CN102869334A - Composition - Google Patents
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- CN102869334A CN102869334A CN2011800217268A CN201180021726A CN102869334A CN 102869334 A CN102869334 A CN 102869334A CN 2011800217268 A CN2011800217268 A CN 2011800217268A CN 201180021726 A CN201180021726 A CN 201180021726A CN 102869334 A CN102869334 A CN 102869334A
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- Prior art keywords
- oil
- gel network
- compositions
- carbon
- conditioning
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Abstract
Conditioning shampoo composition comprising: i) a cleansing phase, ii) a conditioning gel network comprising a fatty material; an anionic surfactant and a cationic surfactant; wherein the conditioning gel network has no overall charge or is anionic; iii) an oil; and iv) a hydrophobically modified cationic deposition polymer; in which cationic deposition polymer and the anionic surfactant of the gel network contain alkyl groups with within 4 carbons of each other.
Description
Technical field
The present invention relates to comprise the compositions of oil.
Summary of the invention
In the hair nursing field, need the improved conditioning shampoo composition that comprises oil.Particularly seek the improvement aspect the product stability when temperature raises especially.
Therefore in addition, the present invention also has advantages of does not need the polymerization suspending agent, reduce the preparation cost.
Common pending application application number EP09163568 has described the cleansing phase that comprises 1-26%wt., wherein has been dispersed with the conditioning shampoo composition of conditioning-gel network, polymerization suspending agent and the cationic deposition polymer of oil.
Therefore, the invention provides a kind of conditioning shampoo composition, it comprises:
I) cleansing phase,
Ii) conditioning-gel network, it comprises fatty material, anion surfactant and cationic surfactant; Wherein said conditioning-gel network in general neutral or anionic;
Iii) oil; With
Iv) the cationic deposition polymer of hydrophobically modified;
Wherein the anion surfactant of cationic deposition polymer and gel network comprises and differs each other 4 carbon with interior alkyl.
All viscosity that this description is mentioned are the viscosity of measuring with 20rpm on the Brookfield viscometer of rotor (spindle) RV5 under 30 ℃.
Preferably, described compositions is 2000-7000cPs 30 ℃ of lower viscosity of measuring.
The conditioning-gel network
Described conditioning-gel network comprises:
(a) fatty material;
(b) gel network anion surfactant, it comprises the alkyl with 16-30 carbon;
(c) cationic surfactant;
Wherein said conditioning-gel network in general neutral or anionic.
Described cationic surfactant provides the stability of the improvement of fatty material/anion surfactant gel network, causes also comprising the conditioning benefit of improvement of the compositions of non-cationic cleansing phase.Anion surfactant in the cleansing phase and the obvious difference of the carbon chain lengths between the anion surfactant in the conditioning-gel improve the stability of conditioning-gel network, and keep its integrity in shampoo Compositions.
Preferably, the anion in the described gel network and cationic surfactant comprise and differ 4, preferably differ 2 with interior carbon, and the carbon of similar number most preferably.More preferably, they comprise differ 4 with interior, more preferably differ 2 with single alkyl interior and most preferably equal length.This helps to keep the stability of gel network.
Preferably, the carbon in the gel netted cation surfactant exists with single alkyl.More preferably gel netted cation surfactant has 16-30 carbon.
Preferably, described cationic surfactant has formula N
+(R
1) (R
2) (R
3) (R
4), R wherein
1, R
2, R
3And R
4(C independently
16-C
30) alkyl or benzyl.
Preferably, R
1, R
2, R
3And R
4In one, two or three are (C independently
16To C
30) alkyl, R
1, R
2, R
3And R
4In other one or more groups are (C
1-C
6) alkyl or benzyl.
Randomly, alkyl in alkyl chain, can comprise one or more esters (OCO-or-COO-) and/or ether (O-) key.Alkyl can be chosen wantonly by one or more hydroxyls and replace.Alkyl can be straight or branched, for the alkyl with 3 or more carbon atoms, can be ring-type.Alkyl can be the saturated two keys (for example, oil base) of one or more C=C that maybe can comprise.Alkyl can be randomly by one or more ethyleneoxy ethoxylations on alkyl chain.
