CN102849983A - Stone paper for lamp decoration and its fabrication method - Google Patents

Stone paper for lamp decoration and its fabrication method Download PDF

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CN102849983A
CN102849983A CN2011101793149A CN201110179314A CN102849983A CN 102849983 A CN102849983 A CN 102849983A CN 2011101793149 A CN2011101793149 A CN 2011101793149A CN 201110179314 A CN201110179314 A CN 201110179314A CN 102849983 A CN102849983 A CN 102849983A
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decorative
paper
stone
stone paper
hollow glass
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CN2011101793149A
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CN102849983B (en
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夏丽蓉
夏开邦
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夏丽蓉
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Abstract

The invention discloses stone paper for lamp decoration and its fabrication method. The stone paper comprises, calculated by weight percentage, hollow glass bead 15-20, metal deactivator 0.5-1.5, antistatic agent 0.5-1.5, lubricant 0.5-1.5, coupling agent 0.5-1.5, fire retardant 0.5-1.5, dispersing agent 0.5-1.5 and polyethylene in balance. The inventive stone paper adopts polyethylene as base material raw material, colorful hollow glass bead as filler, and other processing additives; the fluid obtained after material mixing has good fluidity and processing property, and can increase roller rotation speed, improve production efficiency and save cost while calendering with a calendering machine; and at the same time, the inventive stone paper satisfies material color variety requirement of lamp decoration.

Description

一种灯具装饰石头纸及其制造工艺 A lamp ornamental stone and paper manufacturing process

[0001] [0001]

技术领域 FIELD

[0002] 本发明涉及合成纸技术领域,具体涉及用作灯具装饰材料的石头纸及其制备方法。 [0002] Technical Field The present invention relates to a synthetic paper, and particularly relates to a method for preparing stone paper luminaire as decorative materials.

[0003]背景技术 [0003] BACKGROUND OF THE INVENTION

[0004] 石头纸,就是用无机矿粉或其它填充料为主要原料,加上适量的聚乙烯和胶合剂做成的。 [0004] Stone paper, is to use inorganic mineral powders as main or other filler material, and with the right amount of glue made of polyethylene. 这种纸防水坚固不易燃烧,重要的是不用砍树造纸,非常环保。 This paper waterproof rugged difficult to burn, it is important to not cut down trees and paper, very environmentally friendly.

[0005] 石头纸产品应用领域极其广泛,可应用于一次性生活消耗用品,比如:垃圾袋、购物袋、食品袋、餐盒、台布、雨衣、防尘罩等;也可应用于文化用纸,比如:印刷纸、书写纸、涂布纸等;还可应用于建材装饰,比如:装饰壁纸、灯具装饰纸等。 [0005] Rock paper product applications is extremely broad and can be used one-time life consumables, such as: garbage bags, shopping bags, food bags, lunch boxes, table cloth, raincoat, dust cover and so on; also be applied to cultural paper , for example: printing paper, writing paper, coated paper; decorative building materials can also be applied, for example: decorative wallpaper, decorative lighting paper. 不管是哪一种类的石头纸,其制作工艺中采用的填料为CaCO3, CaSO4,蒙脱土,滑石粉等,使用这些填料使流体的流动性差,加工性能不好,用压延机压延时辊筒的转速不快,生产效率低。 No matter what kind of stone paper filler used in its production process as CaCO3, CaSO4, montmorillonite, talc and the like, the use of these fillers the flow of the fluid is poor, poor processing performance, when used of the calender rolls speed fast, low production efficiency. 此外,作为装饰用途的石头纸,对其外观、色彩提出了更高的要求。 Further, as the stone paper decorative purposes, its appearance, a higher color requirements. 而现有的石头纸的外观色泽单一,无法满足灯具对装饰材料色彩丰富的要求。 The appearance and color of existing single stone paper, unable to meet the demand for decorative lighting rich color material.

[0006]发明内容 [0006] SUMMARY OF THE INVENTION

[0007] 本发明的目的在于克服上述现有技术的不足,提供一种灯具装饰石头纸,其外观色泽丰富,满足灯具对装饰材料的要求。 [0007] The object of the present invention is to overcome the disadvantages of the prior art described above, there is provided a decorative stone paper luminaire, rich color and appearance, to meet the requirements of the decorative lamp materials.

