二甲基娃氧烧))。 [0098] Particularly preferred silicone conditioning agents are silicone emulsions such as those, the polydiorganosiloxane formed from silicones such as polydiorganosiloxanes in particular polydimethyl silicone alkyl (which have the CTFA designation dimethicone (dimethicone burning oxygen Wa)), the light having end groups of poly methyl baby _ ■ burning oxygen (which have the CTFA designation Dimethiconol (poly dimethyl siloxane alcohol _ ■)) and amino-functional polydimethyl siloxanes (which have the CTFA designation amodimethicond amino terminated polydimethyl Wa oxygen burning)). [0099] 在本发明的组合物中,乳液液滴的Sauter平均液滴直径(D3,2)范围通常为0. 01到20微米,更优选0. 2到10微米。 [0099] In the compositions of the present invention, the Sauter mean droplet diameter of the emulsion droplets (D3,2) generally range from 0.01 to 20 microns, more preferably from 0.2 to 10 microns. [0100] 用于测定Sauter平均液滴直径(D3,2)的合适方法是使用仪器如马尔文粒度分析仪(Malvern Mastersizer))通过激光散射测定。 Suitable method [0100] for measuring the Sauter mean droplet diameter (D3,2) is the use of instruments such as the Malvern particle size analyzer (Malvern Mastersizer)) measured by laser light scattering. [0101] 用于本发明组合物的合适的硅氧烷乳液可从硅氧烷供应商如Dow Corning和GE Silicones获得。 [0101] Suitable silicone emulsions used in the compositions of the present invention can be obtained from suppliers of silicones such as Dow Corning and GE Silicones. 优选使用这种预形成硅氧烷乳液以便于处理及硅氧烷粒径的控制。 Preferably such pre-formed silicone emulsions used to facilitate processing and control of silicone particle size. 这种预形成硅氧烷乳液通常还包含合适的乳化剂,例如阴离子或非离子乳化剂,或其混合物,且可以通过化学乳化方法(例如乳液聚合)或使用高剪切混合机通过机械乳化制备。 Such pre-formed silicone emulsions will typically additionally comprise a suitable emulsifier such as an anionic or nonionic emulsifier, or mixture thereof, and may be prepared by a chemical emulsification by mechanical emulsification methods (e.g. an emulsion polymerization) or by using high shear mixer . Sauter 平均液滴直径(D3,2)小于0. 15微米的预形成硅氧烷乳液通常称为微乳液。 Pre Sauter mean droplet diameter (D3,2) of less than 0.15 microns to form a silicone emulsion is generally termed microemulsions. [0102] 合适的预形成硅氧烷乳液的例子包括乳液DC2-1766、DC2-1784、DC-1785、 DC-1786、DC-1788 和微乳液DC2-1865 和DC2-1870,都可从Dow Corning 获得。 Examples [0102] Suitable pre-formed silicone emulsions include emulsions DC2-1766, DC2-1784, DC-1785, DC-1786, DC-1788 and microemulsions DC2-1865 and DC2-1870, available from Dow Corning obtain. DC7051 是优选的硅氧烷。 DC7051 is a preferred silicone. 这些都是聚二甲基硅氧烷醇的乳液/微乳液。 These emulsions are dimethicone alcohol / microemulsions. 氨基封端聚二甲基硅氧烷乳液例如DC2-8177 和DC939 (来自Dow Corning)和SME253 (来自GE Silicones)也是合适的。 Amino terminated polydimethylsiloxane emulsions such as DC2-8177 and DC939 (from Dow Corning) and SME253 (from GE Silicones) are also suitable. [0103] 如例如WO 03/094874中所述,还合适的是其中某些类型的高分子量的表面活性嵌段共聚物已经和硅氧烷乳液液滴混合的硅氧烷乳液。 [0103] The example described in WO 03/094874, also suitable are silicone emulsions in which the surface active block copolymers of a high molecular weight and certain types of silicone emulsion droplets have been mixed. 在这种材料中,所述硅氧烷乳液液滴优选由上面描述的聚二有机硅氧烷形成。 In such materials, the silicone emulsion of polydiorganosiloxane droplets are preferably formed from the above description. 表面活性嵌段共聚物的一种优选形式是下式:[0104] HO (CH2CH2O) x (CH (CH3) CH2O) y (CH2CH2O) XH[0105] 其中X的平均值是4或以上,且y的平均值是25或以上。 