The cationic surfactant that is fit to that is used for conditioner composition of the present invention comprises hexadecyltrimethylammonium chloride, INCROQUAT TMC-80 ECONOL TM22, hexadecylpyridinium chloride, tetramethyl ammonium chloride, tetraethylammonium chloride, stearyl dimethyl benzyl ammonium chloride, cocoyl trimethyl ammonium chloride, PEG-2-oil base ammonio methacrylate and their corresponding hydroxide.Other cationic surfactants that are fit to comprise those materials with quaternary ammonium-5, quaternary ammonium-31 and the Quaternium-18 of CTFA name.The mixture of above-mentioned any material also can be fit to.The useful especially cationic surfactant that is used for conditioner of the present invention is hexadecyltrimethylammonium chloride, and is commercially available, for example from the GENAMIN CTAC of Hoechst Celanese company.The another kind of useful especially cationic surfactant that is used for conditioner of the present invention is INCROQUAT TMC-80 ECONOL TM22, and is commercially available, for example from the GENAMIN KDMP of Clariant.
Another example that is used for suitable cationic surfactant kind of the present invention uses separately or mixes use with one or more other cation reconciliation statement surface-active agents, is following (i) and combination (ii):
(i) corresponding to the amidoamines of general formula (I):
R wherein
1The hydrocarbyl chain with 10 or more carbon atoms, R
2And R
3Be independently selected from the hydrocarbyl chain of 1 to 10 carbon atom, and
M is from 1 to 10 integer; And
(ii) acid.
As used herein, the term hydrocarbyl chain refers to alkyl chain or alkenylene chain.
Preferred amidoamines chemical compound be those corresponding to the chemical compound of formula I, wherein, R
1To have approximately 11 to the about alkyl of 24 carbon atoms, R
2And R
3Be hydrocarbyl residue independently of one another, preferred alkyl has approximately 1 to 4 carbon atom, and m is 1 to about 4 integer.
Preferably, R
2And R
3Methyl or ethyl.
Preferably, m is 2 or 3, i.e. ethylidene or propylidene.
Comprise the stearamide propyl dimethylamine in this used preferred amidoamines, the stearamide propyl diethylamine, stearmide ethyl diethylamine, stearmide ethyl dimethylamine, the palmitamide diemethylamine, palmitamide propyl group diethylamine, palmitamide ethyl diethylamine, palmitamide ethyl dimethylamine, mountain Yu amido propyl dimethylamine, mountain Yu amido propyl diethylamine, mountain Yu amide ethyl diethylamine, mountain Yu amide ethyl dimethylamine, Semen arachidis hypogaeae amido propyl dimethylamine, Semen arachidis hypogaeae amido propyl diethylamine, Semen arachidis hypogaeae amide ethyl diethylamine, Semen arachidis hypogaeae amide ethyl dimethylamine and their mixture.
Stearamide propyl dimethylamine, stearmide ethyl diethylamine and their mixture in this useful particularly preferred amidoamines.
Comprise in this useful commercially available amidoamines: commercially available from Inolex (Philadelphia, Pennsylvania, the U.S.) trade name LEXAMINE S-13 and commercially available from Nikko (Tokyo, Japan) the stearamide propyl dimethylamine of AMIDOAMINE MSP, the commercially available stearmide ethyl diethylamine that is called AMIDOAMINE S from the commodity of Nikko, commercially available from Croda (northern Humberside, Britain) the mountain Yu amido propyl dimethylamine of commodity INCROMINE BB by name and commercially available from Scher (Clifton, New Jersey, U.S.) the various amidoamines of commodity SCHERCODINE by name.
Acid (ii) can be any protonated organic acid or mineral acid of amidoamines that can make in the hair-treatment composition.Available suitable acid herein comprises hydrochloric acid, acetic acid, tartaric acid, fumaric acid, lactic acid, malic acid, succinic acid and their mixture.Preferably, described acid is selected from acetic acid, tartaric acid, hydrochloric acid, fumaric acid and their mixture.
The primary effect of acid is the amidoamines in the protonated hair-treatment composition, thereby forms tertiary ammonium salt (TAS) at the hair-treatment composition situ.Effectively TAS is volatile quaternary ammonium or pseudo-quaternary ammonium cation surfactant.
Suitable is, comprises the acid of capacity so that all amido amine that exist are protonated, namely be at least with compositions in the equimolar at least level of amount of the amido amine that exists.
The level of cationic surfactant in the gross weight of cationic surfactant, generally is 0.01 to 10% based on the gross weight of compositions, more preferably 0.02 to 7.5%, and 0.05 to 5% scope most preferably.
The anion surfactant of gel network comprises and has 16-30 carbon, the alkyl chain of preferred 16-22 carbon.
