CN102863674A - Preparation method of white ABS (acrylonitrile-butadiene-styrene copolymer) functional master batches - Google Patents
Preparation method of white ABS (acrylonitrile-butadiene-styrene copolymer) functional master batches Download PDFInfo
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- CN102863674A CN102863674A CN2012103500522A CN201210350052A CN102863674A CN 102863674 A CN102863674 A CN 102863674A CN 2012103500522 A CN2012103500522 A CN 2012103500522A CN 201210350052 A CN201210350052 A CN 201210350052A CN 102863674 A CN102863674 A CN 102863674A
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Abstract
The invention discloses a preparation method of white ABS (acrylonitrile-butadiene-styrene copolymer) functional master batches and belongs to the technical field of high polymer material preparation. The preparation method includes: firstly, weighing, by weight, 10-20 parts of silicon dioxide, 40-50 parts of titanium dioxide, 2-3 parts of lubricants, 0.3-0.8 part of coupling agents and 10-20 parts of composite resin and feeding the components into a high-speed mixer for mixing for 7-8 minutes; and then transferring the mixture to a twin-screw extruder for melt extrusion with the extrusion temperature controlled at 150-200 DEG C, and performing air cooling so that the white ABS functional master batches are obtained. The white ABS functional master batches have the advantages of easiness in cost control and dispersion, uniform color and difficulty in dust generation.
Description
Technical field
The invention belongs to field of polymer material preparing technology, be specifically related to a kind of preparation method of ABS white functional master batch
Background technology
The problems such as adding man-hour, normal operation toner or Masterbatch are painted, but there is easy diffusion in Masterbatch, pollutes the shortcoming of operating area, is seldom adopted by producer, and colour batch easy color and luster inequality that occurs when painted, and aberration is restive.Therefore, when the ABS material was painted, control color and luster all even aberration needed the as early as possible problem of solution at present.And then, if can make the functional agglomerate of preparing remedy these shortcomings, have so good positive effect
Summary of the invention
Task of the present invention is to provide a kind of preparation method of ABS white functional master batch, and the simple and functional master batch that obtain of the method technique has and is easy to disperse and the uniform characteristics of color and luster.
Task of the present invention is finished like this, a kind of preparation method of ABS white functional master batch, and it is 2 ~ 3 parts of 40 ~ 50 parts of 0 ~ 20 part of silica 1, titanium dioxides, lubricants, 0.3 ~ 0.8 part of the coupling agent that will take by weighing by weight first; With mix 7-8min in 10 ~ 20 parts of input high-speed mixers of compound resin, then be transferred to twin screw extruder and melt extrude, extrusion temperature is controlled to be 150-200 ℃, obtains ABS white functional master batch after air-cooled.
In a specific embodiment of the present invention, described silicon-dioxide is the silicon-dioxide that vapor phase process is produced.
In another specific embodiment of the present invention, described titanium dioxide is anatase thpe white powder.
In another specific embodiment of the present invention, described lubricant is stearic acid.
In another specific embodiment of the present invention, described coupling agent is γ-mercaptopropyl trimethoxysilane.
Also have in the specific embodiment of the present invention, described compound resin is that 80% polyethylene and mass percent are that 20% ABS resin forms by mass percent.
Have cost by the ABS white functional master batch of the inventive method preparation and be easy to control, be easy to disperse, color and luster is the strong point of even difficult generation dust all.
Embodiment
Embodiment 1:
Mix 7-8min in 16 parts of input high-speed mixers of 0.6 part of 2 parts of 40 parts of 20 parts of silicon-dioxide, anatase thpe white powders, stearic acid, the γ-mercaptopropyl trimethoxysilane that the vapor phase process that will take by weighing is by weight first produced and compound resin (mass percent be 80% polyethylene be 20% ABS resin composition with mass percent), then being transferred to twin screw extruder melt extrudes, extrusion temperature is controlled to be 150 ℃, obtains ABS white functional master batch after air-cooled.
Embodiment 2:
Mix 7-8min in 10 parts of input high-speed mixers of 0.3 part of 2.2 parts of 45 parts of 0 part of silica 1, anatase thpe white powders, stearic acid, the γ-mercaptopropyl trimethoxysilane that the vapor phase process that will take by weighing is by weight first produced and compound resin (mass percent be 80% polyethylene be 20% ABS resin composition with mass percent), then being transferred to twin screw extruder melt extrudes, extrusion temperature is controlled to be 200 ℃, obtains ABS white functional master batch after air-cooled.