A preferred form of the surface active block copolymer is of the formula: [0104] HO (CH2CH2O) x (CH (CH3) CH2O) y (CH2CH2O) XH [0105] wherein X is the average of 4 or more, and y an average value of 25 or more. [0106] 表面活性嵌段共聚物的另一种优选形式是下式:(HO (CH2CH2O) a (CH (CH3) CH2O) b) 2-N-CH2-CH2-N ((OCH2CH (CH3)) b (OCH2CH2) a0H) 2[0107] 其中a的平均值是2或以上,b的平均值是6或以上。 [0106] Another preferred form of the surface active block copolymer is of the formula: (HO (CH2CH2O) a (CH (CH3) CH2O) b) 2-N-CH2-CH2-N ((OCH2CH (CH3)) b (OCH2CH2) a0H) 2 [0107] wherein the mean value of a is 2 or more, b is an average value of 6 or more. [0108] 也可以使用上面描述的硅氧烷乳液的任意混合物。 [0108] may also be used any mixture of the above-described silicone emulsions. [0109] 基于本发明组合物的总重量,以上描述的硅氧烷乳液以硅氧烷的总重量计通常以O. 05到15%、优选O. 5到12%的水平存在于本发明组合物中。 [0109] based on the total weight of the composition of the present invention, the above described silicone emulsion to the total weight of the silicone count typically O. 05 to 15% preferably O. 5 to 12% level present in the compositions of the present invention It was. [0110] 所述硅氧烷优选以O. 5到15重量%、更优选I到12重量%存在。 [0110] The silicone is preferably O. 5 to 15% by weight, more preferably from I to 12% by wt. [0111] 任选地,本发明的组合物还可以包含如下所述的成分,以提高性能和/或消费者可接收性。 [0111] Optionally, the compositions of the invention may also comprise ingredients as described below to enhance performance and / or consumer acceptability. [0112] 所述组合物可以包括辅助表面活性剂,以帮助赋予组合物美观、物理或清洁性质。 [0112] The composition can include co-surfactants, to help impart aesthetic composition, physical or cleansing properties. [0113] 辅助表面活性剂的例子是非离子表面活性剂,基于所述组合物的总重量,其可以以O. 5到10%,优选O. 7到6重量%的量存在。 [0113] Examples of co-surfactant is a nonionic surfactant, based on total weight of the composition, which may be O. 5 to 10%, preferably present in an amount by weight% of O. 7 to 6. [0114] 例如,可以包含在本发明洗发剂组合物中的典型的非离子表面活性剂包括脂肪族(C8-C18)伯或伸直链或支链醇或酚类和环氧烷(通常为环氧乙烷且通常具有6到30个环氧乙烷基团)的缩合产物。 Typical nonionic surfactants [0114] for example, may be included in shampoo compositions of the present invention include aliphatic (C8-C18) primary or straight-chain or branched-chain alcohols or phenols with alkylene oxides (usually ethylene oxide and generally having from 6 to 30 ethylene oxide groups) condensation products. [0115] 其他典型的非离子表面活性剂包括单-或二烷基烷醇酰胺。 [0115] Other representative nonionic surfactants include mono - or di-alkyl alkanolamides. 例子包括椰油单-或二乙醇酰胺和椰油单-异丙醇酰胺。 Examples include coco mono - or di-ethanolamide and coco mono - isopropanolamide. 特别优选的非离子表面活性剂是椰油单乙醇酰胺。 Particularly preferred nonionic surfactant is coco mono- ethanolamide. [0116] 可以包含在本发明洗发剂组合物中的另外非离子表面活性剂是烷基多糖苷(APG)。 Further nonionic surfactants [0116] can be included in shampoo compositions of the invention are the alkyl polyglycosides (APG). 通常,所述APG是包含与由一个或多个糖基基团构成的单元(block)(任选地通过桥连基团)连接的烷基的烷基多糖苷。 Typically, the APG is one which comprises an alkyl group and an alkyl unit (block) is composed of one or more glycosyl groups linked (optionally via a bridging group) polyglycoside. 优选的APG由下式定义:[0117] RO-(G)n[0118] 其中R是可以是饱和或不饱和的支链或直链烷基,且G是糖基。 Preferred APG defined by the formula: [0117] RO- (G) n [0118] where R is a saturated or unsaturated, branched or straight chain alkyl group, and G is a saccharide group. [0119] R可以代表约C5到约C2tl的平均烷链长度。 [0119] R may represent a mean alkyl chain length of from about C5 to about C2tl. 优选地,R代表约C8到约C12的平均烷链长度。 Preferably, R represents approximately an average alkyl chain length of C8 to C12 is about. 最优选地,R值为约9. 5到约10. 5。 Most preferably, R is about 9.5 to about 10.5. G可以选自C5或C6单糖残基,优选是糖苷。 G may be selected from C5 or C6 monosaccharide residues, preferably a glucoside. G 可以选自葡萄糖、木糖、乳糖、果糖、甘露糖及其衍生物。 G may be selected from glucose, xylose, lactose, fructose, mannose and derivatives thereof. 优选G是葡萄糖。 Preferably G is glucose. ·[0120] 聚合度η的值可以为约I到约10或更大。 * [0120] The polymerization degree η to a value of about 10 or greater can be about I. 优选地,η值为约I. I到约2。 Preferably, η is about 2 to about I. I. 最优选地,η值为约I. 3到约1.5。 Most preferably, η is about 1.5 to about I. 3. [0121] 用于本发明的合适的烷基多糖苷是可商购的,且包括例如标明为来自S印pic的Oramix NS10、来自Henkel 的Plantaren 1200 和Plantaren 2000 的那些物质。 [0121] Suitable alkyl polyglycosides according to the present invention are commercially available, and include, for example, marked as Oramix NS10 from the S printed pic, Plantaren 1200 from Henkel, and Plantaren 2000 of those materials. [0122] 本发明的组合物中可包含的其他糖衍生的非离子表面活性剂包括Cltl-C18N-烷基(C1-C6)多羟基脂肪酸酰胺,例如C12-C18N-甲基葡糖酰胺,如在例如WO 92 06154和US 5 194 639中描述的,和N-烷氧基多羟基脂肪酸酰胺(例如Cltl-C18N-(3-甲氧基丙基)葡糖酰胺)。 [0122] Other sugar-derived nonionic surfactant composition of the present invention may contain include Cltl-C18N- alkyl (C1-C6) polyhydroxy fatty acid amides, such as C12-C18N- methyl glucamides, as for example, WO 92 06154 and US 5 194 639 is described, and N- alkoxy polyhydroxy fatty acid amides (e.g. Cltl-C18N- (3- methoxypropyl) glucamide). [0123] 辅助表面活性剂的优选的例子是两性或两性离子表面活性剂,其包含量基于组合物的总重量可以为O. 5至大约10%、优选为I至6%重量。 [0123] Preferred examples of co-surfactants are amphoteric or zwitterionic surfactant, which comprises based on the total weight of the composition may be O. 5 to about 10%, preferably I to 6 percent by weight. [0124] 两性或两性离子表面活性剂的例子包括烷基氧化胺、烷基甜菜碱、烷基酰胺丙基甜菜碱、烷基磺基甜菜碱(磺基甜菜碱)、烷基甘氨酸盐、烷基羧基甘氨酸盐、烷基两性乙酸盐、烷基两性丙酸盐、烷基两性甘氨酸盐、烷基酰胺丙基羟基磺基甜菜碱、酰基牛磺酸盐和酰基谷氨酸盐,其中烷基和酰基具有8至19个碳原子。 Examples [0124] amphoteric or zwitterionic surfactants include alkyl amine oxides, alkyl betaines, alkyl amidopropyl betaines, alkyl sulfobetaines (sultaines), alkyl glycinates, alkyl group carboxyglycinates, alkyl amphoacetates, alkyl amphopropionates, alkyl amphoglycinates, alkyl amidopropyl hydroxyl sultaine, acyl taurates and acyl glutamates, wherein the alkyl and acyl groups having from 8 to 19 carbon atoms. 本发明的洗发剂中使用的典型的两性和两性离子表面活性剂包括月桂基氧化胺、椰油基二甲基磺基丙基甜菜碱、月桂基甜菜碱、椰油酰胺丙基甜菜碱和椰油酰两性基乙酸钠。 Typical amphoteric and zwitterionic surfactants for use in shampoos of the invention include lauryl amine oxide, coco dimethyl sulfopropyl betaine, lauryl betaine, cocamidopropyl betaine and cocoamphodiacetate, sodium acetate. [0125] 特别优选的两性或两性离子表面活性剂是椰油酰胺丙基甜菜碱。 [0125] A particularly preferred amphoteric or zwitterionic surfactant is cocamidopropyl betaine. [0126] 任何上述两性或两性离子表面活性剂的混合物也可以是合适的。 [0126] a mixture of any of the foregoing amphoteric or zwitterionic surfactants may also be suitable. 优选的混合物是椰油酰胺丙基甜菜碱与如上所述的其它两性或两性离子表面活性剂的混合物。 Preferred mixtures are those of cocamidopropyl betaine with further amphoteric or zwitterionic surfactants as described above. 优选的其它两性或两性离子表面活性剂是椰油酰两性基乙酸钠。 