Preferably, described anion surfactant is sulfate or sulfonate, more preferably sulfate, most preferably cetostearyl sodium sulfate.
Preferably, the carbon in the gel network anion surfactant is to exist with single alkyl.
Gel network comprises anion surfactant, is used for making gel network obtain whole anionic charge, perhaps makes the whole neutral of gel network.
Preferably, the ratio of the cationic surfactant (c) in the anion surfactant in the gel network (b) and the gel network is 6: 1 to 20: 1, most preferably 9: 1 to 13: 1.
Gel network comprises anion surfactant, is used for making gel network obtain whole anionic charge, perhaps makes the whole neutral of gel network.
The netted anion surfactant of gel is with 0.1 to 5 % by weight, and more preferably 0.5 to 2.0 % by weight is present in the compositions.
Preferably, described fat material is selected from fatty acid, fatty acid amide, aliphatic alcohol, fatty ester and their mixture.Aliphatic alcohol is very preferred.
Preferably, described fat material comprises and has 14 to 30 carbon atoms, more preferably 16 to 22 fat-based.The example of suitable aliphatic alcohol comprises spermol, stearyl alcohol and their mixture.The example of suitable fatty ester is glyceryl monostearate.
The content of fat material is generally 0.01 to 10% of composition weight in the compositions of the present invention, and preferred 0.1 to 5%.
Preferably, the ratio of anion surfactant (b) is 0.1: 1 to 100: 1 in aliphatic alcohol in the gel network (a) and the gel network, preferred 1.2: 1 to 50: 1, and more preferably 1.5: 1 to 10: 1, most preferably from about 2: 1.
Preferably, the anion of gel network and fat material comprise and differ in 4, preferably differ 2 with the alkyl of interior carbon, most preferably have identical carbon number.More preferably, they comprise and differ in 4, more preferably differ 2 with the single alkyl of interior carbon, most preferably have the single alkyl of identical length.This helps to keep the stability of gel network.
The dewatering cationic deposited polymer
Compositions of the present invention comprises the cationic deposition polymer of hydrophobically modified.
Preferably, the cationic deposition polymer of described hydrophobically modified has the carbochain that comprises 14-30 carbon.Preferably, described carbochain is the monoalkyl chain, and is more preferably unbranched.
Suitable cationic deposition polymer can be homopolymer, and it can be replaced by cation or can be formed by two or more monomers.The weight average molecular weight of polymer (Mw) is normally at 1000 to 6 megadaltons, more preferably 100,000 to 2 megadaltons.This polymer will have the cation nitrogen-containing group, such as quaternary ammonium or protonated amino or their mixture.If the molecular weight of polymer is excessively low, then conditioning effect is poor.If too high, the wire drawing of compositions when causing toppling over the high problem of tensile viscosity then may appear.
The cation nitrogen-containing group generally exists as the substituent group on a part of monomeric unit of cationic polymer.Therefore, when polymer was not homopolymer, it can comprise the non-cationic monomeric unit at interval.This base polymer is at CTFA cosmetic composition guide (Cosmetic Ingredient Directory), describes in the 3rd edition.Select the ratio of cation and non-cationic monomeric unit, to give the cationic charge density of the required scope of polymer, be generally 0.1-5meq/gm, more preferably 0.2-3.0meq/gm.The cationic charge density of polymer can suitably be determined by Kjeldahls method, such as the chemical assay of the nitrogen of description in American Pharmacopeia (US Pharmacopoeia).
The particular types and the pH that depend on compositions, cationic amine can be primary, the second month in a season or tertiary amine.General preferred secondary amine and tertiary amine, particularly preferably tertiary amine.
Vinyl monomer and amine that amine replaces can carry out polymerization with the amine form, and then by the quaternized ammonium that is converted into.
The cationic polymer of hydrophobically modified can comprise and is derived from amine-and/or the mixture of the monomeric unit of the monomer of quaternary ammonium-replacement and/or compatible spacer monomers.
Be used for dewatering cationic deposited polymer of the present invention can by from guar gum, Semen sophorae, he draws the hydrophobically modified deposited polymer of (tara) glue, Fructus Gleditsia, Cortex Cinnamomi, Semen Trigonellae and Ramulus et Folium Delonicis regiae to obtain.Other useful polymer can comprise xanthan gum, gellan gum (gellan gum), Weilan gum (welan gum), La Mushan glue (rhamsan gum), Rhizoma amorphophalli, mannan, Radix Acaciae senegalis, soybean polysaccharide, wooden fructan (xylofructose gum), polyglucose (starch) and tamarind gum.