Embodiment 3:
Mix 7-8min in 20 parts of input high-speed mixers of 0.5 part of 2.6 parts of 42 parts of 5 parts of silica 1s, anatase thpe white powders, stearic acid, the γ-mercaptopropyl trimethoxysilane that the vapor phase process that will take by weighing is by weight first produced and compound resin (mass percent be 80% polyethylene be 20% ABS resin composition with mass percent), then being transferred to twin screw extruder melt extrudes, extrusion temperature is controlled to be 190 ℃, obtains ABS white functional master batch after air-cooled.
Embodiment 4:
Mix 7-8min in 15 parts of input high-speed mixers of 0.8 part of 3 parts of 44 parts of 8 parts of silica 1s, anatase thpe white powders, stearic acid, the γ-mercaptopropyl trimethoxysilane that the vapor phase process that will take by weighing is by weight first produced and compound resin (mass percent be 80% polyethylene be 20% ABS resin composition with mass percent), then being transferred to twin screw extruder melt extrudes, extrusion temperature is controlled to be 180 ℃, obtains ABS white functional master batch after air-cooled
Claims (6)
1.
A kind of preparation method of ABS white functional master batch is characterized in that it is 2 ~ 3 parts of 40 ~ 50 parts of 0 ~ 20 part of silica 1, titanium dioxides, lubricants, 0.3 ~ 0.8 part of the coupling agent that will take by weighing by weight first; With mix 7-8min in 10 ~ 20 parts of input high-speed mixers of compound resin, then be transferred to twin screw extruder and melt extrude, extrusion temperature is controlled to be 150-200 ℃, obtains ABS white functional master batch after air-cooled.
2.
The preparation method of ABS white functional master batch according to claim 1 is characterized in that described silicon-dioxide is the silicon-dioxide that vapor phase process is produced.
3.
The preparation method of ABS white functional master batch according to claim 1 is characterized in that described titanium dioxide is anatase thpe white powder.
4.
The preparation method of ABS white functional master batch according to claim 1 is characterized in that described lubricant is stearic acid.
5.
The preparation method of ABS white functional master batch according to claim 1 is characterized in that described coupling agent is γ-mercaptopropyl trimethoxysilane.
6.
The preparation method of ABS according to claim 1 white functional master batch is characterized in that described compound resin is that 80% polyethylene and mass percent are that 20% ABS resin forms by mass percent
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012103500522A CN102863674A (en) | 2012-09-20 | 2012-09-20 | Preparation method of white ABS (acrylonitrile-butadiene-styrene copolymer) functional master batches |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012103500522A CN102863674A (en) | 2012-09-20 | 2012-09-20 | Preparation method of white ABS (acrylonitrile-butadiene-styrene copolymer) functional master batches |
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| CN102863674A true CN102863674A (en) | 2013-01-09 |
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| CN2012103500522A Pending CN102863674A (en) | 2012-09-20 | 2012-09-20 | Preparation method of white ABS (acrylonitrile-butadiene-styrene copolymer) functional master batches |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141701A (en) * | 2017-06-26 | 2017-09-08 | 成都工业学院 | It is a kind of for ABS based nano composite materials of 3D printing and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995122A (en) * | 2005-12-31 | 2007-07-11 | 攀钢集团攀枝花钢铁研究院 | Nano modified plastic agglomerate dedicated for open-air utensil |
| CN101717554A (en) * | 2009-12-16 | 2010-06-02 | 广东盛恒昌化学工业有限公司 | Plastic profiled bar decorative layer combination material with metal-like natural texture, preparation method and application thereof |
| CN102260401A (en) * | 2011-07-20 | 2011-11-30 | 上海瑞尔实业有限公司 | Method for preparing toughened, reinforced and anti-aging acrylonitrile-butadiene-styrene (ABS) nano composite material |
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2012
- 2012-09-20 CN CN2012103500522A patent/CN102863674A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995122A (en) * | 2005-12-31 | 2007-07-11 | 攀钢集团攀枝花钢铁研究院 | Nano modified plastic agglomerate dedicated for open-air utensil |
| CN101717554A (en) * | 2009-12-16 | 2010-06-02 | 广东盛恒昌化学工业有限公司 | Plastic profiled bar decorative layer combination material with metal-like natural texture, preparation method and application thereof |
| CN102260401A (en) * | 2011-07-20 | 2011-11-30 | 上海瑞尔实业有限公司 | Method for preparing toughened, reinforced and anti-aging acrylonitrile-butadiene-styrene (ABS) nano composite material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107141701A (en) * | 2017-06-26 | 2017-09-08 | 成都工业学院 | It is a kind of for ABS based nano composite materials of 3D printing and preparation method thereof |
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Application publication date: 20130109 |