[0008] 为实现上述目的,本发明采用如下技术方案: [0008] To achieve the above object, the present invention adopts the following technical solution:

一种灯具装饰石头纸,由按质量百分比计的以下组分组成: A lamp stone decorative paper, the following components in percentage by mass of the composition:

空心玻璃微珠:15%〜20% Hollow glass microspheres: 15% ~ 20%

金属钝化剂:0. 5%〜I. 5% Metal deactivators:.. 0 5% ~I 5%

防静电剂:0. 5%〜I. 5% Antistatic agent:.. 0 5% ~I 5%

润滑剂:0. 5%〜I. 5% Lubricant:.. 0 5% ~I 5%

偶联剂:0. 5%〜I. 5% Coupling agent:.. 0 5% ~I 5%

阻燃剂:0. 5%〜I. 5% Flame retardants:.. 0 5% ~I 5%

分散剂:0. 5%〜I. 5% Dispersant:.. 0 5% ~I 5%

聚乙烯:余量。 Polyethylene: margin.

[0009] 空心玻璃微珠不同于一般制作石头纸所米用的常用填料,如CaCO3, CaSO4,蒙脱土,滑石粉等,它的主要成分是二氧化硅,也是一种无机物。 [0009] Unlike the production of hollow glass microspheres stone paper used by m common fillers, such as CaCO3, CaSO4, montmorillonite, talc and the like, its main component is silicon dioxide, is also an inorganic material. 空心玻璃微珠是中空的球型体,像滚珠轴承一样。 Hollow glass microspheres are hollow spherical body, like a ball the same. 碳酸钙与塑料结合对流体流动有阻滞作用,而空心玻璃微珠是球形体,就像滚珠轴承一样,能促使流体畅快流动。 Calcium carbonate and plastic combined with fluid flow blocking, and hollow glass beads are spherical bodies, like ball bearings, like, fun can promote fluid flow. 与碳酸钙比较,空心玻璃微珠的单位螺杆转数通过量可以增加10%左右。 Comparison of calcium carbonate, hollow glass microspheres the number of screw revolutions per unit amount may increase by about 10%. 因此,相比现有的CaCO3, CaSO4,蒙脱土,滑石粉等填料,空心玻璃微珠的加工性能好,加工时,压延机辊筒的转速可以增加,相应地提高了生产效率,降低生产成本。 Thus, compared to conventional processing performance CaCO3, CaSO4, montmorillonite, talc and other fillers, hollow glass beads, the processing speed of the calender rolls can be increased, a corresponding increase production efficiency, reduce production cost.

[0010] 此外,空心玻璃微珠是一种透明材料,颜色多样,采用不同颜色的空心玻璃微珠可以制作成各种不同颜色的石头纸。 [0010] In addition, hollow glass beads is a transparent material, various colors, using different colors of hollow glass microspheres may be made into a variety of different colors of stone paper. 如蓝色的空心玻璃微珠在光线的照射下,会呈现蓝色光,而其它颜色的光线就被过滤掉。 The hollow glass microspheres in the blue light irradiation, will show a blue light, while other color light can be filtered out. 如果是两种或两种以上颜色的空心玻璃微珠混合,那么在光线的照射下,呈现的颜色还是相同数量的相同颜色,例如,蓝色的空心玻璃微珠与黄色的空心玻璃微珠混合,那么在光线的照射下,呈现以蓝黄两色为主的多色效果,不会变成绿色。 If hollow glass beads of two or more mixed colors, then the light irradiation, or the color presented by the same number of the same color, e.g., blue mixing hollow glass microspheres and hollow glass microspheres yellow , then in the light irradiation, showing blue and yellow-based multi-color effect, it does not become green. 而白色的空心玻璃微珠在光线的照射下,会呈现五颜六色。 And hollow glass microspheres in the white light irradiation, there will be colorful. 因此,可以根据使用需求,将某一种颜色或几种不同颜色的空心玻璃微珠混合在一起作为填料,制作出不同颜色的石头纸,满足灯具对装饰材料色彩的要求。 Thus, according to needs, by mixing hollow glass microspheres of a certain color or several different colors as the filler together, they produce different colored stone paper, to meet the requirements of the decorative lamp color material.