The cationic deposition polymer of hydrophobically modified and the anion surfactant of gel network comprise and differ 4, preferably differ 2 with interior carbon, the alkyl of the carbon of similar number most preferably.More preferably, they comprise differ 4 with interior, more preferably differ 2 with single alkyl interior, most preferably equal length.This helps to keep the stable and reduction of gel network to the needs of suspending agent.
Similarly, the fatty material of the cationic deposition polymer of hydrophobically modified and gel network comprises and differs 4, preferably differs 2 with interior carbon, the alkyl of the carbon of similar number most preferably.More preferably, they comprise differ 4 with interior, more preferably differ 2 with interior carbon, the single alkyl of equal length most preferably.This helps to keep the stable and reduction of gel network to the needs of suspending agent.
Based on the gross weight of compositions, the content of the cationic polymer that exists in the shampoo Compositions of the present invention is generally 0.01% to 5%, preferred 0.05% to 2%, more preferably 0.07% to 1.2% in the gross weight of cationic polymer.
Oil
Described oil can be any personal care product's of being generally used for oil, for example polyolefin oil, ester oil, triglyceride oil, hydrocarbon ils and composition thereof.Preferably, described oil is light oil.
Preferred oil comprises and is selected from following oil:
-the viscosity that records under 30 ℃ is the oil of 0.1 to 500 centipoise.
-viscosity is greater than the oil of 500 centipoises (500-500000cp), its contain the highest 20% than low viscosity part (less than 500cp).
Described oil can be dispersed in the gel network or as the part of cleansing phase.In gel network, will obtain improved stability such as fruit oil.
In cleansing phase, product can easily be processed such as fruit oil.
Poly ﹠ Alpha ,-olefin oil
Preferably, described oil is poly ﹠ Alpha ,-olefin oil.Such as silicone oil, these materials can increase the conditioning benefit of the present composition.The poly alpha olefin oils that is fit to comprises derived from having 6 to 16 carbon, those of the 1-olefinic monomer of preferred 6 to 12 carbon.The limiting examples of material comprises 1-hexene, 1-octene, 1-decene, 1-dodecylene, tetradecene, cetene, branched chain isomer, such as 4-methyl-1-pentene and their mixture.
Preferred poly alpha olefin comprises that commercially available number-average molecular weight from Mobil is about 500 Puresyn 6 (trade name), and molecular weight is that approximately 3000 Puresyn 100 and molecular weight are the about poly decene of 6000 Puresyn 300.
Preferably, poly ﹠ Alpha ,-olefin oil is with 0.05 to 10% of composition weight, and particularly 0.2 to 5%, especially 0.5 to 3% amount exists.
Triglyceride oil
What be fit to is triglyceride oils, comprise fat and oils, comprise natural fat and oils, such as Jojoba oil, soybean oil, sunflower seed oil, Testa oryzae oil, American Avocado Tree oil, almond oil, olive oil, Oleum sesami, Oleum Ricini, Oleum Cocois, Cortex cocois radicis Petiolus Trachycarpi oil, Oleum helianthi, mink oil, cocoa butter, Adeps Bovis seu Bubali, Adeps Sus domestica, the fixed oil that obtains by the above-mentioned oils of hydrogenation, and synthetic single, two and triglyceride, such as myristin and 2 ethyl hexanoic acid glyceride.
Preferably, described triglyceride oil is with 0.05 to 10% of described composition weight, and particularly 0.2 to 5%, especially 0.5 to 3% exists.
Hydrocarbon ils
The hydrocarbon ils that is fit to has at least 12 carbon atoms, and comprises paraffin oil, polyolefin oil, mineral oil, saturated and undersaturated dodecane, saturated and undersaturated tridecane, saturated and the undersaturated tetradecane, saturated and undersaturated pentadecane, saturated and undersaturated hexadecane and their mixture.Also can use these chemical compounds collateralization isomer and than the hydrocarbon of long-chain.That also be fit to is C
2-6The polymeric hydrocarbon of alkenyl monomer, such as polyisobutylene.
Preferably, described hydrocarbon ils is with 0.05 to 10% of described composition weight, and particularly 0.2 to 5%, and especially from 0.5 to 3% exist.