Other preferred amphoteric or zwitterionic surfactant is sodium acetate cocoamphodiacetate. [0127] 本发明的组合物可以包含用于改善性能和/或消费者接受度的其他成分。 The composition [0127] of the present invention may contain other ingredients for improving the performance and / or consumer acceptance of. 这类成分包括芳香剂、染料和颜料、PH调节剂、珠光剂或遮光剂、粘度调节剂及防腐剂或抗微生物齐U。 Such ingredients include fragrance, dyes and pigments, PH adjusting agents, pearlescent agents or opacifiers, viscosity modifiers, and preservatives or antimicrobials together U. 这些成分的每一种以有效实现其目的的量存在。 Each of these ingredients in an effective amount to achieve its object is present. 一般地,这些任选的成分各自以总组合物重量的最高5%的水平包含在组合物中。 Generally these optional ingredients are each the highest level of 5% of the total weight of the composition contained in the composition. [0128] 通过以下非限制性的实施例进一步说明本发明,其中,除非另有说明,所有提及的百分比是基于总重量以重量计。 [0128] The present invention is further illustrated by the following non-limiting examples in which, unless otherwise stated, all percentages mentioned are by weight based on total weight.

Figure CN102869334AD00101
Figure CN102869334AD00111

Claims (9)

1.调理洗发剂组合物,其包含: i)清洁相,ϋ)调理凝胶网络,其包含脂肪物质、阴离子表面活性剂和阳离子表面活性剂;其中所述调理凝胶网络总体不带电荷或者是阴离子型;iii)油;和iv)疏水改性的阳离子沉积聚合物;其中阳离子沉积聚合物和凝胶网络的阴离子表面活性剂包含彼此相差4个碳以内的烧基。 1. Conditioning shampoo composition comprising: i) a cleansing phase, ϋ) conditioning gel network, comprising a fatty substance, an anionic surfactant and a cationic surfactant; wherein the conditioning gel network overall charge or anionic; iii) an oil; and iv) a hydrophobically modified cationic deposition polymer; wherein the anionic surfactant and a cationic deposition polymer gel network comprising different from each other within the group of four carbon burning.
2.根据权利要求I的组合物,其中所述调理凝胶网络包含选自脂肪醇、脂肪酯、脂肪酸和脂肪酰胺的脂肪物质。 2. The composition according to claim I, wherein the conditioning gel network selected from the group comprising fatty alcohols, fatty esters, fatty acids and fatty acid amide of fatty substances.
3.根据权利要求2的组合物,其中所述脂肪物质是直链或支链的且具有14-30个碳。 3. A composition according to claim 2, wherein the fatty substance is a straight-chain or branched and having 14-30 carbons.
4.根据前述任一项权利要求的组合物,其中所述凝胶网络阴离子表面活性剂具有16-22个碳。 According to any of the preceding composition claims, wherein the gel network anionic surfactant having 16-22 carbons.
5.根据前述任一项权利要求的组合物,其中所述调理凝胶网络包含具有14-30个碳的阳离子表面活性剂。 According to any of the preceding composition claims, wherein the conditioning gel network comprising a cationic surfactant having 14 to 30 carbons.
6.根据前述任一项权利要求所述的组合物,其中所述疏水改性的阳离子沉积聚合物具有14-30个碳的碳链。 6. The composition according to any of the preceding claims, wherein the hydrophobically modified cationic deposition polymer having a carbon chain of 14-30 carbons.
7.根据前述任一项权利要求所述的组合物,其中所述油选自聚α-烯烃油、酯油、甘油三酯油、烃油及其混合物。 7. The composition according to any of the preceding claims, wherein said oil is selected from poly-α- olefin oils, ester oils, triglyceride oils, hydrocarbon oils and mixtures thereof.
8.根据前述任一项权利要求所述的组合物,其中所述油在30°C下在带有转子RV5的布氏粘度计上并以20rpm测定的粘度为O. 1-500厘泊。 8. The composition of any preceding claim, wherein the oil at 30 ° C on a Brookfield viscometer with RV5 rotor and the viscosity was measured 20rpm O. 1-500 centipoise.
9.根据前述任一项权利要求所述的组合物,其还包含硅氧烷。 According to any of the preceding claims composition further comprises a silicone.
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