[0011] 优选地,所述空心玻璃微珠的比重为I. 5〜2. O g/ Cm3,直径为20um40um。 [0011] Preferably, the specific gravity of hollow glass microspheres I. 5~2. O g / Cm3, diameter 20um40um.

[0012] 偶联剂能改善合成树脂与无机填充剂或增强材料界面性能,在加工过程中可降低树脂熔体的粘度,改善填充剂的分散度以提高加工性能,进而使制品获得良好的表面质量及机械热和电能。 [0012] coupling agent can improve the synthetic resin and the inorganic filler or reinforcing material interface properties, the melt viscosity of the resin during processing can be reduced, improving the dispersion of the filler in order to improve processability, and thus the article surface to obtain a good quality and mechanical and thermal energy. 作为优化选择,所述偶联剂为硅酸酯偶联剂、钛酸酯偶联剂、硅烷偶联剂中的一种或两种以上混合。 Selected as an optimization, the coupling agent is a silicon coupling agent, a titanate coupling agent, silane coupling agent or a mixture of two or more.

[0013] 作为优化选择,所述金属钝化剂为N,N' - 二亚水杨基丙二胺。 [0013] As optimization Alternatively, the metal deactivator is N, N '- disalicylidene propylenediamine.

[0014] 润滑剂可以降低摩擦副的摩擦阻力,减缓产品的磨损。 [0014] The lubricant may reduce the frictional resistance of the friction, the wear mitigation products. 润滑剂还能对摩擦副起冷却、清洗和防止污染等作用。 Lubricants can also play the sub friction cooling, cleaning and prevention of contamination effect. 为了改善产品的润滑性能,在产品中添加润滑剂,所述润滑剂优选为硬脂酸镁、微粉硅胶、滑石粉、聚乙二醇、月挂醇硫酸镁中的一种或两种以上混合。 In order to improve the lubrication performance of the product, the product in the lubricant, the lubricant is preferably magnesium stearate, aerosil, talc, polyethylene glycol, alcohol hanging over magnesium month of one or two or more mixed .

[0015] 阻燃剂能赋予聚合物难燃性的功能,延迟或防止塑料尤其是高分子类塑料的燃烧。 [0015] a flame retardant imparting flame retardancy of a functional polymer, in particular delaying or preventing the combustion plastic polymer-based plastic. 因此,在产品中加入阻燃剂,所述阻燃剂优选为氢氧化镁,氢氧化铝,聚磷酸铵,八溴醚,磷酸三苯酯,六溴环十二烷,硼酸锌,十溴二苯乙烷,包覆红磷中的一种或两种以上混合。 Thus, addition of a flame retardant in the product, preferably the flame retardant is magnesium hydroxide, aluminum hydroxide, ammonium polyphosphate, octabromodiphenyl ether, triphenyl phosphate, hexabromocyclododecane alkoxy, zinc borate, decabromodiphenyl diphenylethane, encapsulated red phosphorus or a mixture of two or more.

[0016] 防电静剂能显著降低塑料制品表面电阻,防静电高效持久,与树脂相容性适宜,而且不影响制品的加工和使用性能。 [0016] Anti-static electricity agent can significantly reduce the surface resistance of plastic products, anti-static, durable and efficient, appropriate compatibility with the resin, and does not affect the processing and use properties of the article. 在产品中加入防电静剂,所述防静电剂优选为乙氧基化硬脂酞胺、乙氧基月桂酷胺、甘油-硬脂酸酯、乙氧基化椰子胺中的一种或两种以上混合。 Adding anti-static agents in electrical products, the antistatic agent is preferably phthalocyanine ethoxylated stearyl amine, ethoxylated lauryl amine cool, glycerol - monostearate, ethoxylated cocoamine one kind or mixing two or more.