Ester oil
Suitable ester oil has at least 10 carbon atoms, and comprises the ester that has derived from the hydrocarbyl chain of fatty acid or alcohol.Typical ester oil is formula R ' COOR, and wherein R ' and R independently represent alkyl or alkenyl, and the total number of carbon atoms of R ' and R is at least 10, preferably at least 20.Also can use two of carboxylic acid-and trialkyl and alkenyl esters.
Preferably, described ester oil is with 0.05 to 10% of described total composition weight, and particularly 0.2 to 5%, and especially 0.5 to 3% exist.
Preferably, described compositions comprises the cleaning anion surfactant, and it comprises the alkyl with 10 to 14 carbon.
Cleansing phase
Compositions of the present invention preferably comprises cleansing phase with the content of the 1-26%wt. of total composition.
Described cleansing phase comprises cleansing surfactants.Described cleansing phase anion surfactant has 8-14 carbon, and more preferably 10-12 is individual, most preferably 12 carbon.More preferably, these carbon exist with single alkyl.
The preferred anionic cleansing surfactants comprises alkali metal alkyl sulfate, more preferably alkyl ether sulfate.Particularly preferred anion cleansing surfactants comprises sodium laureth sulfate.
The content of described cleansing surfactants is 5 to 26 % by weight of total composition.
Other components
Aqueous shampoo Compositions of the present invention can further comprise suspending agent, yet, if the suspending agent that described compositions comprises less than 0.1wt% is preferred, preferred suspending agent-containing not.
Preferably, hair care composition of the present invention is aqueous, that is, they with water or aqueous solution or easily molten (lyotropic) liquid crystalline phase as its main component.
Aptly, based on the gross weight of described compositions, described compositions comprises 10 to 98%, preferred 30 to 95% water.
Compositions of the present invention preferably comprises siloxanes.
Particularly preferred polysiloxanes conditioner is silicone emulsion, those that are for example formed by siloxanes such as polydiorganosiloxanepolyurea, described polydiorganosiloxanepolyurea is polydimethylsiloxane (its CTFA called after dimethicone (polydimethylsiloxane)), the polydimethylsiloxane (its CTFA called after dimethiconol (dimethiconol)) with hydroxyl end groups and amino-functional polydimethylsiloxane (its CTFA called after amodimethicone (amino-terminated polydimethylsiloxane)) particularly.
In compositions of the present invention, the Sauter average droplet size (D of emulsion droplet
3,2) scope is generally 0.01 to 20 micron, more preferably 0.2 to 10 micron.
Be used for measuring Sauter average droplet size (D
3,2) appropriate method be to use instrument such as Ma Erwen Particle Size Analyzer (Malvern Mastersizer)) pass through determination of laser light scattering.
The suitable silicone emulsion that is used for the present composition can be from siloxanes supplier such as Dow Corning and GE Silicones acquisition.Preferred this pre-formed silicone emulsion of use is so that the control of processing and siloxanes particle diameter.This pre-formed silicone emulsion also comprises suitable emulsifying agent usually, for example anion or nonionic emulsifier, or its mixture, and can or use high shear mixer prepare by machinery emulsification by chemical emulsification method (for example emulsion polymerisation).Sauter average droplet size (D
3,2) be commonly referred to microemulsion less than 0.15 micron pre-formed silicone emulsion.
The example of suitable pre-formed silicone emulsion comprises emulsion DC2-1766, DC2-1784, DC-1785, DC-1786, DC-1788 and microemulsion DC2-1865 and DC2-1870, all can obtain from Dow Corning.DC7051 is preferred siloxanes.These all are the emulsion/microemulsions of dimethiconol.Amino-terminated aqueous emulsion of dimethyl polysiloxane fluid for example DC2-8177 and DC939 (from Dow Corning) and SME253 (from GE Silicones) also is suitable.
Described in for example WO 03/094874, also suitable be wherein some type high molecular the surface activity block copolymer with the silicone emulsion of silicone emulsion droplets mixing.In this material, described silicone emulsion drop is preferably formed by above-described polydiorganosiloxanepolyurea.A kind of preferred form of surface activity block copolymer is following formula:
HO(CH
2CH
2O)
x(CH(CH
3)CH
2O)
y(CH
2CH
2O)
xH
Wherein the meansigma methods of x be 4 or more than, and the meansigma methods of y be 25 or more than.
The another kind of preferred form of surface activity block copolymer is following formula: (HO (CH
2CH
2O)
a(CH (CH
3) CH
2O)
b)
2-N-CH
2-CH
2-N ((OCH
2CH (CH
3))
b(OCH
2CH
2)
aOH)
2
Wherein the meansigma methods of a be 2 or more than, the meansigma methods of b be 6 or more than.
Also can use any mixture of above-described silicone emulsion.
Based on the gross weight of the present composition, silicone emulsion described above in the gross weight of siloxanes usually with 0.05 to 15%, preferred 0.5 to 12% level is present in the present composition.
Described siloxanes is preferably with 0.5 to 15 % by weight, more preferably 1 to 12 % by weight exists.
Randomly, compositions of the present invention can also comprise composition as described below, but to improve performance and/or consumer's acceptance.
Described compositions can comprise cosurfactant, and compositions is attractive in appearance to help to give, physics or cleaning properties.
The example of cosurfactant is non-ionic surface active agent, and based on the gross weight of described compositions, it can be with 0.5 to 10%, and the amount of preferred 0.7 to 6 % by weight exists.
The typical ionic surfactant pack that for example, can be included in the shampoo Compositions of the present invention is drawn together aliphatic (C
8-C
18) uncle or the condensation product of extended chain or branched-chain alcoho or phenols and alkylene oxide (be generally oxirane and usually have 6 to 30 ethylene oxide groups).
That other typical ionic surfactant pack are drawn together is single-or the dialkyl group alkanolamide.Example comprise cocos nucifera oil single-or diglycollic amide and cocos nucifera oil list-isopropanol amide.Particularly preferred non-ionic surface active agent is coconut monoethanol amide.
The other non-ionic surface active agent that can be included in the shampoo Compositions of the present invention is APG (APG).Usually, described APG is the APG that comprises the alkyl that is connected with the unit that is made of one or more glycosyl groups (block) (randomly passing through bridged group).Preferred APG is defined by following formula:
RO-(G)
n
Wherein R is can be saturated or undersaturated branched-chain or straight-chain alkyl, and G is glycosyl.
R can represent approximately C
5Arrive approximately C
20Average alkyl chain length.Preferably, R represents approximately C
8Arrive approximately C
12Average alkyl chain length.Most preferably, the R value is approximately 9.5 to approximately 10.5.G can be selected from C
5Or C
6Monosaccharide residue, preferably glucosides.G can be selected from glucose, xylose, lactose, fructose, mannose and derivant thereof.Preferred G is glucose.
The value of polymerization degree n can be approximately 1 to approximately 10 or larger.Preferably, the n value is approximately 1.1 to approximately 2.Most preferably, the n value is approximately 1.3 to approximately 1.5.
It is commercially available being used for suitable APG of the present invention, and comprise the Oramix NS10 that for example is marked as from Seppic, from the Plantaren 1200 of Henkel and those materials of Plantaren 2000.
The derivative ionic surfactant pack of other sugar that can comprise in the compositions of the present invention is drawn together C
10-C
18N-alkyl (C
1-C
6) polyhydroxy fatty acid amide, for example C
12-C
18The N-methyl glucose amide, as in for example WO 92 06154 and US 5 194 639, describing, and N-alkoxyl polyhydroxy fatty acid amide (C for example
10-C
18N-(3-methoxy-propyl) glucamide).
The preferred example of cosurfactant is both sexes or zwitterionic surfactant, its packet content based on the gross weight of compositions can for 0.5 to about 10%, be preferably 1 to 6% weight.
The example of both sexes or zwitterionic surfactant comprises alkyl amine oxide, alkyl betaine, alkylamide propyl-betaine, alkyl sulfo betaines (sulfobetaines), alkyl glycinate, alkyl carboxyl glycinate, alkyl both sexes acetate, alkyl both sexes propionate, alkyl both sexes glycinate, alkylamide propyl hydroxyl sulfo betaine, acyl taurine salt and acyl glutamate, and wherein alkyl and acyl group have 8 to 19 carbon atoms.The typical both sexes of using in the shampoo of the present invention and zwitterionic surfactant comprise lauryl amine oxide, cocoyl dimethyl sulfopropyl betaine, lauryl betaine, cocamido propyl betaine and cocos nucifera oil acyl both sexes guanidine-acetic acid sodium.
Particularly preferred both sexes or zwitterionic surfactant are cocamido propyl betaine.
The mixture of any above-mentioned both sexes or zwitterionic surfactant also can be suitable.Preferred mixture is the mixture of cocamido propyl betaine and aforesaid other both sexes or zwitterionic surfactant.Preferred other both sexes or zwitterionic surfactant are cocos nucifera oil acyl both sexes guanidine-acetic acid sodium.