[0017] 分散剂可以防止固定颗粒的沉降和凝聚,稳定所分散的颜料散体,调整颜料粒子的运动性,具体体现在:提高光泽、提高着色力和遮盖力、改善展色和调色性、防止浮色发花、防止絮凝等方面。 [0017] The dispersant may be fixed to prevent settling and agglomeration of particles, the dispersion stability of the pigment dispersion, the pigment particles of the adjusting movement, embodied in: improved gloss, improved color strength and opacity, improving color development of the toner and prevent flooding and floating, prevent flocculation and so on. 本产品采用具有多种颜色的空心玻璃微珠为填料,加工时添加分散齐U,有利于空心玻璃微珠的着色力。 This product uses hollow glass microspheres having a plurality of colors filler, homogeneous dispersion is added during processing U, the coloring power in favor of hollow glass microspheres. 所述分散剂优先为硬脂酸锌、硬酯酸钙、微晶石蜡、聚乙二醇、三硬酯酸甘油、油酸铣中的一种或两种以上混合。 The dispersant priority zinc stearate, calcium stearate, microcrystalline waxes, polyethylene glycols, glycerol tristearate oleic milling of one or two or more mixed for.

[0018] 本发明的另一目的是提供上述石头纸的制备方法,其包括如下步骤: [0018] Another object of the present invention to provide a method for preparing the above-described stone paper, comprising the steps of:

A、将各组分真空干燥至物料含水量不超过3%。 A, the components of the vacuum dried to a moisture content of not more than 3% of the material. ;

B、将上述物料干燥后送至造粒机中,先在室温下搅拌冷混,然后加热到100°C -IlO0C热混,物料充分混合均勻后造粒; B, and said material to the granulator and dried, first at room temperature for cold mix was stirred, then heated to 100 ° C -IlO0C hot mix, after thorough mixing and uniform granulation;

C、将造粒后的物料送至压延机上压延,压至厚度为O. 2-0. 5mm,得到本发明的灯具装饰石头纸。 C, the granulated material to the calender after the calender, pressed to a thickness of O. 2-0. 5mm, stone decorative lighting paper obtained according to the present invention.

[0019] 本发明的灯具装饰石头纸采用聚乙烯为基材原料,颜色多样的空心玻璃微珠为填料,并添加其它加工助剂,物料混合后流体的流动性好、加工性能好,用压延机压延时可以增加辊筒的转速,提高生产效率,节约成本。 [0019] The decorative lighting paper according to the present invention employs a stone polyethylene base material, various colors of hollow glass microspheres as filler, and other processing aids added, the materials mixed fluid fluidity good, good processability, with calendar when the machine speed can be increased calender roll, improve production efficiency and cost savings. 同时,产品还满足了灯具装饰对材料色彩丰富的需求。 At the same time, the product also satisfies the lighting decoration of colorful material needs.

[0020] [0020]

具体实施方式 Detailed ways

[0021] 下面结合具体实施例子对本发明一种灯具装饰石头纸及其制造工艺作进一步详细说明,实施例中,如无特别说明,组分均为质量百分比。 [0021] connection with the following examples of specific embodiments of the present invention and a lamp decorative stone paper manufacturing process is further described in detail, embodiments, unless otherwise specified, are percent by mass component.

[0022] [0022]

实施例I 配方: Formulation Example I:

比重为I. 5g/ cm3的白色空心玻璃微珠20%,金属钝化剂O. 5%,防静电剂O. 5%,润滑剂 Specific gravity I. 5g / cm3 white 20% hollow glass microspheres, metal deactivators O. 5%, antistatic agent O. 5%, of lubricant

I. 5%,偶联剂O. 5%,阻燃剂O. 5%,分散剂O. 5%,聚乙烯:余量。 I. 5%, the coupling agent O. 5%, the flame retardant O. 5%, dispersant O. 5%, the polyethylene: the balance.

[0023] 其中,白色空心玻璃微珠的直径为20um,金属钝化剂为N,N' - 二亚水杨基丙二胺;防静电剂为乙氧基化硬脂酞胺;润滑剂为硬脂酸镁;偶联剂为硅酸酯偶联剂;阻燃剂为氢氧化镁和氢氧化铝等量混合;分散剂为硬脂酸锌。 [0023] wherein, white diameter of 20um hollow glass microspheres, metal deactivator is N, N '- disalicylidene propylenediamine; antistatic agent is an ethoxylated stearyl amine phthalocyanine; lubricant is magnesium stearate; coupling agent is silicon coupling agents; flame retardant is mixed equal amounts of aluminum hydroxide and magnesium hydroxide; dispersing agent is zinc stearate.