Compositions of the present invention can comprise be used to other compositions that improve performance and/or consumer's acceptance.This constituents comprises aromatic, dyestuff and pigment, pH adjusting agent, pearling agent or opacifier, viscosity modifier and antiseptic or antimicrobial.Each of these compositions exists with the amount of effective its purpose of realization.Usually, these optional compositions are included in the compositions with the highest 5% level of total composition weight separately.
Further specify the present invention by following nonrestrictive embodiment, wherein, except as otherwise noted, all percentage ratios of mentioning are based on gross weight by weight.
Embodiment
Claims (9)
1. conditioning shampoo composition, it comprises:
I) cleansing phase,
Ii) conditioning-gel network, it comprises fatty material, anion surfactant and cationic surfactant; Wherein said conditioning-gel network in general neutral or anionic;
Iii) oil; With
Iv) the cationic deposition polymer of hydrophobically modified;
Wherein the anion surfactant of cationic deposition polymer and gel network comprises and differs each other 4 carbon with interior alkyl.
2. according to claim 1 compositions, wherein said conditioning-gel network comprises the fatty material that is selected from aliphatic alcohol, fatty ester, fatty acid and fatty acid amide.
3. according to claim 2 compositions, wherein said fatty material be straight or branched and have 14-30 carbon.
4. according to the compositions of aforementioned each claim, wherein said gel network anion surfactant has 16-22 carbon.
5. according to the compositions of aforementioned each claim, wherein said conditioning-gel network comprises the cationic surfactant with 14-30 carbon.
6. according to the described compositions of aforementioned each claim, the cationic deposition polymer of wherein said hydrophobically modified has the carbochain of 14-30 carbon.
7. according to the described compositions of aforementioned each claim, wherein said grease separation is from poly ﹠ Alpha ,-olefin oil, ester oil, triglyceride oil, hydrocarbon ils and composition thereof.
8. according to the described compositions of aforementioned each claim, wherein said oil in the viscosity of on the Brookfield viscometer of rotor R V5 and take 20rpm, measuring under 30 ℃ as the 0.1-500 centipoise.
9. according to the described compositions of aforementioned each claim, it also comprises siloxanes.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10161636.5 | 2010-04-30 | ||
| EP10161636 | 2010-04-30 | ||
| PCT/EP2011/056162 WO2011134832A2 (en) | 2010-04-30 | 2011-04-18 | Composition |
Publications (1)
| Publication Number | Publication Date |
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| CN102869334A true CN102869334A (en) | 2013-01-09 |
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| EP (1) | EP2563318A2 (en) |
| JP (1) | JP2013525393A (en) |
| CN (1) | CN102869334A (en) |
| AR (1) | AR081186A1 (en) |
| BR (1) | BR112012027261A2 (en) |
| EA (1) | EA201291134A1 (en) |
| MX (1) | MX2012012688A (en) |
| TW (1) | TW201204398A (en) |
| WO (1) | WO2011134832A2 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014044660A1 (en) * | 2012-09-18 | 2014-03-27 | L'oreal | Cosmetic assembly and cosmetic composition comprising an anionic surfactant, a solid fatty alcohol and a cationic polymer, cosmetic treatment process and conditioning device |
| FR2995529B1 (en) * | 2012-09-18 | 2015-12-25 | Oreal | COSMETIC ASSEMBLY, COSMETIC PROCESSING METHOD AND PACKAGING DEVICE |
| FR2995527B1 (en) * | 2012-09-18 | 2014-11-14 | Oreal | COSMETIC COMPOSITION COMPRISING ANIONIC SURFACTANT, SOLID FATTY ALCOHOL, AMPHOTERIC OR CATIONIC POLYMER, NON-IONIC SURFACTANT AND WATER-SOLUBLE SALT |
| JO3368B1 (en) | 2013-06-04 | 2019-03-13 | Janssen Pharmaceutica Nv | 6,7-DIHYDROPYRAZOLO[1,5-a]PYRAZIN-4(5H)-ONE COMPOUNDS AND THEIR USE AS NEGATIVE ALLOSTERIC MODULATORS OF MGLUR2 RECEPTORS |