[0024] 制备方法:将配方中的物料真空干燥至物料含水量为2%。 Preparation [0024] Method: The material was dried in vacuo formulation to a moisture content of 2 mass%. ;干燥后的物料送至造粒机中,先在室温下搅拌冷混,然后加热到100°c热混,如此冷混和热混交替进行,直到物料充分混合均匀,然后造粒;将造粒后的物料送至压延机上压延,压至厚度为O. 5mm,得到本发明的灯具装饰石头纸。 ; Dried material to the granulator, stirred first at room temperature for cold mix, then heated to 100 ° c hot mix, cold mix hot mix so alternately, until the material fully mixed, and then pelletized; granulated after rolling the material to the calender, pressed to a thickness of O. 5mm, to give decorative lighting paper according to the present invention rock. 该石头纸在光线的照射下就会呈现五颜六色。 The stones in the light irradiation of the paper will be presented colorful.

[0025] [0025]

实施例2 配方: Formulation Example 2:

比重为2. O g/ cm3的蓝色透明空心玻璃微珠15%,金属钝化剂I. 5%,防静电剂O. 5%,润滑剂O. 5%,偶联剂I. 5%,阻燃剂O. 5%,分散剂I. 5%,聚乙烯:余量。 A specific gravity of 2. O g / cm3 transparent blue 15% hollow glass microspheres, metal deactivators I. 5%, antistatic agent O. 5%, the lubricant O. 5%, the coupling agent I. 5% , flame retardants O. 5%, dispersant I. 5%, the polyethylene: the balance.

[0026] 其中,蓝色透明空心玻璃微珠的直径为40um,金属钝化剂为N,N'- 二亚水杨基丙二胺;防静电剂为乙氧基月桂酷胺;润滑剂为微粉硅胶、滑石粉等量混合;偶联剂为钛酸酯偶联剂;阻燃剂为聚磷酸铵;分散剂为硬酯酸钙。 [0026] wherein the diameter of the blue transparent hollow glass microsphere is 40um, metal deactivator is N, N'- disalicylidene propylenediamine; antistatic agent is an ethoxylated amine lauryl cool; lubricant is Aerosil, mixing equal amounts of talc; coupling agent is a titanate coupling agent; flame retardant is ammonium polyphosphate; dispersing agent is calcium stearate.

[0027] 制备方法:将配方中的物料真空干燥至物料含水量为3%。 Preparation [0027] Method: The material was dried in vacuo formulations to 3% moisture content of materials. ;干燥后的物料送至造粒机中,先在室温下搅拌冷混,然后加热到110°c热混,如此冷混和热混交替进行,直到物料充分混合均匀,然后造粒;将造粒后的物料送至压延机上压延,压至厚度为O. 2mm,得到本发明的灯具装饰蓝色石头纸。 ; Dried material to the granulator, stirred first at room temperature for cold mix, then heated to 110 ° c hot mix, cold mix hot mix so alternately, until the material fully mixed, and then pelletized; granulated after rolling the material to the calender, pressed to a thickness of O. 2mm, the present invention is to obtain decorative lighting paper blue stone. 该石头纸在光线照射下会呈现蓝色。 The stone paper exposed to light would appear blue.

[0028] [0028]

实施例3 配方: Formulation Example 3:

比重为I. 6 g/ cm3的红色空心玻璃微珠16%,金属钝化剂O. 6%,防静电剂O. 7%,润滑剂 Specific gravity I. 6 g / cm3 red 16% hollow glass microspheres, metal deactivators O. 6%, antistatic agent O. 7%, of lubricant

I. 2%,偶联剂O. 8%,阻燃剂O. 6%,分散剂I. 0%,聚乙烯:余量。 I. 2%, coupling O. 8%, the flame retardant O. 6%, dispersant I. 0%, the polyethylene: the balance.

[0029] 其中,红色空心玻璃微珠的直径为30um,金属钝化剂为N,N' - 二亚水杨基丙二胺;防静电剂为甘油-硬脂酸酯;润滑剂为聚乙二醇;偶联剂为硅烷偶联剂;阻燃剂为磷酸三苯酯,六溴环十二烷两种按等量混合;分散剂为三硬酯酸甘油。 [0029] wherein the diameter of the red 30um hollow glass microspheres, metal deactivator is N, N '- disalicylidene propylenediamine; antistatic agent is glycerol - monostearate; polyethylene lubricant is glycols; coupling agent is a silane coupling agent; triphenyl phosphate, hexabromocyclododecane flame retardant is alkoxy by mixing two equal amounts; dispersing agent is glyceryl tristearate. [0030] 制备方法:将配方中的物料真空干燥至物料含水量不超过2. 5%。 Preparation [0030] Method: The formulation of the material was dried in vacuo to a moisture content of not more than 2.5 mass%. ;干燥后的物料送至造粒机中,先在室温下搅拌冷混,然后加热到105°C热混,如此冷混和热混交替进行,直到物料充分混合均匀,然后造粒;将造粒后的物料送至压延机上压延,压至厚度为O. 4mm,得到本发明的灯具装饰红色石头纸。 ; Dried material to the granulator, stirred first at room temperature for cold mix, then heated to 105 ° C hot mix, cold mix hot mix so alternately, until the material fully mixed, and then pelletized; granulated after rolling the material to the calender, pressed to a thickness of O. 4mm, to give a red lamp of the present invention, decorative stone paper. 该石头纸在光线照射下会呈现红色。 The stone paper exposed to light will appear red.

[0031] [0031]

实施例4 配方: Formulation Example 4:

比重为I. 8 g/ cm3的蓝色空心玻璃微珠8%和橙色空心玻璃微珠9%,金属钝化剂O. 7%,防静电剂O. 5%,润滑剂I. 0%,偶联剂O. 9%,阻燃剂O. 7%,分散剂I. 1%,聚乙烯:余量。 Specific gravity I. 8 g / cm3 hollow glass microspheres blue and orange 8% 9% hollow glass microspheres, metal deactivators O. 7%, antistatic agent O. 5%, the lubricant I. 0%, coupling O. 9%, the flame retardant O. 7%, dispersant I. 1%, the polyethylene: the balance.

[0032] 其中,蓝色空心玻璃微珠和橙色空心玻璃微珠的直径为25um,金属钝化剂为N, N'-二亚水杨基丙二胺;防静电剂为乙氧基化椰子胺;润滑剂为聚乙二醇和月挂醇硫酸镁按等量混合;偶联剂为硅酸酯偶联剂和钛酸酯偶联剂按等量混合;阻燃剂为硼酸锌,十溴二苯乙烷,包覆红磷三种按等量混合;分散剂为三硬酯酸甘油和油酸铣按等量混合。 [0032] wherein the diameter of the blue and orange hollow glass microspheres is 25um hollow glass microspheres, metal deactivator is N, N'- disalicylidene propylenediamine; antistatic agent is an ethoxylated coconut amine; and lubricant is polyethylene glycol months hanging over magnesium mixed equal amounts of alcohol; coupling agent is mixed in an equal amount of silica coupling agent and titanate coupling agent; zinc borate as flame retardant, decabromodiphenyl diphenylethane, encapsulated red phosphorus by mixing equal amounts of three kinds; dispersing agent is glyceryl tristearate and milling mixed equal amounts of oleic acid.

[0033] 制备方法:将配方中的物料真空干燥至物料含水量不超过2. 4%。 Preparation [0033] Method: The formulation of the material was dried in vacuo to a moisture content of not more than 2.4 mass%. ;干燥后的物料送至造粒机中,先在室温下搅拌冷混,然后加热到108°C热混,如此冷混和热混交替进行,直到物料充分混合均匀,然后造粒;将造粒后的物料送至压延机上压延,压至厚度为O. 3mm,得到本发明的灯具装饰多色石头纸。 ; Dried material to the granulator, stirred first at room temperature for cold mix, then heated to 108 ° C hot mix, cold mix hot mix so alternately, until the material fully mixed, and then pelletized; granulated after rolling the material to the calender, pressed to a thickness of O. 3mm, the present invention is to obtain a multicolor decorative stone paper luminaire. 主色为蓝色和橙色。 Main color is blue and orange.

[0034] [0034]

实施例5 配方: Formulation Example 5:

比重为2. O g/ cm3的蓝色空心玻璃微珠9%和黄色空心玻璃微珠9%,金属钝化剂O. 5%,防静电剂I. 5%,润滑剂O. 5%,偶联剂O. 5%,阻燃剂I. 5%,分散剂:0. 6%,聚乙烯:余量。 A specific gravity of 2. O g / cm3 hollow glass microspheres blue and yellow 9% 9% hollow glass microspheres, metal deactivators O. 5%, antistatic agent I. 5%, the lubricant O. 5%, coupling O. 5%, the flame retardant I. 5%, dispersant: 06% polyethylene: balance.