| US10912719B2 (en) | 2014-10-20 | 2021-02-09 | The Procter And Gamble Company | Personal care composition and method of making |
| JP7021120B2 (en) * | 2016-06-27 | 2022-02-16 | ザ プロクター アンド ギャンブル カンパニー | Shampoo composition containing gel network |
| US10945935B2 (en) | 2016-06-27 | 2021-03-16 | The Procter And Gamble Company | Shampoo composition containing a gel network |
| WO2019236646A1 (en) | 2018-06-05 | 2019-12-12 | The Procter & Gamble Company | Clear cleansing composition |
| MX2021005464A (en) | 2018-12-14 | 2021-06-18 | Procter & Gamble | Shampoo composition comprising sheet-like microcapsules. |
| US11896689B2 (en) | 2019-06-28 | 2024-02-13 | The Procter & Gamble Company | Method of making a clear personal care comprising microcapsules |
| MX2022008714A (en) | 2020-02-14 | 2022-08-08 | Procter & Gamble | Bottle adapted for storing a liquid composition with an aesthetic design suspended therein. |
| BR112022023902A2 (en) * | 2020-06-19 | 2022-12-27 | Unilever Ip Holdings B V | CONDITIONER COMPOSITION AND METHOD TO INCREASE THE DEPOSITION OF A PARTICULATE BENEFIT AGENT |
| US11633072B2 (en) | 2021-02-12 | 2023-04-25 | The Procter & Gamble Company | Multi-phase shampoo composition with an aesthetic design |
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| WO1999002122A1 (en) * | 1997-07-09 | 1999-01-21 | The Procter & Gamble Company | Hair care composition comprising hydrophobically modified cationic cellulose |
| US20060024256A1 (en) * | 2002-06-04 | 2006-02-02 | Wells Robert L | Shampoo containing a gel network |
| WO2009112420A1 (en) * | 2008-03-14 | 2009-09-17 | Unilever Plc | Conditioning shampoo composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5194639A (en) | 1990-09-28 | 1993-03-16 | The Procter & Gamble Company | Preparation of polyhydroxy fatty acid amides in the presence of solvents |
| CA2092556C (en) | 1990-09-28 | 1997-08-19 | Mark Hsiang-Kuen Mao | Polyhydroxy fatty acid amide surfactants to enhance enzyme performance |
| EP1505949B1 (en) | 2002-05-10 | 2007-02-07 | Unilever Plc | Conditioning shampoo composition |
| US8349302B2 (en) * | 2002-06-04 | 2013-01-08 | The Procter & Gamble Company | Shampoo containing a gel network and a non-guar galactomannan polymer derivative |
-
2011
- 2011-04-18 BR BR112012027261A patent/BR112012027261A2/en not_active IP Right Cessation
- 2011-04-18 CN CN2011800217268A patent/CN102869334A/en active Pending
- 2011-04-18 EA EA201291134A patent/EA201291134A1/en unknown
- 2011-04-18 WO PCT/EP2011/056162 patent/WO2011134832A2/en active Application Filing
- 2011-04-18 EP EP11714583A patent/EP2563318A2/en not_active Withdrawn
- 2011-04-18 MX MX2012012688A patent/MX2012012688A/en not_active Application Discontinuation
- 2011-04-18 JP JP2013506584A patent/JP2013525393A/en not_active Withdrawn
- 2011-04-27 TW TW100114713A patent/TW201204398A/en unknown
- 2011-04-28 AR ARP110101470 patent/AR081186A1/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999002122A1 (en) * | 1997-07-09 | 1999-01-21 | The Procter & Gamble Company | Hair care composition comprising hydrophobically modified cationic cellulose |
| US20060024256A1 (en) * | 2002-06-04 | 2006-02-02 | Wells Robert L | Shampoo containing a gel network |
| CN101267797A (en) * | 2005-09-16 | 2008-09-17 | 宝洁公司 | Shampoo containing a gel network |
| CN101267796A (en) * | 2005-09-16 | 2008-09-17 | 宝洁公司 | Shampoo containing a gel network |
| WO2009112420A1 (en) * | 2008-03-14 | 2009-09-17 | Unilever Plc | Conditioning shampoo composition |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011134832A2 (en) | 2011-11-03 |
| TW201204398A (en) | 2012-02-01 |
| BR112012027261A2 (en) | 2017-07-18 |
| MX2012012688A (en) | 2013-02-26 |
| EP2563318A2 (en) | 2013-03-06 |
| EA201291134A1 (en) | 2013-04-30 |
| WO2011134832A3 (en) | 2012-10-18 |
| AR081186A1 (en) | 2012-07-04 |
| JP2013525393A (en) | 2013-06-20 |
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