[0035] 其中,蓝色空心玻璃微珠和黄色空心玻璃微珠的直径为35um,金属钝化剂为N, N' - 二亚水杨基丙二胺;防静电剂为乙氧基月桂酷胺、甘油-硬脂酸酯、乙氧基化椰子三种按等量混合;润滑剂为月挂醇硫酸镁;偶联剂为硅酸酯偶联剂和硅烷偶联剂按等量混合;阻燃剂为十溴二苯乙烷和包覆红磷按等量混合;分散剂为聚乙二醇、三硬酯酸甘油、油酸铣中三种按等量混合。 [0035] wherein the diameter of the blue and yellow hollow glass microspheres are hollow glass microspheres 35um, metal deactivator is N, N '- disalicylidene propylenediamine; antistatic agent is an ethoxylated lauryl cool amines, glycerol - monostearate, ethoxylated coconut mixed equal amounts of three kinds; linked to an alcohol lubricant is magnesium months; coupling agent is mixed in an equal amount of a silicon coupling agent and a silane coupling agent; decabromodiphenylethane flame retardant and red phosphorus coated by mixing equal amounts; dispersing agent is a polyethylene glycol, glycerol tristearate, oleic acid, of three milling by mixing equal amounts.

[0036] 制备方法:将配方中的物料真空干燥至物料含水量不超过2. 7%。 Preparation [0036] Method: The formulation of the material was dried in vacuo to a moisture content of not more than 2.7 mass%. ;干燥后的物料送至造粒机中,先在室温下搅拌冷混,然后加热到110°c热混,如此冷混和热混交替进行,直到物料充分混合均匀,然后造粒;将造粒后的物料送至压延机上压延,压至厚度为O. 3mm,得到本发明的灯具装饰多色石头纸。 ; Dried material to the granulator, stirred first at room temperature for cold mix, then heated to 110 ° c hot mix, cold mix hot mix so alternately, until the material fully mixed, and then pelletized; granulated after rolling the material to the calender, pressed to a thickness of O. 3mm, the present invention is to obtain a multicolor decorative stone paper luminaire. 以蓝色和黄色为主。 Mainly in blue and yellow.

[0037] [0037]

上述实施例仅为本发明的优选实施方式,不能以此来限定本发明的保护范围,本领域的技术人员在本发明的基础上所做的任何非实质性的变化及替换均属于本发明的保护范围。 The above-described embodiments are only preferred embodiments of the present invention, not intended to limit the scope of the present invention, any insubstantial changes and substitutions skilled in the art on the basis of the present invention is made to belong to the present invention protected range.

Claims (9)

1. ー种灯具装饰石头纸,其特征在干:由按质量百分比计的以下组分组成: 空心玻璃微珠:15%〜20% 金属钝化剂:0. 5%〜I. 5% 防静电剂:0. 5%〜I. 5% 润滑剂:0. 5%〜I. 5% 偶联剂:0. 5%〜I. 5% 阻燃剂:0. 5%〜I. 5% 分散剂:0. 5%〜I. 5% 聚こ烯:余量。 1. Stone paper ー kinds of decorative lamps, characterized in that the dry: the following components in percentage by mass of the composition: hollow glass microspheres: 15% ~20% metal deactivators:.. 0 5% ~I 5% anti static agent:.. 0 5% ~I 5% lubricant:.. 0 5% ~I 5% coupling agent:.. 0 5% ~I 5% flame retardant:.. 0 5% ~I 5% dispersant:.. 0 5% ~I 5% poly-ene ko: balance.
2.如权利要求I所述的灯具装饰石头纸,其特征在于:所述偶联剂为硅酸酯偶联剂、钛酸酷偶联剂、硅烷偶联剂中的ー种或两种以上混合。 2. Decorative stone paper luminaire according to claim I, wherein: the coupling agent is a silicon coupling agent, titanate coupling agent cool, ー or two or more kinds of the silane coupling agent mixing.
3.如权利要求I所述的灯具装饰石头纸,其特征在于:所述金属钝化剂为N,N' - ニ亚水杨基丙ニ胺。 Decorative stone paper lamps I according to claim 2, wherein: the metal deactivator is N, N '- disalicylidene propylene ni ni amine.
4.如权利要求I所述的灯具装饰石头纸,其特征在于:所述润滑剂为硬脂酸镁、微粉硅胶、滑石粉、聚こニ醇、月挂醇硫酸镁中的ー种或两种以上混合。 4. The decorative lighting paper stone according to claim I, wherein: said lubricant is magnesium stearate, aerosil, talc, polyethylene ko ni alcohols, one alcohol ー hanging over magnesium month or two species mixed above.
5.如权利要求I所述的灯具装饰石头纸,其特征在干:所述阻燃剂为氢氧化镁,氢氧化铝,聚磷酸铵,八溴醚,磷酸三苯酯,六溴环十二烷,硼酸锌,十溴ニ苯こ烷,包覆红磷中的ー种或两种以上混合。 Magnesium hydroxide, aluminum hydroxide, ammonium polyphosphate, octabromodiphenyl ether, triphenyl phosphate, the flame retardant is hexabromocyclododecane ten: decorative lamp as claimed in claim I stone paper, characterized in that dry dioxane, zinc borate, decabromodiphenyl ni ko alkyl benzene, or two or more kinds ー encapsulated red phosphorus mixed.
6.如权利要求I所述的灯具装饰石头纸,其特征在于:所述防静电剂为こ氧基化硬脂酞胺、こ氧基月桂酷胺、甘油-硬脂酸酷、こ氧基化椰子胺中的ー种或两种以上混合。 6. Decorative stone paper luminaire according to claim I, wherein: the antistatic agent is Thalidomide ko stearyl group, lauryl group ko cool amines, glycerol - Cool stearate, ko groupー mixing two kinds or more coconut amine.
7.如权利要求I所述的灯具装饰石头纸,其特征在于:所述分散剂为硬脂酸锌、硬酷酸钙、微晶石蜡、聚こニ醇、三硬酯酸甘油、油酸铣中的ー种或两种以上混合。 7. The decorative lighting paper stone according to claim I, wherein: the dispersing agent is zinc stearate, calcium cool, microcrystalline wax, polyethylene ko ni alcohols, glycerol tristearate, oleic acidー mixing two kinds or more of milling.
8.如权利要求I所述的灯具装饰石头纸,其特征在于:所述空心玻璃微珠的比重为I. 5 〜2. O g/ cm3,直径为20um---40um。 8. Decorative stone paper luminaire according to claim I, wherein: the specific gravity of hollow glass microspheres I. 5 ~2 O g / cm3, a diameter of 20um --- 40um.
9. ー种制备权利要求I所述的灯具装饰石头纸的方法,其特征在于包括以下步骤: A、将各组分真空干燥至物料含水量不超过3%。 9. The method of claim ー species prepared decorative lamps I according to the stone sheet, comprising the steps of: A, dried in vacuo to a moisture content of materials the components less than 3%. ; B、将上述物料干燥后送至造粒机中,先在室温下搅拌冷混,然后加热到100°C -IlO0C热混,物料充分混合均勻后造粒; C、将造粒后的物料送至压延机上压延,压至厚度为O. 2-0. 5mm,得到本发明的灯具装饰石头纸。 ; B, the above material was dried in the granulator to the first cold mix stirred at room temperature, then heated to 100 ° C -IlO0C hot mix, after thorough mixing and uniform granulation; C, after the granulated material on the calender to the calender, pressed to a thickness of O. 2-0. 5mm, stone decorative lighting paper obtained according to the present invention.
CN201110179314.9A 2011-06-29 2011-06-29 Stone paper for lamp decoration and its fabrication method CN102849983B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106835850A (en) * 2016-12-30 2017-06-13 芜湖市哈贝纸业有限公司 A kind of anti-mildew packing case paper of shock resistance

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1229719A (en) * 1998-03-25 1999-09-29 香港商龙盟环保纸(集团)有限公司 Mfg. method for environmental protective paper

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1229719A (en) * 1998-03-25 1999-09-29 香港商龙盟环保纸(集团)有限公司 Mfg. method for environmental protective paper

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106835850A (en) * 2016-12-30 2017-06-13 芜湖市哈贝纸业有限公司 A kind of anti-mildew packing case paper of shock resistance

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